Volatile fluxes from volcanoes

Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-³He, ²¹⁰Po, SO₂-and chemical ratios of volatile species in lavas and volcanic gases.
These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO₂, SO₂ and trace metals.
They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them.
The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction.     

Subduction fluxes through geologic time

Much of the author’s research career has been spent working both on modern oceanic volcanic systems and at the same time looking at their Archaean counterparts. Many authors have attempted to make inferences on early Earth models based on modern processes which can be increasingly well constrained. In this short review it will be shown how we are beginning to understand and quantify inputs to modern subduction systems and some questions are posed as to how these processes may have affected Earth’s evolution in its distant past.     

Anthropogenic heat fluxes in urban agglomerations

Doklady Earth Sciences -     

Manganese fluxes from Mississippi Delta sediments

Massive sediment deposition on the Mississippi River Delta establishes reducing conditions sufficient to bring about Mn dissolution in the top millimeters of sediment. As a result, significant fluxes of dissolved Mn pass from the Delta sediments to the overlying water column. This process is examined by study of chemical partitioning of Mn in river particulates and Delta sediments and from interstitial water chemistry. Remobilized Mn is actively transported away from the Delta area with aluminosilicate detritus thereby providing “excess” Mn to the deep Gulf of Mexico at the expense of the Delta sediments.     

Estimates of sediment fluxes in Long Island Sound

Monthly measurements of suspended sediment concentration and salinity were made at 29 stations along the axis of Long Island Sound from August 1987 through February 1988. The measurements were combined in a 29-segment, two-layer box model to calculate the total sediment fluxes and accumulation rates. Estimates of the total suspended load range from 300,000 metric tons, corresponding to an average residence time of about 2.3 months. Average accumulation rates calculated with the model ranged from about 0.024 mm month^?1 to 0.150 mm month^?1 for a net annual rate of 0.92 mm yr^?1. This is in good agreement with geochemically determined sedimentation rates of 0.75±0.13 mm yr^?1 and suggests an oceanic source of sediment equivalent to about 45% of the mud accumulated in the sound.     

长江氮的输送通量

1997年枯水期(11～12月)和1998年丰水期(8月和10月),对长江流域从金沙江至河口干流和主要支流、湖泊各种形态的氮(N)进行了调查。各种形态N的基本输送模式为,从上游至河口通量逐渐增加,其中以硝酸盐(NO₃-N)、溶解无机氮(DIN)、总溶解氮(TDN)和总氮(TN)最显著,这与它们的稳定程度有关。长江口各种形式N的输出通量大部分是由中、下游贡献的,特别是枯水期。支流和湖泊贡献的N大约占输出通量的一半以上,其中洞庭湖水系贡献最大,鄱阳湖水系次之。长江枯、丰期三态无机N的输送和输出通量中,NO₃ N占绝大部分。各种形式的溶解N输送和输出通量中,DIN是主要的。在所有形式的N中,溶解形式的N占绝大部分。长江枯、丰期干、支流各种形式N通量和长江口各种形式N的输出通量主要受径流量所控制,与人类活动密切相关。并提出了长江各种形式N的输送方程式。     

Stellar fluxes in numerical dynamical models of open clusters

Fluxes of stars in models of open clusters that are nonstationary in the regular field of the cluster are analyzed. An equilibrium distribution function describes the state of these models from the beginning of their dynamical evolution. Violent relaxation in the open-cluster models proceeds under equilibrium conditions in phase space and does not result in virial equilibrium. The cluster relaxation times in the one-dimensional spaces of a number of stellar-motion parameters are estimated. The stellar fluxes are anisotropic in some two-dimensional parameter spaces. Such open-cluster models exhibit a number of manifestations of self-organization (an energy flux toward the center of the cluster and a transfer of energy from large-scale to small-scale motions, periodic decreases in the entropies of the cluster models with a period equal to that of oscillations of the regular field of the cluster, etc.). It is concluded that violent relaxation represents one form of self-organization in such systems.     

Turbulent fluxes over east-central Arabian sea during MONEX

Fluxes of momentum, latent heat and sensible heat at fixed stations in the east-central Arabian sea during MONEX were studied. Observations at the same locations at different periods as well as simultaneous observation at different locations were compared. During the advance of monsoon, momentum flux showed remarkable increase. Latent heat loss from sea also increased while sensible heat flux, in general, changed direction to become a gain by the sea. SST decreased by about 1.5°C and air temperature decreased by about 1°C during the advance phase. A north-south difference in SST in the study region seemed to be favourable for the genesis of onset vortex of monsoon. The possible differential effect of this storm at two different locations, depending upon the SST before the storm, is also discussed.     

Manganese and copper fluxes from continental margin sediments

Total dissolvable Cu and Mn have been measured in seawaters collected from the continental shelf of the eastern Bering Sea. Copper concentrations of < 3 nmole kg⁻¹ were measured over the shelf break but concentrations increased to >4 nmole kg⁻¹ inshore of a hydrographie front over the 100 m isobath. Manganese concentrations also were low over the shelf break, <10 nmole kg⁻¹, and increased systematically to concentrations >10 nmole kg⁻¹ inshore of the hydrographic front. Depth distributions of Mn at all continental shelf stations showed gradients into the sediments, with concentrations typically >20 nmole kg⁻¹ in a bottom layer extending about 30 m off the bottom. Benthic Cu and Mn fluxes are indicated by cross-shelf pore water profiles that show interfacial concentrations more than an order of magnitude greater than in bottom water. These data and the results of a model of metal transport across the shelf suggest that Cu and Mn fluxes, estimated at 2 and 18 nmole cm⁻²y⁻¹, respectively, from continental shelf sediments may be one “source” of these metals to the deep sea.     

Significance of bacteria in carbon fluxes in the Arabian Sea

In the Arabian Sea, temporal contiguity of highly oligotrophic and eutrophic periods, along with high water temperatures, may result in unique features of bacteriaorganic matter coupling, nutrient cycling and sedimentation, which are unlike those in the classical oligotrophic and eutrophic waters. Bacteria-phytoplankton interactions are suggested to influence phytoplankton aggregation and its timing. It is also hypothesized that, within aggregates, hydrolytic ectoenzyme activity, together with condensation reactions between the hydrolysis products, produce molecular species which are not readily degraded by pelagic bacteria. Accumulation of a reservoir of such slow-to-degrade dissolved organic carbon (DOC) is proposed to be a carbon flux and energy buffer, which moderates the response of bacteria to the dramatic variations in primary production in the Arabian Sea. Use of the slow-to-degrade DOC pool during the intermonsoon could temporarily render the Arabian Sea net-heterotrophic and a source of CO₂ to the atmosphere. Stored DOC is also suggested to balance the observed deficit between mesopelagic carbon demand and the sinking particulate organic carbon supply. Knowledge of the significance of bacteria in carbon storage and cycling in the Arabian Sea is needed to understand the response of the ocean’s biogeochemical state to strong physical forcing and climate change.     

Mercury transformations and fluxes in sediments of a riverine wetland

Porewater samples were obtained on five occasions during spring, summer and fall by in situ dialysis from three sites of a large freshwater wetland situated along the St. Lawrence River. These samples were analysed for total dissolved mercury ([Hg]_T) and methylmercury ([MeHg]) concentrations and for complementary variables including dissolved sulfate, sulfide and elemental sulfur concentrations. Sediment cores were obtained on three occasions from one of these sites for the determination of total mercury ({Hg}_T) and methylmercury ({MeHg}) concentration as well as mercury methyltransferase (HgMT) activity profiles. {MeHg} and HgMT activity varied with time and sediment depth. The porewater [Hg]_T and [MeHg] depth profiles varied with time and among sites. Modeling the porewater [MeHg] profiles with a one-dimensional reaction-transport equation allowed identification of the sediment depths where MeHg is produced or consumed, as well as an estimate of the net in situ MeHg production rates in the sediments. The model-predicted depths of MeHg production, as well as the sulfate concentration and the HgMT activity depth distributions are all consistent with the involvement of sulfate reducing bacteria in the production of MeHg.     

Effect of source integration on the geochemical fluxes from springs

Geochemical fluxes from watersheds are typically defined using mass-balance methods that essentially lump all weathering processes operative in a watershed into a single flux of solute mass measured in streamflow at the watershed outlet. However, it is important that we understand how weathering processes in different hydrological zones of a watershed (i.e., surface, unsaturated, and saturated zones) contribute to the total geochemical flux from the watershed. This capability will improve understanding of how geochemical fluxes from these different zones may change in response to climate change. Here, the geochemical flux from weathering processes occurring solely in the saturated zone is investigated. This task, however, remains exceedingly difficult due to the sparsity of subsurface sampling points, especially in large, remote, and/or undeveloped watersheds. In such cases, springflow is often assumed to be a proxy for groundwater (defined as water residing in fully saturated geologic formations). However, springflow generation may integrate different sources of water including, but not limited to, groundwater. The authors’ hypothesis is that long-term estimates of geochemical fluxes from groundwater using springflow proxies will be too large due to the integrative nature of springflow generation. Two conceptual models of springflow generation are tested using endmember mixing analyses (EMMA) on observations of spring chemistries and stable isotopic compositions in a large alpine watershed in the San Juan Mountains of southwestern Colorado. In the “total springflow” conceptual model, springflow is assumed to be 100% groundwater. In the “fractional springflow” conceptual model, springflow is assumed to be an integration of different sources of water (e.g., groundwater, unsaturated flow, preferential flow in the soil, etc.) and groundwater is only a fractional component. The results indicate that groundwater contributions in springflow range from 2% to 100% overall and no springs are consistently composed of 100% groundwater; providing support for the fractional springflow conceptual model. Groundwater contributions are not strongly correlated with elevation, spring contributing area, spring discharge, or seasonality. This variability has a profound effect on long-term geochemical fluxes. The geochemical fluxes for total springflow overestimate long-term solute release by 22–48% as compared to fractional springflow. These findings illustrate that springflow generation, like streamflow generation, integrates many different sources of water reflecting solute concentrations obtained along many different geochemical weathering pathways. These data suggest that springs are not always ideal proxies for groundwater. Springs may be integrating very distinct portions of the groundwater flow field and these groundwater contributions may become mixed at the spring emergence with much younger sources of water that have never resided in the groundwater system.     

Ecosystem metabolism and carbon fluxes of a tidally-dominated coastal lagoon

The metabolism and carbon flux in the western sector of the highly dynamic coastal lagoon Ria Formosa (south Portugal) were assessed to elucidate the relative importance of the contribution of the main communities, the treated sewage inputs from the adjacent city of Faro, and the exchange with the adjacent coastal waters to the ecosystem metabolism. The results depict the Ria Formosa as being a highly productive ecosystem dominated by the seagrassZostera noltii. The community dominated by the seagrassCymodocea nodosa had half of the gross production ofZ. noltii, followed by bare sediments and phytoplankton. The net contribution of seagrasses to community metabolism was negligible, as bothZ. noltii andC. nodosa showed a production: respiration ratio close to 1. Benthic microalgae emerge as the most important components of the net metabolism. The western sector of Ria Formosa was in metabolic balance during the summer when the study was done. Even though the total net ecosystem production was 7.22 Kmol C d⁻¹, the error associated with this estimate was 8.38 Kmol C d⁻¹, so ecosystem net production was not significantly different from zero. The Ria Formosa ecosystem is shallow and rapidly flushed by the tides, which force an important exchange of dissolved organic carbon (DOC) and particulate organic carbon (POC) with the adjacent coastal waters. The daily net export rate to the adjacent coastal waters, 0.98 Kmol d⁻¹, represented 7.6% of the net ecosystem production, suggesting that the bulk of the net ecosystem production accumulates within the ecosystem. The organic carbon retention in the western sector of the Ria Formosa is higher than net production, because the allochthonous carbon inputs from urban sewage enter the carbon mass balance with about 40% of the autochthonous processes, at about 1.6 Kmol d⁻¹ of DOC and 2.8 Kmol d⁻¹ of POC. The western sector of Ria Formosa has an organic carbon sink of about 46.4 tons per year. Most of this is harvested in the form of molluscs (clams, cuttlefish, etc.) and fish (sea bream, sea bass, etc.). The total carbon harvested every year in the form of bivalves is about 40 tons, rendering the Ria Formosa the most productive seafood area in Portugal.     

Sediment-water oxygen and nutrient fluxes in a river-dominated estuary

Sediment oxygen uptake and net sediment-water fluxes of dissolved inorganic and organic nitrogen and phosphorus were measured at two sites in Fourleague Bay, Louisiana, from August 1981, through May 1982. This estuary is an extension of Atchafalaya Bay which receives high discharge and nutrient loading from the Atchafalaya River. Sediment O₂ uptake averaged 49 mg m^?2 h^?1. On the average, ammonium (NH₄ ⁺) was released from the sediments (mean flux =+129 μmol m^?2 h^?1), and NO₃ ^? was taken up (mean flux =?19 μmol m^?2h^?1). However, very different NO₃ ^? fluxes were observed at the two sites, with sediment uptake at the upper, river-influenced, high NO₃ ^? site (mean flux =?112 μmol m^?2 h^?1) and release at the lower, marine-influenced low NO₃ ^? site (mean flux =+79 μmol m^?2 h^?1). PO₄ ^3? fluxes were low and often negative (mean flux =?8 μmol m^?2 h^?1), while dissolved organic phosphorus fluxes were high and positive (mean flux =+124 μmol m^?2 h^?1). Dissolved organic nitrogen fluxes varied greatly, ranging from a mean of +305 μmol m^?2 h^?1 at the lower bay, to ?710 μmol m^?2 h^?1 at the upper bay. Total dissolved nitrogen and phosphorus fluxes indicated the sediments were a nitrogen (mean flux =+543 μmol m^?2 h^?1) and phosphorus source (mean flux =+30 μmol m^?2 h^?1) at the lower bay, and a nitrogen sink (mean flux =?553 μmol m^?2 h^?1) and phosphorus source (mean flux =+17 μmol m^?2 h^?1) in the upper bay. Mean annual O∶N ration of the positive inorganic sediment fluxes were 27∶1 at the upper bay and 18∶1 at the lower bay. Based on these data we hypothesize that nitrification and denitrification are important sediment processes in the upper bay. We further hypothesize that Atchafalaya River discharge affects sediment-water fluxes through seasonally high nutrient loading which leads to net nutrient uptake by sediments in the upper bay and release in the lower bay, where there is less river influnces.     

Human footprints on greenhouse gas fluxes in cryogenic ecosystems

Various human footprints on the flux of biogenic greenhouse gases from permafrost-affected soils in Arctic and boreal domains in Russia are considered. Tendencies of significant growth or suppression of soil CO₂ fluxes change across types of human impact. Overall, the human impacts increase the mean value and variance of local soil CO₂ flux. Human footprint on methane exchange between soil and atmosphere is mediated by drainage. However, all the types of human impact suppress the sources and increase sinks of methane to the land ecosystems. N₂O flux grew under the considered types of human impact. Based on the results, we suggest that human footprint on soil greenhouse gases fluxes is comparable to the effect of climate change at an annual to decadal timescales.     

Importance of grid-cell area in the estimation of estuarine residual fluxes

Estimation of residual fluxes in estuarine cross sections is a very important procedure to establish, among others aspects, residence time of contaminants, circulation pattern, and sediment transport dynamics. However, the analytical procedure to obtain such values is not trivial and is presented in detail, demonstrating the importance of the grid-cell area as a weighting element in the calculation of spatial averages. The procedure is tested with four different grid designs and it is shown that grids with proportional columns and rows are the only ones that do not introduce statistical noise in the estimation of the residual fluxes. The four designs are also tested with data from a cross section of the Bahía Blanca Estuary (Argentina), results again show that the proportional columns and rows grid provide the best approach in calculating residual fluxes.     

Predicting solar radiation fluxes for solar energy system applications

The mean daily global solar radiation flux is influenced by astronomical, climatological, geographical, geometrical, meteorological, and physical parameters. This paper deals with the study of the effects of influencing parameters on the mean daily global solar radiation flux, and also with the computation of the solar radiation flux at the surface of the earth in locations without solar radiation measurements. The reference–real data were borrowed from the Iranian Meteorological Organization. The analysis of data showed that the mean daily solar radiation flux on a horizontal surface is related to parameters such as: mean daily extraterrestrial solar radiation, average daily ratio of sunshine duration, mean daily relative humidity, mean daily maximum air temperature, mean daily maximum dew point temperature, mean daily atmospheric pressure, and sine of the solar declination angle. Multiple regression and correlation analysis were applied to predict the mean daily global solar radiation flux on a horizontal surface. The models were validated when compared with the reference–measured data of global solar radiation flux. The results showed that the models estimate the global solar radiation flux within a narrow relative error band. The values of mean bias errors and root mean square errors were within acceptable margins. The predicted values of global solar radiation flux by this approach can be used for the design and performance estimation in solar applications. The model can be used in areas where meteorological stations do not exist and information on solar radiation flux cannot be obtained experimentally.