Fluid evolution during burial and Variscan deformation in the Lower Devonian rocks of the High-Ardenne slate belt (Belgium): sources and causes of high-salinity and C–O–H–N fluids

Fluid inclusions in quartz veins of the High-Ardenne slate belt have preserved remnants of prograde and retrograde metamorphic fluids. These fluids were examined by petrography, microthermometry and Raman analysis to define the chemical and spatial evolution of the fluids that circulated through the metamorphic area of the High-Ardenne slate belt. The earliest fluid type was a mixed aqueous/gaseous fluid (H₂O–NaCl–CO₂–(CH₄–N₂)) occurring in growth zones and as isolated fluid inclusions in both the epizonal and anchizonal part of the metamorphic area. In the central part of the metamorphic area (epizone), in addition to this mixed aqueous/gaseous fluid, primary and isolated fluid inclusions are also filled with a purely gaseous fluid (CO₂–N₂–CH₄). During the Variscan orogeny, the chemical composition of gaseous fluids circulating through the Lower Devonian rocks in the epizonal part of the slate belt, evolved from an earlier CO₂–CH₄–N₂ composition to a later composition enriched in N₂. Finally, a late, Variscan aqueous fluid system with a H₂O–NaCl composition migrated through the Lower Devonian rocks. This latest type of fluid can be observed in and outside the epizonal metamorphic part of the High-Ardenne slate belt. The chemical composition of the fluids throughout the metamorphic area, shows a direct correlation with the metamorphic grade of the host rock. In general, the proportion of non-polar species (i.e. CO₂, CH₄, N₂) with respect to water and the proportion of non-polar species other than CO₂ increase with increasing metamorphic grade within the slate belt. In addition to this spatial evolution of the fluids, the temporal evolution of the gaseous fluids is indicative for a gradual maturation due to metamorphism in the central part of the basin. In addition to the maturity of the metamorphic fluids, the salinity of the aqueous fluids also shows a link with the metamorphic grade of the host-rock. For the earliest and latest fluid inclusions in the anchizonal part of the High-Ardenne slate belt the salinity varies respectively between 0 and 3.5 eq.wt% NaCl and between 0 and 2.7 eq.wt% NaCl, while in the epizonal part the salinity varies between 0.6 and 17 eq.wt% NaCl and between 3 and 10.6 eq.wt% for the earliest and latest aqueous fluid inclusions, respectively. Although high salinity fluids are often attributed to the original sedimentary setting, the increasing salinity of the fluids that circulated through the Lower Devonian rocks in the High-Ardenne slate belt can be directly attributed to regional metamorphism. More specifically the salinity of the primary fluid inclusions is related to hydrolysis reactions of Cl-bearing minerals during prograde metamorphism, while the salinity of the secondary fluid inclusions is rather related to hydration reactions during retrograde metamorphism. The temporal and spatial distribution of the fluids in the High-Ardenne slate belt are indicative for a closed fluid flow system present in the Lower Devonian rocks during burial and Variscan deformation, where fluids were in thermal and chemical equilibrium with the host rock. Such a closed fluid flow system is confirmed by stable isotope study of the veins and their adjacent host rock for which uniform δ¹⁸0 values of both the veins and their host rock demonstrate a rock-buffered fluid flow system.     

Textural and isotopic development of marble assemblages during the Barrovian-style M2 metamorphic event,Naxos, Greece

A detailed petrological analysis of the marble assemblages observed within the M2 metamorphic complex on Naxos is presented. Two distinct periods of mineral growth are documented; the first is associated with prograde M2 metamorphism and the second with retrograde M2 metamorphism occurring during ductile extensional thinning of the complex. The textural and miner-alogical characteristics and the carbon and oxygen isotope compositions of each generation are described, and the P-T-X _{CO 2} conditions at which these two mineral generations were stable, and the compositions of the fluids present during metamorphism are characterised. Whereas the low variance and stable isotope compositions of prograde siliceous dolomite assemblages are consistent with internally buffered fluid evolution, the retrograde mineral generation is shown to have grown as a result of the infiltration of a water-rich fluid phase that transported silica, Al₂O₃, Na₂O and FeO into the host rocks. This observation, together with the stable isotope compositions of the retrograde calcite, and the fact that occurrences of veins of this type are limited to marbles in the highest grade areas (T>600° C) of the metamorphic complex, suggests that the fluids responsible for vein formation were generated during the crystallisation of melts as the metamorphic complex cooled from peak temperatures. The existence of this second generation of minerals has significant implications for previous studies of heat transport by fluid flow on Naxos, because many of the unusually low ¹⁸O compositions of pelites at high grades may be ascribable to the effects of interaction with retrograde M2 fluids, rather than with prograde fluids.     

Deformational history of the Precambrian Kolar Schist Belt,South India: Constraints for the tectonic evolution

In the Kolar Schist Belt well-preserved small-scale diastrophic structures suggest four phases of folding (F₁ — F₄). The near coaxial F₁ andF ₂folds are both isoclinal with long-drawn out limbs and sharp hinges. The axial planes of bothF ₁andF ₂folds are subvertical with N-S strikes; these control the linear outcrop pattern of the Schist belt. The later folds (F ₃and F₄) are important in small-to-intermediate scales only and are accommodation structures formed during the relaxation period of the early folding episodes. Mesoscopic shear zones, post-F₂ but pre-F₃ in age, are present in all the rock types in this area. The F₁ and F₂ folds and the mesoscopic shear zones were formed during a continuous E-W subhorizontal compression. Available geochemical and isotopic data show that the Kolar Schist Belt with ensimatic setting is bounded by two granitic terrains of contrasting evolutionary histories. This, together with E-W subhorizontal compression over a protracted period of time, strengthens the recent suggestions that the Kolar Schist Belt represents a suture. This belt then marks the site of a continent-continent collision event of late Archaean-early Proterozoic age.     

Geometry and evolution of superposed folding in the Zawar lead-zinc mineralised belt,Rajasthan

The lead-zinc bearing Proterozoic rocks of Zawar, Rajasthan, show classic development of small-scale structures resulting from superposed folding and ductile shearing. The most penetrative deformation structure noted in the rocks is a schistosity (S ₁) axial planar to a phase of isoclinal folding (F ₁). The lineations which parallel the hinges ofF ₁ folds are deformed by a set of folds (F ₂) having vertical or very steep axial planes. At many places a crenulation cleavage (S ₂) has developed subparallel to the axial planes ofF ₂ folds, particularly in the psammopelitic rocks. The plunge and trend ofF ₂ folds vary widely over the area. Deformation ofF ₂ folds into hook-shaped geometry and development of another set of axial planar crenulation cleavage are the main imprints of the third generation folds (F ₃) in the region. In addition to these, there are at least two other sets of cleavage planes with corresponding folds in small scales. More common among these is a set of recumbent and reclined folds (F ₄), developed on steeply dipping early-formed planes. Kink bands and associated sharp-hinged folds represent the other set (F ₅). Two major refolded folds are recognizable in the map pattern of the Zawar mineralised belt. The larger of the two, the Main Zawar Fold (MZF), shows a broad hook-shaped geometry. The other large-scale structure is the Zawarmala fold, lying south-west of the MZF. Both the major structures show truncation of lithological units along their respective east ‘limbs’, and extreme variation in the width of formations. The MZF is primarily the result of superimposition ofF ₃ onF ₂.F ₁ folds are relatively smaller in scale and are recognizable in the quartzite unit which responded to deformation mainly by buckle shortening. Large-scale pinching-and-swelling that appears in the outcrop pattern seems to be a pre-F₂ feature. The structural evolutionary model worked out to explain the chronology of the deformational features and the large-scale out-crop pattern envisages extreme east-west shortening following formation ofF ₁ structures, resulting in the formation of tight and isoclinal antiforms (F ₂) with pinched-in synforms in between. These latter zones evolved into a number of ductile shear zones (DSZs). The east-west refolding of the large-scaleF ₂ isoclinal antiforms seems to be the consequence of a continuous deformation and resultant migration of folds along the DSZs. The main shear zone which wraps the Zawar folds followed a curved path. Because of the penetrative nature of theF ₂ movement, the early lineations which were at high angles to the later ones (as is evident in the west of Zawarmala), became subparallel to the trend ofF ₂ folding over a large part of the area. Further, the virtually coaxial nature ofF ₂ andF ₃ folds and the refolding ofF ₃ folds by a new set of N-S folds is an indication of continuous progressive deformation.     

The nature of fluids during pegmatite development in metamorphic terrains: Evidence from Hamadan complex,Sanandaj-Sirjan metamorphic zone,Iran

In the Sanandaj-Sirjan zone of metamorphic belt of Iran, the area south of Hamadan city comprises of metamorphic rocks, granitic batholith with pegmatites and quartz veins. Alvand batholith is emplaced into metasediments of early Mesozoic age. Fluid inclusions have been studied using microthermometry to evaluate the source of fluids from which quartz veins and pegmatites formed to investigate the possible relation between host rocks of pegmatites and the fluid inclusion types. Host minerals of fluid inclusions in pegmatites are quartz, andalusite and tourmaline. Fluid inclusions can be classified into four types. Type 1 inclusions are high salinity aqueous fluids (NaCl_eq >12 wt%). Type 2 inclusions are low to moderate salinity (NaCl_eq <12 wt%) aqueous fluids. Type 3 and 4 inclusions are carbonic and mixed CO₂-H₂O fluid inclusions. The distribution of fluid inclusions indicate that type 1 and type 2 inclusions are present in the pegmatites and quartz veins respectively in the Alvand batholith. This would imply that aqueous magmatic fluids with no detectable CO₂ were present during the crystallization of these pegmatites and quartz veins. Types 3 and 4 inclusions are common in quartz veins and pegmatites in metamorphic rocks and are more abundant in the hornfelses. The distribution of the different types of fluid inclusions suggests that CO₂ fluids generated during metamorphism and metamorphic fluids might also contribute to the formation of quartz veins and pegmatites in metamorphic terrains.     

Mega-fold interference patterns in the Beishan orogen (NW China) created by change in plate configuration during Permo-Triassic termination of the Altaids

Kilometer-size fold interference patterns in the Beishan Orogenic Collage (BOC) in the southernmost Altaids formed by fold superimposition in fossiliferous Permian sedimentary rocks. First-phase (F₁), upright and almost north-trending folds, were refolded by E- to ENE-trending F₂ folds, whose axial planes and axes are vertical or subvertical. From east to west there is a regional change in style of interference patterns from lobate–cuspate-, to crescent- to mushroom-shape. This variation is accompanied by a westward decrease in the F₂ interlimb angle and related to a higher percentage of coarse-grained clastic rocks, suggesting a dependence of the F₂ deformation on lithology. Axial planar slaty cleavages are well developed in F₁ and poorly developed in F₂ folds. The superposed folds mainly underwent flexural-slip and flexural flow folding to give rise to the lobate–cuspate pattern, and to the crescent pattern caused by flattening and flexural flow folding where the sediments were unconsolidated and enriched in fluids. The two folding events are interpreted to result from a major change in plate configuration that caused the inversion of an inter-arc basin during the final amalgamation of the BOC in the latest Permian to early to mid-Triassic. The two folding events bracketed between a maximum detrital zircon age of <273 Ma, and the youngest age of an intruded dyke at 219.0 ± 1.2 Ma suggest rapid plate reconfiguration related to final amalgamation of the Altaids orogen.     

Extensional tectonic origin of gneissosity and related structures of the Feiran–Solaf metamorphic belt, Sinai, Egypt

The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S₁, and is almost everywhere parallel to lithological layering, S₀. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S₀. S₁ formed by coaxial pure shear flattening strain (Z normal to S₀, i.e. vertical; with X and Y both extensional and lying in S₁). This strain also produced chocolate tablet boudinage of some layers and S₁-concordant sills and veins. S₁ has a strong stretching lineation L₁ with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L₁-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F₁ folds with hinges parallel to the stretching lineation. F₁ fold asymmetry variations do not support previous models involving macroscopic F₁ folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.     

New constraints on UHT metamorphism in the Eastern Ghats Province through the application of phase equilibria modelling and in situ geochronology

High Mg–Al granulites from the Sunki locality in the central portion of the Eastern Ghats Province record evidence for the high-temperature peak and retrograde evolution. Peak metamorphic phase assemblages from two samples are garnet + orthopyroxene + quartz + ilmenite + melt and orthopyroxene + spinel + sillimanite + melt, respectively. Isochemical phase diagrams (pseudosections) based on bulk rock compositions calculated in the chemical system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) and Al contents in orthopyroxene indicate peak UHT metamorphic conditions in excess of 960 °C and 9.7 kbar. Microstructures and the presence of cordierite interpreted to record the post-peak evolution show that the rocks underwent decompression and minor cooling from conditions of peak UHT metamorphism to conditions of ~ 900 °C at ~ 7.5 kbar. In situ U–Pb isotope analyses of monazite associated with garnet and cordierite using the Sensitive High Resolution Ion Microprobe (SHRIMP) yield a weighted mean ²⁰⁷Pb/²³⁵U age of ca. 980 Ma, which is interpreted to broadly constrain the timing of high-temperature monazite growth during decompression and melt crystallization at ~ 900–890 °C and 7.5 kbar. However, the range of ²⁰⁷Pb/²³⁵U monazite ages (from ca. 1014 Ma to 959 Ma for one sample and ca. 1043 Ma to 922 Ma for the second sample) suggest protracted monazite growth during the high-temperature retrograde evolution, and possibly diffusive lead loss during slow cooling after decompression. The results of the integrated petrologic and geochronologic approach presented here are inconsistent with a long time gap between peak conditions and the formation of cordierite-bearing assemblages at lower pressure, as proposed in previous studies, but are consistent with a simple evolution of a UHT peak followed by decompression and cooling.     

Superposed folding in the Honakere arm of the Chitradurga-Karighatta schist belt in the Dharwar tectonic province,southern India,and its bearing on the Sargur-Dharwar relation

The supracrustal enclave within the Peninsular Gneiss in the Honakere arm of the Chitradurga-Karighatta belt comprises tremolite-chlorite schists within which occur two bands of quartzite coalescing east of Jakkanahalli(12°39′N; 76°41′E), with an amphibolite band in the core. Very tight to isoclinal mesoscopic folds on compositional bands cut across in the hinge zones by an axial planar schistosity, and the nearly orthogonal relation between compositional bands and this schistosity at the termination of the tremolite-chlorite schist band near Javanahalli, points to the presence of a hinge of a large-scale, isoclinal early fold (F₁). That the map pattern, with an NNE-plunging upright antiform and a complementary synform of macroscopic scale, traces folds 'er generation (F ₂),is proved by the varying attitude of both compositional bands (S₀) and axial pranar schistosity (S ₁), which are effectively parallel in a major part of the area. A crenulation cleavage (S ₂) has developed parallel to the axial planes of theF ₂ folds at places. TheF ₂ folds range usually from open to rarely isoclinal style, with theF ₁ andF ₂ axes nearly parallel. Evidence of type 3 fold interference is also provided by the map pattern of a quartzite band in the Borikoppalu area to the north, coupled with younging directions from current bedding andS ₀ -S ₁ inter-relation. Although statistically theF ₁ andF ₂ linear structures have the same orientation, detailed studies of outcrops and hand specimens indicate that the two may make as high an angle as 90°. Usually, in these instances, theF ₁ lineations are unreliable around theF ₂ axes, implying that theF ₂ folding was by flexural slip. In zones with very tight to almost isoclinalF ₂ folding, however, buckling attendant with flattening has caused a spread of theF ₁ lineations almost in a plane. Initial divergence in orientation of theF ₁ lineations due to extreme flattening duringF ₁ folding has also resulted in a variation in the angle between theF ₁ andF ₂lineations in some instances. Upright later folding (F₃) with nearly E-W strike of axial planes has led to warps on schistosity, plunge reversals of theF ₁ andF ₂ axes, and increase in the angle between theF ₁ andF ₂ lineations at some places. Large-scale mapping in the Borikoppalu sector, where the supposed Sargur rocks with ENE ‘trend’ abut against the N-‘trending’ rocks of the Dharwar Supergroup, shows a continuity of rock formations and structures across the hinge of a large-scaleF ₂ fold. This observation renders the notion, that there is an angular unconformity here between the rocks of the Sargur Group and the Dharwar Supergroup, untenable.     

Structural pattern and strain history of a superposed fold system in the Precambrian of Central Rajasthan,India. II. Strain history

Analysis of shapes of folds, together with other structures such as axial plane foliation boudinage, mullions and cross joints, show that the F₁ folds in the ‘main Raialo syncline’ were formed by buckling, and were subsequently modified by flattening normal to the axial planes and lengthening along the axis. The apparent buckle shortening of the F₁ folds generally ranges between 70 and 80%. The folds were formed by simple shear (giving place to pure shear at certain stages) in an almost north-south direction on subhorizontal beds. Progressive deformation in the later stage of F₁ folding resulted in gentle upright folding of F₁ axial planes on F₁′ axes slightly oblique to F₁. The F₂ folds, whose average shortening ranges from 20 to 30%, were also formed by buckling caused by horizontal compression in a nearly northwest-southeast direction. This folding was preceded and followed in some instances by homogeneous strain, as deduced fro mthe shapes of the F₂ folds and the nature of variation of the F₁ lineations. The F₃ conjugate structures developed when the maximum compressive strain was vertical and the intermediate compressive strain northwest-southeast, almost normal to the subvertical F₂ axial planes. The increase in the amplitude of the F₂ folds in the last phase of F₂ folding in certain zones resulted in an excess of vertical load, which dissipated with the formation of the F₃ structures. In the last stage of movement (F₄) the maximum compressive strain became horizontal along the strike of F₂ axial planes, whereas the minimum compressive strain was normal to them. The F₄ structures, therefore, point to a longitudinal shortening with reference to large scale F₂ folding.     

Structural analysis and implicit 3D modelling of high-grade host rocks to the Venetia kimberlite diatremes,Central Zone,Limpopo Belt,South Africa

The Beit Bridge Complex of the Central Zone (CZ) of the Limpopo Belt hosts the 519 ± 6 Ma Venetia kimberlite diatremes. Deformed shelf- or platform-type supracrustal sequences include the Mount Dowe, Malala Drift and Gumbu Groups, comprising quartzofeldspathic units, biotite-bearing gneiss, quartzite, metapelite, metacalcsilicate and ortho- and para-amphibolite. Previous studies define tectonometamorphic events at 3.3–3.1 Ga, 2.7–2.5 Ga and 2.04 Ga. Detailed structural mapping over 10 years highlights four deformation events at Venetia. Rules-based implicit 3D modelling in Leapfrog Geo™ provides an unprecedented insight into CZ ductile deformation and sheath folding. D₁ juxtaposed gneisses against metasediments. D₂ produced a pervasive axial planar foliation (S₂) to isoclinal F₂ folds. Sheared lithological contacts and S₂ were refolded into regional, open, predominantly southward-verging, E–W trending F₃ folds. Intrusion of a hornblendite protolith occurred at high angles to incipient S₂. Constrictional-prolate D₄ shows moderately NE-plunging azimuths defined by elongated hornblendite lenses, andalusite crystals in metapelite, crenulations in fuchsitic quartzite and sheath folding. D₄ overlaps with a: 1) 2.03–2.01 Ga regional M₃ metamorphic overprint; b) transpressional deformation at 2.2–1.9 Ga and c) 2.03 Ga transpressional, dextral shearing and thrusting around the CZ and d) formation of the Avoca, Bellavue and Baklykraal sheath folds and parallel lineations.     

Relationship between CO2-dominated fluids,hydrothermal alterations and gold mineralization in the Red Lake greenstone belt,Canada

The Red Lake greenstone belt is one of the foremost Au mining camps in Canada and hosts the world-class Campbell-Red Lake Au deposit. Belt-scale hydrothermal alteration is characterized by proximal ferroan dolomite zones associated with Au mineralization surrounded by distal calcite zones, both being accompanied by potassic alterations (sericite, muscovite, and biotite). At the Campbell-Red Lake and Cochenour deposits Au mineralization (in particular high-grade ore) is associated with silica and sulfides (especially arsenopyrite) that replace carbonate ± quartz veins and the host rocks. The prevalence of carbonic fluid inclusions and rare occurrence of aqueous-bearing inclusions in carbonate–quartz–Au veins in the Campbell-Red Lake deposit, and the consistency of homogenization temperatures of carbonic inclusions within individual fluid inclusion assemblages (FIA), have been interpreted to indicate that H₂O-poor, CO₂-dominated fluids were responsible for the carbonate veining and Au mineralization. Further studies of fluid inclusions in carbonate–quartz veins within and outside the deformation zone hosting the Campbell-Red Lake deposit (the Red Lake Mine trend) including the Cochenour Au deposit, the Redcon Au prospect, and outcrops in the distal calcite zone also reveal the dominance of carbonic fluid inclusions in vein minerals. These studies indicate that CO₂-dominated fluids were flowing through fractures during carbonate vein formation and Au mineralization both within and outside major structures. The carbonic fluid may have been initially undersaturated with water, or it may have resulted from phase separation of an H₂O–CO₂–NaCl fluid. In the latter case, phase separation modeling indicates that the initial fluid likely had XCO₂${\text{X}}_{{\text{CO}}_2}$ values larger than 0.8. Calculations based on hydrothermal mineral assemblages indicate XCO₂${\text{X}}_{{\text{CO}}_2}$ values in the host rocks from 0.025 to 0.85, reflecting a change from CO₂-dominated fluids in the fractures (veins) to H₂O-dominated fluids in the host rocks away from the fractures. The CO₂-dominated fluids were likely advected from granulite facies in the deeper crust, whereas the H₂O-dominated fluids were derived from the ambient host rocks of amphibole to greenschist facies. Calculations based on CO₂ requirements and source constraints indicate that the mineralizing fluids were likely two orders of magnitude more enriched in Au than the commonly assumed values of a few μg/L, which may explain why the Campbell-Red Lake deposit has a very high-grade of Au (average 21 g/t for the whole deposit and 81 g/t for the Goldcorp High-Grade zone). Fluid inclusion data suggest that the carbonate veining and Au mineralization likely took place at depths from 7 to 14 km. The development of crustiform–colloform structures in the carbonate ± quartz veins, which was previously interpreted to indicate relatively shallow environments, may alternatively have been related to extremely high fluid pressures and the CO₂-dominated nature of the fluids, which could have enhanced the brittle properties of the rocks due to their high wetting angles.     

Fluid record of rock exhumation across the brittle–ductile transition during formation of a Metamorphic Core Complex (Naxos Island,Cyclades, Greece)

Fluid inclusions trapped in quartz veins hosted by a leucogneiss from the southern part of the Naxos Metamorphic Core Complex (Attic‐Cycladic‐Massif, Greece) were studied to determine the evolution of the fluid record of metamorphic rocks during their exhumation across the ductile/brittle transition. Three sets of quartz veins (V‐M2, V‐BD & V‐B) are distinguished. The V‐M2 and V‐BD are totally or, respectively, partially transposed into the foliation of the leucogneiss. They formed by hydrofracturing alternating with ductile deformation accommodated by crystal‐plastic deformation. The V‐B is discordant to the foliation and formed by fracturing during exhumation without subsequent ductile transposition. Fluids trapped during crystal–plastic deformation comprise two very distinct fluid types, namely a CO₂‐rich fluid and a high‐salinity brine, that are interpreted to represent immiscible fluids generated from metamorphic reactions and the crystallization of magmas respectively. They were initially trapped at ～625 °C and 400 MPa and then remobilized during subsequent ductile deformation resulting in various degrees of mixing of the two end‐members with later trapping conditions of ～350 °C and 140 MPa. In contrast, brittle microcracks contain aqueous fluids trapped at 250 °C and 80 MPa. All veins display a similar δ¹³C pointing to carbon that was trapped at depth and then preserved in the fluid inclusions throughout the exhumation history. In contrast, the δD signature is marked by a drastic difference between (i) V‐M2 and V‐BD veins that are dominated by carbonic, aqueous‐carbonic and high‐salinity fluids of metamorphic and magmatic origin characterized by δD between ?56‰ and ?66‰, and (ii) V‐B veins that are dominated by aqueous fluids of meteoric origin characterized by δD between ?40‰ and ?46‰. The retrograde P–T pathway implies that the brittle/ductile transition separates two structurally, chemically and thermally distinct fluid reservoirs, namely (i) the ductile crust into which fluids originating from crystallizing magmas and fluids in equilibrium with metamorphic rocks circulate through a geothermal gradient of 30 °C km^?1 at lithostatic pressure, and (ii) the brittle upper crust through which meteoric fluids percolate through a high geothermal gradient of 55 °C km^?1 at hydrostatic pressure.     

Structural pattern and strain history of a superposed fold system in the Precambrian of Central Rajasthan,India. I. Structural pattern in the ‘main Raialo syncline’, Central Rajasthan

Marble, calc-silicate rock, quartzite and mica schist of Precambrian age in the ‘main Raialo syncline’ in the Udaipur district of central Rajasthan, India, have been affected by folding of four main generations (F₁–F₄), the first two of which are seen in the scale of map to microsection. The very tight to isoclinal F₁ folds with long limbs and thickened hinges are generally reclined or inclined, and plunge gently castward or westward where least reoriented. The axial planes of the F₁ folds have been involved in upright warps on east-west axes (F₁′), nearly coaxial with the F₁ folds, in some sectors. These folds have been overprinted by upright F₂ folding of varying tightness with the axial planes striking north to northeast, resulting in interference patterns of different types in all scales. A penetrative axial plane foliation related to F₁ folding and a crenulation cleavage parallel to the F₂ axial pianes are seen in the micaceous rocks. Two sets of conjugate folds and kink bands of smail scale have been superimposed on the F₁–F₂ folds in thinly foliated rocks. The first of these sets (F₃) has its conjugate axial planes dipping gently northeast and southwest, whereas the paired axial planes of the later set (F₄) are vertical with north-northwest and east-west strikes.     

Tectonic setting of the Balaram-Kui-Surpagla-Kengora granulites of the South Delhi Terrane of the Aravalli Mobile Belt,NW India and its implication on correlation with the East African Orogen in the Gondwana assembly

Granulites are developed in various tectonic settings and during different geological periods, and have been used for continental correlation within supercontinent models. In this context the Balaram-Kui-Surpagla-Kengora granulites of the South Delhi Terrane of the Aravalli Mobile Belt of northwestern India are significant. The granulites occur as shear zone bounded lensoidal bodies within low-grade rocks of the South Delhi Terrane and comprise pelitic and calcareous granulites, a gabbro-norite-basic granulite suite and multiple phases of granites of the Ambaji suite. The granulites have undergone three major phases of folding and shearing. The F₁ and F₂ folds are coaxial along NE-SW axis, and F₃ folds are developed across the former along NW-SE axis. Thus, various types of interference patterns are produced. The granulite facies metamorphism is marked by a spinel–cordierite–garnet–sillimanite–quartz assemblage with melt phase and is synkinematic to the F₁ phase of folding. The peak thermobarometric condition is set at ≥850 °C and 5.5–6.8 kb. The granulites have been exhumed through thrusting along multiple ductile shear zones during syn- to post-F₂ folding. Late-stage shearing has produced cataclasites and pseudotachylites. Sensitive High Resolution Ion MicroProbe (SHRIMP) U–Pb dating of zircon from pelitic granulites and synkinematically emplaced granites indicate that: (1) the sedimentary succession of the South Delhi Terrane was deposited between 1240 and 860 Ma with detritus derived from magmatic sources with ages between 1620 and 1240 Ma; (2) folding and granulite metamorphism have taken place between ca. 860 and 800 Ma, and exhumation at around ca. 800–760 Ma; and (3) the last phase of granitic activity occurred at ca. 759 Ma. This shows, for the first time, that the granulites of the South Delhi Terrane are much younger than those of the Sandmata Granulite Complex of the northern part of the Aravalli Mobile Belt, the Saussar granulites of the Central India Mobile Belt and the Eastern Ghats Mobile Belt. Instead, they show similarities to the Neoproterozoic granulites of the Circum Indian Orogens that include the East African Orogen (East Africa and Madagascar), the Southern Granulite Terrane of India and much of Sri Lanka. We suggest that the South Delhi Basin probably marks a trace of the proto-Mozambique Ocean in NW India within Gondwana, that closed when the Marwar Craton, arc fragments (Bemarivo Belt in Madagascar and the Seychelles) and components of the Arabian-Nubian Shield collided with the Aravalli-Bundelkhand Protocontinent at ca. 850–750 Ma.     

Transpressional deformation,strain partitioning and fold superimposition in the southern Chinese Altai,Central Asian Orogenic Belt

Transpressional deformation has played an important role in the late Paleozoic evolution of the western Central Asian Orogenic Belt (CAOB), and understanding the structural evolution of such transpressional zones is crucial for tectonic reconstructions. Here we focus on the transpressional Irtysh Shear Zone with an aim at understanding amalgamation processes between the Chinese Altai and the West/East Junggar. We mapped macroscopic fold structures in the southern Chinese Altai and analyzed their relationships with the development of the adjacent Irtysh Shear Zone. Structural observations from these macroscopic folds show evidence for four generations of folding and associated fabrics. The earlier fabric (S₁), is locally recognized in low strain areas, and is commonly isoclinally folded by F₂ folds that have an axial plane orientation parallel to the dominant fabric (S₂). S₂ is associated with a shallowly plunging stretching lineation (L₂), and defines ∼NW-SE tight-close upright macroscopic folds (F₃) with the doubly plunging geometry. F₃ folds are superimposed by ∼NNW-SSE gentle F₄ folds. The F₃ and F₄ folds are kinematically compatible with sinistral transpressional deformation along the Irtysh Shear Zone and may represent strain partitioning during deformation. The sub-parallelism of F₃ fold axis with the Irtysh Shear Zone may have resulted from strain partitioning associated with simple shear deformation along narrow mylonite zones and pure shear-dominant deformation (F₃) in fold zones. The strain partitioning may have become less efficient in the later stage of transpressional deformation, so that a fraction of transcurrent components was partitioned into F₄ folds.     

Structural history of the Arthur Lineament,northwest Tasmania: An analysis of critical outcrops

The Arthur Lineament of northwestern Tasmania is a Cambrian (510 ± 10 Ma) high‐strain metamorphic belt. In the south it is composed of metasedimentary and mafic meta‐igneous lithologies of the ‘eastern’ Ahrberg Group, Bowry Formation and a high‐strain part of the Oonah Formation. Regionally, the lineament separates the Rocky Cape Group correlates and ‘western’ Ahrberg Group to its west from the relatively low‐strain parts of the Oonah Formation, and the correlated Burnie Formation, to its east. Early folding and thrusting caused emplacement of the allochthonous Bowry Formation, which is interpreted to occur as a fault‐bound slice, towards the eastern margin of the parautochthonous ‘eastern’ Ahrberg Group metasediments. The early stages of formation of the Arthur Lineament involved two folding events. The first deformation (CaD₁) produced a schistose axial‐planar fabric and isoclinal folds synchronous with thrusting. The second deformation (CaD₂) produced a coarser schistosity and tight to isoclinal folds. South‐plunging, north‐south stretching lineations, top to the south shear sense indicators, and south‐verging, downward‐facing folds in the Arthur Lineament suggest south‐directed transport. CaF₁ and CaF₂ were rotated to a north‐south trend in zones of high strain during the CaD₂ event. CaD₃, later in the Cambrian, folded the earlier foliations in the Arthur Lineament and produced west‐dipping steep thrusts, creating the linear expression of the structure.     

Discrete proterozoic structural terranes associated with low-P, high-T metamorphism, Anmatjira Range, Arunta Inlier, central Australia: tectonic implications

Structural overprinting relationships indicate that two discrete terranes, Mt. Stafford and Weldon, occur in the Anmatjira Range, northern Arunta Inlier, central Australia. In the Mt. Stafford terrane, early recumbent structures associated with D_1a,_1b deformation are restricted to areas of granulite facies metamorphism and are overprinted by upright, km-scale folds F_1c), which extend into areas of lower metamorphic grade. Structural relationships are simple in the low—grade rocks, but complex and variable in higher grade equivalents. The three deformation events in the Mt. Stafford terrane constitute the first tectonic cycle (D₁-D₂) deformation in the Weldon terrane comprises the second tectonic cycle. The earliest foliation (S_2a) was largely obliterated by the dominant reclined to recumbent mylonitic foliation (S_2b), produced during progressive non-coaxial deformation, with local sheath folds and W- to SW-directed thrusts. Locally, (D_2d) tectonites have been rotated by N—S-trending, upright (F_2c) folds, but the regional upright fold event (F_2d), also evident in the adjacent Reynolds Range, rotated earlier surfaces into shallow-plunging, NW—SE-trending folds that dominate the regional outcrop pattern.The terranes can be separated on structural, metamorphic and isotopic criteria. A high-strain D₂ mylonite zone, produced during W- to SW-directed thrusting, separates the Weldon and Mt. Stafford terranes. 1820 Ma megacrystic granites in the Mt. Stafford terrane intruded high-grade metamorphic rocks that had undergone D_1a and D_1b deformation, but in turn were deformed by S_1c, which provides a minimum age limit for the first structural—metamorphic event. 1760 Ma charnockites in the Weldon terrane were emplaced post-D_2a, and metamorphosed under granulite facies conditions during D_2b, constraining the second tectonic cycle to this period.Each terrane is associated with low-P, high-T metamorphism, characterized by anticlockwise P—T—t paths, with the thermal peaks occurring before or very early in the tectonic cycle. These relations are not compatible with continental-style collision, nor with extensional tectonics as the deformation was compressional. The preferred model involves thickening of previously thinned lithosphere, at a stage significantly after (>50 Ma) the early extensional event. Compression was driven by external forces such as plate convergence, but deformation was largely confined to and around composite granitoid sheets in the mid-crust. The sheets comprise up to 80% of the terranes and induced low-P, high-T metamorphism, including migmatization, thereby markedly reducing the yield strength and accelerating deformation of the country rocks. Mid-crustal ductile shearing and reclined to recumbent folding resulted, followed by upright folding that extended beyond the thermal anomaly. Thus, thermal softening induced by heat-focusing is capable of generating discrete structural terranes characterized by subhorizontal ductile shear in the mid-crust, localized around large granitoid intrusions.     

Genesis of superimposed hypogene and supergene Fe orebodies in BIF at the Madoonga deposit, Yilgarn Craton, Western Australia

The Madoonga iron ore body hosted by banded iron formation (BIF) in the Weld Range greenstone belt of Western Australia is a blend of four genetically and compositionally distinct types of high-grade (>55 wt% Fe) iron ore that includes: (1) hypogene magnetite–talc veins, (2) hypogene specular hematite–quartz veins, (3) supergene goethite–hematite, and (4) supergene-modified, goethite–hematite-rich detrital ores. The spatial coincidence of these different ore types is a major factor controlling the overall size of the Madoonga ore body, but results in a compositionally heterogeneous ore deposit. Hypogene magnetite–talc veins that are up to 3 m thick and 50 m long formed within mylonite and shear zones located along the limbs of isoclinal, recumbent F₁ folds. Relative to least-altered BIF, the magnetite–talc veins are enriched in Fe₂O_3(total), P₂O₅, MgO, Sc, Ga, Al₂O₃, Cl, and Zr; and depleted in SiO₂ and MnO₂. Mafic igneous countryrocks located within 10 m of the northern contact of the mineralised BIF display the replacement of primary igneous amphibole and plagioclase, and metamorphic chlorite by hypogene ferroan chlorite, talc, and magnetite. Later-forming, hypogene specular hematite–quartz veins and their associated alteration halos partly replace magnetite–talc veins in BIF and formed during, to shortly after, the F₂-folding and tilting of the Weld Range tectono-stratigraphy. Supergene goethite–hematite ore zones that are up to 150 m wide, 400 m long, and extend to depths of 300 m replace least-altered BIF and existing hypogene alteration zones. The supergene ore zones formed as a result of the circulation of surface oxidised fluids through late NNW- to NNE-trending, subvertical brittle faults. Flat-lying, supergene goethite–hematite-altered, detrital sediments are concentrated in a paleo-topographic depression along the southern side of the main ENE-trending ridge at Madoonga. Iron ore deposits of the Weld Range greenstone belt record remarkably similar deformation histories, overprinting hypogene alteration events, and high-grade Fe ore types to other Fe ore deposits in the wider Yilgarn Craton (e.g. Koolyanobbing and Windarling deposits) despite these Fe camps being presently located more than 400 km apart and in different tectono-stratigraphic domains. Rather than the existence of a synchronous, Yilgarn-wide, Fe mineralisation event affecting BIF throughout the Yilgarn, it is more likely that these geographically isolated Fe ore districts experienced similar tectonic histories, whereby hypogene fluids were sourced from commonly available fluid reservoirs (e.g. metamorphic, magmatic, or both) and channelled along evolving structures during progressive deformation, resulting in several generations of Fe ore.     

Planar, non-planar and refolded sheath folds in the Phulad Shear Zone, Rajasthan, India

Progressive ductile shearing in the Phulad Shear Zone of Rajasthan, India has produced a complex history of folding, with development of planar, non-planar and refolded sheath folds. There are three generations of reclined folds, F₁, F₂ and F₃, with a striping lineation (L₁) parallel to the hinge lines of F₁. The planar sheath folds of F₁ have long subparallel hinge lines at the flanks joining up in hairpin curves at relatively small apices. L₁ swerves harmoniously with the curving of F₁ hinge line. There is a strong down-dip mineral lineation parallel to the striping lineation in most places, but intersecting it at apices of first generation sheath folds. Both the striping and the mineral lineation are deformed in U-patterns over the hinges of reclined F₂ and F₃. Folding of axial surfaces and hinge lines of earlier reclined folds by later folds was accompanied by very large stretching and led to the development of non-planar sheaths. The reclined folds of all the three generations were deformed by a group of subhorizontal folds. Each generation of fold initially grew with the hinge line at a very low angle with the Y-axis of bulk non-coaxial strain and was subsequently rotated towards the down-dip direction of maximum stretching. The patterns of deformed lineations indicate that the stretching along the X-direction was extremely large, much in excess of 6000 percent.