首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
This paper examines the influence of sorbed gas type and pressure on the strength of coal. Particular attention is focused on the influence of gas type and pressures on drillability characteristics of coal and particle size distribution of drill cuttings. Drillability of coal has a strong bearing on the strength properties of coal. Based on fracture mechanics and mechanical rock cutting, weaker rocks are easier to drill and the drill cuttings produced are generally coarse in size. Accordingly a specially designed precision drill was used to drill coal samples under both normal atmospheric and confined gas pressure conditions. Indications of changes to coal strength as a result of increased sorbed gas pressure were examined by analysing the particle size distribution of the drill flushing. A laser controlled Malvern Mastersizer S particle size analyser with measuring range between 0.05 m and 900 m was used to study the particle size distribution. This paper demonstrates that there is a definite variation in the range of particle size distribution with particles obtained from drilling coal samples not subjected to gas pressures in comparison with those obtained from samples drilled under confined gas pressure. Gas types also have an influence. Higher proportions of coarse particles were produced when the confined gas was changed from CH4 to CO2. A change in the rate of drilling under varying confining pressure and gas type was also evident. The rate of drilling in air (at normal atmospheric conditions) was slower than at higher confining pressures. The highest drill rates were obtained with CO2 confinement.  相似文献   

3.
This paper reviews the history of the foundation of the Commission on New Minerals in Russia (1956) and the same Commission of the International Mineral Association (IMA). The terms mineral species, subspecies, and variety are considered. The nomenclature of mineral groups of lovozerite, eudialyte, and apatite is given as examples of using a root name and its suffixes.  相似文献   

4.
Natural damage such as fissures and pores make the rock microstructure show strong heterogeneity,which influences the failure process and mode. In this paper,the numerical test of freeze-thaw sandstone splitting failure with natural damage was carried out based on CT non-destructive identification technology,combined with digital image processing technology and CASRock numerical simulation software. The analysis of splitting failure mode,deformation localization and crack evolution process of freeze-thaw sandstone with natural damage reveals the failure mechanism of sandstone with natural damage under freeze-thaw and load. The results show that the expansion of primary pores(cracks)and the formation of new pores in sandstone are the main forms of freeze-thaw rock failure evolution. The failure of rock containing natural damage under freeze-thaw and load is related to the degree and distribution of natural damage. The generation of secondary cracks mostly occurs in natural damage-intensive areas. During the loading process,the stress in the localized damage zone is far greater than sandstone’s overall stress,and rock’s failure in the localized damage zone is synchronized with the energy release and stress release in the region. Localized damage reflects the evolution of cracks in rocks and helps to predict the direction of sandstone crack development. The failure mode of rock is related to the number of freeze-thaw cycles. The freeze-thaw cycles make the sandstone with natural damage gradually change from brittle failure to ductile failure,and the change of the overall strength of the rock is a gradual deterioration process. © 2022 Science Press (China).  相似文献   

5.
Forty-one water samples in each season(both pre-and post-monsoon) were collected from different for-mations of the Kadiri schist belt located in the Anantapur district,Andhra Pradesh.The specific electrical conductiv-ity(EC) of these water samples was measured at 25℃ by using specific conductivity bridge.The specific conductiv-ity values of the water samples were also calculated by multiplying ionic concentrations with conductivity factor.It is found that the observed EC values of all water samples collected in both the seasons are different from the esti-mated EC values because of the electro-chemical properties of ions in water.  相似文献   

6.
《Applied Geochemistry》2001,16(6):651-658
Two different mathematical techniques have been used to analyse data obtained from a set of experiments in which a range of radiotracers were sorbed onto two contrasting lake sediments. The advantages and disadvantages of the two techniques have been evaluated. Both approaches to the analysis were capable of providing rate parameters which can be used to determine the mobility and rate of removal of trace species from the water column. However, the values of the parameters were often different, depending upon which approach was used and, in some cases, even the number of sorption processes identified was method dependent.  相似文献   

7.
Brezzi  Lorenzo  Gabrieli  Fabio  Cola  Simonetta 《Acta Geotechnica》2020,15(3):695-714
Acta Geotechnica - The collapse test with granular or cohesive materials known as ‘slump test’ is a simple, small-scale experiment. It can be used to study the rheology of soil masses...  相似文献   

8.
Adsorption of dissolved copper and phosphate by natural and peroxide-treated marine sediments was compared. A three-fold increase in copper adsorption and a six-fold increase in phosphate adsorption was caused by the peroxide treatment. Indigenous organic matter evidently interferes with adsorption.Clay minerals coated with heptadecanoic acid adsorbed somewhat less copper, phosphate, and hexadecane than uncoated clays, but slightly more nonadecanoic acid and anthracene.  相似文献   

9.
Potential applications of Nano-scale science and technology are discussed in mineralogy,ore deposits,cosmochemistry and environmental sciences.Adsorption of nanometersized gold was experimentally studied on a variety of minerals and rocks.  相似文献   

10.
There is a severe phenomenon of blowing snow by wind in winter in Mayitas area of Xinjiang. Road traffic interruptions and casualties caused by wind and snow disasters often occur. The existing engineering measures can alleviate the problems of low visibility and problems with accumulating snow on pavement caused by wind and snow to a certain extent, but cannot completely eliminate the impact. Aiming at the problem that the blowing snow disaster difficult to be completely cured under strong wind conditions, a shed tunnel engineering treatment scheme is proposed, and a wind tunnel simulation experiment is carried out on the shed tunnel form and snow prevention scheme at the entrance of the tunnel. The wind tunnel experimental section is 8 m long, 1. 3 m horizontally wide and 1 m high. The shed tunnel model is made by 1:60 scale 3D printing method, the snow barrier model is made of wooden strips, and the simulation medium is made of fine sand, refined salt and sawdust. Firstly, three kinds of shed structures, including fully enclosed, overhanging and ventilated, were simulated under the condition of 90° wind direction, and compared with the form of blowing snow stacking. Three parameters for similarity were used:density, particle size and stacking shape. The similarity is determined by weighted Euclidean distance between simulation medium and blowing snow, the similarity of the slump angle of the predecessors is verified, and the most suitable medium for simulating blowing snow is deduced. According to the experimental results, combined with the actual situation of wind blowing and snow disasters in Mayitas, flow field of the closed shed tunnel by a wind direction angle of 30° has been separately conducted with or without protective measures. The results show that when the wind tunnel stacking experiment is used to study the deposition state of blowing snow under non-low temperature conditions, the sawdust has good similarity with the blowing snow in the process of wind and snow movement. A large amount of medium was poured into the ventilated shed during the experiment, which proved that its anti-wind and snow performance was not ideal. By contrast, the closed shed and the overhanging shed have better wind and snow prevention effects. The snow barrier has a good blowing snow inhibition function at the entrance. From the stacking experiment, in the comparison with and without snow barrier, volume of the medium in the shed is very different, which proves that the snow barrier can effectively prevent the blowing snow from entering the shed. Among them, the difference in wind speed inside and outside the shed is obvious, which proves that snow barrier can significantly reduce the wind speed outside the shed and has the function of inhibiting the formation of weak wind areas inside the shed. The study has confirmed that the shed tunnel project with suitable snow barrier layout plan for tunnel entrance protection is an effective means to control wind and snow disasters. For highway traffic in Xinjiang, it is a feasible solution to use shed tunnel engineering to control blowing snow disasters. After dealing with the snow deposition at the entrance of shed tunnel, the shed tunnel engineering form of low-cost environment integration and the vehicle operation safety guarantee measures of long-distance shed tunnel are the problems that need to be solved in the future. © 2022 Tianjin Press of Chinese Herbal Medicines. All rights reserved.  相似文献   

11.
The partitioning of Gd in the experimental system diopside-aqueous vapor as a function of temperature, pressure, composition of the phases, time, grain size, solid-liquid ratio and Gd concentration has been investigated. A radioactive tracer measurement was used to determine Gd concentration in the separated phases. Diposides were reacted with aqueous vapor containing tracer Gd and reversibility was tested by reacting Gd-doped diopsides with pure aqueous vapor. Equilibration of Gd between the bulk of the diopside and the liquid was found to be limited by the slow rate of Gd diffusion in diopside, maximum value of D = 2 × 10?15cm2sec?1 at 800°C and 1 kb. Depending on whether the diopside was previously synthesized or synthesized from an oxide mix during the experiment, Gd concentrations were zoned in the crystal such that higher concentrations existed at the edges or center, respectively. Equilibrium is difficult to achieve in these experiments, but at the optimum experimental conditions for equilibration, the Gd diopside-aqueous vapor distribution coefficient is 20 ± 6 (800°C, 1 kb) in approximate agreement with previous results of 55 ± 23. Changing the composition of the aqueous vapor indicated that possible mechanisms for Gd substitution included coupling of Gd3+ with H+ or Na+ replacing 2Ca2+, or substitution of 2Gd3+ for 3Ca2+ with formation of a cation vacancy.  相似文献   

12.
In the present study, influence of wetting–drying cycles on swelling pressures of sand–bentonite mixtures used in the construction of sanitary landfills to have an impermeable liner was investigated before and after lime treatment of the mixtures. Swelling pressure tests were conducted to see if the swelling pressures were affected by wetting–drying cycles. First series of specimens were prepared as a mixture of sand and bentonite only. In the first series of specimens, sand was mixed with bentonite in various proportions with their optimum water contents and compacted by using standard proctor energy. In the second series of the specimens, lime in various proportions was added to the mixtures of sand–bentonite. Then, the sand–bentonite mixtures stabilized by lime were compacted with the standard proctor energy at their optimum moisture contents. Five wetting–drying cycles were performed on each specimen and values of swelling pressures were measured at the end of each cycle. Results of swelling pressure tests indicated that the swelling pressure is decreased when lime is added to the mixtures. In addition, decrements were observed on swelling pressures by wetting–drying cycles. The results of the experiments of this investigation showed that the beneficial effect of lime stabilization to control the swelling pressures was partly lost by the wetting–drying cycles. However, the test results indicated that the swelling pressures of the specimens made of sand–bentonite mixtures stabilized by lime were lower than the swelling pressures of the specimens made of only sand–bentonite mixtures.  相似文献   

13.
In this study, a laboratory-scale biotrickling filter (BTF) is used to remove Triethylamine (TEA) from gaseous wastes. The BTF is made of stainless steel with a height of 210 cm and an internal diameter of 21 cm packed with lava rocks. TEA elimination pattern was evaluated by changing empty bed residence times (EBRTs). The maximum elimination capacity (EC) has been determined to be 87 g/m3/h. At all EBRTs 52, 31, 20, and 10 s, contaminant transferring from gas phase to liquid was more than the EC. Also, the removal efficiency was 100 % for a mass loading of 100 g/m3/h. While the liquid recirculation velocity of 3.466 m3/m2/h was maintained, the flow rate was adjusted to 60, 100, 156, and 312 L/min. The results show that due to the high solubility of TEA in water for all the EBRTs, TEA can be solved in the circulated liquid and then be degraded gradually by microorganisms. Therefore, the least EBRT of 10 s is more appropriate.  相似文献   

14.
Fractionation between Nb and Ta, elements generally regarded as geochemical ‘identical twins’, is a key to deciphering the formation of the continental crust (CC). Here we show that Nb/Ta of rutile grains in eclogitic rocks from the Chinese Continental Scientific Drilling (CCSD) project are remarkably heterogeneous but overall subchondritic at core depths of 100–700 m, and are less variable and mainly suprachondritic at core depths of 700–3025 m, indicating clear Nb/Ta fractionation across a subducted slab. To understand the potential mechanism of Nb/Ta fractionation within the subducted plate, we analysed by laser ablation ICPMS a thermal migration experiment in which a wet andesite was placed in a large thermal gradient (300°C/cm with ends ranging from 950–350°C) at 0.5Gpa. Results show that Nb, Ta and Ti, driven by the thermal gradient, preferentially migrate by diffusion through supercritical fluids into the cooler end of the experiment (at 650–350°C). Due to contrasting Nb and Ta thermal migration patterns, dramatic fractionation between Nb, Ta, and Ti took place in the cooler end. Experimental results are consistent with the measured Nb, Ta in rutile from CCSD drillhole samples. We consider that major fractionation between Nb, Ta must occur before rutile appears, most likely during the prograde blueschist to amphibole–eclogite transformation, when Ti is also mobile. Before rutile appears, partitioning between Ti‐rich dominant minerals such as amphiboles and fluids in the hotter region where dehydration preferentially occurs, produces Nb–Ta–Ti‐rich fluids with subchondritic Nb/Ta, and dehydration residues with suprachondritic Nb/Ta. Meanwhile, owing to evolution of the thermal gradient within the subducting slab, thermal migration of Nb, Ta, and Ti in aqueous fluids result in Nb, Ta, and Ti enrichment in the cooler region and depletion in the hotter region. As a result of high‐pressure metamorphism, hydrous rutile‐rich eclogites with overall subchondritic Nb/Ta form in the cooler region, whereas relatively anhydrous rutile‐poor eclogites with suprachondritic Nb/Ta form in the hotter region. Subsequently, partial melting of hydrous rutile‐rich eclogites with initial subchondritic Nb/Ta at deeper levels transfers overall subchondritic Nb/Ta coupled with Nb, Ta, and Ti depletion characteristics to the CC, leaving dry rutile‐poor eclogites with suprachondritic Nb/Ta and rutile‐rich residual eclogites with overall, heterogeneous subchondritic Nb/Ta as a complementary reservoir to the CC.  相似文献   

15.
In a series of timed experiments, monazite inclusions are induced to form in the Durango fluorapatite using 1 and 2 N HCl and H2SO4 solutions at temperatures of 300, 600, and 900°C and pressures of 500 and 1,000 MPa. The monazite inclusions form only in reacted areas, i.e. depleted in (Y+REE)+Si+Na+S+Cl. In the HCl experiments, the reaction front between the reacted and unreacted regions is sharp, whereas in the H2SO4 experiments it ranges from sharp to diffuse. In the 1 N HCl experiments, Ostwald ripening of the monazite inclusions took place both as a function of increased reaction time as well as increased temperature and pressure. Monazite growth was more sluggish in the H2SO4 experiments. Transmission electron microscopic (TEM) investigation of foils cut across the reaction boundary in a fluorapatite from the 1 N HCl experiment (600°C and 500 MPa) indicate that the reacted region along the reaction front is characterized by numerous, sub-parallel, 10–20 nm diameter nano-channels. TEM investigation of foils cut from a reacted region in a fluorapatite from the 1 N H2SO4 experiment at 900°C and 1,000 MPa indicates a pervasive nano-porosity, with the monazite inclusions being in direct contact with the surrounding fluorapatite. For either set of experiments, reacted areas in the fluorapatite are interpreted as replacement reactions, which proceed via a moving interface or reaction front associated with what is essentially a simultaneous dissolution–reprecipitation process. The formation of a micro- and nano-porosity in the metasomatised regions of the fluorapatite allows fluids to permeate the reacted areas. This permits rapid mass transfer in the form of fluid-aided diffusion of cations to and from the growing monazite inclusions. Nano-channels and nano-pores also serve as sites for nucleation and the subsequent growth of the monazite inclusions.  相似文献   

16.
Wei  Xiao  Liu  Huanzi  Ku  Taeseo 《Acta Geotechnica》2020,15(10):2905-2923
Acta Geotechnica - Cement stabilization is a useful and widely adopted method to improve the engineering properties of soils. However, characterization of the unconfined compressive strength, a...  相似文献   

17.
Wang  Dong-Wei  Zhu  Cheng  Tang  Chao-Sheng  Li  Sheng-Jie  Cheng  Qing  Pan  Xiao-Hua  Shi  Bin 《Acta Geotechnica》2021,16(9):2759-2773

Deep geological repository is a favorable choice for the long-term disposal of nuclear wastes. Bentonite–sand mixtures have been proposed as the potential engineered barrier materials because of their suitable swelling properties and good ability to seal under hydrated repository conditions. To investigate the effects of sand grain size on the engineering performance of bentonite–sand mixtures, we prepare five types of bentonite–sand mixtures by mixing bentonite with sand of varying particle size ranges (0.075–0.25 mm, 0.25–0.5 mm, 0.5–1 mm, 1–2 mm and 2–5 mm, respectively). We carry out sequential oedometer tests under different simulated repository conditions, including constant vertical stress (CVS), constant stiffness (CS) and constant volume (CV) conditions. The microstructural heterogeneity and anisotropy of these soil mixtures are characterized through the quantitative analysis of micro-CT scanning results. Experimental results reveal that both sand grain size and boundary condition significantly influence the swelling of soil mixtures. Under three conditions, the temporal evolutions of swelling stress and strain follow similar trends that they increase faster at the beginning and gradually stabilize afterward. Comparing the ultimate values, swelling strains follow CVS?>?CS?>?CV, while swelling stresses follow CV?>?CS?>?CVS. Under CS boundary conditions, as the stiffness coefficient increases, the swelling pressure increases and the swelling strain decreases. CT results further indicate that mixtures with larger sand inclusions are more structurally heterogeneous and anisotropic, resulting in increased inter-particle friction and collision and a higher energy dissipation during the swelling process. Moreover, the non-uniform distribution of bentonite in local zones would be intensified, which plays an important role in compromising swelling behavior. Therefore, soil samples mixed with larger sand particles present a smaller swelling stress and strain values. This study may guide the choice of engineered barrier materials toward an improved design and assessment of geological repository facilities.

  相似文献   

18.
Dong  Hui  Peng  Bocheng  Gao  Qian-Feng  Hu  Yin  Jiang  Xiuzi 《Acta Geotechnica》2021,16(2):595-611

Because of spatial variability and complex compositions, the mechanical test results of natural soil–rock mixtures (SRMs) are often discrete and lack reproducibility, which has greatly restricted the practical application of the experimental findings. The objective of this study was to examine the general mechanical behavior of SRMs under the influences of some hidden factors (e.g., structural parameters, parent rock type and weathering degree). To that end, the abstraction idea was adopted to prepare purified SRM samples. Large-scale triaxial tests were performed on these purified materials. On this basis, the influences of three structural parameters on the mechanical behavior of SRMs were studied. Moreover, the relationship between the shear strength and parent rock type and that between the shear strength and the spatial distribution of rock blocks were quantified. Some additional intrinsic behavior was distinguished from individual experimental phenomena through the comparative analysis of the test data in this study and those reported in the literature. The results show that the hidden factors had significant influences on the mechanical behavior of SRMs. A greater saturated uniaxial compressive strength of rock blocks generally led to a larger shear strength of SRMs. According to the significance of their influences on the shear strength parameters of SRMs, the structural parameters are ordered as: the gradation of rock blocks, the initial dry density of sample and the spatial distribution of rock blocks. The deformation and failure feature of SRMs were considerably affected by the spatial distribution of rock blocks and shear rate. And the shear strength parameters of SRMs were mainly influenced by the content of grains between 40 and 60 mm. The findings of this study would provide useful guidance for engineering practice.

  相似文献   

19.
20.
Photodegradation of chrysene, benzo (a) pyrene and benzo (g, h, i) perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this stud…  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号