Artificial recharge through a thick, heterogeneous unsaturated zone

Thick, heterogeneous unsaturated zones away from large streams in desert areas have not previously been considered suitable for artificial recharge from ponds. To test the potential for recharge in these settings, 1.3 x 10(6) m(3) of water was infiltrated through a 0.36-ha pond along Oro Grande Wash near Victorville, California, between October 2002 and January 2006. The pond overlies a regional pumping depression 117 m below land surface and is located where thickness and permeability of unsaturated deposits allowed infiltration and saturated alluvial deposits were sufficiently permeable to allow recovery of water. Because large changes in water levels caused by nearby pumping would obscure arrival of water at the water table, downward movement of water was measured using sensors in the unsaturated zone. The downward rate of water movement was initially as high as 6 m/d and decreased with depth to 0.07 m/d; the initial time to reach the water table was 3 years. After the unsaturated zone was wetted, water reached the water table in 1 year. Soluble salts and nitrate moved readily with the infiltrated water, whereas arsenic and chromium were less mobile. Numerical simulations done using the computer program TOUGH2 duplicated the downward rate of water movement, accumulation of water on perched zones, and its arrival at the water table. Assuming 10 x 10(6) m(3) of recharge annually for 20 years, a regional ground water flow model predicted water level rises of 30 m beneath the ponds, and rises exceeding 3 m in most wells serving the nearby urban area.     

Groundwater flow and implications for groundwater contamination north of Prewitt,New Mexico,U.S.A.

In the southern San Juan Basin, New Mexico, strata of Permian and younger age dip gently toward the center of the basin. Most previous investigators believed that recharge to these strata occurred by precipitation on the outcrops and groundwater flowed downdip to the north and northeast. Recent water-level measurements in an undeveloped part of the basin near Prewitt, New Mexico, show that groundwater at shallow depths in alluvium and bedrock flows southward, opposite to the dip direction, and toward a major ephemeral drainage in a strike valley. North of this area, groundwater in deep bedrock aquifers does appear to flow northward. This information suggests that there are two groundwater circulation patterns; a shallow one controlled by topography and a deeper one controlled by geologic structure.Significant amounts of recharge to sandstone aquifers by infiltration through outcrops is unlikely due to the near-vertical exposures on cliffs, the gentle dip of the strata, and small annual precipitation. Numerical model results suggest that recharge to bedrock aquifers may be from downward leakage via aquitards over large areas and leakage from narrow alluvial aquifers in the subcrop area. The recharge mechanism is controlled by the hydraulic conductivity of the strata.As the flow path is controlled by hydraulic conductivity contrasts, geologic structure, and topography, contamination movement from surface impoundments is likely to be difficult to predict without a thorough hydrogeological site investigation.     

Groundwater recharge from an oxbow lake-wetland system in the Mississippi Alluvial Plain

The Mississippi River Valley Alluvial Aquifer ranks among the most overdrafted aquifers in the United States due to intensive irrigation. Concern over declining water levels has increased focus on understanding the sources of recharge. Numerous oxbow lakes overlie the aquifer that are often considered hydraulically disconnected from the groundwater system due to fine-grained bottom sediments. In the current study, groundwater levels in and around a 445-ha oxbow lake-wetland in Mississippi were monitored for a 2-year period that included an unusually long low-water condition in the lake (>17 months), followed by a high-water event lasting over 4 months before returning to earlier low-water levels. The high-water pulse (>4 m rise) provided a unique opportunity to track the impact in the underlying alluvial aquifer. During low-water conditions, groundwater flowed westward beneath the lake. Following the lake rise, groundwater beneath and near the perimeter responded as quickly as the same day, with more delayed responses moving away from the lake. Within 2 months, a groundwater mound formed near the centre of the oxbow (>3 m increase), with a reversal in the local hydraulic gradient towards the east. Flow returned to a westward gradient when the lake level dropped back below 0.3 m. Analysis of precipitation and nearby river stage could not account for the observed behavior. Recharge to the aquifer is attributed to rising water levels spreading over point bar deposits and into the surrounding forested wetlands where preferential flow pathways are likely to exist due to buried and decomposing tree remains. An earlier study in the wetland demonstrated an increasing redox potential in isolated zones, consistent with the existence of preferential flow pathways through the bottom sediments (Lahiri & Davidson, 2020). Retaining high-water levels in oxbow lakes could be a relatively low-cost water management practice for enhancing aquifer recharge.     

The Effect of Modeled Recharge Distribution on Simulated Groundwater Availability and Capture

Simulating groundwater flow in basin‐fill aquifers of the semiarid southwestern United States commonly requires decisions about how to distribute aquifer recharge. Precipitation can recharge basin‐fill aquifers by direct infiltration and transport through faults and fractures in the high‐elevation areas, by flowing overland through high‐elevation areas to infiltrate at basin‐fill margins along mountain fronts, by flowing overland to infiltrate along ephemeral channels that often traverse basins in the area, or by some combination of these processes. The importance of accurately simulating recharge distributions is a current topic of discussion among hydrologists and water managers in the region, but no comparative study has been performed to analyze the effects of different recharge distributions on groundwater simulations. This study investigates the importance of the distribution of aquifer recharge in simulating regional groundwater flow in basin‐fill aquifers by calibrating a groundwater‐flow model to four different recharge distributions, all with the same total amount of recharge. Similarities are seen in results from steady‐state models for optimized hydraulic conductivity values, fit of simulated to observed hydraulic heads, and composite scaled sensitivities of conductivity parameter zones. Transient simulations with hypothetical storage properties and pumping rates produce similar capture rates and storage change results, but differences are noted in the rate of drawdown at some well locations owing to the differences in optimized hydraulic conductivity. Depending on whether the purpose of the groundwater model is to simulate changes in groundwater levels or changes in storage and capture, the distribution of aquifer recharge may or may not be of primary importance.     

Semi‐Arid Aquifer Responses to Forest Restoration Treatments and Climate Change

The purpose of this study was to develop an interpretive groundwater‐flow model to assess the impacts that planned forest restoration treatments and anticipated climate change will have on large regional, deep (>400 m), semi‐arid aquifers. Simulations were conducted to examine how tree basal area reductions impact groundwater recharge from historic conditions to 2099. Novel spatial analyses were conducted to determine areas and rates of potential increases in groundwater recharge. Changes in recharge were applied to the model by identifying zones of basal area reduction from planned forest restoration treatments and applying recharge‐change factors to these zones. Over a 10‐year period of forest restoration treatment, a 2.8% increase in recharge to one adjacent groundwater basin (the Verde Valley sub‐basin) was estimated, compared to conditions that existed from 2000 to 2005. However, this increase in recharge was assumed to quickly decline after treatment due to regrowth of vegetation and forest underbrush and their associated increased evapotranspiration. Furthermore, simulated increases in groundwater recharge were masked by decreases in water levels, stream baseflow, and groundwater storage resulting from surface water diversions and groundwater pumping. These results indicate that there is an imbalance between water supply and demand in this regional, semi‐arid aquifer. Current water management practices may not be sustainable into the far future and comprehensive action should be taken to minimize this water budget imbalance.     

Groundwater Microbial Communities Along a Generalized Flowpath in Nomhon Area,Qaidam Basin,China

Spatial distribution (horizonal and vertical) of groundwater microbial communities and the hydrogeochemistry in confined aquifers were studied approximately along the groundwater flow path from coteau to plain in the Nomhon area, Qinghai‐Tibet plateau, China. The confined groundwater samples at different depths and locations were collected in three boreholes through a hydrogeological section in this arid and semi‐arid area. The phylogenetic analysis of 16S rRNA genes and multivariate statistical analysis were used to elucidate similarities and differences between groundwater microbial communities and hydrogeochemical properties. The integrated isotopic geochemical measurements were applied to estimate the source and recharge characteristics of groundwater. The results showed that groundwater varied from fresh to saline water, and modern water to ancient water following the flowpath. The recharge characteristics of the saline water was distinct with that of fresh water. Cell abundance did not vary greatly along the hydrogeochemical zonality; however, dissimilarities in habitat‐based microbial community structures were evident, changing from Betaproteobacteria in the apex of alluvial fan to Gammaproteobacteria and then to Epsilonproteobacteria in the core of the basin (alluvial‐lacustrine plain). Rhodoferax, Hydrogenophaga, Pseudomonas, and bacterium isolated from similar habitats unevenly thrived in the spatially distinct fresh water environments, while Sulfurimonas dominanted in the saline water environment. The microbial communities presented likely reflected to the hydrogeochemical similarities and zonalities along groundwater flowpath.     

Conceptualizing leakage and storage contributions from long open interval wells in regional deep basin flow models

Deep basin aquifers are increasingly used in water‐stressed areas, though their potential for sustainable development is inhibited by overlying aquitards and limited recharge rates. Long open interval wells (LOIWs)—wells uncased through multiple hydrostratigraphic units—are present in many confined aquifer systems and can be an important mechanism for deep basin aquifers to receive flow across aquitards. LOIWs are a major control on flow in the deep Cambrian–Ordovician sandstone aquifers of the upper Midwest, USA, providing a source of artificial leakage from shallow bedrock aquifers and equilibrating head within the sandstone aquifers despite differential pumpage. Conceptualizing and quantifying this anthropogenic flow has long been a challenge for groundwater flow modellers, particularly on a regional scale. Synoptic measurements of active production wells and well completion data for northeast Illinois form the basis for a transient, head‐specified MODFLOW model that determines mass balance contributions to the region and estimates LOIW leakage to the aquifers. Using this insight, transient LOIW leakage was simulated using transiently changing K_V zones in a traditional, Q‐specified MODFLOW‐USG model, a novel approach that allows the K_V in a cell containing a LOIW to change transiently by use of the time‐variant materials (TVM) package. With this modification, we achieved a consistent calibration through time, averaging 19.9 m root mean squared error. This model indicates that artificial leakage via LOIWs contributed a minimum of 10–13% of total flow to the sandstone aquifers through the entire history of pumping, up to 50% of flow around 1930. Removal from storage exceeds 40% of flow during peak withdrawals, much of this flow sourced from units other than the primary sandstone aquifers via LOIWs. As such, understanding the timing and magnitude of LOIW leakage is essential for predicting future water availability in deep basin aquifers.     

Groundwater behaviour in Tenerife,volcanic island (Canary Islands,Spain)

Tenerife is the largest of the seven Canary Islands, encompassing an area of 2,058 km². It is situated in the Atlantic Ocean between 16–17°W longitude and 28–29°N latitude. The topography of the island is characterized by generally steep slopes. The Teide Volcano has an elevation of 3,718 m. Precipitation is caused mainly by invasions of maritime polar air. Maximum mean precipitation recorded for 25-year period (1940–1965) is 1,000 mm.The fractured volcanic aquifer of the Old Basaltic Series is the main supplier of groundwater in Tenerife. Smaller quantities of groundwater are supplied by the Cañadas Series and minor amounts by alluvial sediments. Groundwater compartments develop in areas of dikes and contacts between permeable and impermeable zones. These compartments are irregular in volume, shape, and structure. The groundwater system forms a tortuous chain of compartments. Water circulates from one groundwater compartment to another through secondary fractures and other permeable elements which branch and intersect. Fractures which extend to the surface play an important role in recharge.The hydrologic system at Tenerife is characterized by three zones: the upper vadose, the lower vadose, and the saturated zone. In both the upper and lower vadose zones the dominant direction of flow is vertical, while in the saturated zone flow is generally oblique toward the sea.     

Field Investigation of a New Recharge Approach for ASR Projects in Near‐Surface Aquifers

Aquifer storage and recovery (ASR) is the artificial recharge and temporary storage of water in an aquifer when water is abundant, and recovery of all or a portion of that water when it is needed. One key limiting factor that still hinders the effectiveness of ASR is the high costs of constructing, maintaining, and operating the artificial recharge systems. Here we investigate a new recharge method for ASR in near‐surface unconsolidated aquifers that uses small‐diameter, low‐cost wells installed with direct‐push (DP) technology. The effectiveness of a DP well for ASR recharge is compared with that of a surface infiltration basin at a field site in north‐central Kansas. The performance of the surface basin was poor at the site due to the presence of a shallow continuous clay layer, identified with DP profiling methods, that constrained the downward movement of infiltrated water and significantly reduced the basin recharge capacity. The DP well penetrated through this clay layer and was able to recharge water by gravity alone at a much higher rate. Most importantly, the costs of the DP well, including both the construction and land costs, were only a small fraction of those for the infiltration basin. This low‐cost approach could significantly expand the applicability of ASR as a water resources management tool to entities with limited fiscal resources, such as many small municipalities and rural communities. The results of this investigation demonstrate the great potential of DP wells as a new recharge option for ASR projects in near‐surface unconsolidated aquifers.     

Divergence and flow direction as indicators of subsurface heterogeneity and stage‐dependent storage in alluvial floodplains

Assuming homogeneity in alluvial aquifers is convenient, but limits our ability to accurately predict stream‐aquifer interactions. Research is needed on (i) identifying the presence of focused, as opposed to diffuse, groundwater discharge/recharge to streams and (ii) the magnitude and role of large‐scale bank and transient storage in alluvial floodplains relative to changes in stream stage. The objective of this research was to document and quantify the effect of stage‐dependent aquifer heterogeneity and bank storage relative to changes in stream stage using groundwater flow divergence and direction. Monitoring was performed in alluvial floodplains adjacent to the Barren Fork Creek and Honey Creek in northeastern Oklahoma. Based on results from subsurface electrical resistivity mapping, observation wells were installed in high and low electrical resistivity subsoils. Water levels in the wells were recorded real time using pressure transducers (August to October 2009). Divergence was used to quantify heterogeneity (i.e. variation in hydraulic conductivity, porosity, and/or aquifer thickness), and flow direction was used to assess the potential for large‐scale (100 m) bank or transient storage. Areas of localized heterogeneity appeared to act as divergence zones allowing stream water to quickly enter the groundwater system, or as flow convergence zones draining a large groundwater area. Maximum divergence or convergence occurred with maximum rates of change in flow rates or stream stage. Flow directions in the groundwater changed considerably between base and high flows, suggesting that the floodplains acted as large‐scale bank storage zones, rapidly storing and releasing water during passage of a storm hydrograph. During storm events at both sites, the average groundwater direction changed by at least 90° from the average groundwater direction during baseflow. Aquifer heterogeneity in floodplains yields hyporheic flows that are more responsive and spatially and temporally complex than would be expected compared to more common assumptions of homogeneity. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of variations of river stage and hydraulic conductivity on temporal scaling of groundwater levels: numerical simulations

It was found in previous studies that groundwater levels may fluctuate as a temporal fractal. In this study numerical simulations of groundwater level fluctuations in an unconfined aquifer near a river were conducted to investigate the effects of aquifer heterogeneity and river stage variations on the fractal behavior of the water levels, h(t). Groundwater recharge was taken to be a white-noise process. The aquifer heterogeneity was simulated with a second-order stationary field of hydraulic conductivity (K) with an exponential variogram model. The results showed that groundwater levels fluctuate as a temporal fractal in both homogeneous and heterogeneous aquifers as long as K is less than 10 m/d. Most aquifers may indeed act as a fractal filter which takes a random non-fractal recharge inputs and produces a fractal responses of groundwater level fluctuations. A crossover in temporal scaling of h(t) may appear in more permeable aquifers. Fluctuations of the groundwater level in a homogeneous aquifer are dominated by the recharge process when the river stage is constant or by the river stage variations when the river stage varies in highly permeable aquifers. Heterogeneity plays an important role in the temporal scaling of h(t) in more permeable aquifers: the stronger the heterogeneity, the stronger the temporal scaling of h(t).     

Sustainability of groundwater usage in northern China: dependence on palaeowaters and effects on water quality,quantity and ecosystem health

A synthesis of groundwater ages, recharge rates and information on processes affecting groundwater quality in northern China highlights the major challenges faced for sustainable management of the region's groundwater. Direct recharge rates range from hundreds of millimetres per year in the North China Plain, to tens of millimetres per year in the Loess Plateau to less than 4 mm/year in the arid northwest. Recharge rates and mechanisms to deep semiconfined and confined aquifers are poorly constrained; however, on the basis of available data, these are likely to be mostly negligible. Severe groundwater level declines (0.5–3 m/year) have occurred throughout northern China in the last three to four decades, particularly in deep aquifers. Radiocarbon dating, stable isotope and noble gas data show that the most intensively extracted deep groundwater is palaeowater, recharged under different climate and land cover conditions to the present. Reservoir construction has reduced surface runoff in mountain‐front areas that would naturally recharge regional Quaternary aquifers in many basins. In combination with intensive irrigation practices, this has resulted in the main recharge source shifting from surface runoff and mountain‐front recharge to irrigation returns. This has reduced infiltration of fresh recharge at basin margins and rapidly increased nitrate concentrations and overall mineralisation in phreatic groundwater over wide areas (in some cases to >400 mg/l and >10 g/l, respectively). In some basins, there is evidence that poor quality shallow water has leaked into deep layers (>200 m) via preferential flow, mixing with palaeowaters stored in semiconfined aquifers. High concentrations of naturally occurring fluoride and arsenic (locally >8.5 and >4 mg/l, respectively) have recently lead to the abandonment of numerous supply wells in northern China, creating further pressure on stressed water resources. Increasing water demand from direct and indirect consumption poses major challenges for water management in northern China, which must consider the full water cycle. Copyright © 2012 John Wiley & Sons, Ltd.     

Aquifer interactions with a polluted mountain river of Nicaragua

The interactions between a stream and nearby shallow aquifers were investigated in a mountain basin being polluted by mercury released during mining in central Nicaragua. Hourly data series of water levels and temperatures were analysed using cross‐correlation. Resistivity imaging was used to map the subsurface and to complement the hydrological data interpretation. The results show the complex hydrogeological conditions that characterize the region, with weathering and fractured rock as main contributors to groundwater transport. The resistivity images suggest the presence of two vertical dykes perpendicular to the stream, and zones rich in clay. The data series indicate a rapid response from the aquifers to recharge events, followed by immediate discharge on a yearly basis. Furthermore, alternating periods of stream infiltration and aquifer discharge were identified. This work demonstrates that surface water pollution is a threat to groundwater quality in the area. Copyright © 2007 John Wiley & Sons, Ltd.     

Migration of induced-infiltrated stream water into nearby aquifers due to seasonal ground water withdrawal

Analysis of stream-aquifer interaction due to ground water extraction has traditionally focused on the determination of the amount of water depleted in the stream. Less attention has been paid to the movement of infiltrated stream water inside aquifer, particularly for agricultural areas. This paper presents a method of using particle-tracking techniques to evaluate the transport of the leaked stream water in the nearby aquifers. Simple stream-aquifer conditions are used to demonstrate the usefulness of the analysis. Travel times, pathlines, and influence zones of stream water were determined between a stream and nearby pumping wells for seasonal ground water extraction areas. When water quantity is a concern, the analyses provide additional information about stream depletion; when water quality is an issue, they offer information for wellhead protection. Analyses were conducted for transient conditions, and both pumping and nonpumping periods were considered. According to the results from the simulation examples, migration of infiltrated stream water into the nearby aquifers is generally slow and most infiltrated stream water does not arrive at the pumping well at the end of a 90-day irrigation season. Infiltrated stream water may remain in the aquifer for several years before arriving at the pumping well. For aquifers with a regional hydraulic gradient toward streams, part of the infiltrated stream water may discharge back to streams during a recovery period.     

Sulfur Hexafluoride and Potassium Bromide as Groundwater Tracers for Managed Aquifer Recharge

Sulfur hexafluoride (SF₆) is an established tracer for use in managed aquifer recharge projects. SF₆ exsolves from groundwater when it encounters trapped air according to Henry's law. This results in its retardation relative to groundwater flow, which can help determine porous media saturation and flow dynamics. SF₆ and the conservative, nonpartitioning tracer, bromide (Br⁻ added as KBr), were introduced to recharge water infiltrated into stacked glacial aquifers in Thurston County, Washington, providing the opportunity to observe SF₆ partitioning. Br⁻, which is assumed to travel at the same velocity as the groundwater, precedes SF₆ at most monitoring wells (MWs). Average groundwater velocity in the unconfined aquifer in the study area ranges from 3.9 to 40 m/d, except in the southwestern corner where it is slower. SF₆ in the shallow aquifer exhibits an average retardation factor of 2.5 ± 3.8, suggesting an air-to-water ratio on the order of 10⁻³ to 10⁻² in the pore space. Notable differences in tracer arrival times at adjacent wells indicate very heterogeneous conductivity. One MW exhibits double peaks in concentrations of both tracers with different degrees of retardation for the first and second peaks. This suggests multiple flowpaths to the well with variable saturation. The confining layer between the upper two aquifers appears to allow intermittent connection between aquifers but serves as an aquitard in most areas. This study demonstrates the utility of SF₆ partitioning for evaluating hydrologic conditions at prospective recharge sites.     

Characteristics of chemistry and stable isotopes in groundwater of Chaobai and Yongding River basin,North China Plain

To identify the groundwater flow system in the North China Plain, the chemical and stable isotopes of the groundwater and surface water were analysed along the Chaobai River and Yongding River basin. According to the field survey, the study area in the North China Plain was classified hydrogeologically into three parts: mountain, piedmont alluvial fan and lowland areas. The change of electrical conductance and pH values coincided with groundwater flow from mountain to lowland areas. The following groundwater types are recognized: Ca? HCO₃ and Ca? Mg? HCO₃ in mountain areas, Ca? Mg? HCO₃ and Na? K? HCO₃ in piedmont alluvial fan areas, and HCO₃? Na in lowland areas. The stable isotope distribution of groundwater in the study area also has a good corresponding relation with other chemical characteristics. Stable isotope signatures reveal a major recharge from precipitation and surface water in the mountain areas. Chemical and stable isotope analysis data suggest that mountain and piedmont alluvial fan areas were the major recharge zones and the lowland areas belong to the main discharge zone. Precipitation and surface water were the major sources for groundwater in the North China Plain. Stable isotopic enrichment of groundwater near the dam area in front of the piedmont alluvial fan areas shows that the dam water infiltrated to the ground after evaporation. As a result, from the stable isotope analysis, isotope value of groundwater tends to deplete from sea level (horizontal ground surface) to both top of the mountain and the bottom of the lowland areas in symmetrically. This suggests that groundwater in the study area is controlled by the altitude effect. Shallow groundwater in the study area belongs to the local flow system and deep groundwater part of the regional flow system. Copyright © 2007 John Wiley & Sons, Ltd.     

Investigating Groundwater Flow Between Edwards and Trinity Aquifers in Central Texas

Understanding the nature of communication between aquifers can be challenging when using traditional physical and geochemical groundwater sampling approaches. This study uses two multiport wells completed within Edwards and Trinity aquifers in central Texas to determine the degree of groundwater inter‐flow between adjacent aquifers. Potentiometric surfaces, hydraulic conductivities, and groundwater major ion concentrations and Sr isotope values were measured from multiple zones within three hydrostratigraphic units (Edwards and Upper and Middle Trinity aquifers). Physical and geochemical data from the multiport wells were combined with historical measurements of groundwater levels and geochemical compositions from the region to characterize groundwater flow and identify controls on the geochemical compositions of the Edwards and Trinity aquifers. Our results suggest that vertical groundwater flow between Edwards and Middle Trinity aquifers is likely limited by low permeability, evaporite‐rich units within the Upper and Middle Trinity. Potentiometric surface levels in both aquifers vary with changes in wet vs. dry conditions, indicating that recharge to both aquifers occurs through distinct recharge areas. Geochemical compositions in the Edwards, Upper, and Middle Trinity aquifers are distinct and likely reflect groundwater interaction with different lithologies (e.g., carbonates, evaporites, and siliceous sediments) as opposed to mixing of groundwater between the aquifers. These results have implications for the management of these aquifers as they indicate that, under current conditions, pumping of either aquifer will likely not induce vertical cross‐formational flow between the aquifers. Inter‐flow between the Trinity and the Edwards aquifers, however, should be reevaluated as pumping patterns and hydrogeologic conditions change.     

Chemical and isotopic methods for management of artificial recharge in Mazraha Station (Damascus Basin,Syria)

Artificially enhancing recharge rate into groundwater aquifer at specially designed facilities is an attractive option for increasing the storage capacity of potable water in arid and semi‐arid region such as Damascus basin (Syria). Two dug wells (I and II) for water injection and 24 wells for water extraction are available in Mazraha station for artificial recharge experiment. Chemical and stable isotopes (δ²H and δ¹⁸O) were used to evaluate artificial recharge efficiency. 400 to 500*10³ m³ of spring water were injected annually into the ambient shallow groundwater in Mazraha station, which is used later for drinking purpose. Ambient groundwater and injected spring water are calcium bicarbonate type with EC about 880 ± 60 μS/cm and 300 ± 50 μS/cm, respectively. The injected water is under saturated versus calcite and the ambient groundwater is over saturated, while the recovered water is near equilibrium. It was observed that the injection process formed a chemical dilution plume that improves the groundwater quality. Results demonstrate that the hydraulic conductivity of the aquifer is estimated around 6.8*10^?4 m/s. The effective diameter of artificial recharge is limited to about 250 m from the injection wells. Mixing rate of 30% is required in order to reduce nitrate concentration below 50 mg/l which is considered the maximum concentration limit for potable water. Deuterium and oxygen‐18 relationship demonstrates that mixing line between injected water and ambient groundwater has a slope of 6.1. Oxygen‐18 and Cl^? plot indicates that groundwater salinity origin is from mixing process, and no dissolution and evaporation were observed. These results demonstrate the efficiency of the artificial recharge experiments to restore groundwater storage capacity and to improve the water quality. Copyright © 2011 John Wiley & Sons, Ltd.     

Electromagnetic‐Induction Logging to Monitor Changing Chloride Concentrations

Water from the San Joaquin Delta, having chloride concentrations up to 3590 mg/L, has intruded fresh water aquifers underlying Stockton, California. Changes in chloride concentrations at depth within these aquifers were evaluated using sequential electromagnetic (EM) induction logs collected during 2004 through 2007 at seven multiple‐well sites as deep as 268 m. Sequential EM logging is useful for identifying changes in groundwater quality through polyvinyl chloride‐cased wells in intervals not screened by wells. These unscreened intervals represent more than 90% of the aquifer at the sites studied. Sequential EM logging suggested degrading groundwater quality in numerous thin intervals, typically between 1 and 7 m in thickness, especially in the northern part of the study area. Some of these intervals were unscreened by wells, and would not have been identified by traditional groundwater sample collection. Sequential logging also identified intervals with improving water quality—possibly due to groundwater management practices that have limited pumping and promoted artificial recharge. EM resistivity was correlated with chloride concentrations in sampled wells and in water from core material. Natural gamma log data were used to account for the effect of aquifer lithology on EM resistivity. Results of this study show that a sequential EM logging is useful for identifying and monitoring the movement of high‐chloride water, having lower salinities and chloride concentrations than sea water, in aquifer intervals not screened by wells, and that increases in chloride in water from wells in the area are consistent with high‐chloride water originating from the San Joaquin Delta rather than from the underlying saline aquifer.     

Impact of Recharge Through Residual Oil Upon Sampling of Underlying Ground Water

At an aviation gasoline spill site in Traverse City, Michigan, historical records indicate a positive correlation between significant rainfall events and increased concentrations of slightly soluble organic compounds in the monitoring wells of the site. To investigate the recharge effect on ground water quality due to infiltrating, water percolating past residual oil and into the saturated zone, an in situ infiltration experiment was performed at the site. Sampling cones were set at various depths below a circular test area, 13 feet (4 meters) in diameter. Rainfall was simulated by sprinkling the test area at a rate sufficiently low to prevent runoff. The sampling cones for soil-gas and ground water quality were installed in the unsaturated and saturated zones to observe the effects of the recharge process. At the time of the test, the water table was below the residual oil layer. The responses of the soil-gas and ground water quality were monitored during the recharge and drainage periods, which resulted from the sprinkling.
Infiltrated water was determined to have transported organic constituents of the residual oil, specifically benzene, toluene, ethylbenzene, and ortho-xylene (BTEX), into the ground water beneath the water table, elevating the aqueous concentrations of these constituents in the saturated zone. Soil-gas concentrations of the organic compounds in the unsaturated zone increased with depth and time after the commencement of infiltration. Reaeration of the unconfined aquifer via the infiltrated water was observed. It is concluded that water quality measurements are directly coupled to recharge events for the sandy type of aquifer with an overlying oil phase, which was studied in this work. Ground water sampling strategies and data analysis need to reflect the effect of recharge from precipitation on shallow, unconfined aquifers where an oil phase may be present.