Marine debris ingestion by coastal dolphins: What drives differences between sympatric species?

This study compared marine debris ingestion of the coastal dolphins Pontoporia blainvillei and Sotalia guianensis in a sympatric area in Atlantic Ocean. Among the 89 stomach contents samples of P. blainvillei, 14 (15.7%) contained marine debris. For S. guianensis, 77 stomach contents samples were analyzed and only one of which (1.30%) contained marine debris. The debris recovered was plastic material: nylon yarns and flexible plastics. Differences in feeding habits between the coastal dolphins were found to drive their differences regarding marine debris ingestion. The feeding activity of P. blainvillei is mainly near the sea bottom, which increases its chances of ingesting debris deposited on the seabed. In contrast, S. guianensis has a near-surface feeding habit. In the study area, the seabed is the main zone of accumulation of debris, and species with some degree of association with the sea bottom may be local bioindicators of marine debris pollution.     

Crustal thickness and adakite occurrence in the Philippines: Is there a relationship?

Adakites are increasingly being recognized worldwide in a variety of tectonic settings. Models on the formation of this geochemically distinct class of volcanic rocks have evolved from partial melting of subducted young, hot oceanic slabs to magmatism resulting from oblique subduction, low‐angle or flat subduction, or even slab‐tearing. Some workers have also pointed to the partial melting of thickened crust to explain the generation of adakitic melts. Rare earth element ratios from adakites and adakitic rocks in the Philippines were used in this study to obtain approximations of the levels where they were generated. These were tied to available geophysical data that defines the crustal thickness of the areas where the samples were collected. High Sm/Yb and La/Yb ratios denote the involvement of amphiboles, and in some cases garnet, in the generation of adakites and adakitic magmas. The presence of amphibole and garnet as residual phases suggests high pressures corresponding to thicker crust (～30 to 45 km). Adakites and adakitic rocks formed through processes other than melting of subducted young oceanic crust would need ≥30 km to account for the heavy rare earth element signatures. If mantle fractionation is not the process involved, crustal thickness is critical to generate adakites and adakitic rocks.     

Catchment properties,function, and conceptual model representation: is there a correspondence?

This study investigates the possible correspondence between catchment structure, as represented by perceptual hydrological models developed from fieldwork investigations, and mathematical model structures, selected on the basis of reproducing observed catchment hydrographs. Three Luxembourgish headwater catchments are considered, where previous fieldwork suggested distinct flow‐generating mechanisms and hydrological dynamics. A set of lumped conceptual model structures are hypothesized and implemented using the SUPERFLEX framework. Following parameter calibration, the model performance is examined in terms of predictive accuracy, quantification of uncertainty, and the ability to reproduce the flow–duration curve signature. Our key research question is whether differences in the performance of the conceptual model structures can be interpreted based on the dominant catchment processes suggested from fieldwork investigations. For example, we propose that the permeable bedrock and the presence of multiple aquifers in the Huewelerbach catchment may explain the superior performance of model structures with storage elements connected in parallel. Conversely, model structures with serial connections perform better in the Weierbach and Wollefsbach catchments, which are characterized by impermeable bedrock and dominated by lateral flow. The presence of threshold dynamics in the Weierbach and Wollefsbach catchments may favour nonlinear models, while the smoother dynamics of the larger Huewelerbach catchment were suitably reproduced by linear models. It is also shown how hydrologically distinct processes can be effectively described by the same mathematical model components. Major research questions are reviewed, including the correspondence between hydrological processes at different levels of scale and how best to synthesize the experimentalist's and modeller's perspectives. Copyright © 2013 John Wiley & Sons, Ltd.     

Mercury in Human Hair and Fish: is there a Hong Kong Male Subfertility Connection?

Hair is a useful indicator of a person’s exposure to mercury. For this reason, hair samples from 94 fertile and 117 subfertile Hong Kong residents were compared over four separate age groups. A typical 30 year old Hong Kong male had a hair mercury concentration of approximately 3.3 mg/kg mercury while a 60 year old Hong Kong subfertile male had a hair mercury concentration of about 7.5 mg/kg. Most of this mercury comes from seafood consumption. Individuals consuming four or more meals of fish per week had a hair mercury of 4.07 mg/kg dry weight of hair while those consuming fish less frequently had significantly lower levels (2.56 mg/kg). Hong Kong residents that consumed no fish had only 1.21 mg/kg hair mercury. The relative risks of males with moderate and high levels of mercury in their hair were significant (p=0.062). Age corrected estimates of risk indicated that compared with men with low levels of mercury in their hair, men with higher levels were twice as likely to be subfertile (relative risk, 1.95) and there was a dose–response trend that was highly significant (p < 0.0005). In light of these risks we concluded that the maximum permitted mercury level in food sold in Hong Kong should be lowered from 0.5 mg/kg wet weight to a level to be determined by risk analysis. In Japan, where fish mercury levels and fish consumption rates are lower than those in Hong Kong, the maximum amount of mercury permitted in food for human consumption is 0.3 mg/kg wet weight.     

Are wind wave heights increasing in south-eastern south American continental shelf between 32°S and 40°S?

In this paper, a possible increase in wind wave heights in the south-eastern south American continental shelf between 32°S and 40°S is investigated. Both time series of in situ (1996–2006) and topex (1993–2001) annual mean significant wave heights gathered at the continental shelf and adjacent ocean present apparent positive trends. Even though these trends are not statistically different from zero, it must be taken into account that the available in situ and satellite data have a short span and, moreover, in situ data present several gaps. Several papers presented evidence about a possible change on the low atmospheric circulation in this region of the southern hemisphere. Consequently, a weak increase in wave height might be occurring, which would be hard to quantify due to the shortness and the insufficiency of the available observations. In order to study a possible trend in mean annual wind wave heights simulating waves nearshore (swan) model forced with ncep/ncar surface wind was implemented in a regional domain for the period 1971–2005. The annual root-mean-square heights of the simulated wave show significant trends at several locations of the inner continental shelf and the adjacent ocean. The most significant increase is observed between 1991–2000 and 1981–1990 decades. The largest difference (0.20 m, 9%) occurs around 34°S–48°W. The wave height increase is somewhat lower, 7%, in the continental shelf and in the río de la plata estuary. The annual mean energy density (spatially averaged) also presents a significant positive trend (0.036 m²/yr) and relatively high inter-annual variability. The possible link between this inter-annual variability and el niño–southern oscillation (enso) was investigated but no apparent relationship was found. A possible increase in the annual mean energy density of waves would be able to produce changes in the littoral processes and, consequently, in the erosion of the coast.     

Association of iron oligomeric species with natural organic matter: a combined EELS and M?ssbauer investigation

The nature of the interaction between iron oxyhydroxide compounds and natural organic matter (NOM) may take various forms and is still a matter of debate. It is an important field to understand, especially for water treatment applications and for the knowledge of iron transport in the environment. The nature of association reached between iron oligomeric species and NOM is here investigated using M?ssbauer spectroscopy and electron energy-loss spectroscopy (EELS) at the Fe-L3 edge. Raw water NOM taken from Moselle River (France), natural humic substances extracted from the riverine suspended matter, and a synthesized humic-like substance, are coagulated with iron nitrate according to a jar-test procedure. The results from M?ssbauer spectroscopy indicate that Fe is present in an octahedral coordination environment, which is consistent with prior X-ray absorption spectroscopy reported in the literature. The areas beneath the peaks (Fe L3 edge) and the peak shapes of EELS spectra differ according to the origin of the organic matter, suggesting that various types of Fe populations can be distinguished using the EELS technique. Combining the selectivity of both M?ssbauer spectroscopy for identifying trace, poorly crystalline Fe solids, oxidation state and of EELS for being able to characterize the population of Fe based on L-edge spectra, appears promising for characterizing Fe in systems containing NOM.     

Slingram EMI prospection: Are vertical orientated devices a suitable solution in archaeological and pedological prospection?

Electromagnetic induction (EMI) is one of the geophysical techniques widely used in soil studies, the slingram devices being held horizontally over the soil surface, i.e. with the coils located at the same height above the ground surface. Our study aims assessing the abilities of slingram devices when held vertically. 1D and 3D modelling have been achieved in order to compare the theoretical responses of vertical devices to the horizontal ones. Some comparative surveys were also undertaken in archaeological contexts to confirm the reliability of theoretical conclusions. Both approaches show that vertical slingram devices are suitable for survey and can constitute an alternative to the usual horizontal orientation. We give a table in Appendix A which contains the calibration coefficient allowing transforming of the values given by some of commercially available devices which would be advantageous to use in vertical orientation     

Is there a great unconformity between Xiamaling and Longshan formations in the North China Craton?

The existence of a 0.3 Ga "great unconformity" between the Mesoproterozoic "Undefined System" Xiamaling Formation and the "Neoproterozoic" Longshan Formation has long been controversial.In this study,stratigraphy,sedimentology,detrital zircon dating,lithium isotope,and major and trace elements were applied to systematically analyze their relationship.Results demonstrate that coarse to fine sandstone-mudstone normal cycles with different grades and thicknesses exist from the Xiamaling to the Long...     

Is there a concrete relationship between energy consumption, economic development and environmental load in developing economies? A case study in Shandong Province, China

Shandong Province is currently experiencing fast urbanization and economic booming. However, low energy efficiency, energy shortage and other energy related issues are becoming the limiting factors for further economic development. Based on the analysis of Resource and Environmental Performance Index (REPI) of the past decade, the energy saving index shows that the energy saving level in Shandong fell behind the national average level in China. The sulfur dioxide saving index, however, shows that sulfur dioxide reduction in Shandong was significant. The energy demands of Shandong in 2010, 2015 and 2020 have been forecasted with the environmental load model. In a projected ideal scenario, the energy consumption does not increase with economic development. On the contrary, Shandong can achieve rapid economic development with less energy consumption and affordable environmental load if the industrial structure is being further optimized, technological upgrading efforts are strengthened, strict pollutant control measures are implemented, and reasonable plans for energy development are established.     

Long-term changes in physical and chemical conditions of nutrient-poor lakes along a latitudinal gradient: is there a coherent phytoplankton community response?

To evaluate climate and atmospheric deposition induced physical and water chemical changes and their effects on phytoplankton communities, we used complete time series (14 years, monthly measurements during the growing season) of 18 physical and chemical variables and phytoplankton data from 13 nutrient-poor Swedish reference lakes along a latitudinal gradient. We found numerous strong significant changes over time that were most coherent among lakes for sulfate concentrations, conductivity, calcium, magnesium, chloride, potassium, water color, surface water temperature and the intensity of thermal stratification. Despite these pronounced coherent physical and water chemical changes over Sweden, the phytoplankton biomass and species richness of six phytoplankton groups, measured at the same time as the water chemical variables, showed only few and weak significant changes over time. The only coherent significant change over Sweden, occurring in seven lakes, was observed in the species richness of chlorophytes. The number of chlorophyte taxa significantly declined over Sweden. Using a partial least square model for each lake, we attributed the decline primarily to an increase in water temperatures and water color, which were among the most important variables for the model performance of each lake. All other taxonomic groups were driven primarily by non-coherent changes in nutrient concentrations, pH and probably also non-coherent grazing pressure. We concluded that coherent phytoplankton responses can only be achieved for taxonomic groups that are driven primarily by coherent physical/chemical changes. According to our study, chlorophytes belong to such a group, making them possible global change indicators. Our findings give new insights into global change effects on different phytoplankton taxonomic groups in nutrient-poor lakes.