交错网格高阶差分算法的改进

利用Taylor公式展开导出了交错网格中可导函数任意次导数的任意偶数阶精度的差分近似式及相应的差分系数,从而改进了常规高精度交错网格有限差分算法中对各个空间导数采用不一致精度的问题。采用推导的交错网格高阶差分算法对一阶弹性波动方程进行数值模拟,得到了精确的数值模拟结果,证明了推导的交错网格高阶差分算法的正确性。     

优化交错网格差分算子的井间地震数值模拟及其频散分析

在井间地震有限差分数值模拟中,用离散化的高阶差分方程近似连续导数的波动方程时,不可避免地会产生数值频散,而数值频散程度则直接影响到地震波数值模拟精度,因此为了得到清晰准确的地震波场记录,必须尽可能地压制数值频散。这里在一阶速度应力弹性波方程的基础上,利用两个约束条件构造拉格朗日函数获取优化差分系数,与泰勒展开差分系数下的交错网格高阶差分模拟结果比较,发现改进的优化交错网格差分算子的高阶差分数值模拟能更有效地压制数值频散,进一步提高交错网格高阶差分数值模拟的精度,为高精度井间地震数据的波场成像、纵横波联合解释等提供可靠依据。     

地震波场的高阶交错网格有限差分模拟

应用高阶交错网格有限差分算法,并加入吸收边界条件和衰减带,对弹性波方程进行模拟,分析了其稳定性和收敛性。通过对各向同性和各向异性介质模型的模拟表明,高阶差分波动方程模拟的网格频散较小、精度较高、效果较好,可为地震勘探及其资料解译提供技术手段。     

基于卷积完全匹配层的旋转交错网格高阶差分法模拟弹性波传播

从一阶速度—应力弹性波方程出发,基于旋转交错网格,推导了时间二阶精度空间2M阶精度的有限差分离散格式。阐述了递归卷积复频移完全匹配层(CPML)边界条件的原理,建立了一阶速度—应力弹性波高阶差分CPML边界条件的递推公式。开展了CPML边界中关键参数m、κ和α的选取实验,通过分析反射误差分布图,选取了CPML边界条件中最优参数。全局反射误差与波场快照都说明,CPML较PML对隐失波具有更优的吸收性能。基于Matlab平台,编写了基于CPML边界的旋转交错网格弹性波正演模拟程序,应用该程序对各向异性介质及随机介质进行了模拟,得到了弹性波正演剖面记录及波场快照,通过对正演剖面记录及波场快照的分析,可以更清楚地了解弹性波在各向异性介质及随机介质的传播特性,指导非均匀介质中地震勘探资料解释。     

交错网格任意阶导数有限差分格式及差分系数推导

交错网格有限差分算法以其高效、精确、实用等优点在地震波数值模拟中得到广泛应用。目前交错网格有限差分的精度已达到时间4阶、空间2N阶;然而在求空间三次导数时,差分格式实际上并未达到所谓的2N阶精度,而是采用了低阶的差分格式及差分系数,这样有利于提高大尺度空间正演时的计算效率;但从计算精度的角度考虑,有必要推导出准确的满足2N阶精度的交错网格有限差分格式及差分系数,以得到更高精度的正演结果。笔者利用Taylor公式展开首次推导出了可导函数任意次导数的任意偶数阶精度的差分近似式及相应的差分系数,从而完善了常规高精度交错网格有限差分算法。采用新推导的交错网格有限差分格式得到的正演波形与解析解进行了对比,证明了新推导的差分格式的正确性,并与常规差分格式的正演波形进行了比较,结果显示,新推导出的交错网格有限差分格式模拟结果稳定性好,精度更高。     

双程声波方程逆时深度偏移

从双程声波方程出发,在交错网格空间中推导了地震波逆时延拓的高阶有限差分算子,依据最佳匹配层(PML)的方程分裂思路,得到了一阶声波方程的PML边界条件及其高阶差分格式,采用零时间成像条件和上行、下行波场互相关成像条件,实现了声波方程的叠后与叠前逆时深度偏移。逆时偏移对sigsbee_2b模型理论数据的偏移成像得到了满意效果。     

含直立裂隙介质的弹性波动方程正演模拟

从具有水平对称轴的横向各向同性（HTI）介质中的弹性波动方程出发,在交错网格空间中采用高阶差分算子对弹性波动方程进行差分离散,得到了HTI介质中地震波正演的高阶有限差分格式,研究并实现了PML吸收边界条件。在此基础上实现了HTI介质中弹性波方程的多波正演。数值算例表明,该方法能够精确模拟弹性波在复杂各向异性介质中的传播过程,得到高精度的正演记录。     

弹性波逆时偏移及其成像条件

从弹性波动方程出发,推导了二维各向同性介质情况下弹性波逆时传播的高阶差分格式,实现了弹性波在数值空间中的逆时延拓。从程函方程出发,采用逆时差分格式求取网格空间中各点的直达波旅行时,以此作为弹性波逆时偏移的成像条件(激发时间成像条件),实现多波多分量资料的逆时偏移。文中给出了几个典型模型的理论记录的偏移结果,数值试验表明,逆时偏移能够使地表接收到的波场准确归位,提高资料处理的精度。     

高阶交错网格有限差分弹性波场模拟的精度分析

交错网格波场数值模拟是目前地震正演中广泛使用的方法,为对比分析不同阶数的差分格式下产生的计算效率和精度差异,重新推导了弹性波方程的4种时间4阶、空间2N阶的差分公式及系数,并计算了他们的稳定性条件。利用这4种差分格式进行弹性波场数值模拟,对比分析了波场快照、合成地震记录及CPU时间。结果表明:时间4阶、空间6+6阶精度的交错网格有限差分方法在进行地震波场数值模拟时具有较高的计算精度和计算效率。      

交错网格地震波场模拟及频散校正策略

交错网格高阶差分解法是地震波场模拟的一种有效方法。较大的时间延拓步长可以提高效率,但可能引起算法不稳定,使模拟无法进行。因此,对于空间网格大小和时间步长的选择要适中。虽然震源子波的主频对模拟精度的影响不大,但适当提高震源子波的主频,可以提高地震波对于薄层的分辨率。FCT方法能够有效地压制数值频散,将FCT方法与交错网格有限差分法相结合,可以提高波场模拟的精度和运算效率。     

Taxonomical and Biogeochemical Investigation of Elements in Holocene Mollusk Shells in the South and Southwestern Marmara Basin, Turkey

Concentrations of some heavy metals and trace elements such as Cr,Ga,Ni,Zn,Mo,Cu, Pb,Yb,Y,Nb,Ti,Sr,Ba,Mn,Sc,Co,V,Zr,Fe,Al,W,Se,Bi,Sb,As,Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated.The distribution of the elements in the shells is categorized into four groups.Of these,concentrations of 12 elements(As,Bi,Cd,Co,Ga,Mo,Nb, Sb,Se,Sc,W and Yb)are below zero [(0.053-0.79)×10~(-6)];concentrations of seven elements(Cr,Ni, Pb,V,Y,Zr and Cu)are(1.0-6.0)×10~(-6);concentrations of four elements(Ti,Mn,Ba and Zn)are 10- 20×10~(-6);and concentrations of five elements(Si,Al,Fe,Mg and Sr)are(47.44-268.11)×10~(-6).The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina(Linné),Pitar-rudis(Poll),Nassarius reticulatus(Linné),Venerupis senescens (Coocconi),Mytilus galloprovincialis(Lamarck),Mytilaster lineatus(Gemelin in Linné)and Chlamys glabra.It was found that,in mollusk taxonomy,the elements have unique values.In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks.In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment.Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment.     

中国煤中的九种金属元素

在煤的加工利用过程中,煤中金属元素进入大气、水体和土壤,以致污染环境,这是人们关心的事。本文将介绍镉、钴、铬、铜、锰、钼、镍、铅、锌等九种元素在我国煤中的分布和赋存情况。     

Selenium and heavy metals content in some Mediterranean soils

The study of metal contents in industrial, agricultural or/and polluted soils compared with natural or unpolluted soils is currently necessary to obtain reference values and to assess soil contamination. Nonetheless, very few works published appear in international journals on elements like Se, Li and Sr in Spanish soils. This study determines the total levels of Se, Li, Sr, As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, Fe, Mn and Ba in 14 natural (unpolluted) soils (Gypsisols, Leptosols, Arenosols and Acrisols), 14 agricultural soils (Anthrosols, Fluvisols and Luvisols), and 4 industrial–urban affected-surface soil horizons (Anthrosols and Fluvisols) of Eastern Spain. The geochemical baseline concentrations (GBC) and reference values (RV) have been established, and the relationships among elements and also between soil properties and elemental concentrations have been analysed. The RV obtained in this study were (mg kg⁻¹): Se 2.68, Li 115, Sr 298, Cd 0.97, Co 35, Cr 217, Cu 46, Ni 50, Pb 137, V 120, Zn 246, Fe 124,472, Mn 2691, and Ba 743. The RV for Se and Li were used as a preliminary approach to assess soil contamination in Spanish soils. The results confirm human impact on Sr, As, Cd, Cr, Cu, Ni, Pb and Zn soil concentrations, but evidence no deviation from natural Se, Li, Co, V, Fe, Mn and Ba concentrations. The results obtained from the statistical analysis reveal significant correlations between some elements and clay and soil organic matter (SOM) contents, indicating that metal concentrations are controlled by soil composition. One particularly interesting finding is the high correlation coefficients obtained between SOM and Se, Cd, Cr, V, Fe, and Mn, and between clay and Cd, Zn, V, Fe and Mn. Once again, these facts confirm the role of SOM and clay minerals in soil functions and that soil is an ecosystem element responsible for maintaining environmental quality.     

Synthesis and Preliminary Characterisation of New Silicate, Phosphate and Titanite Reference Glasses

Eleven synthetic silicate and phosphate glasses were prepared to serve as reference materials for in situ microanalysis of clinopyroxenes, apatite and titanite, and other phosphate and titanite phases. Analytical results using different micro-analytical techniques showed that the glass fragments were homogeneous in major and trace elements down to the micrometre scale. Trace element determinations using inductively coupled plasma-mass spectrometry (ICP-MS), multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS), laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) and secondary ionisation mass spectrometry (SIMS) showed good agreement for most elements (Li, Be, B, Cs, Rb, Ba, Sr, Ga, Pb, U, Th, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Er, Tm, Yb, Lu, Zr, Hf, Ta, Nb) studied and provide provisional recommended values.     

Geological characteristics of the Sizhuang gold deposit in the region of Jiaodong, Shandong Province——A study on tectono-geochemical ore prospecting of ore deposits

Tectono-geochemical samples were systematically collected from 5 drillcores along the No. 304 explora-tion line and at the -310 m level under the pit in the mining area, totalling 705 samples from the metamorphic rocks, granites, altered rocks and orebodies, and were determined for their contents of 20 kinds of elements including Au, Ag, As, Sb, Hg, Cu,,Pb, Zn, Sn, Bi, Mo, Co, Ni, Mn, Cr, V, Ti, Ba, Rb, Sr, etc. By using the Surfer software the geochemical exploration line profile maps for the 20 kinds of elements and the curves for the element geochemical contents of individual ore vein groups were established. In conbination with the geochemical map analytical method and Gregorian’s zoning index calculation method, the vertical, longitudinal and lateral zonation sequences of the elements were ascertained and the geochemical three-dimentional zonation model of the primary halos was estab-lished on the basis of the analysis of metallogenic structures and alteration zonation. Coupled with the results of analysis of the geology and geochemistry data, it may be concluded that the process of alteration of granites in the mining area is also accompanied with the process of gold enrichment and mineralization. With the intensification of alteration of granites from granite →potash feldspathization granite →sericite-quartz alteration granite, seric-ite-quartz rocks →beresitized granite, pyrite sericite-quartz rock, silicified granite →gold ore, the contents of thio-phile ore-forming elements such as Au, Ag, As, Cu, Bi, Mo, Pb, Sb, Hg, and Sn tended to increase. Factor analysis of trace elements indicated: factor F2 (Au, Ag, Cu, Sn, As) represents the element association brought in at the main stage of hydrothermal metallogenesis; factor F4 (Bi, Sb) and factor F5 (Pb, Zn) represent the ore-forming element association supperposed during the late stage of Au-bearing sulfides. By using the Gregorian’s zoning index and map analysis method we have ascertained the primary halo axial zonation sequence (form frontal halo →tail halo): Pb, Zn, Mn, Ba, Sr, Rb, As, Sb, Ag, Cu, Sn, Mo, Au, Bi, Hg, Ti, Cr, V, Ni, and Co. The geochemical anomalies in the mining area display a tendency of lateral plunging to WS, which is consistent with the lateral plunging of orebodies and mineralization alteration zone. Comprehensive analysis of the results of investigations on ore-controlling structures, mineralization-alteration zonation and geochemical zonation of the primary halos indicates that the gold orebodies in this area are still of greater extension.     

Geochemical and mineralogical properties of sulfide-bearing fine-grained sediments in Finland

 The geochemical and mineralogical characteristics of bulk samples and various size fractions of sulfide-bearing fine-grained sediments in the Petalax area, western Finland, were studied with ICP-AES (aqua regia digestion and "total" digestion) and X-ray diffraction. The sediments, which are dominated by particles <0.06 mm (clay and silt size), are composed of phyllosilicates (micas, kaolinite, chlorite, vermiculite), quartz, feldspars, amphiboles, organic matter, and secondary S minerals. The chemical analyses show that Na, Ca, and Sr are enriched in the silt and sand fractions, that Zr is enriched in the silt fraction, and that the concentrations of all other studied metals (Al, Ba, Co, Cr, Cu, Fe, K, La, Mg, Mn, Nb, Ni, Sc, Th, Ti, V, Y, and Zn) increase from the sand to the clay fraction. Sodium, Ca, and Sr occur largely in poorly dissolved feldspars, which explains the distribution of these metals in the sediments. The increase in the concentrations of most metals in the clay fraction is interpreted to be the result mainly of an increase in phyllosilicates in this size fraction. A geochemical comparison between the sulfide-bearing fine-grained sediments and glacial till shows that the former are enriched in several potentially toxic metals. It is therefore argued that the hydrological and ecological problems associated with the sulfide-bearing sediments are related not only to the production of acidity in oxidized layers, but also to mobilization and dispersion of toxic metals. Strategies to minimize damage of freshwater systems in areas covered with sulfide-bearing fine-grained sediments are suggested. Received: 20 February 1997 · Accepted: 25 August 1997     

Abundances and modes of occurrence of trace elements in the Çan coals (Miocene), Çanakkale-Turkey

This study presents the concentrations and modes of occurrence of trace elements in 81 coal samples from the Çan basin of northwestern Turkey. The concentration of trace elements in coal were determined by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry. Additionally, traditional coal parameters were studied by proximate, ultimate, X-ray diffraction, and petrographic analyses. Twenty trace elements, including As, B, Ba, Be, Cd, Cu, Co, F, Hg, Mo, Ni, Pb, Sb, Se Sn, Th, Tl, U, V, and Zn, receive much attention due to their related environmental and human health concerns. The Çan coals investigated in this study are lignite to sub-bituminous coal, with a broad range of ash yields and sulphur contents. The trace element concentrations show variety within the coal seams in the basin, and the affinities vary among locations. The concentrations of B, Ba, Be, Cd, Cu, Co, F, Hg, Mo, Ni, Pb, Sb, Se, Sn, Tl, and Zn in Çan coals are within the Swaine's worldwide concentration range, with the exception of As, Th, U, and V. On the other hand, compared with world coals, the Çan basin coals have higher contents of As, B, Cu, Co, Mo, Pb, Th, U, V, and Zn. Based on statistical analyses, most of the trace elements, except for U, show an affinity to ash yield. Elements including As, Cd, Hg, Se, Cu, Mo, Ni, and Zn, show a possible association with pyrite; however, the elements Se, B, and Mo can be have both organic and inorganic associations.     

Taxonomical and Biogeochemical Investigation of Elements in Holocene Mollusk Shells in the South and Southwestern Marmara Basin,Turkey

Concentrations of some heavy metals and trace elements such as Cr, Ga, Ni, Zn, Mo, Cu, Pb, Yb, Y, Nb, Ti, Sr, Ba, Mn, Sc, Co, V, Zr, Fe, Al, W, Se, Bi, Sb, As, Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated. The distribution of the elements in the shells is categorized into four groups. Of these, concentrations of 12 elements （As, Bi, Cd, Co, Ga, Mo, Nb, Sb, Se, Sc, W and Yb） are below zero [（0.053-0.79）×10^-6]; concentrations of seven elements （Cr, Ni, Pb, V, Y, Zr and Cu） are （1.0-6.0）×10^-6; concentrations of four elements （Ti, Mn, Ba and Zn） are 10- 20×10^-6; and concentrations of five elements （Si, Al, Fe, Mg and Sr） are （47.44-268.11）×10^-6. The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina （Linn6）, Pitar rudis （Poli）, Nassarius reticulatus （Linn6）, Venerupis senescens （Coocconi）, Mytilus galloprovincialis （Lamarck）, Mytilaster lineatus （Gemelin in Linne） and Chlamys glabra. It was found that, in mollusk taxonomy, the elements have unique values. In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks. In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment. Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment.     

内潮汐沉积研究及其存在的问题

内潮汐沉积是深水沉积研究中的一个非常年轻的研究领域,自1990年发现首例内潮汐沉积以来,沉积学工作者做了 大量不懈的努力,不仅发现了一系列内潮汐沉积实例,而且还对已发现的内潮汐沉积的特征、垂向序列和沉积模式进行了 总结,同时还认为内潮汐沉积可能成为油气潜在的良好储层。但是到目前为止,发现的内潮汐沉积的研究实例十分有限, 因此,内潮汐沉积研究中还存在一系列的尚待解决的问题。首先是内潮汐沉积的鉴别标志和识别方法尚不完善;其次是目 前尚缺少现代内潮汐沉积的典型实例研究,难以全面认识内潮汐对沉积作用的影响;第三是沉积学研究尚未将海洋物理学 的相关研究成果应用在内潮汐沉积的研究中,也未开展相关的内潮汐沉积实验模拟研究,更未利用地层记录中内潮汐沉积 特征反演内潮汐的物理特征,从而制约了内潮汐沉积的形成过程、形成机理、形成条件和形成环境的研究;第四是对内潮 汐沉积的研究意义认识不足。在下一步的研究中,应结合海洋物理学的相关研究成果对现代内潮汐沉积进行观察和研究, 同时开展相关的内潮汐沉积的实验模拟研究,并对古代内潮汐沉积进行反演研究。此外,还应将理论研究与油气等资源研 究相结合,从而更好地促进内潮汐沉积研究的发展。     

Determination of major and trace elements in European bottled mineral water — Analytical methods

A total of 1785 European bottled water samples were analyzed using standard laboratory methods. The bottled water samples were purchased in 2008 at supermarkets throughout 40 European countries. The samples were analyzed for 71 chemical parameters (As, Al, As, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, Br⁻, HCO₃⁻, Cl⁻, F⁻, NH₄⁺, NO₂⁻, NO₃⁻, PO₄³⁻, SO₄²⁻, SiO₂, pH, and EC) by quadrupole inductively coupled emission spectroscopy (ICP-QMS, trace elements), inductively coupled plasma atomic emission spectroscopy (ICP-AES, major elements), ion chromatography (IC, anions), atomic fluorescence spectrometry (AFS, Hg), titration (alkalinity), photometric methods (NH₄⁺), potentiometric methods (pH), and conductometric methods (specific electrical conductivity, EC). A very strict quality control procedure was followed by analysing blanks, international reference materials, an internal project standard, and duplicate analyses, as well as by analysing 23 elements by both ICP-QMS and ICP-AES. Analysis of marketed bottled water from springs, wells or boreholes, apart from the evaluation of its quality with respect to inorganic elements, it may provide a cheap alternative to obtain a first impression about groundwater chemistry at the European scale.