羌塘错尼地区新生代火山岩研究

同位素年代学、岩石学、矿物化学和岩石地球化学特征研究表明,羌塘错尼地区火山岩可以划分为3套岩石组合：①高钾钙碱性火山岩(44Ma～38Ma);②钾玄岩质火山岩;③强碱性火山岩(34Ma～19Ma)。3套火山岩均是大陆碰撞造山后期岩浆作用的产物,始新世以来,随着该区由碰撞、挤压作用发展到出现走滑,应力环境由挤压转变为张性,导致依次喷发高钾钙碱性火山岩、钾玄岩质火山岩和强碱性火山岩。强碱性火山岩的地球化学特征暗示了岩浆源区受到过地幔流体的强烈交代作用。     

东昆仑西部野马泉地区三叠纪花岗岩成因与构造背景

位于青海省东昆仑西部的野马泉地区三叠纪花岗岩分布广泛,本文通过花岗岩岩石学、地球化学、年代学研究,将晚古生代—早中生代造山旋回同碰撞阶段时限厘定为235~224 Ma,后碰撞时限厘定为224~204 Ma。研究表明,同碰撞阶段代表性侵入岩岩石组合为石英二长闪长岩-花岗闪长岩,具有钙碱性-高钾钙碱性系列准铝质-弱过铝质I型花岗岩的特征,岩石形成于下地壳或中下地壳,与幔源物质底侵作用和俯冲大洋物质"滞后"局部熔融有关,花岗闪长岩具有adakitic岩亲和性的特点。后碰撞阶段代表性侵入岩岩石组合为似斑状二长花岗岩-二长花岗岩-花岗斑岩,具有高钾钙碱性-钾玄岩系列准铝质-强过铝质S型花岗岩的特征,岩石形成于上地壳,含闪长质包体二长花岗岩源区具有EMⅡ富集地幔的印记,有别于不含包体的二长花岗岩。三叠纪花岗岩的形成可能经历了地幔底侵-洋壳"滞后"熔融和地壳熔融的深部过程。     

扬子北缘晚古元古代A型花岗质岩:Columbia超大陆裂解的证据

为约束扬子陆块晚古元古代构造演化历史,以华山观岩体的钾长花岗岩和二长花岗岩为研究对象,开展地球化学、年代学、全岩Nd同位素及锆石Hf同位素分析。锆石U-Pb定年结果显示钾长花岗岩和二长花岗岩的结晶年龄分别为1860±12 Ma(MSWD=0.69)和1832±14 Ma(MSWD=0.48)。两类岩石都显示铝质A型花岗岩的地球化学特征,一致的ε_(Hf)(t)值(-10.9～-13.8)及其二阶段模式年龄(2962～3183 Ma),揭示其由同一套太古宙的地壳部分熔融形成。综合已有ε_(Hf)(t)值资料,表明扬子陆块广泛存在两套太古宙长英质地壳(3.0～3.5 Ga; 3.5～3.9 Ga),为华山观两类花岗岩的岩浆形成提供了物源。华山观岩体两类花岗岩的锆石饱和温度揭示源岩位于较深的地壳,且二长花岗岩的形成有更多热源的参与。结合扬子陆块同期(～1.85Ga)A型花岗岩的地球化学数据,认为华山观钾长花岗岩具有后碰撞A_2型花岗岩的特征,形成于后碰撞伸展环境,而华山观二长花岗岩具有A_1型花岗岩的地球化学特征,暗示造山后伸展到陆内裂谷过渡的构造背景,可能与Columbia超大陆裂解有关。     

冈底斯带门巴区晚白垩世花岗岩年代学、地球化学及构造背景

门巴区晚白垩世花岗岩主要分布于冈底斯中段的扎雪、金达和桑巴附近,由黑云母钾长花岗岩、钾长花岗岩和二云母钾长花岗岩及花岗闪长岩等组成。其中花岗闪长岩SHRIMP 锆石U--Pb 年龄为68. 8 ± 1. 6 Ma; 钾长花岗岩黑云母K--Ar 年龄为78. 2 ± 1. 2 Ma 和81. 5 ± 1. 4 Ma; 黑云母钾长花岗岩和二云母钾长花岗岩的黑云母K--Ar 分别为90. 8 ± 1. 81 Ma 和91. 2 ± 1. 8 Ma。岩石学和地球化学分析结果表明,S 型和低Sr 低Yb 特征的黑云母钾长花岗岩和二云母钾长花岗岩形成于拉萨地块与羌塘地块碰撞造山过程中的地壳加厚背景; S 型和总体低Sr、高Yb 特征的钾长花岗岩形成于造山带晚期阶段的伸展背景; I 型花岗闪长岩应是新特提斯洋俯冲作用的结果,形成于岛弧构造环境。     

长江中下游贵池矿集区燕山期岩浆作用及其地质意义:年代学、地球化学及Sr-Nd-Hf同位素证据

长江中下游贵池地区燕山期侵入岩发育,与成矿关系密切.本文对该区侵入岩开展了详细的锆石U-Pb年代学、地球化学及Sr-Nd-Hf同位素研究.结果表明,马头花岗闪长斑岩形成于147±2Ma,而花园巩石英二长岩形成于127±1Ma,比花岗闪长斑岩晚约20Ma.早期的花岗闪长斑岩(147 ～ 145Ma)为高钾钙碱性系列,具有高Al2O3、Sr含量和Sr/Y、La/Yb比值,以及低的Y、Yb含量,与埃达克质岩的地球化学特征一致;而晚期石英二长岩(127Ma)和石英正长岩为钾玄岩系列,具有高的(Na2O+ K2O)、Zr、Nb、Y含量和Y/Nb、Yb/Ta比值,与造山带A2型花岗岩地球化学特征相似;碱长花岗岩(125～124Ma)同样具有A型花岗岩的地球化学特征,但与石英二长岩、石英正长岩相比,碱长花岗岩的Y/Nb、Yb/Ta比值相对较低,具板内环境A1型花岗岩的地球化学特征.因此,贵池地区岩浆岩从早期的埃达克质岩变为晚期的A型花岗岩,反应了晚中生代时期长江中下游地区的构造环境由大陆边缘环境向伸展环境的转变.     

西藏羌塘戈木错渐新世钾质火山岩的地球化学特征及其构造意义

羌塘戈木错出露一套30Ma的钾质火山岩,岩石类型包括橄榄碱玄岩、橄榄粗面玄武岩、霓辉粗面岩和含白榴石响岩。火山岩的SiO2含量变化于46%~60%之间,Al2O3含量在13%~21%之间,Mg#介于0.14和0.63之间,K2O/Na2O>1。岩石强烈富集轻稀土元素（LREE）,亏损相容元素（Cr、Ni）和高场强元素（Nb、Ta、Ti）,全岩εHf(t)值变化于-1.28~-6.20之间。研究表明,戈木错火山岩母岩浆起源于软流圈流体交代的古俯冲地幔楔的低程度熔融,同源岩浆经历了AFC作用。戈木错火山岩和区域上的鱼鳞山、火车头山钾质—超钾质火山岩共同组成了羌塘渐新世钾质—超钾质火山岩带。综合南羌塘新生代火山岩岩浆性质的演化,认为岩浆的产生可能与35Ma左右羌塘陆内俯冲板片断离导致的软流圈上涌-岩石圈减薄作用有关。     

羌塘沱沱河地区多才玛二长岩SHRIMP锆石U-Pb年代学及岩石地球化学

对青海省羌塘地块东北缘沱沱河多才玛铅锌矿区二长岩进行了系统的锆石U-Pb年龄和地球化学研究。结果表明二长岩属于钙碱性-高钾钙碱性,准铝质岩石,具有较高的Na_2O和较低的K_2O、MgO。样品的高Rb/Sr比值(0.21~0.47)、低Nb/Ta比值(13.25~14.02)和低Mg#值等特征显示二长岩岩浆来源于地壳。样品富集轻稀土元素(LREE)、大离子亲石元素(LILE)(Rb,Ba,K,Sr),以及活泼的不相容元素(Th、U),同时亏损高场强元素(HFSE)(Nb、Ta、P、Ti),与弧火山岩特征相似。二长岩的SHRIMP锆石U-Pb定年结果为(65.8±1.1)Ma,显示其形成于晚白垩世—早古新世。结合区域地质背景,推测多才玛二长岩形成于特提斯大洋板块的后期深俯冲阶段。     

柴北缘西段小赛什腾山黑云母二长花岗岩和石英闪长岩岩石成因及其动力学背景：锆石U-Pb年代学、地球化学和Hf同位素约束

位于柴北缘西段的小赛什腾山分布大量海西晚期中酸性岩浆岩,其形成时代和成因类型对揭露区域构造演化具有十分重要的意义。本研究以小赛什腾山二叠纪黑云母二长花岗岩和石英闪长岩作为研究对象,对其进行岩相学、锆石U-Pb年代学、岩石地球化学及Lu-Hf同位素研究。结果表明,黑云母二长花岗岩和石英闪长岩的成岩年龄分别为272±3 Ma和273±2 Ma,指示两者均形成于早—中二叠世。地球化学结果显示,黑云母二长花岗岩属弱过铝质钾玄岩系列I型花岗岩,石英闪长岩为准铝质钙碱性系列I型花岗岩,两者均不同程度富集大离子亲石元素Rb、Th、K等,亏损Nb、Ta、Ti等高场强元素,具有典型的弧岩浆地球化学特征。锆石Lu-Hf同位素表明黑云母二长花岗岩具正的ε_Hf(t)值(2.04～8.16)和较年轻的二阶段Hf模式年龄(t_DM2=0.77～1.16 Ga)。结合前人研究成果,认为小赛什腾山早—中二叠世黑云母二长花岗岩和石英闪长岩均为宗务隆洋俯冲消减的产物,石英闪长岩为玄武质洋壳板片发生部分熔融产生的熔体遭受地幔橄榄岩混染而成,而黑云母二长花岗岩为洋壳熔融产生的岩浆底侵...     

大兴安岭东北部哈拉巴奇花岗岩体锆石U-Pb年龄及其成因

哈拉巴奇岩体主要由二长花岗岩钾长花岗岩和花岗闪长岩组成。样品的LAICPMS锆石UPb年龄测定和主量及微量元素的分析结果表明,哈拉巴奇岩体为两次侵位的早古生代花岗岩体,其中二长花岗岩钾长花岗岩的侵位时间较早(500Ma),花岗闪长岩的侵位时间相对较晚(461Ma);岩体具有后造山花岗岩类的岩石组合特征和地球化学特征,为额尔古纳地块与兴安地块碰撞拼贴作用结束后的后造山阶段的产物;二长花岗岩钾长花岗岩和花岗闪长岩起源于相同的岩浆源区,其源区物质可能是中元古代期间地幔中新增生的地壳物质,二者地球化学特征的差别是源岩部份熔融程度不同所致。     

藏北高原新生代火山岩地球化学系列划分及成因分析

根据K—Ar法和Ar-Ar法定年数据，藏北新生代火山岩从早到晚可划分为多格错仁和走构油茶错高钾钙碱性系列(40—30Ma)、巴毛穷宗和鱼鳞山白榴石碧玄岩—响岩系列(29—24Ma)以及黑石北湖钾玄岩系列(1．5Ma)。从岩石化学和同位素方面对区内新生代火山岩进行了研究，认为藏北新生代火山岩同时具有板内碱性玄武岩和岛弧玄武岩的双重地球化学特征。在成因和源区上各系列存在着差异，高钾钙碱性系列为富集地幔玄武岩底侵作用导致地壳物质部分熔融的产物，并经历了地壳的AF过程。而白榴石碧玄岩—响岩系列和钾玄岩系列来自与古俯冲有关的“古老富集地幔”，为岩浆分离结晶作用的产物。岩浆起源深度随时间变新逐渐变大。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.