Sedimentary rock-hosted Au deposits of the Dian–Qian–Gui area, Guizhou, and Yunnan Provinces, and Guangxi District, China

Sedimentary rock-hosted Au deposits in the Dian–Qian–Gui area in southwest China are hosted in Paleozoic and early Mesozoic sedimentary rocks along the southwest margin of the Yangtze (South China) Precambrian craton. Most deposits have characteristics similar to Carlin-type Au deposits and are spatially associated, on a regional scale, with deposits of coal, Sb, barite, As, Tl, and Hg. Sedimentary rock-hosted Au deposits are disseminated stratabound and(or) structurally controlled. The deposits have many similar characteristics, particularly mineralogy, geochemistry, host rock, and structural control. Most deposits are associated with structural domes, stratabound breccia bodies, unconformity surfaces or intense brittle–ductile deformation zones, such as the Youjiang fault system. Typical characteristics include impure carbonate rock or calcareous and carbonaceous host rock that contains disseminated pyrite, marcasite, and arsenopyrite—usually with μm-sized Au, commonly in As-rich rims of pyrite and in disseminations. Late realgar, orpiment, stibnite, and Hg minerals are spatially associated with earlier forming sulfide minerals. Minor base–metal sulfides, such as galena, sphalerite, chalcopyrite, and Pb–Sb–As–sulphosalts also are present. The rocks locally are silicified and altered to sericite–clay (illite). Rocks and(or) stream-sediment geochemical signatures typically include elevated concentrations of As, Sb, Hg, Tl, and Ba. A general lack of igneous rocks in the Dian–Qian–Gui area implies non-pluton-related, ore forming processes. Some deposits contain evidence that sources of the metal may have originated in carbonaceous parts of the sedimentary pile or other sedimentary or volcanic horizons. This genetic process may be associated with formation and mobilization of petroleum and Hg in the region and may also be related to As-, Au-, and Tl-bearing coal horizons. Many deposits also contain textures and features indicative of strong structural control by tectonic domes or shear zones and also suggest syndeformational ore deposition, possibly related to the Youjiang fault system. Several sedimentary rock-hosted Au deposits in the Dian–Qian–Gui area also are of the red earth-type and Au grades have been concentrated and enhanced during episodes of deep weathering.     

Geodynamically indicated targeting strategy for shale‐hosted massive sulfide Pb–Zn–Ag mineralisation in the Western Fold Belt,Mt Isa terrane

There is ongoing debate with respect to the genetic models for shale‐hosted massive sulfide Pb–Zn–Ag deposits contained in the Palaeoproterozoic to Mesoproterozoic intracontinental Isa Superbasin in the Western Fold Belt, Mt Isa terrane. Favourable sites of mineralisation can be predicted based on understanding the tectonic setting of the Isa Superbasin, the structural controls of mineralisation and the chemically favourable environments for ore deposition. Shale‐hosted massive sulfide Pb–Zn–Ag deposits are hosted in successions deposited during the dominant sag‐phase of the Isa Superbasin. These deposits are localised at the intersections of major basin‐scale extensional faults and are hosted in both shallow‐marine and deeper water carbonaceous shales that are characteristically anoxic and located near or at maximum flooding surfaces. All major shale‐hosted massive sulfide Pb–Zn–Ag deposits are located to the west of the Mt Isa Rift (ca 1710–1670 Ma). This spatial association is explained by an asymmetrical lithosphere extension model for the evolution of the Isa Superbasin. Elevated geothermal gradients at the location of maximum subcrustal lithospheric thinning to the west of the Mt Isa Rift may have driven the migration of basinal brines. Increased subsidence at this location produced favourable anoxic sedimentary horizons for metal precipitation during orebody formation.     

Crustal lineaments, distribution of lower crustal intrusives and structural evolution of the Vøring Margin, NE Atlantic; new insight from wide-angle seismic models

Five lineaments on the volcanic Vøring Margin, NE Atlantic, have been identified in crustal scale models derived from Ocean Bottom Seismograph (OBS) data. It is suggested that the Vøring Basin can be divided in four compartments bounded by the Jan Mayen Fracture Zone/Lineament, a new lineament defined from this study, the Gleipne Lineament, the Surt Lineament and the Bivrost Lineament. The NW–SE trending Jan Mayen-, Gleipne- and Bivrost lineaments probably represent old zones of weakness controlling the onset of the early Eocene seafloor spreading, whereas the Surt- and New lineaments, rotated ca. 30° symmetrically from the azimuth of the Gleipne Lineament, may represent adjustment features related to the early Cretaceous/early Tertiary rifting. The longest landward extent of a lower crustal high-velocity body, assumed to represent intrusions related to the last phase of rifting, is found between the New Lineament and the Gleipne Lineament, where the body extends across the Helland Hansen Arch. Northeastwards in the Vøring Basin, the landward limit of the body steps gradually seawards, closely related to the interpreted lineaments. Northeast of the Gleipne Lineament, the body terminates close to the Fles Fault Complex, north of the Surt Lineament, it extends across the Nyk High, and northeast of the Bivrost Lineament the intrusions terminate around the Vøring Escarpment. Evidence for an interplay between active and passive rifting components is found on regional and local scales on the margin. The active component is evident through the decrease in magmatism with increased distance from the Icelandic plume, and the passive component is documented through the fact that all found crustal lineaments to a certain degree acted as barriers to magma emplacement. The increased thickness of the continental crust on the seaward side of the Vøring Escarpment, the upwarping of Moho and thinning of the lower crustal high-velocity layer in the western part of the Vøring Basin, as well as a strong shallowing of the Moho observed in parts of the area between the Jan Mayen Fracture Zone/Lineament and the New Lineament, can be explained by lithospheric delamination models.     

澳大利亚Cloncurry地区铁矿化岩石与铜金矿化的时空关系

澳大利亚Cloncurry地区大部分被元古宙地层所覆盖,其中赋存有大量世界级的成矿热液系统。大型热液系统大都与含磁铁矿或赤铁矿等铁氧化物的铁矿化岩石密切相关。铁氧化物和铜金矿化的矿物学、地球化学及年代学特征反映出成矿过程可能涉及到多种流体间的作用和水岩反应。对Cloncurry地区典型矿床和区域Na-Ca热液系统的研究表明,含铁氧化物的铁矿化岩石与铜金矿化之间的关系可分为4类:①贫磁铁矿或赤铁矿的"Kiruna-型"铁矿化岩石;②铜金矿化赋存于含铁氧化物的铁矿化岩石中;③与铁氧化物有关的铜金矿化;④少量或者不含铁氧化物的铜金矿化。该分类提供了一些与铁氧化物有关的铜金矿化成因联系、矿物学和矿化类型信息。     

Geochemistry and evolution of ore-forming fluids of the Yueshan Cu–Au skarn- and vein-type deposits, Anhui Province, South China

The Yueshan mineral belt is geotectonically located at the centre of the Changjiang deep fracture zone or depression of the lower Yangtze platform. Two main types of ore deposits occur in the Yueshan orefield: Cu–Au–(Fe) skarn deposits and Cu–Mo–Au–(Pb–Zn) hydrothermal vein-type deposits. Almost all deposits of economic interest are concentrated within and around the eastern and northern branches of the Yueshan dioritic intrusion. In the vicinity of the Zongpu and Wuhen intrusions, there are many Cu–Pb–Zn–Au–(S) vein-type and a few Cu–Fe–(Au) skarn-type occurrences.Fluid inclusion studies show that the ore-forming fluids are characterised by a Cl⁻(S)–Na⁺–K⁺ chemical association. Hydrothermal activity associated with the above two deposit types was related to the Yueshan intrusion. The fluid salinity was high during the mineralisation processes and the fluid also underwent boiling and mixed with meteoric water. In comparison, the hydrothermal activity related to the Zongpu and Wuhen intrusions was characterised by low salinity fluids. Chlorine and sulphur species played an important role in the transport of ore-forming components.Hydrogen- and oxygen-isotope data also suggest that the ore-forming fluids in the Yueshan mineral belt consisted of magmatic water, mixed in various proportions with meteoric water. The enrichment of ore-forming components in the magmatic waters resulted from fluid–melt partitioning. The ore fluids of magmatic origin formed large Cu–Au deposits, whereas ore fluids of mixed magmatic-meteoric origin formed small- to medium-sized deposits.The sulphur isotopic composition of the skarn- and vein-type deposits varies from − 11.3‰ to + 19.2‰ and from + 4.2‰ to + 10.0‰, respectively. These variations do not appear to have been resulted from changes of physicochemical conditions, rather due to compositional variation of sulphur at the source(s) and by water–rock interaction. Complex water–rock interaction between the ore-bearing magmatic fluids and sedimentary wall rocks was responsible for sulphur mixing. Lead and silicon isotopic compositions of the two deposit types and host rocks provide similar indications for the sources and evolution of the ore-forming fluids.Hydrodynamic calculations show that magmatic ore-forming fluids were channelled upwards into faults, fractures and porous media with velocities of 1.4 m/s, 9.8 × 10^− 1 to 9.8 × 10^− 7 m/s and 3.6 × 10^− 7 to 4.6 × 10^− 7 m/s, respectively. A decrease of fluid migration velocity in porous media or tiny fractures in the contact zones between the intrusive rocks and the Triassic sedimentary rocks led to the deposition of the ore-forming components. The major species responsible for Cu transport are deduced to have been CuCl, CuCl₂⁻, CuCl₃²⁻ and CuClOH, whereas Au was transported as Au₂(HS)₂S²⁻, Au(HS)₂⁻, AuHS and AuH₃SiO₄ complexes. Cooling and a decrease in chloride ion concentration caused by fluid boiling and mixing were the principal causes of Cu deposition. Gold deposition was related to decrease of pH, total sulphur concentration and fO₂, which resulted from fluid boiling and mixing.Geological and geochemical characteristics of the two deposit types in the Yueshan mineral belt suggest that there is a close genetic relationship with the dioritic magmatism. Geochronological data show that the magmatic activity and the mineralisation took place between 130 and 136 Ma and represent a continuous process during the Yanshanian time. The cooling of the intrusions and the mineralisation event might have lasted about 6 Ma. The cooling rate of the magmatic intrusions was 80 to 120 °C my^− 1, which permitted sufficient heat supply by magma to the ore-forming system.     

Metallogenesis of the Carajás Mineral Province, Southern Amazon Craton, Brazil: Varying styles of Archean through Paleoproterozoic to Neoproterozoic base- and precious-metal mineralisation

The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO₂ and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.     

Orogenic gold mineral systems of the Western Lachlan Orogen (Victoria) and the Hodgkinson Province (Queensland): Crustal metal sources and cryptic zones of regional fluid flow

Orogenic gold mineral systems in the Western Lachlan Orogen (Victoria) and the Hodgkinson Province (Queensland) produced gold provinces characterised by vastly different scales of gold endowment and strongly uneven distribution of gold mineralisation within each province. The volume of hydrous pyrite-bearing rocks undergoing metamorphic devolatilisation during thermo-tectonic events driving orogenic gold mineral systems represents a fundamental first-order constraint on the total gold endowment and its broad spatial distribution, both between and within the provinces. Most of the largest gold deposits in both regions occur in linear, richly-endowed metallogenic zones, oblique to the dominant regional structures and related to deep crustal domain boundaries. These boundaries, with only subtle surface expressions, were the major regional structural controls which promoted focused near-vertical flow of mineralising metamorphic fluids above the outer margins of cratonic blocks in the lower crust. Recognised major faults represented only more local scale and often indirect controls on the focused fluid flow, particularly effective above the deep cratonic block boundaries overlain by relatively thick crustal source rocks.     

Siliciclastic shoreline to growth‐faulted,turbiditic sub‐basins: The Proterozoic River Supersequence of the upper McNamara Group on the Lawn Hill Platform,northern Australia

The River Supersequence represents a 2nd‐order accommodation cycle of approximately 15 million years duration in the Isa Superbasin. The River Supersequence comprises eight 3rd‐order sequences that are well exposed on the central Lawn Hill Platform. They are intersected in drillholes and imaged by reflection seismic on the northern Lawn Hill Platform and crop out in the McArthur Basin of the Northern Territory. South of the Murphy Inlier the supersequence forms two south‐thickening depositional wedges on the Lawn Hill Platform. The northern wedge extends from the Murphy Inlier to the Elizabeth Creek Fault Zone and the southern wedge extends from Mt Caroline to the area south of Riversleigh Station. On the central Lawn Hill Platform the River Supersequence attains a maximum thickness of 3300 m. Facies are dominantly fine‐grained siliciclastics, but the lower part comprises a mixed carbonate‐siliciclastic succession. Interspersed within fine‐grained facies are sharp‐based sandstone and conglomeratic intervals interpreted as lowstand deposits. Such lowstand deposits represent a wide range of depositional systems and palaeoenvironments including fluvial channels, shallow‐marine shoreface settings, and deeper marine turbidites and sand‐rich submarine fans. Associated transgressive and highstand deposits comprise siltstone and shale deposited below storm wave‐base in relatively quiet, deep‐water settings similar to those found in a mid‐ to outer‐shelf setting. Seismic analysis shows significant fault offsets and thickness changes within the overall wedge geometry. Abrupt thickness changes across faults over small horizontal distances are documented at both the seismic‐ and outcrop‐scales. Synsedimentary fault movement, particularly along steeply north‐dipping, largely northeast‐trending normal faults, partitioned the depositional system into local sub‐basins. On the central Lawn Hill Platform, the nature of facies and their thickness change markedly within small fault blocks. Tilting and uplift of fault blocks affected accommodation cycles in these areas. Erosion and growth of fine‐grained parts of the section is localised within fault‐bounded depocentres. There are at least three stratigraphic levels within the River Supersequence associated with base‐metal mineralisation. Of the seven supersequences in the Isa Superbasin, the River Supersequence encompasses arguably the most dynamic period of basin partitioning, syndepositional faulting, facies change and associated Zn–Pb–Ag mineralisation.     

Mobility of rare-earth elements and copper during shear-zone-related retrograde metamorphism

In Mid Proterozoic crystalline rocks of the Mount Isa Inlier, around Cloncurry, Australia, 2000 km² of alteration and brecciation are the product of high-temperature (> 450 °C) concentrated saline solution activity. During retrogression, this fluid was locally responsible for mobility of V, Y, Nb and light rare-earth elements (15 × enrichment). Copper and S were leached during alteration and this may have been a significant source of components in nearby Cu-Au deposits. Similar rare-earth-element behaviour has been observed in the hematite breccias which host Cu-sulfides at the giant Olympic Dam Cu-Au deposit.     

Mapping of prospectivity and estimation of number of undiscovered prospects for lode gold,southwestern Ashanti Belt,Ghana

In the southwestern part of the Ashanti Belt, the results of fractal and Fry analyses of the spatial pattern of 51 known mines/prospects of (mostly lode) gold deposits and the results of analysis of their spatial associations with faults and fault intersections suggest different predominant structural controls on lode gold mineralisation at local and district scales. Intersections of NNE- and NW-trending faults were likely predominantly involved in local-scale structural controls on lode gold mineralisation, whilst NNE-trending faults were likely predominantly involved in district-scale structural controls on lode gold mineralisation. The results of the spatial analyses facilitate the conceptualisation and selection of spatial evidence layers for lode gold prospectivity mapping in the study area. The applications of the derived map of lode gold prospectivity and a map of radial density of spatially coherent lode gold mines/prospects results in a one-level prediction of 37 undiscovered lode gold prospects. The applications of quantified radial density fractal dimensions of the spatial pattern of spatially coherent lode gold mines/prospects result in an estimate of 40 undiscovered lode gold prospects. The study concludes finally that analysis of the spatial pattern of discovered mineral deposits is the key to a strong link between mineral prospectivity mapping and assessment of undiscovered mineral deposits.     

Recognition of the regional lineaments of Iran: Using geospatial data and their implications for exploration of metallic ore deposits

The relationship between major structural lineaments and locations of ore deposits in Iran has been investigated using geospatial data. In the course of lineament extraction, satellite images, aeromagnetic data, digital elevation model (DEM) and structural maps were processed and the lineaments and large-scale faults were identified. The extracted lineaments, based on subjective assessment, from each dataset were imported into GIS software and the “lineament map of Iran” was prepared by data integration. The analysis for selecting significant lineament was mainly based on fault correlated lineament and lineament with field map fractures, which was sets as benchmarks for compiling a final output map. Four major regional lineament trends of N–S, E–W, NW–SE and NE–SW were identified in the data of all images, which are corresponded to the structural zones and the major fault systems of Iran. The mineral deposits (active and abandoned) and mineral indications database compiled are based on the published maps, papers, reports and the ore deposits data files of Geological Survey of Iran. Integrating the output of these two datasets by GIS software resulted in the “Combined Map of Lineaments and Gold, Copper, Lead, Zinc and Iron Deposits of Iran”. The number and distance of ore deposits toward the lineaments were processed by the counting and cumulative methods in the GIS software's. Approximately, over 90% of the ore deposits of Iran are located in the central part of the lineaments (15 km on each side) which are concordant with a definition of large lineament. About 50% of these mineral deposits are closer than 5 km to the lineaments. There are significant correlations between lineament density and intersections with ore deposits occurrences. The observed associations at this scale are informative in establishing exploration strategy and decreasing exploration risks for detailed work on ore deposit scale.     

Rhenium–osmium systematics of the Mount Isa copper orebody and the Eastern Creek Volcanics,Queensland, Australia: implications for ore genesis

The syn-tectonic breccia-hosted Mount Isa Cu deposit in northwest Queensland is the largest sediment-hosted Cu deposit in Australia. Whole-rock samples of chalcopyrite-rich Cu ore form an isochron with a Re–Os age of 1,372 ± 41 Ma. This age is more than 100 Ma younger than the previously accepted age of Cu ore formation, an Ar–Ar mineral age for biotite separated from the host rocks within the alteration envelope to the Cu orebody. This discrepancy cannot be unequivocally resolved due to a lack of other absolute geochronological constraints for Cu mineralisation or the deformation event associated with Cu emplacement. The 1,372 ± 41 Ma date may reflect (a) the time of Cu deposition, (b) the time of a hydrothermal event that reset the Re–Os signature of the Cu ore or (c) mixing of the Re–Os isotope systematics between the host rocks and Cu-bearing fluids. However, a range of published Ar–Ar and Rb–Sr dates for potassic alteration associated with Cu mineralisation also records an event between 1,350 and 1,400 Ma and these are consistent with the 1,372 Ma Re–Os age. The 1.8 Ga Eastern Creek Volcanics are a series of tholeiitic basalts with a primary magmatic Cu enrichment which occur adjacent to the Mount Isa Cu deposit. The whole-rock Os isotopic signature of the Eastern Creek Volcanics ranges from mantle-like values for the upper Pickwick Member, to more radiogenic/crustal values for the lower Cromwell Member. The Re–Os isotope signature of the Cu ores overlaps with those calculated for the two volcanic members at 1,372 Ma; hence, the Os isotope data are supportive of the concept that the Os in the Cu ores was sourced from the Eastern Creek Volcanics. By inference, it is therefore postulated that the Eastern Creek Volcanics are the source of Cu in the Mount Isa deposit, as both Os and Cu are readily transported by oxidised hydrothermal fluids, such as those that are thought to have formed the Cu orebody. The Pickwick Member yields a Re–Os isochron age of 1,833 ± 51 Ma, which is within error of previously reported age constraints. The initial ¹⁸⁷Os/¹⁸⁸Os isotopic ratio of 0.114 ± 0.067 (γOs = −0.7) is slightly subchondritic, and together with other trace element geochemical constraints, is consistent with a subcontinental lithospheric mantle source. The Pickwick Member records a minimum age of ca. 1.95 Ga for melt depletion in the subcontinental lithospheric mantle beneath the Mount Isa Inlier prior to the extraction of the magmas which formed the Eastern Creek Volcanics. This corresponds with the end of subduction-related magmatism along the eastern margin of the Northern Australian Craton, which included the Mount Isa Inlier.     

Recognition of geochemical footprints of mineral systems in the regolith at regional to continental scales

Understanding the character of Australia's extensive regolith cover is crucial to the continuing success of mineral exploration. We hypothesise that the regolith contains geochemical fingerprints of processes related to the development and preservation of mineral systems at a range of scales. We test this hypothesis by analysing the composition of surface sediments within greenfield regional-scale (southern Thomson Orogen) and continental-scale (Australia) study areas. In the southern Thomson Orogen area, the first principal component (PC1) derived in our study [Ca, Sr, Cu, Mg, Au and Mo at one end; rare earth elements (REEs) and Th at the other] is very similar to the empirical vector used by a local company (enrichment in Sr, Ca and Au concomitant with depletion in REEs) to successfully site exploration drill holes for Cu–Au mineralisation. Mapping of the spatial distribution of PC1 in the region reveals several areas of elevated values and possible mineralisation potential. One of the strongest targets in the PC1 map is located between Brewarrina and Bourke in northern New South Wales. Here, exploration drilling has intersected porphyry Cu–Au mineralisation with up to 1 wt% Cu, 0.1 g/t Au, and 717 ppm Zn. The analysis of a comparable geochemical dataset at the continental scale yields a compositionally similar PC1 (Ca, Sr, Mg, Cu, Au and Mo at one end; REEs and Th at the other) to that of the regional study. Mapping PC1 at the continental scale shows patterns that (1) are spatially compatible with the regional study and (2) reveal several geological regions of elevated values, possibly suggesting an enhanced potential for porphyry Cu–Au mineralisation. These include well-endowed mineral provinces such as the Curnamona and Capricorn regions, but also some greenfield regions such as the Albany-Fraser/western Eucla, western Murray and Eromanga geological regions. We conclude that the geochemical composition of Australia's regolith may hold critical information pertaining to mineralisation within/beneath it.     

Correlation between distribution and shape of VMS deposits and regional deformation patterns,Skellefte district,northern Sweden

The Skellefte district in northern Sweden is host to abundant volcanogenic massive sulphide (VMS) deposits comprising pyritic, massive, semi-massive and disseminated Zn–Cu–Au ± Pb ores surrounded by disseminated pyrite and with or without stockwork mineralisation. The VMS deposits are associated with Palaeoproterozoic upper crustal extension (D₁) that resulted in the development of normal faults and related transfer faults. The VMS ores formed as sub-seafloor replacement in both felsic volcaniclastic and sedimentary rocks and partly as exhalative deposits within the uppermost part of the volcanic stratigraphy. Subsequently, the district was subjected to deformation (D₂) during crustal shortening. Comparing the distribution of VMS deposits with the regional fault pattern reveals a close spatial relationship of VMS deposits to the faults that formed during crustal extension (D₁) utilising the syn-extensional faults as fluid conduits. Analysing the shape and orientation of VMS ore bodies shows how their deformation pattern mimics those of the hosting structures and results from the overprinting D₂ deformation. Furthermore, regional structural transitions are imitated in the deformation patterns of the ore bodies. Plotting the aspect ratios of VMS ore bodies and the comparison with undeformed equivalents in the Hokuroko district, Japan allow an estimation of apparent strain and show correlation with the D₂ deformation intensity of the certain structural domains. A comparison of the size of VMS deposits with their location shows that the smallest deposits are not related to known high-strain zones and the largest deposits are associated with regional-scale high-strain zones. The comparison of distribution and size with the pattern of high-strain zones provides an important tool for regional-scale mineral exploration in the Skellefte district, whereas the analysis of ore body shape and orientation can aid near-mine exploration activities.     

Tectonostratigraphy and base-metal mineralization controls, Aravalli province (western India): New interpretations from geophysical data analysis

Analysis and synthesis of multi-disciplinary geoscience information from geological literature/maps and from digitally-processed aeromagnetic and gravity data pertinent to the Aravalli province were carried out to address some hitherto unresolved questions about the tectonostratigraphy of this Archaean–Proterozoic metallogenic province. Based on the magnetic anomalies, several tectonic domains were identified. These domains, bounded by regional-scale geophysical lineaments, have distinct crustal, lithological, metamorphic, and metallogenic characteristics and correlate broadly with lithostratigraphic belts identified by several earlier workers. New interpretations on the tectonostratigraphy and the base-metal mineralization controls in the Aravalli province are as follows. The Hindoli sequences, in the eastern parts of the province, constitute an independent Palaeo–Proterozoic tectonic domain and do not form part of the Archaean basement complex. The base-metal-bearing metasedimentary enclaves in the central parts of the province also constitute an independent Palaeo–Proterozoic tectonic domain, which is quite distinct from the surrounding (basement complex?) rocks. The base-metal-bearing metavolcano-sedimentary sequences in the western parts of the province constitute an independent Neo–Proterozoic tectonic domain. The base-metal deposits in the province are spatially associated with the regional-scale lineaments and with the mafic metavolcanic rocks deduced from the aeromagnetic data. The regional-scale lineaments, which possibly represent Proterozoic crustal-scale faults, are plausible structural controls on the base-metal mineralization in the province. The mafic metavolcanic rocks are plausible heat-source controls on the SEDEX- and/or VMS-type base-metal mineralizations and are possible metal-source controls on the VMS-type base-metal mineralization in the province.     

Genesis of sediment-hosted stratiform copper–cobalt deposits, central African Copperbelt

The Neoproterozoic central African Copperbelt is one of the greatest sediment-hosted stratiform Cu–Co provinces in the world, totalling 140 Mt copper and 6 Mt cobalt and including several world-class deposits (10 Mt copper). The origin of Cu–Co mineralisation in this province remains speculative, with the debate centred around syngenetic–diagenetic and hydrothermal-diagenetic hypotheses.The regional distribution of metals indicates that most of the cobalt-rich copper deposits are hosted in dolomites and dolomitic shales forming allochthonous units exposed in Congo and known as Congolese facies of the Katangan sedimentary succession (average Co:Cu = 1:13). The highest Co:Cu ratio (up to 3:1) occurs in ore deposits located along the southern structural block of the Lufilian Arc. The predominantly siliciclastic Zambian facies, exposed in Zambia and in SE Congo, forms para-autochthonous sedimentary units hosting ore deposits characterized by lower a Co:Cu ratio (average 1:57). Transitional lithofacies in Zambia (e.g. Baluba, Mindola) and in Congo (e.g. Lubembe) indicate a gradual transition in the Katangan basin during the deposition of laterally correlative clastic and carbonate sedimentary rocks exposed in Zambia and in Congo, and are marked by Co:Cu ratios in the range 1:15.The main Cu–Co orebodies occur at the base of the Mines/Musoshi Subgroup, which is characterized by evaporitic intertidal–supratidal sedimentary rocks. All additional lenticular orebodies known in the upper part of the Mines/Musoshi Subgroup are hosted in similar sedimentary rocks, suggesting highly favourable conditions for the ore genesis in particular sedimentary environments. Pre-lithification sedimentary structures affecting disseminated sulphides indicate that metals were deposited before compaction and consolidation of the host sediment.The ore parageneses indicate several generations of sulphides marking syngenetic, early diagenetic and late diagenetic processes. Sulphur isotopic data on sulphides suggest the derivation of sulphur essentially from the bacterial reduction of seawater sulphates. The mineralizing brines were generated from sea water in sabkhas or hypersaline lagoons during the deposition of the host rocks. Changes of Eh–pH and salinity probably were critical for concentrating copper–cobalt and nickel mineralisation. Compressional tectonic and related metamorphic processes and supergene enrichment have played variable roles in the remobilisation and upgrading of the primary mineralisation.There is no evidence to support models assuming that metals originated from: (1) Katangan igneous rocks and related hydrothermal processes or; (2) leaching of red beds underlying the orebodies. The metal sources are pre-Katangan continental rocks, especially the Palaeoproterozoic low-grade porphyry copper deposits known in the Bangweulu block and subsidiary Cu–Co–Ni deposits/occurrences in the Archaean rocks of the Zimbabwe craton. These two sources contain low grade ore deposits portraying the peculiar metal association (Cu, Co, Ni, U, Cr, Au, Ag, PGE) recorded in the Katangan sediment-hosted ore deposits. Metals were transported into the basin dissolved in water.The stratiform deposits of Congo and Zambia display features indicating that syngenetic and early diagenetic processes controlled the formation of the Neoproterozoic Copperbelt of central Africa.     

The geochemistry, mineralogy and maturity of gossans derived from volcanogenic Zn–Pb–Cu deposits of the eastern Lachlan Fold Belt, NSW, Australia

The Eastern Highlands of Australia have probably been in existence since the Late Cretaceous or earlier and so there has been ample time for mature gossan profiles to form over outcropping volcanogenic Zn–Pb–Cu mineralisation in the eastern Lachlan Fold Belt. The mature gossan profiles are characterised by the upward progression from supergene sulfides to secondary sulfates, carbonates and phosphates into a Fe-oxide dominated surficial capping which may contain boxwork textures after the original sulfides (as at the Woodlawn massive sulfide deposit). However, the region has locally been subjected to severe erosion and the weathering profile over many deposits is incomplete (immature) with carbonate and phosphate minerals, especially malachite, being found in surficial material. These immature gossans contain more Cu, Pb and Zn but lower As, Sn (and probably Au) than the mature gossans. Although Pb is probably the best single pathfinder for Zn–Pb–Cu VHMS deposits of the eastern Lachlan Fold Belt, Ag, As, Au, Bi, Mo, Sb and Sn are also useful, with most of these elements able to be concentrated in substantial amounts in Fe oxides and alunite–jarosite minerals.     

Crustal lineament control on magmatism and mineralization in northwestern Argentina: geological, geophysical, and remote sensing evidence

The relationship between long-lived deep crustal lineaments and the locations of magmatic centers and associated mineral deposits has been investigated in the Puna region of northwestern Argentina, through the analysis of regional aeromagnetic surveys, Landsat images, and geological information. The good exposure and excellent preservation of basement and supracrustal geology in this region makes it particularly suitable for such a study. At a regional scale, several contrasting magnetic domains are recognized, which correlate with crustal geology. Two basement domains are separated by a NNE-trending boundary, which is believed to correlate with a Paleozoic suture zone between the Pampia (to the southeast) and Arequipa–Antofalla terranes (to the northwest). Locally overlying these basement terranes is the Cenozoic magmatic domain, which is best developed in the N–S-trending volcanic arc at the western edge of the Puna (the Cordillera Occidental). In addition, four southeast-trending volcanic zones extend for several hundred kilometers across the Puna. Many important mineral deposits and areas of hydrothermal alteration are associated with these volcanic breakouts, and we have selected three such areas for more detailed study: Bajo de la Alumbrera (Argentina's largest porphyry copper deposit), Cerro Galán (the largest ignimbrite caldera in Argentina, with associated hydrothermal alteration zones), and El Queva (a historic polymetallic district located within a major volcanic range). A comparison of lineament maps generated from aeromagnetic and Landsat TM images reveals broad correlation between these different remote sensing techniques, which respectively highlight subsurface magnetic and surface geological features. In addition, the locations of magmatic and hydrothermal centers can be related to the interpreted structural framework, and are seen to occur near the intersections of major lineament zones. It is suggested that in three dimensions, such intersection zones form trans-lithospheric columns of low strength and high permeability during transpressional or transtensional tectonic strain, and may thereby serve as conduits for magma ascent to the shallow crust. Pooling of large volumes of deeply derived magma in shallow crustal magma chambers may then result in voluminous devolatilization and the formation of hydrothermal mineral deposits. It is important to note that in this model, structural intersections serve as facilitators for magma ascent and volatile exsolution, but do not in themselves cause this process—other factors such as magma supply rate and tectonic stress are essential primary ingredients, and local magmatic and volcanic processes affect the ultimate potential for ore formation. Nevertheless, we suggest that lineament analysis provides a valuable framework for guiding the early stages of mineral exploration; other regional and local geological considerations must then be applied to identify priority targets within this framework.     

鄂西北地区银金多金属矿床地质特征与成矿规律

鄂西北地区指湖北省武当山及其西北部等地,位于青峰断裂北侧,是秦岭成矿带的重要组成部分,以产银、金等多金属而闻名,蕴含了银洞沟、许家坡、佘家院、六斗等大中型银金(铅锌)或金(锑)矿床。根据区内矿床分布特征及控制因素,以十堰—鲍峡断裂为界将其划分为北带与南带。北带多以金、金锑矿床为主,沿郧阳—郧西断裂两侧分布,矿床多产在上覆陡山沱组地层和古生界地层中;南带主要有银洞沟银金矿床、许家坡金银矿床,矿床集中产于新元古界武当山群。区内矿床均受NW向韧性韧脆性剪切带及其次级断裂控制。碳氢氧同位素组成显示区内银金、金矿床成矿流体以变质热液为主,后期混入了大气降水,而金锑矿床可能为大气降水主导。硫同位素组成显示成矿流体的区域活动性和地层硫源特征。根据成矿元素的富集特征,下伏武当山群Cu、Pb、Zn、Au、Ag元素富集,在上覆陡山沱组、灯影组及古生界地层中依次出现Ag-Au、Au-Ag、Au、Au-Sb矿床,而在研究区西部的陕西境内泥盆纪地层有大量的Au-Sb、Hg-Sb矿。区内成矿元素的垂向分布特征符合地壳连续模式,矿床形成与地层本身具有较高丰度有密切联系,并在构造控制下就位。结合矿床地质、成矿流体及成矿时代,认为鄂西北地区银金、金、金锑矿床是形成于三叠纪古特提斯洋缝合过程中洋陆增生体制下的造山型矿床。