Characteristics of natural low pH groundwater in the coastal aquifers near Beihai, China

Groundwater with low total dissolved solids （less than 200 mg/L） occurs in the unconfined and confined aquifers near Beihai in southern Guangxi, China. Under natural conditions the groundwater ranges in pH from 3,33 to 7,0 with an average value of 5.12. The pH in the unconfined aquifer varies from 3.67 to 7.0 with an average value of 5.17 and the pH in the confined aquifer is in the range 3.33-6.97 with an average value of 5.07. The pH in the groundwater does not show significantly increasing or decreasing trends with time. Fluctuations in pH exist at some of the monitoring wells and the pH in groundwater is a bit higher in the rainy season than in the dry season, Monitoring data show that the pH in rainwater is higher than in groundwater in the unconfined aquifer, whereas the pH in the latter is a bit higher than in the confined aquifer. A slightly decreasing trend in the pH was also found from the inland area to the coastal zone. The occurrence of weakly acidic groundwater in this area is attributed to the recharge from low pH precipitation and the multi-aquifer and leaky groundwater system.     

Numerical simulation of sea water intrusion near Beihai, China

 A leaky aquifer system occurs in the coastal plain near Beihai, China. Seawater intrusion into the confined aquifer took place along the northern coast. Chloride concentrations at some observation wells increased steadily from 1988 and were at their peak in 1993. A quasi-three-dimensional element model has been developed to simulate the spatial and temporal evolution of hydraulic heads and chloride concentrations of the groundwater near the northern coast. The simulation model was based on the transition zone approach, which requires simultaneous solution of the governing water flow and solute transport equations. An irregular grid of a quadrangle was used to discretize the flow domain. Various aquifer parameters were verified with the numerical model in order to obtain satisfactory matches between computed values and observed data from an investigation. Three pumpage schemes were designed to use the calibrated model for prediction of future changes in water levels and chloride concentrations in groundwater in the study area. Results show that seawater intrusion would worsen in the confined aquifer if the current rates of groundwater pumpage continue. The alternative, to eliminate pumpage in the intruded area and to moderate pumpage rates from water supply wells far from the seashore, may limit seawater intrusion significantly and is considered attractive in the area. Received: 27 September 1999 · Accepted: 27 December 1999     

海潮及其影响下海岸带地下水位时间序列的周期性和滞后性

运用谱分析原理，对广西北海市海潮及受海潮影响的滨海含水层地下水位时间序列进行分析，求出海潮和观测孔水位变化的周期及地下水位滞后于海潮的时间，分析水位滞后时间与离海岸的垂直距离之间的关系。结果表明，北海市海潮和海岸带地下水位有约344．82h（14．37d）的长周期变化和约24．7h、12．5h的短周期波动，距海岸2175、2350、2375m的3个观测孔地下水位对海潮的滞后时间分别为5．5、6．25和7h，滞后时间随离海岸的距离增大大体上呈线性增加。     

Occurrence of salt water above fresh water in dynamic equilibrium in a coastal groundwater flow system near De Panne, Belgium

A salt water lens is found above fresh water under the shore between Dunkerque (France) and Nieuwpoort (Belgium). This inverse density distribution is in a dynamic equilibrium. It develops due to the infiltration of salt water on the back shore during high tide. Under this salt water lens, water infiltrated in the adjacent dune area flows towards the sea and discharges at the seabed. This water quality distribution differs from the classic salt water wedge under fresh water described in the literature. Here, the evolution to this water quality distribution is simulated with a density dependent numerical model. A large tidal range, shore morphology and a permeable groundwater reservoir are the main conditions for the observed water quality distribution. By altering these conditions, intermediate water quality distributions between the classic salt water wedge and the one discussed here develop. Based on these simulations, it is expected that similar kinds of inverse density distribution could be present in a number of coastal areas, which have tides, a gently sloping shore and a permeable substratum.     

A thick lens of fresh groundwater in the southern Lihue Basin,Kauai, Hawaii,USA

A thick lens of fresh groundwater exists in a large region of low permeability in the southern Lihue Basin, Kauai, Hawaii, USA. The conventional conceptual model for groundwater occurrence in Hawaii and other shield-volcano islands does not account for such a thick freshwater lens. In the conventional conceptual model, the lava-flow accumulations of which most shield volcanoes are built form large regions of relatively high permeability and thin freshwater lenses. In the southern Lihue Basin, basin-filling lavas and sediments form a large region of low regional hydraulic conductivity, which, in the moist climate of the basin, is saturated nearly to the land surface and water tables are hundreds of meters above sea level within a few kilometers from the coast. Such high water levels in shield-volcano islands were previously thought to exist only under perched or dike-impounded conditions, but in the southern Lihue Basin, high water levels exist in an apparently dike-free, fully saturated aquifer. A new conceptual model of groundwater occurrence in shield-volcano islands is needed to explain conditions in the southern Lihue Basin. Electronic Publication     

Some factors affecting TDS and pH values in groundwater of the Beihai coastal area in southern Guangxi,China

Groundwater of low total dissolved solids (TDS) of 10 mg/L and low pH ranging commonly from 4.0 to 7.0 occurs in the unconsolidated unconfined and confined aquifers in the coastal plain near Beihai, Guangxi, China. Minerals in the unconsolidated sediment of Quaternary are predominated by quartz (more than 50%) with small amount of clay minerals, such as kaolinite, illite and chlorite. SiO₂ accounts for most (more than 70%) of the chemical compositions of the sediments. The sediments contain low concentrations of soluble constituents (below 300 μg/g) and are predominated by SO₄. Abundant recharge from low-TDS precipitation and a long time’s dissolution of the unconsolidated sediments containing small amount of soluble compositions lead to low TDS of the groundwater in the area.     

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai,southern China

Salinization in coastal aquifers is usually related to both seawater intrusion and water–rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl^?, Na⁺, Ca²⁺, Mg²⁺ and SO ₄ ^2– ), as well as the isotopic content and ratios (²H, ¹⁸O, ⁸⁷Sr/⁸⁶Sr and ¹³C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.     

Evolution of the groundwater environment under a long-term exploitation in the coastal area near Zhanjiang, China

Aquifers consisting of unconsolidated sediments in the coastal area near Zhanjiang in southern China are grouped into the shallow, middle-deep and deep aquifer systems. Groundwater exploitation began in the 1950s in this district and has increased from year to year since 1980. Measurements of groundwater levels and monitoring data of groundwater chemistry at some 60 wells since 1981 are examined to analyze the evolution of hydrodynamics and hydrochemistry in the coastal aquifers. The results indicate that groundwater levels in the middle-deep and deep aquifer systems have fallen continuously and the extents of the depression cones in water levels have increased in the past two decades, even though the water levels recovered to some degree during the period of 1997–2001. In 2004, the lowest water levels in the middle-deep and deep aquifer systems were 23.58 and 21.84 m below sea level, respectively. The groundwater has TDS ranging from 40 to 550 mg/L, and is of low pH, commonly varies between 4 and 7. Concentrations of total iron and manganese exceed the concentration limits of the drinking water standards. The hardness is in the range of 10–250 mg/L. Chloride contents of the groundwater range from 10 to 60 mg/L. The chloride and TDS do not show systematically increasing trends. Although the water levels in the exploitation center near the coast are significantly lower than the sea level and the depression cones of water levels in the middle-deep and deep aquifer systems have expanded to the sea, sea water intrusion has not been observed until recently. This phenomenon is quite unique in the coastal area near Zhanjiang.     

Numerical simulation of groundwater flow for a coastal plain in Japan: data collection and model calibration

Using a three-dimensional finite element model, this study characterizes groundwater flow in a costal plain of the Seto Inland Sea, Japan. The model characterization involved taking field data describing the aquifer system and translating this information into input variables that the model code uses to solve governing equations of flow. Geological geometry and the number of aquifers have been analyzed based on a large amount of geological, hydrogeological and topographical data. Results of study demonstrate a high correlation between the ground surface elevation and the groundwater level in the shallow coastal aquifer. For calibrating the numerical groundwater model, the groundwater flow was simulated in steady state. In addition, the groundwater level and trend in the transient state has also been elucidated. The numerical result provides excellent visual representations of groundwater flow, presenting resource managers and decision makers with a clear understanding of the nature of the types of groundwater flow pathways. Results build a base for further analysis under different future scenarios.     

Escalation of salinity levels in the quaternary aquifers of the Ganga alluvial plain,India

A detailed water quality analysis was carried out in the quaternary aquifer system of the marginal alluvial plain (Ganga Plain) in Bah Tahsil, Agra district, India. The electrical conductivity of 50 samples each from dug wells, hand pumps and tube wells was analysed for the study of salinity levels in shallow, intermediate and deep aquifers. Out of 50, 20 samples of each were also analysed for other chemical constituents such as Na⁺, K⁺, Cl⁻, F⁻ and TDS. The analyses show drastic changes in the salinity levels of shallow, intermediate and deep aquifers. The deep aquifers are more saline compared to the shallow and intermediate aquifers. On the contrary, the concentration of chemical constituents such as Na⁺, K⁺, Cl⁻ and F⁻ was more in the shallow aquifers compared to the deep aquifers. Moreover, there is an indication that the salinity and concentration of the above chemical constituents also escalate with time in each aquifer. The chemical constituents such as Na⁺, K⁺, Cl⁻, F⁻ and TDS range from 51 to 165 mg/l, 1 to 14 mg/l, 224 to 1,459 mg/l, 0 to 1.5 mg/l and 750 to 2,650 mg/l, respectively. Over a 3-year period, the salinity levels have sharply increased and the average F level has increased by 0.1–0.3 mg/l. An attempt has been made here to discuss the factors causing the variation and escalation of chemical constituents and salinity in the water of the three aquifers.     

Tidal controls on coastal groundwater conditions: field investigation of a macrotidal system

Previous studies of coastal groundwater resources have not properly explored the hydraulic conditions at coastal and estuarine boundaries, despite recognised influences of oceanic and estuarine water-level fluctuations (e.g. tides and waves) on groundwater near these boundaries. Such influences may have important implications for determining submarine groundwater discharge and seawater intrusion. In this paper, oceanic and estuarine controls on the hydrology of coastal aquifers are characterised for a macrotidal system—the Pioneer Valley coastal plain, northeastern Australia. The tidal water-table over-height (tide-induced increase in average water-table height at the coastline) is quantified at three locations and compared with theoretical estimates, which assume simplified physiographical conditions compared with those encountered at the field sites. The results indicate that local geological conditions, beach morphology and characteristics of tidal forcing control the behaviour of nearshore groundwater within the system. Existing analytical and numerical solutions that are commonly applied as first-pass estimates are found to be insufficient for predicting observed tidal water-table over-height in the Pioneer Valley, due to the sediment heterogeneities, non-uniform beach slopes and large tidal ranges of the system. The study reveals the spatial and temporal variability in tidally influenced hydraulic heads at the estuarine and coastal boundaries of the aquifer, and provides estimates of tidal water-table over-height up to 2.41 m during spring tides. These findings highlight the complexity of coastal groundwater systems, and the need to incorporate appropriate nearshore and near-estuary boundary conditions in models of regional groundwater flow in coastal aquifers.     

Evaluation of groundwater quality in coastal areas: implications for sustainable agriculture

Seawater intrusion is a problem in the coastal areas of Korea. Most productive agricultural fields are in the western and southern coastal areas of the country where irrigation predominantly relies on groundwater. Seawater intrusion has affected agricultural productivity. To evaluate progressive encroachment of saline water, the Korean government established a seawater intrusion monitoring well network, especially in the western and southern part of the peninsula. Automatic water levels and EC monitoring and periodic chemical analysis of groundwater help track salinization. Salinization of fresh groundwater is highly associated with groundwater withdrawal. A large proportion of the groundwaters are classified as Na–Cl and Ca–Cl types. The Na–Cl types represent effects of seawater intrusion. The highest EC level was over 1.6 km inland and high Cl values were observed up to 1.2 km inland. Lower ratios of Na/Cl and SO₄/Cl than seawater values indicate the seawater encroachment. A linear relation between Na and Cl represents simple mixing of the fresh groundwater with the seawater. The saline Na–Cl typed groundwaters showed Br/Cl ratios similar to or less than seawater values. The Ca–HCO₃ type groundwaters had the highest Br/Cl ratios. Substantial proportions of the groundwaters showed potential for salinity and should be better managed for sustainable agriculture.     

Fluoride contamination in groundwater resources of Alleppey,southern India

Alleppey is one of the thickly populated coastal towns of the Kerala state in southern India.Groundwater is the main source of drinking water for the 240,991 people living in this region.The groundwater is being extracted from a multi-layer aquifer system of unconsolidated to semi-consolidated sedimentary formations,which range in age from Recent to Tertiary.The public water distribution system uses dug and tube wells.Though there were reports on fluoride contamination,this study reports for the first time excess fluoride and excess salinity in the drinking water of the region.The quality parameters,like Electrical Conductivity(EC) ranges from 266 to 3900 μs/cm,the fluoride content ranges from 0.68 to2.88 mg/L,and the chloride ranges between the 5.7 to 1253 mg/L.The main water types are Na-HC03,NaCO_3 and Na-Cl.The aqueous concentrations of F~- and CO_3~(2-) show positive correlation whereas F~- and Ca~(2+) show negative correlation.The source of fluoride in the groundwater could be from dissolution of fluorapatite,which is a common mineral in the Tertiary sediments of the area.Long residence time,sediment-groundwater interaction and facies changes(Ca-HCO_3 to Na-HCO_3) during groundwater flow regime are the major factors responsible for the high fluoride content in the groundwater of the area.High strontium content and high EC in some of the wells indicate saline water intrusion that could be due to the excess pumping from the deeper aquifers of the area.The water quality index computation has revealed that 62%of groundwater belongs to poor quality and is not suitable for domestic purposes as per BIS and WHO standards.Since the groundwater is the only source of drinking water in the area,proper treatment strategies and regulating the groundwater extraction are required as the quality deterioration poses serious threat to human health.     

Measurement of vertical environmental-head profiles in unconfined sand aquifers using a multi-channel manometer board

The vertical hydraulic gradient in an unconfined sand aquifer frequently exceeds the horizontal gradient when measured close to a surface discharge boundary, around an abstraction bore or close to a saline interface. The vertical gradient can be efficiently investigated using a multi-channel manometer board connected to a bundled piezometer installed using hollow-stem-auger-drilling techniques. The design and construction of a manometer board is described. Manometer board data from a site in a 30-m-deep fresh-water aquifer adjacent to a pumping bore are described. The bore is screened in the lower part of the aquifer and the impacts of partial penetration are evident on the manometer board results. Data are then described from the centre of a coastal sand spit where fresh water overlies saline water. Fluid electrical conductivity measurements from the individual tubes of the bundled piezometer are used to derive fluid density at each of the bundled piezometer ports. The average fluid density of water above the mini-piezometer port at each depth is then calculated using Gaussian quadrature. The environmental-water head profiles are compared to point-water and fresh-water head profiles and the implications of the incorrect use of point-water or fresh-water head vertical profiles are clearly demonstrated.     

The use of geoprocessing to assess vulnerability on the east coast aquifers of Rio de Janeiro State,Brazil

The east coast of Rio de Janeiro State, Brazil, shows a worrying overlap between areas with intrinsic groundwater vulnerability and the most significant urban expansion zones. It experienced a rapid population growth in recent years, mainly due to the tourism industry, resulting in a significant pressure on drinking groundwater resources. In this regard, development and use of techniques to control and protect areas susceptible to contamination is crucial. The elaboration of aquifer vulnerability maps is thus extremely helpful to support water resources management. The aim of the work is to present the methodological approach in the use of Geoprocessing techniques to obtain a suitable groundwater vulnerability model in Rio de Janeiro east coast. Considering the existing problems and the current land use and characteristics of the study region, it is clear that the most vulnerable areas (that is, “extreme” and “very high” vulnerability areas), coincide with the most significant zones of urban occupation, corresponding to 11% of the total study area, demanding adoption of urgent measures in the near future. Geoprocessing tools and remote sensing for characterization of Rio de Janeiro’s east coast aquifer vulnerability gave good results, representing a satisfactory method for management actions at low cost.     

Evaluation and mapping of Dead Sea coastal aquifers salinity using Transient Electromagnetic (TEM) resistivity measurements

Evaporite karst has intensively developed recently along the Dead Sea (DS) coastal area in Israel and Jordan. It takes place in very saline groundwater dissolving buried salt layers, causing collapse of the surface. In this paper, groundwater salinity throughout the DS coastal area is investigated using the Transient Electromagnetic (TEM) method. Twenty-eight TEM soundings along the DS coastal area were carried out close to observation boreholes to calibrate resistivity–salinity relationships. Groundwater electrical conductivity was measured in these boreholes, and its salinity was analyzed at the laboratory by the Geological Survey of Israel (GSI). Quantitative relationships between bulk resistivity (ρ_x), water resistivity (ρ_w) and chloride concentration (C_cl) were derived in the resistivity range less than 1.0 Ω·m that enabled to evaluate the salinity of the aquifer in in situ conditions. Average values of the effective porosity of sandy sediments, φ_e = 0.32, and of silty ones, φ_e = 0.44, were used to generate the corresponding Archie equations. The study has shown that a DS aquifer with bulk resistivity in the range of 0.55–1.0 Ω·m contains in pores brine with 50–110 g_chloride/l of (22–50% of that in saturated conditions, respectively), i.e. it keeps the potential to dissolve up to 114–174 g/l of salt.     

我国潮汐潮流区域预报的发展

简要回顾了我国潮汐潮流区域预报的发展过程。1959—1964年期间按前苏联杜瓦宁方法编制的永久潮流表是第一代预报产品,该产品提供了我国近海若干站点5 m层潮流预报资料。1970—1978年期间按方国洪提出的方法而研制的永久预报图表集是第二代预报产品,提供了基本上覆盖我国近海的多层潮流预报资料;这两代产品均以纸质图表为载体。2005—2006年期间方国洪等研制了第三代预报产品,覆盖了我国近海各海区,分辨率达到5′×5′,垂向10层,并可自动内插到任意点和任意水层。同时介绍了三代产品的研发过程及基本原理。     

Modeling freshening time and hydrochemical evolution of groundwater in coastal aquifers of Shenzhen,China

This work investigated the freshening time and hydrochemical evolution of coastal groundwater in two brackish aquifers in Shenzhen, China. One was the brackish aquifer that resulted from heavy pumping, and the other was the aquifer reclaimed from the coastal sea. Freshening time and hydrochemical evolution of brackish aquifers were quantitatively evaluated using PHREEQC 2.0, a one-dimensional reactive-transport model. Freshening time was shown to mainly depend on pore water velocity, while the chemical composition of groundwater was determined by the cation exchange capacity of the aquifer. It was shown that after heavy pumping ceased, the freshening time for the original coastal aquifer ranged from 20 to over 80 years. While for the coastal reclaimed aquifer, the freshening time was from 85 to 140 years, which depended on the hydraulic conductivity of the fill materials in the reclaimed site. During aquifer freshening, groundwater evolved from Na–Cl type to Ca–Mg–HCO₃ or Na–HCO₃ type. A sensitivity analysis showed that the freshening time was most sensitive to the pore water velocity in the aquifer, while the groundwater chemical composition was most sensitive to the values of cation exchange capacity of the aquifer. As for the dispersivity, it had almost no effect on the freshening time and the chemical composition of groundwater.     

Assessment of groundwater residence times in the pore aquifers of the River Elbe Basin

An area covering assessment of the groundwater residence times for the upper pore aquifers in the River Elbe Basin was performed. Residence times were determined by combining groundwater velocities and flow distances along each flow-path to the surface waters using a two-dimensional model approach. Groundwater velocity was calculated as a function of hydraulic conductivity, hydraulic gradient and effective yield of pore space. Flow paths were obtained by an analysis of the morphology of the groundwater table. The mean groundwater residence time in the pore aquifers of the River Elbe Basin was quantified to about 25 years. A strong temporal blurring in the different regions between less than one year and more than 250 years was obtained. For the regional groundwater management in the Elbe Basin the groundwater residence times are an important parameter, which helps to take into account the temporal dimension in the assessment of the impact of political measures aiming at the improvement of groundwater quality with regard to diffuse pollutants (e.g. nitrate).