Progressive failure of sheeted rock slopes: the 2009–2010 Rhombus Wall rock falls in Yosemite Valley,California, USA

Progressive rock‐fall failures in natural rock slopes are common in many environments, but often elude detailed quantitative documentation and analysis. Here we present high‐resolution photography, video, and laser scanning data that document spatial and temporal patterns of a 15‐month‐long sequence of at least 14 rock falls from the Rhombus Wall, a sheeted granitic cliff in Yosemite Valley, California. The rock‐fall sequence began on 26 August 2009 with a small failure at the tip of an overhanging rock slab. Several hours later, a series of five rock falls totaling 736 m³ progressed upward along a sheeting joint behind the overhanging slab. Over the next 3 weeks, audible cracking occurred on the Rhombus Wall, suggesting crack propagation, while visual monitoring revealed opening of a sheeting joint adjacent to the previous failure surface. On 14 September 2009 a 110 m³ slab detached along this sheeting joint. Additional rock falls between 30 August and 20 November 2010, totaling 187 m³, radiated outward from the initial failure area along cliff (sub)parallel sheeting joints. We suggest that these progressive failures might have been related to stress redistributions accompanying propagation of sheeting joints behind the cliff face. Mechanical analyses indicate that tensile stresses should occur perpendicular to the cliff face and open sheeting joints, and that sheeting joints should propagate parallel to a cliff face from areas of stress concentrations. The analyses also account for how sheeting joints can propagate to lengths many times greater than their depths behind cliff faces. We posit that as a region of failure spreads across a cliff face, stress concentrations along its margin will spread with it, promoting further crack propagation and rock falls. Published in 2012. This article is a US Government work and is in the public domain in the USA.     

Modelling the lava dome extruded at Soufrière Hills Volcano, Montserrat, August 2005–May 2006: Part II: Rockfall activity and talus deformation

During many lava dome-forming eruptions, persistent rockfalls and the concurrent development of a substantial talus apron around the foot of the dome are important aspects of the observed activity. An improved understanding of internal dome structure, including the shape and internal boundaries of the talus apron, is critical for determining when a lava dome is poised for a major collapse and how this collapse might ensue. We consider a period of lava dome growth at the Soufrière Hills Volcano, Montserrat, from August 2005 to May 2006, during which a  100 × 10⁶ m³ lava dome developed that culminated in a major dome-collapse event on 20 May 2006. We use an axi-symmetrical Finite Element Method model to simulate the growth and evolution of the lava dome, including the development of the talus apron. We first test the generic behaviour of this continuum model, which has core lava and carapace/talus components. Our model describes the generation rate of talus, including its spatial and temporal variation, as well as its post-generation deformation, which is important for an improved understanding of the internal configuration and structure of the dome. We then use our model to simulate the 2005 to 2006 Soufrière Hills dome growth using measured dome volumes and extrusion rates to drive the model and generate the evolving configuration of the dome core and carapace/talus domains. The evolution of the model is compared with the observed rockfall seismicity using event counts and seismic energy parameters, which are used here as a measure of rockfall intensity and hence a first-order proxy for volumes. The range of model-derived volume increments of talus aggraded to the talus slope per recorded rockfall event, approximately 3 × 10³–13 × 10³ m³ per rockfall, is high with respect to estimates based on observed events. From this, it is inferred that some of the volumetric growth of the talus apron (perhaps up to 60–70%) might have occurred in the form of aseismic deformation of the talus, forced by an internal, laterally spreading core. Talus apron growth by this mechanism has not previously been identified, and this suggests that the core, hosting hot gas-rich lava, could have a greater lateral extent than previously considered.     

From geotechnical analysis to quantification and modelling using LiDAR data: a study on rockfall in the Reintal catchment,Bavarian Alps,Germany

In the year 2007, enhanced rockfall activity was observed within the scarp of a 500 BP rockslide in the Reintal catchment (Northern Calcareous Alps, Germany); the largest of a series of events took place in August, when almost 50000 m³ of rock were detached from the subvertical rock face and deposited on a talus cone. In this case study, we focus on three aspects of rockfall research: first, we compile detailed geomorphological and geotechnical findings to explain the causes of the recent events. The results of laboratory tests and stability estimations suggest that rockfall activity will persist in the future as the old rockslide scarp still contains unstable rock masses. Second, we use digital elevation data from a pre‐event airborne LiDAR survey (ALS) and post‐event terrestrial laserscanning (TLS) to quantify landform changes and the mass balance of the rockfall event(s). The widespread availability of ALS elevation data provides a good opportunity to quantify fresh events using a comparatively inexpensive TLS survey; this approach is complicated by uncertainties resulting from the difficult coregistration of ALS and TLS data and the specific geometric problems in steep (ALS) and flat (TLS) terrain; it is therefore limited to at least medium‐sized events. Third, the event(s) is simulated using the results of the LiDAR surveys and a modified GIS‐based rockfall model in order to test its capability of predicting the extent and the spatial distribution of deposition on the talus cone. Results show that the model generally reproduces the process domain and the spatial distribution of topographic changes but frequently under‐ and over‐estimates deposition heights. Copyright © 2011 John Wiley & Sons, Ltd.     

River channel dynamics following extirpation of wolves in northwestern Yellowstone National Park,USA

Historical records indicate that gray wolves (Canis lupus) were extirpated from the upper Gallatin River Basin in the early 1900s. Following the removal of these large carnivores, elk (Cervis elaphus) began to increasingly browse streamside vegetation in the winter range, causing widespread loss of formerly extensive willow (Salix spp.) communities. Historical aerial photographs and chronosequences of ground photographs were used to characterize general changes in vegetation and channel morphology over time. In August of 2004, riparian vegetation and channel cross‐sections were surveyed along three reaches of the upper Gallatin River. Reach A was located upstream of the elk winter range (control reach) whereas reaches B and C (treatment reaches) were located within the elk winter range. Willow cover on floodplains averaged 85 per cent for reach A, but only 26 per cent and 5 per cent for reaches B and C, respectively. The average return period of calculated bankfull discharges was 3·1 yrs for reach A but increased to 32·4 yrs and 10·6 yrs for reaches B and C, respectively. The long‐term loss of streamside vegetation allowed channels to generally increase in hydraulic capacity (via increases in width, incision or both) and decrease their hydrologic connectivity with adjacent floodplains. This study documents, perhaps for the first time, the resultant impacts to riparian vegetation functions and stream channel characteristics following the extirpation of a large mammalian carnivore. Copyright © 2006 John Wiley & Sons, Ltd.     

Runout analysis of a large rockfall in the Dolomites/Italian Alps using LIDAR derived particle sizes and shapes

LiDAR data were used to quantify and analyse a rockfall event which occurred in 2003 in the Western Dolomites (Italian Alps). In addition to previously existing airborne laserscanning (ALS) data, high resolution terrestrial laserscanning (TLS) data were collected. By using the original point clouds, the volume, axial ratio and runout length of single boulders as well as the surface roughness in the runout zone of the rockfall were derived. The total volume of the rockfall event of approximately 10 000 m³ was estimated by a reconstruction of the pre‐event surface at the detachment zone. The analysis of the laser scanning data of the accumulation zone revealed a power law scaling for boulder volumes larger than 8 m³. The dependence of runout length on boulder volume is complex; it is moderated by particle sphericity. In addition, we used ALS and TLS data to derive the spatial distribution of surface roughness on the talus cone. TLS allow for more accurate roughness mapping than ALS data, but for most applications the point density of ALS data seems to be sufficiently high to derive measures of roughness. Different sampling approaches for plane fitting on the scale of 5 m did not show significant effects besides the computational time. The results of our analyses provide important perspectives for rockfall modelling and process understanding with potential applications in both ‘applied’ (natural hazards) and ‘pure’ geomorphological research. Copyright © 2012 John Wiley & Sons, Ltd.     

Inundation and isolation: dynamics of phytoplankton communities in seasonal inundated flood plain waters of the Lower Odra Valley National Park — Northeast Germany

The flood plains of the Lower Odra are inundated in winter and spring and are desiccated in summer and autumn. Phytoplankton composition as well as its seasonal succession in permanent oxbows and separate lakes were investigated between 1993 and 1996. Solitary centric diatoms were the characteristic phytoplankton taxa of these flood plain waters. They dominated the main channel non-seasonally, the flood plains during the entire inundation phase and long periods of the isolation phase. Only during long phases of low mixing (maximal 1.5-2 months in summer) separate water bodies were dominated by Cyano- and/or Dinophyceae. This special feature of the Lower Odra Valley is explained by the Inundation-Isolation-Model of phytoplankton development influenced by inundation. Out of a high diverse algal spectrum of 495 taxa, specialities such as 9 endangered taxa and 6 halophilous taxa were discussed. Additionally, taxon specific cell-volumes and maxima of biovolumes were given.     

Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.     

Rock hardness and landform development in the Gunong Mulu National Park,Sarawak, E. Malaysia

Rock hardness, measured by the Schmidt Test Hammer, is an important factor in explaining some of the sharp contrasts in relief and wide variety of landforms in The Gunong Mulu National Park. It is also useful in consideration of contemporary geomorphological processes, such as landsliding.     

Influence of basin characteristics on baseflow and stormflow chemistry in the Great Smoky Mountains National Park,USA

Relationships between stream chemistry and elevation, area, Anakeesta geology, soil properties, and dominant vegetation were evaluated to identify the influence of basin characteristics on baseflow and stormflow chemistry in eight streams of the Great Smoky Mountains National Park. Statistical analyses were employed to determine differences between baseflow and stormflow chemistry, and relate basin‐scale factors governing local chemical processes to stream chemistry. Following precipitation events, stream pH was reduced and aluminium concentrations increased, while the response of acid neutralizing capacity (ANC), nitrate, sulfate, and base cations varied. Several basin characteristics were highly correlated with each other, demonstrating the interrelatedness of topographical, geological, soil, and vegetative parameters. These interrelated basin factors uniquely influenced acidification response in these streams. Streams in higher‐elevation basins (>975 m) had significantly lower pH, ANC, sodium, and silicon and higher nitrate concentrations (p < 0.05). Streams in smaller basins (<10 km²) had significantly lower nitrate, sodium, magnesium, silicon, and base cation concentrations. In stormflow, streams in basins with Anakeesta geology (>10%) had significantly lower pH and sodium concentrations, and higher aluminium concentrations. Chemical and physical soil characteristics and dominant overstory vegetation in basins were more strongly correlated with baseflow and stormflow chemical constituents than topographical and geological basin factors. Saturated hydraulic conductivity, of all the soil parameters, was most related to concentrations of stormflow constituents. Basins with higher average hydraulic conductivities were associated with lower stream pH, ANC, and base cation concentrations, and higher nitrate and sulfate concentrations. These results emphasize the importance of soil and geological properties influencing stream chemistry and promote the prioritization of management strategies for aquatic resources. Copyright © 2012 John Wiley & Sons, Ltd.     

Historic range of variability in geomorphic processes as a context for restoration: Rocky Mountain National Park,Colorado, USA

Evaluation of historic range of variability (HRV) is an effective tool for determining baseline conditions and providing context to researchers and land managers seeking to understand and enhance ecological function. Incorporating HRV into restoration planning acknowledges the dynamic quality of landscapes by allowing variability and disturbance at reasonable levels and permitting riverine landscapes to adapt to the physical processes of their watersheds. HRV analysis therefore represents a practical (though under‐utilized) method for quantifying process‐based restoration goals. We investigated HRV of aggradational processes in the subalpine Lulu City wetland in Rocky Mountain National Park to understand the impacts of two centuries of altered land use and to guide restoration planning following a human‐caused debris flow in 2003 that deposited up to 1 m of sand and gravel in the wetland. Historic aerial photograph interpretation, ground penetrating radar surveys, and trenching, coring, and radiocarbon dating of valley‐bottom sediments were used to map sediment deposits, quantify aggradation rates, and identify processes (in‐channel and overbank fluvial deposition, direct hillslope input, beaver pond filling, peat accumulation) creating alluvial fill within the wetland. Results indicate (i) the Lulu City wetland has been aggrading for several millennia, (ii) the aggradation rate of the past one to two centuries is approximately six times higher than long‐term pre‐settlement averages, (iii) during geomorphically active periods, short‐term aggradation rates during the pre‐settlement period were probably much higher than the long‐term average rate, and (iv) the processes of aggradation during the last two centuries are the same as historic processes of aggradation. Understanding the HRV of aggradation rates and processes can constrain management and restoration scenarios by quantifying the range of disturbance from which a landscape can recover without active restoration. Copyright © 2011 John Wiley & Sons, Ltd.     

Channel‐planform evolution in four rivers of Olympic National Park,Washington, USA: the roles of physical drivers and trophic cascades

Identifying the relative contributions of physical and ecological processes to channel evolution remains a substantial challenge in fluvial geomorphology. We use a 74‐year aerial photographic record of the Hoh, Queets, Quinault, and Elwha Rivers, Olympic National Park, Washington, USA, to investigate whether physical or trophic‐cascade‐driven ecological factors – excessive elk impacts after wolves were extirpated a century ago – are the dominant drivers of channel planform in these gravel‐bed rivers. We find that channel width and braiding show strong relationships with recent flood history. All four rivers widened significantly after having been relatively narrow in the 1970s, consistent with increased flood activity since then. Channel planform also reflects sediment‐supply changes, evident from landslide response on the Elwha River. We surmise that the Hoh River, which shows a multi‐decadal trend toward greater braiding, is adjusting to increased sediment supply associated with rapid glacial retreat. These rivers demonstrate transmission of climatic signals through relatively short sediment‐routing systems that lack substantial buffering by sediment storage. Legacy effects of anthropogenic modification likely also affect the Quinault River planform. We infer no correspondence between channel evolution and elk abundance, suggesting that trophic‐cascade effects in this setting are subsidiary to physical controls on channel morphology. Our findings differ from previous interpretations of Olympic National Park fluvial dynamics and contrast with the classic example of Yellowstone National Park, where legacy effects of elk overuse are apparent in channel morphology; we attribute these differences to hydrologic regime and large‐wood availability. Published 2016. This article is a U.S. Government work and is in the public domain in the USA     

Oxygen and hydrogen isotope ratios of chert from the Sixtymile Formation in Grand Canyon National Park,USA:a warm palaeoclimate,freshwater deposit

New oxygen and hydrogen isotope ratios of chert from middle, intraformational breccias, and upper breccia members of the Sixtymile Formation(SMF) in eastern Grand Canyon National Park(AZ) yield palaeoclimate estimates between 27 and 33 °C. The isotopic compositions of cherts define a domain approximately parallel to the meteoric water line when plotted on a δD–δ~(18)O diagram; these data indicate that meteoric water was involved during formation of the chert. In thin section, the absence of interlocking mega quartz(35 lm) and silicafilled fractures and veins, along with preserved micromorphological silica fabrics, suggest that the chert has not been permeated by later hydrothermal fluids. Petrographic observations in thin section such as cyclic silica precipitation phases and glaebular micromorphologic fabrics lend support to the interpretation that meteoric waters were involved during chert precipitation. The post 742 Ma SMF has been correlated with diamictite(transition) beds of the Kingston Peak Formation(CA), which in turn have been interpreted to have been deposited during the Sturtian Ice Age(~750–700 Ma). Absence of facetted and striated clasts and other diagnostic glaciogenic features in the SMF,an unconformable contact with the stratigraphically older Chuar Group, coupled with warm palaeotemperature data inferred from stable isotope values of chert, tentatively suggest that deposition of sediment in the SMF likely did not take place during the Sturtian Ice Age.     

Numerical analysis of coastal cliff failure along the Pembrokeshire Coast National Park,Wales, UK

Cliff stability within the Pembrokeshire Coast National Park was evaluated using a numerical model applied at four sites representative of rock mass failure phenomena and major sedimentary geological sequences. The sites were: Mill Bay, (Old Red Sandstone); St Govan's Head, Carboniferous Limestone (Dinantian); Druidston, Millstone Grit (Namurian) and Lower Coal Measures (Westphalian); and Wiseman's Bridge, Lower Coal Measures (Westphalian). The study integrated a range of geotechnical parameters, measured in the field and laboratory, into a model to predict the likely failure mechanisms. The model is based on the existence of rock prisms delineated by structural parameters, i.e. joints, bedding planes and critical tension fractures behind the cliff face. An iterative approach is used to define the dip of the most probable, stepped failure surface at the base of any potentially unstable multiblock system and to calculate the sliding and toppling forces for each block in the cliff mass. Prediction compared favourably with field observations at three of the four selected sites, i.e. Druidston, St Govan's Head and Wiseman's Bridge. At Druidston sliding is predicted and dominates in the basal blocks, whilst toppling is confined to the upper cliff and is dependent on movement of the lower structural units. St Govan-s Head is shown to have a low risk of toppling and sliding and this was predicted except where basal undercutting reaches a depth of 1·0 m or lateral forces exceed 100 kN m⁻² when failure could occur. Copyright © 1998 John Wiley & Sons, Ltd.     

Simulating the water budget of a Prairie Potholes complex from LiDAR and hydrological models in North Dakota,USA

Abstract

Hydrological processes of the wetland complex in the Prairie Pothole Region (PPR) are difficult to model, partly due to a lack of wetland morphology data. We used Light Detection And Ranging (LiDAR) data sets to derive wetland features; we then modelled rainfall, snowfall, snowmelt, runoff, evaporation, the “fill-and-spill” mechanism, shallow groundwater loss, and the effect of wet and dry conditions. For large wetlands with a volume greater than thousands of cubic metres (e.g. about 3000 m³), the modelled water volume agreed fairly well with observations; however, it did not succeed for small wetlands (e.g. volume less than 450 m³). Despite the failure for small wetlands, the modelled water area of the wetland complex coincided well with interpretation of aerial photographs, showing a linear regression with R² of around 0.80 and a mean average error of around 0.55 km². The next step is to improve the water budget modelling for small wetlands.

Editor Z.W. Kundzewicz; Associate editor X. Chen

Citation Huang, S.L., Young, C., Abdul-Aziz, O.I., Dahal, D., Feng, M., and Liu, S.G., 2013. Simulating the water budget of a Prairie Potholes complex from LiDAR and hydrological models in North Dakota, USA. Hydrological Sciences Journal, 58 (7), 1434–1444.     

Deciphering topographic signals of glaciation and rock uplift in an active orogen: a case study from the Olympic Mountains,USA

Estimating recent patterns of erosion and rock uplift within Cenozoic orogens has proven difficult as signals of these processes have been obfuscated by Plio‐Pleistocene glaciation. The topography of many mountain ranges integrates the effects of long‐lived rock uplift, Late‐Cenozoic climate variation, and post‐glacial landscape adjustment. In this study, we employ a suite of topographic analyses to study the relief of an active mountain range on a sub‐catchment scale in an effort to the separate the long‐term signal of rock uplift from perturbations due to shorter‐lived climate signals. We focus on the Olympic Mountains, USA, where patterns of exhumation and glaciation have been previously estimated; however, our methods and results are broadly applicable to other orogens. Our analysis shows that Plio‐Pleistocene alpine glaciers and the Cordilleran Ice Sheet have reduced the elevations of channel profiles and created anomalously low channel relief in the Olympic Mountains. Large low‐gradient areas formed at lower elevations where ice sheets were present and alpine glaciers widened and deepened valleys. In the more rugged core of the range, near‐threshold hillslopes along the margins of the oversteepened glacially‐carved valleys, dominate the range. This implies a strong Plio‐Pleistocene glacial climate control on the topography over the more recent evolution of the Olympic Mountains. However, the broad relief structure of the range appears to still record the regional rock uplift pattern and is suggestive of an east‐plunging antiform, consistent with folding of the subducting plate or underplating of accreted rocks. Copyright © 2017 John Wiley & Sons, Ltd.     

Hydrogeology of desert springs in the Panamint Range,California, USA: Geologic controls on the geochemical kinetics,flowpaths, and mean residence times of springs

Over 180 springs emerge in the Panamint Range near Death Valley National Park, CA, yet, these springs have received very little hydrogeological attention despite their cultural, historical, and ecological importance. Here, we address the following questions: (1) which rock units support groundwater flow to springs in the Panamint Range, (2) what are the geochemical kinetics of these aquifers, and (3) and what are the residence times of these springs? All springs are at least partly supported by recharge in and flow through dolomitic units, namely, the Noonday Dolomite, Kingston Peak Formation, and Johnnie Formation. Thus, the geochemical composition of springs can largely be explained by dedolomitization: the dissolution of dolomite and gypsum with concurrent precipitation of calcite. However, interactions with hydrothermal deposits have likely influenced the geochemical composition of Thorndike Spring, Uppermost Spring, Hanaupah Canyon springs, and Trail Canyon springs. Faults are important controls on spring emergence. Seventeen of twenty-one sampled springs emerge at faults (13 emerge at low-angle detachment faults). On the eastern side of the Panamint Range, springs emerge where low-angle faults intersect nearly vertical Late Proterozoic, Cambrian, and Ordovician sedimentary units. These geologic units are not present on the western side of the Panamint Range. Instead, springs on the west side emerge where low-angle faults intersect Cenozoic breccias and fanglomerates. Mean residence times of springs range from 33 (±30) to 1,829 (±613) years. A total of 11 springs have relatively short mean residence times less than 500 years, whereas seven springs have mean residence times greater than 1,000 years. We infer that the Panamint Range springs are extremely vulnerable to climate change due to their dependence on local recharge, disconnection from regional groundwater flow (Death Valley Regional Flow System - DVRFS), and relatively short mean residence times as compared with springs that are supported by the DVRFS (e.g., springs in Ash Meadows National Wildlife Refuge). In fact, four springs were not flowing during this campaign, yet they were flowing in the 1990s and 2000s.     

谈远震特别区域震相记录特征与震相识别——以大同国家测震台观测资料为例

以大同国家测震台观测资料为例,总结了震中距10~°50°范围内特别区域地震震相特征和震相识别的方法,对震相识别的难点进行了说明,以图例的形式为判读震相提供了依据。     

Sulfur geochemistry of hydrothermal waters in Yellowstone National Park, Wyoming, USA. II. Formation and decomposition of thiosulfate and polythionate in Cinder Pool

Cinder Pool is an acid-sulfate-chloride boiling spring in Norris Geyser Basin, Yellowstone National Park. The pool is unique in that its surface is partially covered with mm-size, black, hollow sulfur spherules, while a layer of molten sulfur resides at the bottom of the pool (18 m depth). The sulfur speciation in the pool was determined on four different days over a period of two years. Samples were taken to evaluate changes with depth and to evaluate the importance of the sulfur spherules on sulfur redox chemistry. All analyses were conducted on site using a combination of ion chromatography and colorimetric techniques.Dissolved sulfide (H₂S), thiosulfate (S₂O₃²⁻), polythionates (S_xO₆²⁻), and sulfate were detected. The polythionate concentration was highly variable in time and space. The highest concentrations were found in surficial samples taken from among the sulfur spherules. With depth, the polythionate concentrations dropped off. The maximum observed polythionate concentration was 8 μM. Thiosulfate was rather uniformly distributed throughout the pool and concentrations ranged from 35 to 45 μM. Total dissolved sulfide concentrations varied with time, concentrations ranged from 16 to 48 μM. Sulfate was relatively constant, with concentrations ranging from 1150 to 1300 μM. The sulfur speciation of Cinder Pool is unique in that the thiosulfate and polythionate concentrations are significantly higher than for any other acid-sulfate spring yet sampled in Yellowstone National Park. Complementary laboratory experiments show that thiosulfate is the intermediate sulfoxyanion formed from sulfur hydrolysis under conditions similar to those found in Cinder Pool and that polythionates are formed via the oxidation of thiosulfate by dissolved oxygen. This last reaction is catalyzed by pyrite that occurs as a minor constituent in the sulfur spherules floating on the pool's surface. Polythionate decomposition proceeds via two pathways: (1) a reaction with H₂S, yielding thiosulfate and elemental sulfur; and (2) by disproportionation to sulfate and thiosulfate.This study demonstrates that the presence of a subaqueous molten sulfur pool and sulfur spherules in Cinder Pool is of importance in controlling the pathways of aqueous sulfur redox reactions. Some of the insights gained at Cinder Pool may be relevant to acid crater lakes where sulfur spherules are observed and variations in polythionate concentrations are used to monitor and predict volcanic activity.     

Hydrogeology of desert springs in the Panamint Range,California, USA: Identifying the sources and amount of recharge that support spring flow

Despite its location in the rain shadow of the southern Sierra Nevada, the Panamint Range hosts a complex mountain groundwater system supporting numerous springs which have cultural, historical, and ecological importance. The sources of recharge that support these quintessential desert springs remain poorly quantified since very little hydrogeological research has been completed in the Panamint Range. Here we address the following questions: (i) what is the primary source of recharge that supports springs in the Panamint Range (snowmelt or rainfall), (ii) where is the recharge occurring (mountain-block, mountain-front, or mountain-system) and (iii) how much recharge occurs in the Panamint Range? We answer questions (i) and (ii) using stable isotopes measured in spring waters and precipitation, and question (iii) using a chloride mass-balance approach which is compared to a derivation of the Maxey–Eakin equation. Our dataset of the stable isotopic composition (δ¹⁸O and δ²H) of precipitation is short (1.5 years), but analyses on spring water samples indicate that high-elevation snowmelt is the dominant source of recharge for these springs, accounting for 57 (±9) to 79 (±12) percent of recharge. Recharge from rainfall is small but not insignificant. Mountain-block recharge is the dominant recharge mechanism. However, two basin springs emerging along the western mountain-front of the Panamint Range in Panamint Valley appear to be supported by mountain-front and mountain-system recharge, while Tule Spring (a basin spring emerging at the terminus of the bajada on the eastern side of the Panamint Range) appears to be supported by mountain-front recharge. Calculated recharge rates range from 19 mm year⁻¹ (elevations < 1000 mrsl) to 388 mm year⁻¹ (elevations > 1000 mrsl). The average annual recharge is approximately 91 mm year⁻¹ (equivalent to 19.4 percent of total annual precipitation). We infer that the springs in the Panamint Range (and their associated ecosystems) are extremely vulnerable to changes in snow cover associated with climate change. They are heavily dependent on snowmelt recharge from a relatively thin annual snowpack. These findings have important implications for the vulnerability of desert springs worldwide.