Extended Sediment Quality Rating for Trace Elements in Urban Waters – Case Study Klinke,Germany

The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.     

Ultrasound‐Assisted Emulsification–Microextraction Combined with Graphite Furnace Atomic Absorption Spectrometry for the Determination of Trace Lead in Water

The ultrasound‐assisted emulsification–microextraction (USAEME) method was combined with graphite furnace atomic absorption spectrometry (GFAAS) for the determination of trace Pb using dithizone (H²DZ) as chelating reagent. Some effective parameters influenced the detection and microextraction, such as ashing temperature and atomization temperature, pH, extraction solvent, sample volume, extraction time, and extraction temperature were selected and optimized. After extraction, the calibration curves for Pb was in the concentration range of 0.1–10 ng mL^?1, and the linear equation was y = 0.097 x + 0.023 (R = 0.99). Under the optimized conditions, the detection limit of the method was 20 pg mL^?1 with an enrichment factor of 70 and the relative standards deviation (RSD) for seven determinations of 1 ng mL^?1 Pb was 11%. The proposed method was successfully applied to determine trace Pb in Yueya Lake water, pond water, and spiked samples. Furthermore, a certified reference material of Environment Water (GBW08607) was analyzed and the determined value was in good agreement with the certified value, which showed the accuracy, recovery, and applicability of the reported method.     

Forecasting Hourly Roadside Particulate Matter in Taipei County of Taiwan Based on First‐Order and One‐Variable Grey Model

In this study, seven types of first‐order and one‐variable grey differential equation model (abbreviated as GM (1, 1) model) were used to forecast hourly roadside particulate matter (PM) including PM₁₀ and PM_2.5 concentrations in Taipei County of Taiwan. Their forecasting performance was also compared. The results indicated that the minimum mean absolute percentage error (MAPE), mean squared error (MSE), root mean squared error (RMSE), and maximum correlation coefficient (R) was 11.70%, 60.06, 7.75, and 0.90%, respectively when forecasting PM₁₀. When forecasting PM_2.5, the minimum MAPE, MSE, RMSE, and maximum R‐value of 16.33%, 29.78, 5.46, and 0.90, respectively could be achieved. All statistical values revealed that the forecasting performance of GM (1, 1, x⁽⁰⁾), GM (1, 1, a), and GM (1, 1, b) outperformed other GM (1, 1) models. According to the results, it revealed that GM (1, 1) was an efficiently early warning tool for providing PM information to the roadside inhabitants.     

MAPGIS软件在矿区重金属元素环境累积效应研究的应用

矿产资源开发引起的重金属污染是人们对资源利用过程中主要环境问题之一。如今,重金属污染的问题已经十分严重,时刻威胁着我们的生活质量。如何通过模拟分析等手段,借助“3S”技术,达到对矿区重金属元素环境累积效应危害的研究分析是当前重要的课题。针对MAPGIS6.7制图工作的一点经验做以总结,旨在使矿区环境污染研究者了解MAPGIS软件在研究重金属环境累积效应中的一点应用。     

临汾市树叶磁性的时空变化特征及其对大气重金属污染的指示

粉煤灰经工厂废气排放进入大气,对人类健康和生态系统都造成了无法弥补的破坏.本文选取具有高空间分辨率优势的树叶作为收集粉煤灰的载体,对临汾市大气中可吸入颗粒物进行磁学参数和重金属含量监测.结果表明,磁化率最大值出现在工厂污染源附近,磁化率空间分布呈现随污染源距离增加而降低的趋势.工业区收集到的磁性颗粒以低矫顽力、粗粒度的磁铁矿为主.夏季磁性矿物来源单一,主要为人为影响.冬季大气中悬浮的磁性颗粒有部分来自于西北风/北风的自然尘降.同一采样点磁化率随时间变化特征表明,树叶的磁学性质可以灵敏和有效地反映较短时期内大气污染的现状.统计分析表明磁化率和重金属元素(铁,铬,镍,铜,铅,钴)之间存在显著相关性.污染负荷指数用于评估研究区域内重金属各元素综合污染的程度.结果显示,在废弃的旧工业区附近无大气污染指示,但在运营中的工厂集中的地区,大气均受到严重污染.污染负荷指数与表征磁性矿物含量的磁化率呈相关性(r2=0.66),因此树叶的磁性参数可以作为大气重金属污染的替代指标.     

Use of the Anion‐Exchange Resin Amberlite IRA‐93 for the Separation of Arsenite and Arsenate in Aqueous Samples

The method described uses the separation of As(III) and As(V) species in aqueous samples by means of the anion‐exchange resin Amberlite IRA‐93. The samples were acidified using acetic acid and passed through a glass column filled with pre‐treated Amberlite IRA‐93 resin. As(III) was poorly adsorbed on the anionic exchanger material, whereas As(V) was retained. The arsenic concentration was measured in the column effluent by graphite furnace AAS (GF‐AAS). The retained As(V) was eluted from the column using 1 M NaOH. Prior to the determination of the As(V) concentration in the NaOH eluate, the eluate was passed through a glass column filled with a cation‐exchange resin (Amberlite 200) to remove sodium ions and minimize the Na⁺ interference with the AAS determination. After calibration the method was applied to the separation of As(III) and As(V) species in two aqueous extracts of arsenic contaminated soils. The results were compared with those obtained from an on‐line separation and determination of As(III) and As(V) in the aqueous soil extracts using a state of the art HPLC‐ICP‐MS system.     

Assessment of Trace Metal Contamination of Drinking Water in the Pearl Valley,Azad Jammu and Kashmir

The aim of this study was to assess trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir (Pakistan). The objectives were to determine physical properties and the dissolved concentration of five trace metals, i. e., lead, copper, nickel, zinc, and manganese, in drinking water samples collected from various sites of municipal water supply, natural water springs and wells in the valley. Concentrations of the metals in the water samples were determined by flame atomic absorption spectrometry. Results showed physical parameters, i. e., appearance, taste and odor within acceptable limits and pH was between 5.5 and 7.0. The observed concentrations of the metals varied between sources of water samples and between sampling sites. Maximum dissolved concentration observed was 4.7 mg/L for Pb and Mn, 4.6 mg/L for Zn, 2.9 mg/L for Ni and 2.8 mg/L for Cu. The observed concentrations of the metals were compared with the World Health Organization's guideline values for drinking water. Overall, the quality of water samples taken from the water springs at Mutyal Mara and Bonjosa was good; however, the water quality was unsuitable for drinking in Kiraki, Kharick, and Pothi Bala localities particularly. Finally, the authors discuss possible causes for increased concentrations of the trace metals in drinking water in the study area.     

Effect of land‐use changes on nonpoint source pollution in the Xizhi River watershed,Guangdong, China

The Annualized Agricultural Non‐point Source (AnnAGNPS) pollution model has been widely used to assess and predict runoff, soil erosion, sediment and nutrient loading with a geographic information system. This article presents a case study of the effect of land‐use changes on nonpoint source (NPS) pollution using the AnnAGNPS model in the Xizhi River watershed, eastern Pearl River Delta of Guangdong province, China. The land‐use changes in the Xizhi River watershed between 1998 and 2003 were examined using the multitemporal remote sensing data. The runoff, soil erosion, sediment transport and nutrient loading 1998 and 2003 were assessed using AnnAGNPS. The effects of land‐use changes on NPS were studied by comparing the simulation results of each year. Our results showed that (i) the NPS loadings increased when forest and grass land converted into paddy, orchard and farmland land, and population size and gross domestic product size as well as the usage amounts of fertilizer and pesticide in the entire watershed were firmly correlated with the NPS loadings; (ii) the land‐use change during fast urbanization in particular when other land types were converted into the development land and buildup land led to increasing of NPS pollution; and (iii) urban land expansion showed more important effects on total organic carbon (TOC) loading compared with nitrogen and phosphorus loadings. Copyright © 2012 John Wiley & Sons, Ltd.     

Heavy metal pollution and assessment in the tidal flat sediments of Haizhou Bay,China

The heavy metal inventory and the ecological risk of the tidal flat sediments in Haizhou Bay were investigated. Results show that the average concentrations of heavy metals in the surface sediments exceeded the environment background values of Jiangsu Province coastal soil, suggesting that the surface sediments were mainly polluted by heavy metals (Cd, Cr, Cu, Mn, Pb and Zn). In addition, the profiles of heavy metals fluxes can reflect the socio-economic development of Lianyungang City, and heavy metals inputs were attributed to anthropogenic activities. Cr, Cu, Pb and Zn were mainly present in the non-bioavailable residual form in surface sediments, whereas Cd and Mn were predominantly in the highly mobile acid soluble and reducible fractions. The ecological risk of the polluted sediments stemmed mainly from Cd and Pb. According to the Sediment quality guidelines (SQGs), however, the adverse biological effects caused by the heavy metals occasionally occurred in tidal flat.     

Comparison of Pb(Ⅱ) and Cd(Ⅱ) micro-interfacial adsorption on fine sediment in the Pearl River Basin,China

The complex micro-interfacial interaction theories of heavy metal ions such as Pb(Ⅱ)and Cd(Ⅱ)adsorption on fine sediment in aqueous solution were not systematically investigated.The aim of this work was to reflect the micro-interfacial adsorption characteristics.Sediment samples were collected from an estuary.The Isothermal and kinetics adsorption experiment were done to acquire the data.Isothermal,kinetics,film diffusion and intraparticle diffusion models were adopted to fit the adsorption experimental data.The results indicated that the Langmuir,Freundlich and Temkin models were suitable for analyzing the isothermal experimental data.The maximum adsorption capacities of Pb(Ⅱ)and Cd(Ⅱ)on the sediment were 1.1377 and 0.9821 mg·g-1,respectively.The qm and KL of the Langmuir model,Kf and nF of the Freundlich model,and b and A of the Temkin model all exhibited a power function relationship with the initial adsorbate concentration.The pseudo-second-order model provided a better fit for the experimental kinetics data compared with the fit of the pseudo-first-order and Elovich models.The pseudo-second-order parameters k2 and qe of Pb(Ⅱ)and qe of Cd(Ⅱ)both had a power function relationship with adsorption time,additionally,the k2 of Cd(Ⅱ)had an exponential function relationship with adsorption time.The liquid-film diffusion parameters kfd of Pb(Ⅱ)and Cd(Ⅱ)were 0.0569 and 0.1806 min
1,respectively.The intraparticle diffusion parameter kid values of Pb(Ⅱ)and Cd(Ⅱ)were 0.0055 mg$g
1$min1/2 and 0.0049 mg$g
1$min1/2,respectively.The physical significance of the model parameters showed that Pb(Ⅱ)adsorption on sediment was stronger than Cd(Ⅱ).The results of this study provided a theoretical reference for the micro-interfacial mechanism of heavy metal ion adsorption on sediment.     

Distribution Study of U,V, Mo,and Zr in Different Sites of Lakes Van and Hazar,River and Seawater Samples by ICP‐MS

The aim of this study is to investigate the concentrations of U, Th, V, Mo, and Zr in natural waters taken from Turkey. Among these water species, Lake Van is the largest soda lake and the fourth largest closed basin on Earth. The water samples were collected from 51 locations between 2008 and 2009. The inductively coupled plasma‐MS was used for determinations. The obtained U and Zr concentrations are in the range of 37–110 µg L^?1 and 17–78 µg L^?1 in Lake Van and 0.53–0.81 µg L^?1 and 0.15–0.19 µg L^?1 in Lake Hazar, respectively. The concentration of uranium in other studied waters varies from the lowest 0.09 µg L^?1 in Tigris (Dicle) river to the highest 4.0 µg L^?1 in Mediterranean Sea water. Mean Mo and V concentrations in the studied water samples were found to be in ranges of 0.1–17 and 2.7–113 µg L^?1, respectively. The obtained highest U concentration in Lake Van correlates with the highest Mo and Zr levels compared to the Lake Hazar and river waters. These results imply that there is a young occurrence of uranium minerals around Lake Van. It is concluded that there is about 50.000 ton of uranium in Lake Van water.     

Effects of Lime‐Based Waste Materials on Immobilization and Phytoavailability of Cadmium and Lead in Contaminated Soil

Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.     

The impact of the October–November 2000 floods on contaminant metal dispersal in the River Swale catchment,North Yorkshire,UK

During the autumn of 2000, large areas of England and Wales were affected by severe flooding, which caused widespread disruption and significant damage to property. This study attempts to determine the impact of these flood events on contaminated sediment dispersal and deposition in the River Swale catchment, Yorkshire, UK, where lead and zinc were extracted and processed in large quantities during the nineteenth century. Seventy samples of overbank and channel‐edge sediments were collected at 35 sites along the River Swale. Inductively coupled plasma‐mass spectrometry was used to measure contaminant metal concentrations in the 2000–63 µm (sand) and <63 µm (silt and clay) size fractions. In both the channel‐edge and overbank sediments collected from the upper and middle reaches of the River Swale, concentrations of lead, zinc and cadmium were found to exceed MAFF guidelines. Highest concentrations correspond to the input of contaminated material from intensively mined tributaries, and elevated levels can be observed 5–10 km downstream of these inputs. This indicates that the remobilization of contaminated material during major flood events is potentially a serious problem for activities such as agriculture that utilize the Swale floodplain. Copyright © 2003 John Wiley & Sons, Ltd.     

The Role of Particulate Matter in the Mobilization of Trace Metals during Anaerobic Digestion of Solid Waste Material Die Bedeutung der partikulären Substanz für die Mobilisierung von Spurenmetallen beim anaeroben Abbau fester Abfallstoffe

Metal ions bound to particulate matter represent the greatest portion (i.e. > 95%) of the total metal content found in leachate from reactor experiments where solid waste material was anaerobically digested. This seems true even though strong complexing agents are in solution which increase the solubility of Pb and Cu by a factor up to 10⁴… 10⁵ over that theoretically predicted according to the solubility of the corresponding sulfide mineral. A titrimetric characterization of the metal ion binding sites of the particulate matter suggests that the metal binding properties of the particulate matter are mainly due to organic, aminoacid-type compounds (amines. thio groups, carboxylic groups) probably of bacterial origin. The change of the concentration of the binding sites with time, together with the change of the composition of the particulate matter indicates that bacterial flocs are suspended in the leachate during the switch from acidogenic to methanogenic conditions — either due to the detachment of bacterial films from the solid material by the intensive gas production or due to the formation of syntrophic methanogenic bacterial associations or a combination of both. A combination of the two factors, strong affinity of bacterial mass to metal ions on the one hand, and suspending of the bacterial mass in the leachate on the other hand, will therefore imply a great mobilizing potential for trace metals. Consequently, the highest concentrations of particulate bound Cd were found in reactor experiments where sewage sludge contaminated with Cd was added to the waste material. An increase of the concentration of dissolved cadmium over the solubility of cadmium sulfide, however, could not be observed.     

A Dynamic Model to Simulate Arsenic,Lead, and Mercury Contamination in the Terrestrial Environment During Extreme Floods of Rivers

Beside damages of infrastructure in industrial regions, extreme floods can cause contamination with particle‐bound pollutants, e. g., due to erosion of soils and sediments. In order to predict contamination with inorganic pollutants, the transport and fate of arsenic, lead, and mercury during a fictive flood event of River Vereinigte Mulde in the region of Bitterfeld (Germany) with 200 years recurrence time was modeled. The finite element model system Telemac2D, which is subdivided into a hydrodynamic (Telemac‐2D), a transport (Subief‐2D), and a water quality module (wq2subief) was applied. The transport and water quality model models were calibrated using results of sediment trap exposures in the floodplain of River Vereinigte Mulde. Model results exhibited that the spatial patterns of particle‐associated arsenic and lead concentrations significantly changed. Extended, mostly agriculturally used areas showed arsenic and lead concentrations between 150 and 200 mg kg^–1 and 250 and 300 mg kg^–1, respectively, while urban areas were to a great extent spared from high contamination with arsenic and lead. Concentrations of particle‐associated mercury showed a pattern distinct from those of arsenic and lead. Outside of small patches with concentrations up to 63 mg kg^–1, concentrations of particle‐associated mercury remained close to zero. Differences in the spatial patterns of the three pollutants regarded mainly arise from significantly different initial and boundary conditions. Sensitivity analyses of initial and boundary conditions revealed a high sensitivity of particle‐bound pollutant concentrations, whereas the sensitivities of concentrations of suspended sediments and soluble pollutants were mediocre to negligible.