南海北部新生代火山岩微量元素与同位素体系特征研究

南海北部新生代火山岩由早期的钙碱性双峰式向晚期的碱性玄武岩和拉斑玄武岩演化，微量元素与同位素体系特征研究表明这种趋势与该地区边缘海的扩张过程相对应，在拉伸作用早期，岩浆来源于富集型岩石圈地幔，而在晚期则来源于亏损的软流圈地幔。     

Crustal Structure and Extension from Slope to Deepsea Basin in the Northern South China Sea

The newly acquired long-cable multi-channel seismic (MCS) lines were used to study the crustal structure and extension in an NW-SE elongated 150 km by 260 Van strip from the slope to the deepsea basin in the northern South China Sea (SCS).These profdes are of good penetration that Moho is recognizable in ～70% length of the lines.Seismostrattgraphic interpretation and time-depth conversion were conducted.A power function D = atb+ c was used in the time-depth conversion,which avoided the under-or over-estimation of the depths of deep-seated interfaces by cubic or quadratic polynomial functions.Contour maps of basement depth,Moho depth,crustal thickness,and crustal stretching factor were obtained for the study area.In the dip direction,the Moho depth decreases stepwisely from 28 km in the outer shelf southwards to 19,15,and 12 km in the deepsea basin,with ramps at the shelf break,lower slope,and the continent ocean boundary (COB),respectively.Accordingly,the crustal thickness decreased southwards from 3,and 7 km spectively.Under the center of the Balynn (白云) sag,the crust thins significantly to ＜ 7 kin.The crustal stretching factor βc was calculated by assuming the original crust thickness of 30 km.In the centers of the Baiyun sag,βc exceeds 5.Tertiary and Quaternary volcanic activities show a general trend of intensifying towards the COB.An important finding of this study is the along-strike variation of the crustal structure.A Moho rise extends from the COB NW-ward until the shelf break,about 170 km long and 50-100 km wide,with Moho depth ＜ 20 kin.This is called the Balyun Moho Nose,which is bounded to the east,west,and north by belts of high Moho gradients indicative of crustal or even lithospheric faults.The doming of Moho in the nose area might he the cause of the W-E segmentation of the crustal and geological structures along the slope of the northern South China Sea,and the cause of the strong crustal stretching in the Baiyun and Liwan (荔湾) sags.     

桂北地区丹洲群锆石U-Pb年代学及对华南新元古代裂谷作用期次的启示

桂北地区丹洲群是南华裂谷盆地南段的一套连续裂谷充填沉积,厘定各组沉积时限及区域地层关系,对理解华南新元古代裂谷作用期次具有重要意义。本文利用LA-ICP-MS锆石U-Pb同位素测年,获得丹洲群合桐组二段和拱洞组底部凝灰岩夹层形成年龄分别为801±4 Ma和781±5 Ma。研究表明,丹洲群白竹组和合桐组一段与下江群甲路组和乌叶组、板溪群沧水铺组和马底驿组、西乡群孙家河组及陆良组一段相当,沉积时限为820~800 Ma;合桐组二段与下江群番召组相当,沉积时限为800~780 Ma;拱洞组可与下江群清水江组、平略组和隆里组,板溪群五强溪组中上部和牛牯坪组,西乡群大石沟组中上部和三郎铺组,陆良组二段及澄江组、开建桥组、莲沱组、虹赤村组和上墅组的中上部直接对比,沉积时限为780~725 Ma。华南新元古代裂谷盆地系统的典型地层锆石年龄存在5组高峰,峰值年龄分别为818±2 Ma、802±1 Ma、780±4 Ma、756±4 Ma及728±5 Ma。综合华南新元古代岩浆活动特征及盆地沉积演化过程,确定华南新元古代裂谷作用可分为两期:820~800 Ma和800~725 Ma。此外,华南新元古代岩浆活动与裂谷作用之间存在明显的耦合关系,但各期岩浆活动对各裂谷盆地的影响程度存在差异。     

对“ 华夏古陆”、“ 华夏地块”及“ 扬子－华夏古陆统一体”等观点的质疑

关於华南大地构造格架及地壳演化存在两种对立的观点：其一，认为华南的基底是“华夏古陆”，或古元古—太古代的“华夏地块”，或“扬子－华夏古陆”。另一种意见认为除小的古老地体外，华南不存在古老基底，而是在洋壳基础上发展起来的地槽褶皱区。华南地槽褶皱区开始于造山纪（2050Ma），它的西部边界是武陵断裂带，与西南地台相邻；其北边界一般认为是长江断裂带，其实很可能是华北地台。对持“华夏古陆”及相似观点进行了质疑和评论，对华南地质一些关键的问题进行了探讨。在此基础上，根椐长期地质研究积累，如地槽相沉积、复理石或浊积岩的巨厚沉积、蛇绿岩套、细碧(角斑岩系、安山岩带、许多下古生代等地层标准化石，以及大量可信的同位素年代学资料等，提出华南从元古代到新生代的主要大地构造单元可分为5个造山带，即：① 武陵—双桥山—双溪坞—舟山造山带；② 震旦—早古生代造山带；③ 海西造山带；④ 印支—燕山火山岩带；⑤ 台东—喜马拉雅火山弧。     

Petroleum System in Deepwater Basins of the Northern South China Sea

The northern South China Sea margin has experienced a rifting stage and a post-rifting stage during the Cenozoic.In the rifting stage,the margin received lacustrine and shallow marine facies sediments.In the post-rifting thermal subsidence,the margin accumulated shallow marine facies and hemipelagic deposits,and the decpwater basins formed.Petroleum systems of deepwater setting have been imaged from seismic data and drill wells.Two kinds of source rocks including Paleogene lacustrine black shale and Oligocene-Early Miocene mudstone were developed in the deepwater basin of the South China Sea.The deepwater reservoirs are characterized by the deep sea channel fill,mass flow complexes and drowned reef carbonate platform.Profitable capping rocks on the top are mudstoues with huge thickness in the post-rifting stage.Meanwhile,the faults developed during the rifting stage provide a migration path favournble for the formation of reservoirs.The analysis of seismic and drilling data suggests that the joint structural and stratigraphic traps could form giant hydrocarbon fields and hydrocarbon reservoirs including syn-rifting graben subaqueous delta,decpwater submarine fan sandstone and reef carbonate reservoirs.     

南海北部油气微生物勘查研究

随着现代生物技术的发展,微生物勘探技术正走向成熟,成为一项经济有效的直接找油方法。探讨了油气微生物勘探指标的选择和甲烷氧化菌的研究方法,应用原位荧光杂交法分析了南海北部表层海水中甲烷氧化菌的丰度,结果发现每升海水中有3.59×104～7.45×106个甲烷氧化菌,并且海水中甲烷浓度与甲烷氧化菌丰度的相关性较高,相关系数达0.861,基于两个指标综合分析海洋油气藏的赋存可以提高指示精度。     

南海北部陆架海底沙波基本特征及属性

南海北部陆架海底沙波是否为残留沙波长期存在争议。为配合陆丰油田的开发,在LF13-2和LF13-1站位之间进行了详细的地形、地貌和海底底流测量。观测数据显示,本研究区发育两组海底沙波。两组沙波的分布和当今的海底地形密切相关,沙波的波宽、波高,沙脊的长度及延伸的方向也都和现今的水深密切相关。此外,沙波区的底质、沉积物颜色等也随现今水深的变化而变化。跨年度的测量结果显示,从2003年夏季到2005年冬季,海底沙波发生了明显的变化,除有明显的沙波迁移,并有新的沙波生成外,沙波区的水深也整体变深,研究区东南端平均加深了0.29m。由于东沙海底高原的存在,东沙区底流有了复杂的变化。实际的观测结果显示,在9MKII站位,向南的退潮流明显大于向北的涨潮流,但在AEM-HR站位,WNW向的涨潮流则稍稍大于ESE向的退潮流。9MKII站位测得的最大底流速为48cm/s,有22%的底流速大于20cm/s,这是启动海底沉积物并能形成海底沙波的最小底流速。本文指出,东沙隆起后,由于强烈的底流侵蚀,在东沙区的中陆架和外陆架区几乎没有现代沉积。构成海底沙波的沉积物主要来自海底地层的剥蚀。测深结果显示的海底加深可能和海底剥蚀有关。很明显,海底沙波和现今的海底底流体系有很好的吻合关系,从而是在现今底流体系条件下形成的,而非晚更新世末次冰期的残留沙波。     

The Earlier Spreading of South China Sea Basin due to the Late Mesozoic to Early Cenozoic Extension of South China Block： Structural Styles and Chronological Evidence from the Dulong-Song Chay Metamorphic Dome, Southwest China

INTRODUCTION Whatmechanismresultedinthespreadingof SouthChinaSeabasin(SCSB)?Wasitreallypro ducedbytheinteractionofperipheralplatesofthe SCSBorAilaoshan RedRiversinistralfault(Fig.1)? Figure1.AnoutlinetectonicmapofSouthChinablockandIndochinablock(modified…     

张英1，郭依群2，莫午零3，胡玉波4

南海北部神狐海域钻探获得的水合物中天然气组分以甲烷为主,为典型干气,气体甲烷碳氢同位素组成揭示天然气为典型的生物成因,为二氧化碳还原形成。南海北部地区在硫酸盐-甲烷还原界面（SMI）以下进入生物甲烷生成阶段,盐度适中,适宜产甲烷菌等菌群的生存和生物甲烷气的生成,埋深200～1500 m层段是生物甲烷的主要生成阶段。中新世中晚期、上新世和第四纪沉积物以泥为主,部分层段为砂泥岩互层,有机质丰度较高,类型好,热演化程度低,生物气生成条件优越,可为浅部天然气水合物的形成提供充足的气源。     

Activity and Formation of Sand Waves on Northern South China Sea Shelf

Sand waves on the northern South China Sea shelf had been considered as stable relict bed form. For the industry use of sea bed between stations LF13-2 and LF13-1, a new round of explorations were conducted. The newly obtained data show that both spacings and amplitudes of sand waves are all systematically changing with water depth. Repeated observations since 2003 to 2004 showed that the sea bed is currently active. Due to strong erosion of surface sediment since Dongsha (东沙) uplifting, there are almost no...     

南海北部晚更新世以来的古海洋环境演化特征——来自N-31柱样的沉积记录

对南海北部N-31柱状样沉积物进行了浮游有孔虫定量分析鉴定、氧碳同位素、碳酸盐含量和粒度测试以及AMS14C测年,并采用古生态转换函数计算了表层海水古温度和温跃层深度,揭示了该海区约55 ka以来的古海洋环境特征.转换函数计算的表层海水古温度结果表明,夏季温度的变化范围为27.0～29.6℃,变化幅度为2.6℃,冬季温...     

云开地区变质基底锆石U-Pb年代学及对华夏地块Grenvillian事件的指示

云开地区前寒武纪变质基底主要是以片麻岩类为代表的高州杂岩和以浅变沉积岩类为代表的云开群,均不同程度受到了后期加里东期和印支期构造-岩浆事件的改造。对高州杂岩中1个变粒岩(YK1016)和1个黑云斜长片麻岩(YK1014-3)、云开群中1个黑云斜长片麻岩(YK1017-1)样品进行了锆石LA-ICP-MS U-Pb定年。样品YK1016中获得的不一致曲线上下交点年龄分别为(1 035±43)Ma和(437±30)Ma(n=16,MSWD=1.3),上交点年龄与10个谐和点207Pb/206Pb加权平均年龄(970±30)Ma(MSWD=0.22)一致,解释为其形成年龄。样品YK1014-3获得的206Pb/238 U表观年龄范围为949~2 395 Ma,主要集中在1 000~1 200 Ma,9个最年轻且谐和的分析点207Pb/206Pb加权平均年龄为(970±32)Ma(MSWD=0.53),对其最大沉积年龄进行了约束。样品YK1017-1获得的206Pb/238 U表观年龄范围为650~2 383 Ma,也主要集中在1 000~1 200 Ma,最年轻且谐和的碎屑锆石年龄将其时代约束在650 Ma。结合云开地区变质基底中已有的高精度年龄数据,认为高州杂岩形成时代为中元古代晚期—新元古代早期,云开群的形成时代为新元古代晚期。另外,研究结果及云开地区已有的数据表明,该区除出露Grenville期岩石外,新元古代变沉积岩中还存在大量Grenville期(900~1 350 Ma)碎屑锆石,部分晶形较好具岩浆起源,这一现象从云开地区一直延伸到华夏东部;但在华夏地块由南往北,Grenville期锆石呈减少趋势,新元古代锆石(820~860 Ma)逐渐增多。这些暗示华夏地块南缘存在一个由南东向北西推进的Grenvillian造山带,和(或)在华夏地块内部存在略晚于Grenville期的构造-岩浆事件。     

Zircon U‐Pb Dating on Granitoids from the Northern South China Sea and its Geotectonic Relevance

Zircon U-Pb ages of 163.8–100.4 Ma and 146.6–134.5?Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165–100?Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165–150?Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong (148–130?Ma) to the Pearl River Mouth basin (127–112?Ma), corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108–97?Ma. A tectonic transformation from slab-subduction to extension should occur at ~100?Ma.     

南海北部白云凹陷08CF7岩心沉积物的磁化率特征及其意义

海洋沉积物的磁性异常与甲烷渗漏活动及其产物密切相关。为揭示南海北部天然气水合物区沉积物磁化率的变化特征及其意义,对白云凹陷08CF7岩心331个沉积物样品的磁化率进行测定和分析。08CF7岩心沉积物磁化率变化范围为554×10-6~2656×10-6SI,平均值为1141×10-6SI。磁化率随深度变化可分为0~188 cm、188~240 cm及240 cm以下等3段,分别与硫酸盐富集带、硫酸盐-甲烷转换界面(SMT)的上部过渡带及SMT相对应。研究表明,海底天然气渗漏是08CF7岩心沉积物磁化率异常变化的可能原因,其机理是：在强烈的还原环境中,甲烷厌氧氧化反应的产物HS-与沉积物中的Fe3+发生反应,形成顺磁性的黄铁矿。沉积物磁化率变化能快速了解SMT状况及其深度,提供了一种识别南海北部天然气水合物的间接方法。     

裂后岩浆活动中岩床复合体的特征:以南海北部和南极西罗斯海地区为例

由于蕴含着潜在的油气勘探和资源储藏信息,岩床复合体在全球范围内被广泛研究。本文基于南海北部三维地震资料以及南极罗斯海地区二维多道地震资料,对岩床复合体的形态特征及分布进行分析,对两个地区岩床复合体的形成时间进行判断,阐述岩床复合体的侵位机制。研究发现,岩床复合体代表性产状除了菱形、碟形及复合型外,还存在沿着层位平行侵入的板状,推测它可能是夭折了的岩床侵入体,以及由几个小型岩床堆叠而成的透镜状岩床复合体。分布上,南海北部岩床主要发育于珠江口盆地白云凹陷三维工区西部,东部只零星可见;南极西罗斯海岩床主要发育于西北角的阿黛尔盆地内。根据岩床上覆的强制褶皱结合区域构造背景,推测南海北部岩床复合体的形成时间为早中新世(15.5 Ma),海底扩张结束之时。残余岩浆将盆地内裂谷时期形成的断层作为岩浆运移的通道,并最终在断层终点处即下中新统近海相砂泥岩地层中实现侵位。南极西罗斯海岩床复合体的形成时间则非常晚,不早于5.5 Ma。该区这期岩浆活动可能与构造作用无关,而是受到冰川消融的影响。研究发现岩床复合体内部的岩床个体互相供给,即深部的大岩床为上覆浅层的小岩床提供岩浆供给,并且互相组合,形成大的岩床复合体。然而,每个岩床复合体则可能由不同的岩浆供给发育而成。     

南极半岛附近海域与南海北部海域多道地震资料对比分析

在中国第33次南极科学考察中, 自然资源部中国地质调查局下属的广州海洋地质调查局“海洋六号”船于2016年12月到2017年2月在南极半岛南设得兰海沟海域获得了1 400多km的高分辨率多道地震资料。这是我国首次在南极海域获得高分辨率多道地震资料, 是一次艰辛的探索和尝试。在出航南极之前, 为了保证采集设备的稳定和取得合理的采集参数, “海洋六号”船在我国南海北部海域多次对采集设备和采集参数进行了检测和试验, 获得了多条高分辨率多道地震资料。通过对比南极半岛附近海域和南海北部海域的地震资料, 在相同采集设备和采集参数的情况下, 表现出了明显不同的特征。     

前中生代海南岛与华夏、扬子陆块的关系——来自海南岛下二叠统峨查组碎屑锆石年龄的信息

海南地块的亲缘性质归属一直存在分歧。选择海南东方市江边乡白查村峨查组进行碎屑锆石LA-ICP-MS U-Pb测年,获得年龄为635～1814Ma,具4个年龄峰值,分别为1700Ma、1580Ma、1073Ma和680Ma,记录了哥伦比亚(1700Ma和1580Ma)、罗迪尼亚(1073Ma)和泛非(680Ma)三大地质事件。1700 Ma、1580Ma和1073Ma三个峰值可与南极洲、越南Song Hien、华夏造山带和扬子陆块东南缘同期的碎屑锆石U-Pb年龄峰值对比,说明海南地块在中元古代与南极洲、越南、华夏和扬子陆块东南缘共同经历了哥伦比亚和格林威尔(罗迪尼亚)造山事件。1700Ma和1580Ma的峰值虽然在扬子陆块东南缘有弱的显示,但在扬子陆块内部基本没有该年龄峰值的报道,680Ma峰值在扬子陆块未出现,说明中—新元古代海南地块与扬子陆块之间相距较远,而与华夏、越南和南极洲较近。     

Lipid Distribution in Marine Sediments from the Northern South China Sea and Association with Gas Hydrate

The distributions of lipids in surface and subsurface sediments from the northern South China Sea were determined. The n-alkanes were in bimodal distribution that is characterized by a centre at n-C16 –n-C20 with maximum at C18(or C19) and n-C27 –n-C31 as well as at C29(or C31). The short-chain alkanes suffered from significant losses due to their slow deposition in the water column, and their presence with a slight even carbon predominance in shallow seafloor sediments was ascribed mainly to the direct input from the benthos. The long-chain alkanes with odd predominance indicate transportion of terrigenous organic matter. Immature hopanoid biomarkers reflect the intense microbial activity for bacteria–derived organic matter and the gradual increase of maturity with burial depth. Abundant n-fatty acid methyl esters(n-FAMEs) that are in distributions coincident with fatty acids were detected in all samples. We proposed that the observed FAMEs originated from the methyl esterification of fatty acids; methanol production by methanotrophs and methanogenic archaea related to the anaerobic oxidation of methane, and sulfate reduction provided an O–methyl donor for methylation of fatty acids. The CH4 released from hydrate dissociation at oxygen isotope stage II of Cores ZD3 and ZS5, which had been confirmed by the occurrence of negative δ13C excursion and spherical pyrite aggregates, could have accelerated the above process and thus maximized the relative content of FAMEs at ZD3-2(400–420 cm depth) and ZS5-2(241–291 cm depth).     

南海北部盆地新生代物源对周边主要河流演化的响应

源汇系统（Source- to- sink system）是将物源区的构造剥蚀、沉积物输送区的沉积物搬运和沉积区的沉积物堆积等视为一个完整系统。沉积物的源区恢复和附近水系重建是源汇研究的热点问题,沉积物碎屑锆石U- Pb定年是源汇系统研究的有效方法之一。南海北部与其周边地区构成了一个完整的源汇系统,通过源汇分析可获得南海北部各盆地沉积物来源及周边主要河流的演化历史。本文通过总结前人在南海北部主要盆地新生代沉积物碎屑锆石U- Pb研究成果,探讨珠江、红河和昆莺琼古河的新生代演化历史。珠江最早的支流北江和东江形成于早渐新世,晚渐新世溯源到西江上游的红水河、左江和右江,中新世溯源到西江中游柳江、桂江和上游的北盘江、南盘江。在晚白垩世—古近纪红河属于青藏高原东缘大型向东南或向南流河流的一部分,之后由于地貌变化形成现今红河。昆莺琼古河在早渐新世开始发育影响到珠江口盆地,在晚渐新世昆莺琼古河雏形已经基本形成,中新世起昆莺琼古河可能向西有一定程度的退缩。     

华夏地块龙泉地区发现亚洲最古老的锆石

锆石这一矿物是迄今为止所发现的地球最初500个百万年间(地质学界通常称为"冥古代")的唯一地壳物质残留,对于了解地球早期地壳演化过程至关重要。近年来,随着高精度SHRIMP测年技术的广泛运用,笔者最近在华夏地块龙泉地区发现了2颗约4100 Ma的碎屑锆石。其中一颗为目前发现亚洲最古老的锆石,其内部结构简单,具有正常的震荡环带,207Pb/206Pb年龄为(4127±4)Ma;其δ18O与地幔岩浆的氧同位素类似,可能来自于早期的幔源岩浆或者未经历地表过程的深部地壳物质的熔融。另外一颗锆石具有明显的核边结构,其核部结晶年龄约为4100 Ma,变质边年龄约为4070 Ma,外围还有2层岩浆增生边年龄介于3800~3600 Ma,代表了该4100 Ma的锆石核部在后期经历了复杂的地壳演化过程,4070 Ma的变质边是目前已获得最为可靠的全球变质年龄。上述发现表明冥古宙时地壳性质和构造环境存在多样性,为认识地球早期大陆演化过程提供了重要新信息。