Upper cretaceous and paleogene sediments from the Northern Kerguelen Plateau

Upper Cretaceous and Paleogene pelagic sediments sampled from the Northern Kerguelen Plateau during cruise MD35 of theMarion Dufresne are described and correlated with the Late Paleogene sequence drilled at site ODP 737 (Leg 119). Taking into account geophysical data obtained by the cruise MD26, a Lower Cretaceous age is computed for the unsampled acoustic basement. A major tectonic/volcanic event in the Late Paleogene, related to rifting, gave rise to a marked unconformity and hiatus termed the “Acoustic Discordance.” Tertiary sediment facies changes were strongly influenced by the evolution of the Antarctic environment.     

Circulation and its seasonal variability in region around the Kerguelen Plateau

A coupled ice-ocean isopycnal numerical model of the Southern Ocean is established tostudy the circulation and its seasonal variability in the region around the Kerguelen Plateau. An analysis of the simulated results shows significant stripe-like structure and non-zonal feature of the Antarctic Cir-cumpolar Current (ACC) in this region. ACC begins to bifurcate and to turn its direction before meeting the plateau. The southernmost branch of ACC is near to the Antarctic coast and displays its strong interaction with the westward Antarctic Slope Current. The northern branch of ACC has a tendency of annual variations while the southern one varies in a semiannual cycle. The variation phases of both branches are coincident with that of the wind stress in this region.     

Seismic stratigraphy and evolution of the Raggatt Basin,southern Kerguelen Plateau

Six major seismic stratigraphic sequences in the Raggatt Basin on the southern Kerguelen Plateau overlie a basement complex of Cretaceous or greater age. The complex includes dipping reflectors which were apparently folded and eroded before the Raggatt Basin developed. The seismic stratigraphic sequences include a basal unit F, which fills depressions in basement; a thick unit, E, which has a mounded upper surface (volcanic or carbonate mounds); a depression-filling unit, D; a thick unit C which is partly Middle to Late Eocene; and two post-Eocene units, A and B, which are relatively thin and more limited in areal extent than the underlying sequences. A mid or Late Cretaceous erosional episode was followed by subsidence and basin development, interrupted by major erosion in the mid Tertiary. Late Cenozoic sedimentation was affected by vigorous ocean currents.     

Origins and maturity of organic matter in mid-Cretaceous black shales from ODP Site 1138 on the Kerguelen Plateau

We have conducted elemental, isotopic, and Rock-Eval analyses of Cenomanian–Santonian sediment samples from ODP Site 1138 in the southern Indian Ocean to assess the origin and thermal maturity of organic matter in mid-Cretaceous black shales found at this high-latitude location. Total organic carbon (TOC) concentrations range between 1 and 20 wt% in black to medium-gray sediments deposited around the Cenomanian–Turonian boundary. Results of Rock-Eval pyrolysis indicate that the organic matter is algal Type II material that has experienced modest alteration. Important contributions of nitrogen-fixing bacteria to the amplified production of organic matter implied by the high TOC concentrations is recorded in δ¹⁵N values between −5 and 1‰, and the existence of a near-surface intensified oxygen minimum zone that favored organic carbon preservation is implied by TOC/TN ratios between 20 and 40. In contrast to the marine nature of the organic matter in the Cenomanian–Turonian boundary section, deeper sediments at Site 1138 contain evidence of contributions land-derived organic matter that implies the former presence of forests on the Kerguelen Plateau until the earliest Cenomanian.     

南大洋凯尔盖朗海台区的流场结构及季节变化

利用冰-海耦合等密面模式模拟了南大洋凯尔盖朗海台区的环流及其季节变化.对模拟结果的分析表明,该海区的南极绕极流具有非常显着的条带状分布和非纬向性特征.南极绕极流流经凯尔盖朗海台时,在海台的南部、中部和北部表现出不同的形式,其南部的一个分支贴近南极大陆,与西向的陆坡流之间有强的相互作用.海台以北的南极绕极流的变化以年周期为主,海台以南的变化以半年周期为主,其时间变化规律与这里的风应力的变化规律是一致的.     

Regional circulation around Heard and McDonald Islands and through the Fawn Trough,central Kerguelen Plateau

The fine-scale circulation around the Heard and McDonald Islands and through the Fawn Trough, Kerguelen Plateau, is described using data from three high-resolution CTD sections, Argo floats and satellite maps of chlorophyll a, sea surface temperature (SST) and absolute sea surface height (SSH). We confirm that the Polar Front (PF) is split into two branches over the Kerguelen Plateau, with the NPF crossing the north-eastern limits of our survey carrying 25 Sv to the southeast. The SPF was associated with a strong eastward-flowing jet carrying 12 Sv of baroclinic transport through the deepest part of Fawn Trough (relative to the bottom). As the section was terminated midway through the trough this estimate is very likely to be a lower bound for the total transport. We demonstrate that the SPF contributes to the Fawn Trough Current identified by previous studies. After exiting the Fawn Trough, the SPF crossed Chun Spur and continued as a strong north-westward flowing jet along the eastern flank of the Kerguelen Plateau before turning offshore between 50°S and 51.5°S. Measured bottom water temperatures suggest a deep water connection between the northern and southern parts of the eastern Kerguelen Plateau indicating that the deep western boundary current continues at least as far north as 50.5°S. Analysis of satellite altimetry derived SSH streamlines demonstrates a southward shift of both the northern and southern branches of the Polar Front from 1994 to 2004. In the direct vicinity of the Heard and McDonald islands, cool waters of southern origin flow along the Heard Island slope and through the Eastern Trough bringing cold Winter Water (WW) onto the plateau. Complex topography funnels flow through canyons, deepens the mixed layer and increases productivity, resulting in this area being the preferred foraging region for a number of satellite-tracked land-based predators.     

The influence of lateral mixing on a phytoplankton bloom: Distribution in the Kerguelen Plateau region

A unique phytoplankton bloom appears every year during the austral spring/summer in the northern Kerguelen Plateau region. The Kerguelen Ocean and Plateau compared Study (KEOPS) showed that an increase in subsurface iron coming up from the seafloor through vertical mixing was responsible for the observed increase in chlorophyll-a above the plateau. We demonstrate that the bloom pattern is not a simple increase of biomass over shallow water: it is strongly influenced by the bathymetry and its spatial extent controlled by strong currents around the plateau. Here we focus on lateral mixing process to explain the particular shape of the bloom. We use the Smagorinsky [1963. General circulation experiments with the primitive equations. I. The basic experiment. Monthly Weather Review 91 (3), 99–164] formula to estimate and map fields of lateral mixing time scales (τ) due to barotropic tidal currents, barotropic atmospheric forced currents, Ekman velocities and geostrophic velocities. Results show that short time scale mixing is strongly influenced by the tides while the other processes have minor influences. Comparisons of τ and satellite chlorophyll-a images show that the spatial pattern of the bloom seems to be delimited by a barrier of high lateral mixing that is essentially due to tides. This emphasises the role played by the tides over the Kerguelen Plateau in supplying iron to the phytoplankton and containing the horizontal shape of the bloom. This is one of the first times such a link has been demonstrated, which has implications for the study of iron advection in the ocean.     

Insights into deposition of Lower Cretaceous black shales from meager accumulation of organic matter in Albian sediments from ODP site 763, Exmouth Plateau,Northwest Australia

The amount and type of organic matter present in an exceptionally complete upper Aptian to lower Cenomanian sequence of sediments from ODP site 763 on the Exmouth Plateau has been determined. Organic carbon concentrations average 0.2%. Organic matter is marine in origin, and its production and preservation was low over the ca. 20-million-year interval recorded by this sequence. Because this section was tectonically isolated from mainland Australia in the early Aptian, it better represents global oceanic conditions than the many basin-edge locations in which Albian-age black shales have been found. Formation of the basin-edge black shales evidently resulted from rapid, turbiditic burial of organic matter rather than from enhanced oceanic production or from basin-wide anoxia during the Albian.     

Geoacoustic and physical properties of carbonate sediments of the Lower Florida Keys

 Near-surface sediment geoacoustic and physical properties were measured from a variety of unconsolidated carbonate sediments in the Lower Florida Keys. Surficial values of compressional and shear speed correlate with sediment physical properties and near-surface acoustic reflectivity. Highest speeds (shear 125–150 m s^-1; compressional 1670–1725 m s^-1) are from sandy sediments near Rebecca Shoal and lowest speeds (shear 40–65 m s^-1; compressional 1520–1570 m s^-1) are found in soft, silty sediments which collect in sediment ponds in the Southeast Channel of the Dry Tortugas. High compressional wave attenuation is attributed to scattering of acoustic waves from heterogeneity caused by accumulation of abundant shell material and other impedance discontinuities rather than high intrinsic attenuation. Compared to siliciclastic sediments, carbonate sediment shear wave speed is high for comparable values of sediment physical properties. Sediment fabric, rather than changes due to the effects of biogeochemical processes, is responsible for these differences.     

Fine resolution 3D temperature fields off Kerguelen from instrumented penguins

The use of diving animals as autonomous vectors of oceanographic instruments is rapidly increasing, because this approach yields cost-efficient new information and can be used in previously poorly sampled areas. However, methods for analyzing the collected data are still under development. In particular, difficulties may arise from the heterogeneous data distribution linked to animals’ behavior. Here we show how raw temperature data collected by penguin-borne loggers were transformed to a regular gridded dataset that provided new information on the local circulation off Kerguelen. A total of 16 king penguins (Aptenodytes patagonicus) were equipped with satellite-positioning transmitters and with temperature–time–depth recorders (TTDRs) to record dive depth and sea temperature. The penguins’ foraging trips recorded during five summers ranged from 140 to 600 km from the colony and 11,000 dives >100 m were recorded. Temperature measurements recorded during diving were used to produce detailed 3D temperature fields of the area (0–200 m). The data treatment included dive location, determination of the vertical profile for each dive, averaging and gridding of those profiles onto 0.1°×0.1° cells, and optimal interpolation in both the horizontal and vertical using an objective analysis. Horizontal fields of temperature at the surface and 100 m are presented, as well as a vertical section along the main foraging direction of the penguins. Compared to conventional temperature databases (Levitus World Ocean Atlas and historical stations available in the area), the 3D temperature fields collected from penguins are extremely finely resolved, by one order finer. Although TTDRs were less accurate than conventional instruments, such a high spatial resolution of penguin-derived data provided unprecedented detailed information on the upper level circulation pattern east of Kerguelen, as well as the iron-enrichment mechanism leading to a high primary production over the Kerguelen Plateau.     

冲绳海槽中部玄武岩的岩石学和地球化学研究

1992年冲绳海槽地质调查时,在134站(126°56′7″E,27°30′0″N)共采集到3件玄武岩样品,其中1件取自134站表层样,另外2件取自134站柱状样中的118-143cm处和193- 218cm处(刀口位置)。通过对上述3件玄武岩样品的岩相学、岩石化学组成、稀土元素和微量元素和锶同位素比值分析研究,认为本区玄武岩具多期次喷发特征,早期喷发形成的玄武岩中单斜辉石质量分数较低,晚期喷发形成的玄武岩中单斜辉石质量分数相对较高,表明了单斜辉石为晚期结晶堆积产物。本区玄武岩稀土配分模式与岛弧拉斑玄武岩基本一致,其⁸⁷Sr与⁸⁶Sr质量分数比值m(⁸⁷Sr)/m(⁸⁶Sr)为0.7046,亦与岛弧拉斑玄武岩相当。最后利用Rb-Sr丰度特征确定本区的地壳厚度为19-24 km。     

冲绳海槽中部玄武岩的岩石学和地球化学研究

1992年冲绳海槽地质调查时,在134站(126°56′7″E,27°30′0″N)共采集到3件玄武岩样品,其中1件取自134站表层样,另外2件取自134站柱状样中的118-143cm处和193- 218cm处(刀口位置)。通过对上述3件玄武岩样品的岩相学、岩石化学组成、稀土元素和微量元素和锶同位素比值分析研究,认为本区玄武岩具多期次喷发特征,早期喷发形成的玄武岩中单斜辉石质量分数较低,晚期喷发形成的玄武岩中单斜辉石质量分数相对较高,表明了单斜辉石为晚期结晶堆积产物。本区玄武岩稀土配分模式与岛弧拉斑玄武岩基本一致,其87Sr与86Sr质量分数比值m(87Sr)/m(86Sr)为0.7046,亦与岛弧拉斑玄武岩相当。最后利用Rb-Sr丰度特征确定本区的地壳厚度为19-24 km。     

Geotechnical characterization of calcareous sediments from the Dry Tortugas Keys and Marquesas Keys CBBL SRP study sites, Lower Florida Keys

Geotechnical characteristics of carbonate sediments from two test sites (Dry Tortugas Keys and Marquesas Keys) in the Lower Florida Keys were investigated as part of the Coastal Benthic Boundary Layer Special Research Program, through an extensive field coring and laboratory testing program conducted by the Marine Geomechanics Laboratory of the University of Rhode Island. Based on results from physical measurements, water content and wet bulk density values for both sites generally showed large variations in the upper 25 cm and little variation below this depth. Sediment samples exhibited low plasticity or nonplastic characteristics. Constant-rate-of-deformation consolidation test results showed strong apparent overconsolidation (stress state ratio >7.5) in the surface sediments (upper 50 cm) at the Dry Tortugas Keys, and light overconsolidation (stress state ratio <1.5) below 50-cm depth at the Marquesas Keys site. In-situ permeability values were between 10^-4 and 10^-7 cm/s at both sites and showed no strong depth dependence in the upper 2 m. Undrained shear strength profiles for Dry Tortugas Keys sediments indicated a marked stiffening with depth, whereas the Marquesas Keys sediments showed a gradual increase with depth. Consolidated isotropically undrained triaxial shear strength test results indicate that the undisturbed sediments had an average effective angle of internal friction of 38°, which is not fully realized until large axial strains on the order of 11% have accumulated. Evidence of cementation was not found in triaxial compression or consolidation test results. The general behavior and characteristics of these sediments are similar to those of granular materials, which is primarily due to their high calcium carbonate contents and lack of cementation.     

The initiation of the southern central Great Barrier Reef: New multiproxy data from Pleistocene distal sediments from the Marion Plateau (NE Australia)

Significant synchronous shifts in the chemistry, mineralogy, grain sizes and color of the sediments at 6 m below sea floor (mbsf) at ODP Site 1195 on the Marion Plateau (NE Australia) are interpreted to reflect a major regional paleoceanographic change: the initiation of the southern province of the Great Barrier Reef (GBR). The onset of this massive carbonate production centre nearby resulted primarily in increased deposition of carbonate-rich sediments of neritic origin. Both sedimentation rate and terrigenous input record a coincident decline attributed to inshore trapping of materials behind the reefs. Our best estimate places the development of reef framework in the southern part of the GBR between 560 and 670 kyr B.P., based on an age model combining magnetostratigraphic and biostratigraphic data. The proposed estimation agrees with previous studies reporting an age between 500 and 930 kyr B.P., constraining more tightly their results. However, it does not support research placing the birth of the GBR in Marine Isotope Stage (MIS) 11 ( 400 kyr), nor the theory of a worldwide modern barrier reef development at that time.     

Iron and manganese micro-precipitates within a cretaceous biosiliceous ooze from the Arctic Ocean: possible hydrothermal source

The oldest sediment most recently recovered from the Arctic Ocean is a biosiliceous ooze nearly devoid of nonbiogenic particles and exhibiting small-scale color changes. Color variations are due to changes in iron and manganese content. These elements are probably of local hydrothermal origin, and the Mn precipitation may be bacteria-mediated. An iron silicate phase seems to form at the expense of biogenic silica. The ooze deposited slowly until a sudden sediment input, probably a volcanigenic deposit now weathered to clay minerals, induced dissolution of siliceous microfossils. This clay layer contains calcium phosphate microspheres enriched in rare earth elements.     

Iron and manganese in the wake of the Kerguelen Islands (Southern Ocean)

As part of the ANTARES 3/F-JGOFS cruise, the distributions of dissolved iron and manganese were measured in October 1995 in the north–east wake of the Kerguelen archipelago (48°40′–49°40′S, 68°70′–70°50′E), an area that shows high phytoplankton biomass (CZCS and SeaWiFS data) in the middle of the High Nutrient Low Chlorophyll (HNLC) Southern Ocean. The study area (about 25,000 km²) comprised a branch of the Polar Front with Antarctic surface water (AASW) intruding northward, shouldering the shelf break of the Kerguelen Plateau. The coastal zone was clearly affected by material of lithogenic origin (riverine discharges, soil leaching by rain waters, aeolian inputs), as well as by inputs from the sediments (effluxes from the sediment–water interface, resuspension from the sediments), its near surface waters showing considerable enrichment in dissolved iron (5.3–12.6 nM) and in dissolved manganese (2.9–8.6 nM). The offshore waters, although less enriched in trace-metals, were also affected by trace-metal inputs from coastal and continental shelf origin. Dissolved iron and manganese concentrations in these waters were 0.46–0.71 and 0.68–1.3 nM, i.e. far over typical antarctic open ocean surface water concentrations of 0.16 nM for iron [Martin, J.H., Gordon, R.M., Fitzwater, S.E., 1990. Iron in Antarctic waters. Nature, 345: 156–158.] and around 0.1 nM for manganese [Martin, J.H., Gordon, R.M., Fitzwater, S.E., 1990. Iron in Antarctic waters. Nature, 345: 156–158; Sedwick, P.N., Edwards, P.R., Mackey, D.J., Griffiths, F.B., Parslow, J.S., 1997. Iron and manganese in surface waters of the Australian subantarctic region. Deep-Sea Res., 44: 1239–1253.]. The dissolved iron enrichment in coastal waters of the Kerguelen Islands is much more important (about 10 times for dissolved iron) than for the Galapagos Islands, another oasis in the HNLC Equatorial oceanic system, where the concentration increase in dissolved iron in the surface waters around the islands is mostly driven by upwelling of the Equatorial Under Current (EUC) as it reaches the Galapagos Platform.     

Buried nodules and associated sediments from the central Indian basin

Buried nodules from siliceous sediments in the central Indian Basin are morphologically variable and mineralogically consist ofd-MnO₂ and incipient todorokite. Compositionally they are weakly diagenetic. The sediment coarse fractions (>63 μm) at different depths show variable abundances of micronodules, volcanic glass shards and biodebris. Dissolution of biodebris increases and abundance of micronodules decreases with increasing depth. Enrichment in Mn, Fe, Cu, Ni, Co, together with a decrease in organic carbon in the sediment column, may result from diagenetic metal remobilization. Diagenetically remobilized trace metals might have been utilized for the growth of micronodules over the buried nodules. The details of the chemical analyses of buried nodules and associated sediments can be obtained from the first author.     

Heavy metals in surface sediments of Waiwhetu Stream,Lower Hutt,New Zealand

Abstract

Surface sediment samples (60 μm‐2 mm, and < 60 μm fractions) from the Waiwhetu Stream, Lower Hutt City, New Zealand, were leached with dilute HCl to remove the mobile heavy‐metal fraction. Cd, Cr, Cu, Pb, Zn, Al, Fe, and Mn analyses of the leachates show that sediments of the upper reaches area of the stream are generally uncontaminated. In contrast, sediments in the lower reaches area are highly contaminated, despite clean‐up measures in the late 1970s. Lead and Zn are the most significantly enriched metals with concentrations over 1000 mg kg^?1 adjacent to some drains. In the polluted zone, metals originate from either upward remobilisation from underlying sediment (contaminated in the early 1960s and 70s) or more recent industrial spillages. Similar trends exhibited by Cd, Cu, Cr, Zn, Pb, and Al indicate that a proportion of the metal enrichment downstream probably results from a naturally higher clay content of sediments near the mouth of the stream. Fe and Mn show reverse trends to the other metals, indicating that a high proportion of these two metals occurs in substrate different to that of the other metals. The orange brick‐coloured sediments of the upper reaches of the stream indicate oxides upstream; the black sediments in the lower reaches indicate sulphides downstream.     

渤海沉积物中产甲烷途径及产甲烷菌群落特征

全球甲烷排放主要来源于厌氧环境中产甲烷菌的代谢活动。采集渤海典型站位沉积物样品,测定了沉积物中甲烷和硫酸盐含量。通过提供不同类型产甲烷底物进行培养,分析了各样品中甲烷产量;通过高通量测序,分析了产甲烷菌群落特征。结果表明,渤海沉积物中产甲烷途径以甲基营养型为主,同时具有H2/CO2还原型途径。同一站点随着深度的增加,甲烷产生量逐渐减少,产甲烷速率相应降低。古菌群落以Crenarchaeota、Asgardaeota和Nanoarchaeota为主,产甲烷菌Ca. Methanofastidiosales占据优势地位。本研究为全面了解产甲烷菌在海洋生境中产甲烷过程提供了重要参考。