Prebiotic carbon in clays from Orgueil and Ivuna (CI), and Tagish Lake (C2 ungrouped) meteorites

Abstract— Transmission electron microscopic (TEM) and electron energy‐loss spectroscopic (EELS) study of the Ivuna and Orgueil (CI), and Tagish Lake (C2 ungrouped) carbonaceous chondrite meteorites shows two types of C‐clay assemblages. The first is coarser‐grained (to 1 μm) clay flakes that show an intense O K edge from the silicate together with a prominent C K edge, but without discrete C particles. Nitrogen is common in some clay flakes. Individual Orgueil and Tagish Lake meteorite clay flakes contain up to 6 and 8 at% C, respectively. The C K‐edge spectra from the clays show fine structure revealing aromatic, aliphatic, carboxylic, and carbonate C. The EELS data shows that this C is intercalated with the clay flakes. The second C‐clay association occurs as poorly crystalline to amorphous material occurring as nanometer aggregates of C, clay, and Fe‐O‐rich material. Some aggregates are dominated by carbonaceous particles that are structurally and chemically similar to the acid insoluble organic matter. The C K‐edge shape from this C resembles that of amorphous C, but lacking the distinct peaks corresponding to aliphatic, carboxylic, and carbonate C groups. Nanodiamonds are locally abundant in some carbonaceous particles. The abundance of C in the clays suggest that molecular speciation in the carbonaceous chondrites is partly determined by the effects of aqueous processing on the meteorite parent bodies, and that clays played an important role. This intricate C‐clay association lends credence to the proposal that minerals were important in the prebiotic chemical evolution of the early solar system.     

The analysis of four cosmic dust particles

A set of four stratospheric particles was reanalysed. These particles registered in the NASA Cosmic Dust Catalogs (CDCs) were classified in the Houston Johnson Space Center (JSC) as the particles of cosmic origin (C). Present energy-dispersive X-ray (EDX) spectra confirmed previous classification and revealed additional features in the chemical composition of the cosmic dust particles.The particles are extremely fine-grained aggregates with bulk chondritic composition. Somewhat higher content of oxygen may indicate a presence of hydroxide containing minerals in their phase composition.     

Investigations on a Large Collection of Cosmic Dust From the Central Indian Ocean

We collected 1,245 spherules from the Central Indian Ocean basin by Magnetic cosmic dust collection (MACDUC) experiment raking the deep sea floor. This collection ranks among the large deep sea collections of cosmic dust. For this study, 168 particles are analyzed with SEM-EDS to characterise their cosmic nature and identify the processes that their morphological features, textures and chemical compositions reveal. All the three basic types of cosmic spherules have been identified: I-type, S-type and the G-type. The silicate or the S-type spherules are dominant in this collection. In all, 115 spherules were sectioned, polished and analyzed for major elements. I-type spherules are mainly composed of Fe and Ni oxides, some have metallic cores where appreciable amounts of Co is observed in addition to glassy phases with lithophile elements are also observed in these spherules. These evidences are supportive of the view that the I-type spherules could be metal grains from carbonaceous/unequilibrated chondritic bodies. The S-type spherules show elemental composition of Mg, Al, Si, Ca, Fe, and Ni approximately similar to chondritic compositions. In addition, some other rare particles such as an S-type sphere which contains a large zoned relict chromite crystal, other spheres with a semi-porphyritic/barred olivine texture are also observed. While most the S-type spherules appear to have carbonaceous chondrites as their parent bodies, the relict grain bearing spherule shows distinctly an ordinary chondritic parent body.     

TEM studies and the shock history of a “mysterite” inclusion from the Krymka LL chondrite

Abstract— The microstructure and composition of the matrix of one carbonaceous inclusion (K1) in the Krymka LL3.1 chondrite were studied using transmission electron microscopy (TEM). K1 has previously shown an enigmatic nature and similarities with volatile‐rich, fine‐grained, dark inclusions of Krymka called “mysterite.” In the present study, four minerals were identified by TEM. Olivine, pyroxene, and pyrrhotite typically have grain sizes of one micrometer; graphite occurs as flakes of a similar size. Olivine shows a moderately high dislocation density most probably caused by shock. Pyroxene shows coexisting ortho‐ and clinoenstatite lamellae that probably originated from shear stress after a shock event or from the rapid cooling of the protoenstatite stability field. However, we demonstrate that in this case, a shock trigger is more likely. Pyrrhotite in the studied sample occurs as a 4C monoclinic superstructure. The graphite flakes in the fragment are well crystallized, as can be seen by discrete spots in the diffraction pattern. In graphite, the degree of crystallization increases with the metamorphic grade. Based on the microstructure of this mineral we conclude that after a first moderate shock event, the residual temperature between 300 °C and 500 °C led to thermal metamorphism. A second shock event, possibly at excavation from the parent body, is responsible for the shock features observed in olivine, pyroxene, and graphite.     

Cosmic rays at ultra high energies (Neutrinos!)

Resonant photo-pion production with the cosmic microwave background predicts a suppression of extragalactic protons above the famous Greisen–Zatsepin–Kuzmin cutoff at about E_GZK ≈ 5 × 10¹⁰ GeV. Current cosmic ray data measured by the AGASA and HiRes Collaborations do not unambiguously confirm the GZK cutoff and leave a window for speculations about the origin and chemical composition of the highest energy cosmic rays. In this work we analyze the possibility of strongly interacting neutrino primaries and derive model-independent quantitative requirements on the neutrino–nucleon inelastic cross section for a viable explanation of the cosmic ray data. Search results on weakly interacting cosmic particles from the AGASA and RICE experiments are taken into account simultaneously. Using a flexible parameterization of the inelastic neutrino–nucleon cross section we find that a combined fit of the data does not favor the Standard Model neutrino–nucleon inelastic cross section, but requires, at 90% confidence level, a steep increase within one energy decade around E_GZK by four orders of magnitude. We illustrate such an enhancement within some extensions of the Standard Model. The impact of new cosmic ray data or cosmic neutrino search results on this scenario, notably from the Pierre Auger Observatory soon, can be immediately evaluated within our approach.     

Major and trace element geochemistry of S‐type cosmic spherules

Micrometeorites that pass through the Earth's atmosphere undergo changes in their chemical compositions, thereby making it difficult to understand if they are sourced from the matrix, chondrules, or calcium–aluminum‐rich inclusions (CAIs). These components have the potential to provide evidence toward the understanding of the early solar nebular evolution. The variations in the major element and trace element compositions of 155 different type (scoriaceous, relict bearing, porphyritic, barred, cryptocrystalline, and glass) of S‐type cosmic spherules are investigated with the intent to decipher the parent sources using electron microprobe and laser ablation inductively coupled plasma‐mass spectrometry. The S‐type cosmic spherules appear to show a systematic depletion in volatile element contents, but have preserved their refractory trace elements. The trends in their chemical compositions suggest that the S‐type spherules comprise of components from similar parent bodies, that is, carbonaceous chondrites. Large fosteritic relict grains observed in this investigation appear to be related to the fragments of chondrules from carbonaceous chondrites. Furthermore, four spherules (two of these spherules enclose spinels and one comprised entirely of a Ca‐Al‐rich plagioclase) show enhanced trace element enrichment patterns that are drastically different from all the other 151 cosmic spherules. The information on the chemical composition and rare earth elements (REEs) on cosmic spherules suggest that the partially to fully melted ones can preserve evidences related to their parent bodies. The Ce, Eu, and Tm anomalies found in the cosmic spherules have similar behavior as that of chondrites. Distinct correlations observed between different REEs and types of cosmic spherules reflect the inherited properties of the precursors.     

The differential cosmic ray energy flux in the light of an ultrarelativistic generalized Lorentzian thermodynamics

The ultrarelativistic generalized Lorentzian quasi-equilibrium thermodynamic energy distribution is tentatively applied to the energy spectrum of galactic cosmic ray fluxes. It is found that the inferred power law slopes contain a component which evolves with cosmic ray energy in steps of thirds, resembling the sequence of structure functions in fully developed Kolmogorov turbulence. Within the generalized thermodynamics the chemical potential is estimated from the deviation of the fluxes at decreasing energy, presumably throwing light on the cosmic ray acceleration mechanism. A relation between involved turbulent volumina and structure functions is obtained. The conclusions drawn hold only within the realm of applicability of thermodynamics to cosmic ray spectra.     

Production,processing and characterization techniques for cosmic dust analogues

Abstract— The laboratory analyses of cosmic dust analogues—that in the context of this paper include interstellar, circumstellar as well as cometary dust—have a critical role in the study of circumstellar and cometary dust. The morphological, structural and chemical characterization of these analogues are critical for comparisons of their infrared and ultraviolet spectra with those obtained by astronomical observations, as well as for modeling purposes. Besides, the results from these laboratory studies are important to the success of space missions to comets when testing and calibrating the payload instruments. The interpretations of returned scientific data would benefit from the comparison with data recorded by the instruments in a laboratory setting for different classes of previously characterized analogues. We produced various types of condensed samples: (1) Mg,Fe‐silicates, (olivine, pyroxene), (2) carbon‐rich dust, and (3) mixed carbon‐silicate dust. The samples were prepared using different techniques, viz. (1) laser bombardment of solid targets in an Ar and O₂ atmosphere, (2) arc discharge in an Ar and H₂ atmosphere, and (3) grinding powders of natural minerals. We simulated various post‐condensation processes, such as thermal annealing, ultraviolet irradiation, ion bombardment and exposure to atomic hydrogen. These processes produced compound samples of a wide range of physico‐chemical properties. To identify their textures, morphologies, grain compositions and crystallographic properties we used electron microscopy and far‐ultraviolet to far‐infrared (millimeter range) spectroscopy.     

On the Analysis of the Complex Forbush Decreases of January 2005

In this work an analysis of a series of complex cosmic ray events that occurred between 17 January 2005 and 23 January 2005 using solar, interplanetary and ground based cosmic ray data is being performed. The investigated period was characterized both by significant galactic cosmic ray (GCR) and solar cosmic ray (SCR) variations with highlighted cases such as the noticeable series of Forbush effects (FEs) from 17 January 2005 to 20 January 2005, the Forbush decrease (FD) on 21 January 2005 and the ground level enhancement (GLE) of the cosmic ray counter measurements on 20 January 2005. The analysis is focusing on the aforementioned FE cases, with special attention drawn on the 21 January 2005, FD event, which demonstrated several exceptional features testifying its uniqueness. Data from the ACE spacecraft, together with GOES X-ray recordings and LASCO CME coronagraph images were used in conjunction to the ground based recordings of the Worldwide Neutron Monitor Network, the interplanetary data of OMNI database and the geomagnetic activity manifestations denoted by K _p and D _st indices. More than that, cosmic ray characteristics as density, anisotropy and density gradients were also calculated. The results illustrate the state of the interplanetary space that cosmic rays crossed and their corresponding modulation with respect to the multiple extreme solar events of this period. In addition, the western location of the 21 January 2005 solar source indicates a new cosmic ray feature, which connects the position of the solar source to the cosmic ray anisotropy variations. In the future, this feature could serve as an indicator of the solar source and can prove to be a valuable asset, especially when satellite data are unavailable.     

双漏模式中的弥散宇宙γ射线

弥散宇宙γ射线产生于初级宇宙线的传播过程,本文利用宇宙线传播的“双漏模式”得出与实验观测谱接近的银河系弥散宇宙γ射线谱。     

Mineralogical constraints on the high-silica martian surface component observed by TES

The Thermal Emission Spectrometer (TES) has observed a high-silica material in the dark regions of Mars that is spectrally similar to obsidian glass and may have a volcanic origin. An alternate interpretation is that the spectrally amorphous material consists of clay minerals or some other secondary material, formed by chemical alteration of surface rocks. The regions where this material is observed (e.g., Acidalia Planitia) have relatively high spectral contrast, suggesting that the high-silica material exists as coarse particulates, indurated soils or cements, within rocks, or as indurated coatings on rock surfaces. The geologic interpretation of this spectral result has major implications for understanding magmatic evolution and weathering processes on Mars. One of the complications in interpreting spectral observations of glasses and clay minerals is that both are structurally and compositionally complex. In this study, we perform a detailed spectroscopic analysis of indurated smectite clay minerals and relate their thermal emission spectral features to structural and crystal chemical properties. We examine the spectral similarities and differences between smectite clay minerals and obsidian glass from a structural-chemical perspective, and make further mineralogical interpretations from previous TES results. The results suggest that neither smectite clays nor any clay mineral with similar structural and chemical properties can adequately explain TES observations of high-silica materials in some martian dark regions. If the spectrally amorphous materials observed by TES do represent an alteration product, then these materials are likely to be poorly crystalline aluminosilicates. While all clay minerals have Si/O ratios ?0.4, the position of the emissivity minimum at Mars suggests a Si/O ratio of 0.4-0.5. The spectral observation could be explained by the existence of a silica-rich alteration product, such as Al- or Fe-bearing opal, an intimate physical mixture of relatively pure silica and other aluminosilicates (such as clay minerals or clay precursors), or certain zeolites. The chemical alteration of basaltic rocks on Mars to phyllosilicate-poor, silica-rich alteration products provides a geologically reasonable and consistent explanation for the global TES surface mineralogical results.     

On possible 'cosmic ray cocoons' of relativistic jets

We consider effects on an (ultra)relativistic jet and its ambient medium caused by high-energy cosmic rays accelerated at the jet side boundary. As illustrated by simple models, during the acceleration process a flat cosmic ray distribution can be created, with gyro-radii for the highest particle energies reaching scales comparable to the jet radius or energy density comparable to the pressure of the ambient medium . In the case of efficient radiative losses, a high-energy bump in the spectrum can dominate the cosmic ray pressure. In extreme cases, the cosmic rays are able to push the ambient medium off, providing a 'cosmic ray cocoon' separating the jet from the surrounding medium. The considered cosmic rays provide an additional jet braking force and lead to a number of consequences for the jet structure and its radiative output. In particular, the dynamic and acceleration time-scales involved are in the range observed in variable active galactic nuclei.     

Chemical models for the contracting W3 IRS4

We have studied the chemical evolution in the central core of a contracting cloud representing W3 IRS4. We modified the equation of temperature to satisfy the physical conditions of W3 IRS4. The chemical rate equations and the hydrodynamics are integrated simultaneously. The contraction is followed from a very low density of n = 10 cm⁻³ to high core density of n = 10⁶ cm⁻³. The chemical evolution is studied for various chemical conditions, including both the effects of varying cosmic ray ionization rate and the effect of ion–dipole molecule collisions.

The main results by using the more extensive chemical network with the most updating reaction rates show that the calculated fractional abundances are in agreement with observation at intermediate and enhanced cosmic ray ionization rate at high depletion of elemental atoms.     

Comparison of the LEW88516 and ALHA77005 martian meteorites: Similar but distinct

Abstract By mineral and bulk compositions, the Lewis Cliff (LEW) 88516 meteorite is quite similar to the ALHA77005 martian meteorite. These two meteorites are not paired because their mineral compositions are distinct, they were found 500 km apart in ice fields with different sources for meteorites, and their terrestrial residence ages are different. Minerals in LEW88516 include: olivine, pyroxenes (low- and high-Ca), and maskelynite (after plagioclase); and the minor minerals chromite, whitlockite, ilmenite, and pyrrhotite. Mineral grains in LEW88516 range up to a few mm. Texturally, the meteorite is complex, with regions of olivine and chromite poikilitically enclosed in pyroxene, regions of interstitial basaltic texture, and glass-rich (shock) veinlets. Olivine compositions range from Fo₆₄ to Fo₇₀, (avg. Fo₆₇), more ferroan and with more variation than in ALHA77005 (Fo₆₉ to Fo₇₃). Pyroxene compositions fall between En₇₇Wo₄ and En₆₅Wo₁₅ and in clusters near En₆₃Wo₉ and En₅₃Wo₃₃, on average more magnesian and with more variation than in ALHA77005. Shock features in LEW88516 range from weak deformation through complete melting. Bulk chemical analyses by modal recombination of electron microprobe analyses, instrumental neutron activation, and radiochemical neutron activation confirm that LEW88516 is more closely related to ALHA77005 than to other known martian meteorites. Key element abundance ratios are typical of martian meteorites, as is its non-chondritic rare earth pattern. Differences between the chemical compositions of LEW88516 and ALHA77005 are consistent with slight differences in the proportions of their constituent minerals and not from fundamental petrogenetic differences. Noble gas abundances in LEW88516, like those in ALHA77005, show modest excesses of ⁴⁰Ar and ¹²⁹Xe from trapped (shock-implanted) gas. As with other ALHA77005 and the shergottite martian meteorites (except EETA79001), noble gas isotope abundances in LEW88516 are consistent with exposure to cosmic rays for 2.5–3 Ma. The absence of substantial effects of shielding from cosmic rays suggest LEW88516 spent this time as an object no larger than a few cm in diameter.     

Identification of minerals and meteoritic materials via Raman techniques after capture in hypervelocity impacts on aerogel

Abstract— Mineral particles analogous to components of cosmic dust were tested to determine if their Raman signatures can be recognized after hypervelocity capture in aerogel. The mineral particles were accelerated onto the silica aerogel by light‐gas‐gun shots. It was found that all the individual minerals captured in aerogel could be identified using Raman (or fluorescence) spectra. The laser beam spot size was ?5 micrometers, and in some cases the captured particles were of a similar small size. In some samples fired into aerogel, a broadening and a shift in the wave numbers of some of the Raman bands was observed, a result of the trapped particles being at elevated temperatures due to laser heating. Temperatures of samples were also estimated from the relative intensities of Stokes and anti‐Stokes Raman bands, or, in the case of corundum particles, from the wave number of fluorescence bands excited by the laser. The temperature varied greatly, dependent upon laser power and the nature of the particle. Most of the mineral particles examined had temperatures below 200 °C at a laser power of about 3 mW at the sample. This temperature is sufficiently low enough not to damage most materials expected to be found captured in aerogel in space. In the worst case, some particles were shown to have temperatures of 500–700 °C. In addition, selected meteorite samples were examined to obtain Raman signatures of their constituent minerals and were then shot into aerogel. It was possible to find Raman signatures after capture in aerogel and obtain a Raman map of a whole grain in situ in the aerogel. It is concluded that Raman analysis is indeed well suited for an in situ analysis of micrometer‐sized materials captured in aerogel.     

Interior textures,chemical compositions,and noble gas signatures of Antarctic cosmic spherules: Possible sources of spherules with long exposure ages

Abstract– The interior texture and chemical and noble gas composition of 99 cosmic spherules collected from the meteorite ice field around the Yamato Mountains in Antarctica were investigated. Their textures were used to classify the spherules into six different types reflecting the degree of heating: 13 were cryptocrystalline, 40 were barred olivine, 3 were porphyritic A, 24 were porphyritic B, 9 were porphyritic C, and 10 were partially melted spherules. While a correlation exists between the type of spherule and its noble gas content, there is no significant correlation between its chemical composition and noble gas content. Fifteen of the spherules still had detectable amounts of extraterrestrial He, and the majority of them had ³He/⁴He ratios that were close to that of solar wind (SW). The Ne isotopic composition of 28 of the spherules clustered between implantation‐fractionated SW and air. Extraterrestrial Ar, confirmed to be present because it had a ⁴⁰Ar/³⁶Ar ratio lower than that of terrestrial atmosphere, was found in 35 of the spherules. An enigmatic spherule, labeled M240410, had an extremely high concentration of cosmogenic nuclides. Assuming 4π exposure to galactic and solar cosmic rays as a micrometeoroid and no exposure on the parent body, the cosmic‐ray exposure (CRE) age of 393 Myr could be computed using cosmogenic ²¹Ne. Under these model assumptions, the inferred age suggests that the particle might have been an Edgeworth‐Kuiper Belt object. Alternatively, if exposure near the surface of its parent body was dominant, the CRE age of 382 Myr can be estimated from the cosmogenic ³⁸Ar using the production rate of the 2π exposure geometry, and implies that the particle may have originated in the mature regolith of an asteroid.     

Is there a news function for an infinite cosmic string?

A special form of the Bondi news function can be associated with an infinite static cosmic string. In case of a radiaing isolated system pierced by an infinite cosmic string, the total news function will be composed of two parts — one characterizing the radiation field, the other the string. Some examples are discussed and related to a recently given solution, which was interpreted as an outgoing gravitational wave due to the splitting of an infinite cosmic string.     

Some string cosmological models in Bianchi Type I space-time

We obtain some cosmological models that are exact solutions of Einstein's field equations. The metric utilized is Marder's metric which is Bianchi Type I and the curvature source is a cloud of strings which are one dimensional objects. Bianchi type cosmological models play an important role in the study of the universe on a scale which anisotropy is not ignored. In this paper we have investigated the effect of cosmic strings on the cosmic microwave background anisotropy. Various physical and geometrical properties of the model are also discussed. The solutions have reported that the cosmic microwave background anisotropy may due to the cosmic strings.     

A MC approach to simulate up- and down-going neutrino showers including local topographic conditions

The extragalactic flux of protons is predicted to be suppressed above the famous Greisen–Zatsepin–Kuzmin cut-off at about E_GZK  50 EeV due to the resonant photo-pion production with the cosmic microwave background. Current cosmic ray data do not give a conclusive confirmation of the GZK cut-off and the quest about the origin and the chemical composition of the highest energy cosmic rays is still open. Amongst other particles neutrinos are expected to add to the composition of the cosmic radiation at highest energies. We present an approach to simulate neutrino induced air showers by a full Monte Carlo simulation chain. Starting with neutrinos at the top of the atmosphere, the performed simulations take into account the details of the neutrino propagation inside the Earth and atmosphere as well as inside the surrounding mountains. The products of the interactions are input for air shower simulations. The mountains are modelled by means of a digital elevation map. To exemplify the potential and features of the developed tools we study the possibility to detect neutrino induced extensive air showers with the fluorescence detector set-up of the Pierre Auger Observatory. Both, down-going neutrinos and up-going neutrinos are simulated and their rates are determined. To evaluate the sensitivity, as a function of the incoming direction, the aperture, the acceptance and the total observable event rates are calculated for the Waxman–Bahcall (WB) bound.     

Weakly ionized cosmic gas: ionization and characterization

Since collective plasma behavior may determine important transport processes (e.g., plasma diffusion across a magnetic field) in certain cosmic environments, it is important to delineate the parameter space in which weakly ionized cosmic gases may be characterized as plasmas. In this short note, we do so. First, we use values for the ionization fraction given in the literature, wherein the ionization is generally assumed to be due primarily to ionization by cosmic rays. We also discuss an additional mechanism for ionization in such environments, namely, the photoelectric emission of electrons from cosmic dust grains in an interstellar FUV radiation field. Simple estimates suggest that under certain conditions this mechanism may dominate cosmic ray ionization, and possibly also the photoionization of metal atoms by the interstellar FUV field, and thereby lead to an enhanced ionization level.