Grading Woodland Soil Water Productivity and Soil Bioavailability in the Semi‐Arid Loess Plateau of China

In the semi‐arid region of the Loess Plateau in China, a portable photosynthesis system (Li‐6400) and a portable steady porometer (Li‐1600) were used to study the quantitative relation between the soil water content (SWC) and trees' physiological parameters including net photosynthesis rate (P_n), carboxylation efficiency (CE), transpiration rate (T_r), water use efficiency of leaf (WUE_L), stomatic conductivity (G_s), stomatal resistance (R_s), intercellular CO₂ (C_i), and stomatal limitation (L_s). These are criteria for grading and evaluating soil water productivity and availability in forests of Black Locust (Robinia pseudoacacia) and Oriental Arborvitae (Platycladus orientalis). The results indicated: To the photosynthesis of Locust and Arborvitae, the SWC of less than 4.5 and 4.0% (relative water content (RWC) 21.5 and 19.0%) belong to “non‐productivity and non‐efficiency water”; the SWC of 4.5–10.0% (RWC 21.5–47.5%) and 4.0–8.5% (RWC 19.0–40.5%) belong to “low productivity and low efficiency water”; the SWC of 10.0–13.5% (RWC 47.5–64.0%) and 8.5–11.0% (RWC 40.5–52.0%) belong to “middle productivity and high efficiency water”; the SWC of 13.5–17.0% (RWC 64.0–81.0%) and 11.0–16.0% (RWC 52.0–76.0%) belong to “high productivity and middle efficiency water”; the SWC of 17.0–19.0% (RWC 81.0–90.5%) and 16.0–19.0% (RWC 76.0–90.5%) belong to “middle productivity and low efficiency water”; the SWC of more than 19.0% (RWC 90.5%) belongs to “low productivity and low efficiency water”. The SWC of about 13.5 and 11.0% (RWC 64.0 and 52.0%) are called “high productivity and high efficiency water”, which provides the further evidence for Locust and Arborvitae to get both higher productivity (P_n and CE) and the highest WUE_L and adaptation to the local environment, respectively.     

Five‐Year Soil Respiration Reflected Soil Quality Evolution in Different Forest and Grassland Vegetation Types in the Eastern Loess Plateau of China

Soil CO₂ efflux in forest and grassland over 5 years from 2005 to 2009 in a semiarid mountain area of the Loess plateau, China, was measured. The aim was to compare the soil respiration and its annual and inter‐annual responses to the changes in soil temperature and soil water content between the two vegetation types for observing soil quality evolution. The differences among the five study years were the annual precipitation (320.1, 370.5, 508.8, 341.6, and 567.4 mm in 2005–2009, respectively) and annual distribution. The results showed that the seasonal change of soil respiration in both vegetation types was similar and controlled by soil temperature and soil water content. The mean soil respiration across 5 years in the forest (3.78 ± 2.68 µmol CO₂ m^?2 s^?1) was less than that in the grassland (4.04 ± 3.06 µmol CO₂ m^?2 s^?1), and the difference was significant. The drought soil in summer depressed soil respiration substantially. The Q₁₀ value across 5‐year measurements was 2.89 and 2.94 for forest and grassland. When soil water content was between wilting point (WP) and field capacity (FC), the Q₁₀ in both types increased with increasing soil water content, and when soil water content dropped to below WP, soil respiration and the Q₁₀ decreased substantially. Although an exponential model was well fitted to predict the annual mean soil respiration for each single year data, it overestimated and underestimated soil respiration, respectively, in drought conditions and after rain for short periods of time during the year. The two‐variable models including temperature and water content variables could be well used to predict soil respiration for both types in all weather conditions. The models proposed are useful for understanding and predicting potential changes in the eastern part of Loess plateau in response to climate change.     

Impacts of Coal Mining on the Aboveground Vegetation and Soil Quality: A Case Study of Qinxin Coal Mine in Shanxi Province,China

The exploitation and utilization of coal resources have been lasting for thousands of years, resulting in a series of ecological environmental problems in China. So far, the mining area has changed into severe and typical damaged ecosystem locally and globally. The coal exploitation history is long in Shanxi province, but goafs are distributed widely. In this study, we addressed this point and took a coal mine, located in Shanxi province where the coal mining has a long exploitation history with goaf densely distributed, as an example. The growth patterns of above ground plant communities, succession characteristics of vegetation community and soil quality characters in the goafs, which could provide theoretical basis for the sustainable development of coal resources and ecological reconstruction in this region, have been studied.     

Evaporation Process in Soil Surface Containing Calcic Nodules on the Northern Loess Plateau of China by Simulated Experiments

Soil containing calcic nodules is widely present on the northern Loess Plateau of China owing to soil genesis under local climate conditions. In most studies, little attention is payed to the effect of calcic nodules on soil evaporation and ecoenvironment, resulting in inaccurate evaporation estimation in this kind of soil and further improper field water management measures and irrigation effects. In this paper, soil column experiments were conducted in order to investigate evaporation process in soil containing calcic nodules and the effect of calcic nodules on soil evaporation was determined. The results indicated that evaporation reduction was positively related to calcic nodule content (CNC = mass of calcic nodules/total mass), and could be estimated by the experiential equation: E_soil = E₀ (1 – 0.4 CNC) (E_soil = actual evaporation, E₀ = theory evaporation in soil without calcic nodules). When CNC was below 0.2, the impact could be neglected. While, as CNC exceeded 0.2, the impact needed to be considered during soil evaporation estimation. As CNC reached 0.5, soil evaporation could be reduced by 7.5 mm, accounting for around 10% of the total soil water. Water balance calculation in soil columns showed that water absorbed by calcic nodules was partially available to evaporation. Water available to evaporation was positively related to CNC, and this water could not exceed 63% of the water absorbed by calcic nodules. Generally, evaporation behavior was dominated by calcic nodule quantity and its water absorption. These results provide new ideas for irrigation measures in arid areas of the globe.     

Modifying Transition Matrix to Evaluate Soil Quality: A Case Study in Karst Region in the West‐Southern China

The soil aggregate stability is a key property of soil quality and reflects soil quality and anti‐erosion ability. The transition matrix between initial and final aggregates condition was established by modifying Niewczas and Witkowska‐Walczak's method by not considering the artificial weights and each size of aggregates fraction on the basis of three reasonable assumptions, and soil aggregate stability index (ASI) was formed through preserving each size of aggregates probability. This ASI is identical to the result by reference, and the transition matrix can be showed to evaluate the soil aggregates stability. Using the transition matrix was furthermore to analyze anti‐breaking ability of different size aggregate by reference material. We found there were different effects for each size aggregate by four methods, simulation rainfall, one cycle of wetting–drying, ten cycles of wetting–drying, and Yoder wetting–sieving. The Yoder wetting–sieving is a severe method that destructed soil aggregates. The ASI by modifying transition matrix method was used to evaluate the aggregates stability under different land utilization in Karst region in Chongqing, China. The ASI of agricultural utilization was lower than abounded cultivated land, shrub‐grass land, secondary forest land, and primeval forest land. For some selected soil properties, when SOM content was <60 g/kg, ASI increased along with the SOM increase. Once the SOM content was >60 g/kg, the ASI was almost unchanged. The sorption moisture content of air‐drying acutely affected ASI too, and the ASI increased along the sorption moisture increasing. SOM content and sorption markedly affected the preserving probability of larger aggregates such as 10–5, 5–3, 3–2, 2–1, and 1–0.5 mm size class. Although CaCO₃ and clay content did not influence preserving probability of each size class of aggregates fiercely, but the influence on small aggregates was higher than that of larger aggregates. The modified transition matrix method could not only calculate soil aggregates stability index, but also analyze more parameters of aggregate experiment, and bring out the each size aggregates characteristics. Thus, the modified transition matrix method could be a better tool to understand soil quality.     

Soil moisture variation in relation to topography and land use in a hillslope catchment of the Loess Plateau, China

The profile characteristics and the temporal dynamics of soil moisture variation were studied at 26 locations in Da Nangou catchment (3.5 km²) in the loess area of China. Soil moisture measurements were performed biweekly at five depths in the soil profile (0–5, 10–15, 20–25, 40–45 and 70–75 cm) from May to October 1998 using Delta-T theta probe. Soil moisture profile type and temporal variation type and their relationship to topography and land use were identified by detrended canonical correspondence analysis (DCCA) and correlation analysis. The profile distribution of time-averaged soil moisture content can be classified into three types i.e. decreasing-type, waving-type and increasing-type. The profile features of soil moisture (e.g. profile gradient and profile variability) are influenced by different environmental factors. The profile type of soil moisture is only attributed to land use while profile gradient and profile variability of soil moisture is mainly related to land use and topography (e.g. landform type and slope). The temporal dynamics of layer-averaged soil moisture content is grouped into three types including three-peak type, synchro-four-peak type and lagged-four-peak type. These types are controlled by topography rather than by land use. The temporal dynamic type of soil moisture shows significant correlation with relative elevation, slope, aspect, while temporal variance displays significant relation with slope shape. The mean soil moisture is related to both the profile and dynamics features of soil moisture and is controlled by both land use and topography (e.g. aspect, position, slope and relative elevation). The spatial variability of soil moisture across landscape varies with both soil depths and temporal evolution.     

Seasonal variations in infiltrability of moss‐dominated biocrusts on aeolian sand and loess soil in the Chinese Loess Plateau

Biocrust effects on soil infiltration have attracted increasing attention in dryland ecosystems, but their seasonal variations in infiltrability have not yet been well understood. On the Chinese Loess Plateau, soil infiltrability indicated by saturated hydraulic conductivity (K_s) of biocrusts and bare soil, both on aeolian sand and loess soil, was determined by disc infiltrometer in late spring (SPR), midsummer (SUM), and early fall (FAL). Then their correlations with soil biological and physiochemical properties and water repellency index (RI) were analysed. The results showed that the biocrusts significantly decreased K_s both on sand during SPR, SUM, and FAL (by 43%, 66%, and 35%, respectively; P < .05) and on loess (by 42%, 92%, and 10%, respectively; P <.05). As compared with the bare soil, the decreased K_s in the biocrusted surfaces was mostly attributed to the microorganism biomass and also to the increasing content of fine particles and organic matter. Most importantly, both the biocrusts and bare soil exhibited significant (F ≥ 11.89, P ≤ .003) seasonal variations in K_s, but their patterns were quite different. Specifically, the K_s of bare soil gradually decreased from SPR to SUM (32% and 42% for sand and loess, respectively) and FAL (29% and 39%); the K_s of biocrusts also decreased from SPR to SUM (59% and 92%) but then increased in FAL (36% and 588%). Whereas the seasonal variations in K_s of the biocrusts were closely correlated with the seasonal variations in RI, the RI values were not high enough to point at hydrophobicity. Instead of that, the seasonal variations of K_s were principally explained by the changes in the crust biomass and possibly by the microbial exopolysaccharides. We conclude that the biocrusts significantly decreased soil infiltrability and exhibited a different seasonal variation pattern, which should be carefully considered in future analyses of hydropedological processes.     

Assessing the spatial and temporal variation of the rainwater harvesting potential (1971–2010) on the Chinese Loess Plateau using the VIC model

Rainwater harvesting could increase the resilience of ecosystems on the Loess Plateau and thus ensure the sustainability of livelihoods that depend on them. As such, it is a key component of strategies for adapting to global climate change. In this study, we used a new method to quantify the rainwater harvesting potential (RWHP) across the whole Loess Plateau and to characterize its spatial and temporal variation over the last four decades on the basis of the variable infiltration capacity model. It was found that that the mean RWHP of the study region was 731.10 × 10⁸ m³, and the average water layer thickness was 114.34 mm. There is considerable scope for rainwater harvesting across the Loess Plateau as a whole, to the extent that it could potentially provide enough water to implement the ‘Grain for Green’ Project. The annual average RWHP decreased slightly from 1971 to 2010, and Hurst exponent analysis indicated that this trend will exhibit long‐term persistence. The annual RWHP was highest in the southeast of the Loess Plateau and lowest in the northwest. Areas with high RWHP values tended to be clustered around the middle reach of the Yellow River. For most areas, there was no significant change between 1971 and 2010. Those areas for which there was a significant decrease in RWHP were primarily located around the upper–middle reaches of the Weihe River, the upper reach of Jinghe River, the eastern Guanzhong Plain, the Qinhe River watershed and the area around Dongsheng. Quantitative assessments of RWHP are likely to be useful for guiding the development and use of innovative rainwater harvesting technologies around the world and could help to relieve the problems caused by water shortages on the Loess Plateau while simultaneously eliminate the major cause of soil erosion. Copyright © 2012 John Wiley & Sons, Ltd.     

Soil seed bank composition and distribution on eroded slopes in the hill‐gully Loess Plateau region (China): influence on natural vegetation colonization

On the Chinese Loess Plateau, serious slope and gully erosion have caused a decrease in soil water capacity and fertility, which has resulted in vegetation degradation and a reduction in agricultural productivity. Great efforts have been made to restore vegetation to control soil erosion, but the efficiency of artificial revegetation is not satisfactory. Natural revegetation is an alternative. However, while soil seed banks are an essential source for natural revegetation, their composition and distribution on eroded slopes remains unknown. In addition, whether or not seed loss during soil erosion limits vegetation colonization is also unknown. In this work, soil seed bank composition and distribution were studied in three situations. Specifically, three main microsites were selected as sampling plots: fish‐scale pits, as artificial deposited micro‐topography; under tussocks, as trap microsites; and open areas, as eroded areas. Soil samples were collected at depths of 0–2 cm, 2–5 cm and 5–10 cm. The soil seed bank was identified using germination experiments, and a total of 34 species were identified. The dominant species in the soil seed bank were annual/biennial herbs with an average proportion more than 90% and density reaching 19,000 seeds m^‐2. The pioneer species Artemisia scoparia was especially abundant. The dominant later successional species, such as Lespedeza davurica, Artemisia giraldii, Artemisia gmelinii, Stipa bungeana and Bothriochloa ischcemum, were present in the soil at a density that ranged from 38 to 1355 seeds m^‐2. Compared with the eroded open areas, the fish‐scale pits retained a higher density of seeds, and the tussocks retained a larger number of species. However, there was no serious reduction of the soil seed bank in the erosion areas. The present study indicates that, on these eroded slopes, the soil seed bank is not the key factor limiting the colonization of natural vegetation. Copyright © 2011 John Wiley & Sons, Ltd.     

Determination of Polycyclic Aromatic Hydrocarbons in Soil by Miniaturized Ultrasonic Extraction and Gas Chromatography‐Mass Selective Detection

A miniaturized ultrasonic extraction procedure was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in soil by gas chromatography‐mass spectrometry. After determination of the most suitable extraction solvent with 5 min sonication time, several other parameters (sample amount, solvent volume and number of extraction times) were optimized using a 2³ factorial experimental design. Recoveries of PAHs from spiked soil samples were over 90% for three different fortification levels between 50 and 300 μg/kg, and relative standard deviations of the recoveries were in the range of < 1–15%. The limits of detection ranged from 0.002 to 1.87 μg/kg. The performance of the developed procedure was also compared with other traditional Soxhlet, shake flask and large scale ultrasonic extraction procedures on real soil samples, and extraction methods showed comparable efficiencies. The proposed procedure required small volumes of solvent and sample. It was practicable, rapid and easy to use for analysis of PAHs in soils.     

Spatiotemporal analysis of climate variability (1971–2010) in spring and summer on the Loess Plateau,China

By using the Variable Infiltration Capacity model with Palmer Drought Severity Index (VIC‐PDSI) model and Standardized Precipitation Index (SPI), spatiotemporal trends of climate variation during the main growing seasons for plants of Loess Plateau between 1971 and 2010 were detected and characterized. The VIC‐PDSI model is established by combining the VIC model with PDSI. The simulation results and the grids system of VIC were applied to substitute for the two‐layer bucket‐type model to do the hydrological accounting, which could improve the physical mechanism of PDSI and expand its application range. Our results suggest that the climate of the study area has experienced a drying and warming trend during the past four decades. Apart from some individual years and regions, there was a perpetuation of water deficit over the Plateau both in spring and summer. The drought frequency increased from southeast to northwest in spring, while the drought frequency decreased from southeast to northwest in summer. The climate in the southern part of the Loess Plateau, accounting for 23.3% of the study region, showed a significant drying and warming trend in spring over the past four decades. The climate variability detected by VIC‐PDSI model shows good agreement with that monitored by SPI. Since a large part of the study region frequently suffered from water shortage during the main growing seasons for plants, people living in such drought‐prone areas should take measures to prevent the negative effects on agricultural production, reforestation, and regional food security caused by drought. Copyright © 2013 John Wiley & Sons, Ltd.     

A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.     

New Strategy to Reduce the Harmful Effects of Smoking: Reducing the Level of N‐nitrosamines in Mainstream Smoke by NaA Zeolite and In vitro and In vivo Investigations

A new effort to control the pollution caused by smoking by use of zeolite sieving the N‐nitrosamines in smoke is depicted and assessed in this paper, which is a first preliminary approach to demonstrate the performance characteristics of zeolite for the reduction of the concentration of N‐nitrosamines in the cigarette smoke. Smoking causes global pollution and is difficult to control because smoke is a complex system containing thousands of components. A new strategy is presented here for the reduction of the harmful effects of smoking through dispersion of zeolite into the tobacco rod of cigarettes to eliminate the N‐nitrosamines once they form in the smoke, and both in vitro and in vivo tests were employed to check the efficiency of this strategy. The impact of zeolite on the combustion of tobacco and the total toxicity of smoke are evaluated for the first time. Lower mutagenic activity and higher CHO cell livability were found for the test cigarette containing zeolite in comparison with the control, and no significant damage was detected in 30‐day animal experiments when exposed to the cigarette smoke. This confirms the feasibility of the new strategy and promotes the potential application of zeolite for protecting public health.