Biogeochemical characteristics of the lower Mississippi River, USA, during June 2003

During June 2003, a period of mid level discharge (17,400 m⁻³ s⁻¹), a parcel of water in the lower Mississippi River was sampled every 2 h during its 4-d transit from river km 362 near Baton Rouge to km 0 at Head of Passes, Louisiana, United States. Properties measured at the surface during each of the 48 stations were temperature, salinity, dissolved organic carbon (DOC), total dissolved nitrogen, dissolved macronutrients (NO₃+NO₂, PO₄, Si(OH)₄), chlorophylla (chla; three size fractions: < 5 μm, 5–20 μm, and > 20 μm) pigment composition by HPLC, total suspended matter (TSM), particulate organic carbon (POC), and particulate nitrogen (PN). Air-water CO₂ flux was calculated from surface water dissolved inorganic carbon and pH. During the 4 d transit, large particles appeared to be settling out of the surface water. Concentrations of chla containing particles > 20 μm declined 37%, TSM declined 43%, POC declined 42% and PN declined 57%. Concentrations of the smaller chla containing particles did not change suggesting only large particulate materials were settling. There was no measurable loss of dissolved NO₃, PO₄, or Si(OH)₄, consistent with the observation that chla did not increase during the 4-d transit. DOC declined slightly (3%). These data indicate there was little autotrophic or heterotrophic activity in the lower Mississippi River at this time, but the system was slightly net heterotrophic.     

Stratigraphic evidence for millennial-scale temporal clustering of earthquakes on a continental-interior fault: Holocene Mississippi River floodplain deposits, New Madrid seismic zone, USA

The earthquake cycles that characterize continental-interior areas that are far from active plate boundaries have proven highly cryptic and difficult to resolve. We used a novel paleoseismic proxy to address this issue. Namely, we reconstructed Holocene Mississippi River channels from maps of floodplain strata in order to identify channel perturbations reflective of major displacement events on the high-hazard and mid-plate Reelfoot thrust fault, New Madrid seismic zone, U.S.A. Only three discrete slip events are currently documented for the Reelfoot fault ( AD 900,  AD 1450, and AD 1812). This study extends this record and, thus, illustrates the utility of stratigraphic proxies as paleoseismic tools. We concurrently offer here some of the first quantified response times for tectonically induced channel pattern changes in large alluvial rivers.

We identified at least two cycles of pervasive meandering that were interrupted by channel-straightening responses occurring upstream of the Reelfoot fault scarp. These straightening responses initiated at 2244 BC +/− 269 to 1620 BC +/− 220 and  AD 900, respectively, and each records initiation of a period of Reelfoot fault slip after millennia of relative tectonic quiescence. The second (or New Madrid) straightening response was triggered by the previously known  AD 900 fault slip event, and this initial low sinuosity has been protracted until the modern day by the latter  AD 1450 and AD 1812 events. The first (or Bondurant) straightening response began a period of several hundred to  1400 years of low river sinuosity which evidences a similar period of multiple recurrent displacement events on the Reelfoot fault. These Bondurant events predate the existing paleoseismic record for the Reelfoot fault.

These data offer initial evidence that slip events on the Reelfoot fault were temporally clustered on millennial scales and, thus, offers the first direct evidence for millennial-scale clustering of earthquakes on a continental-interior fault. This carries additional ramifications. Namely, faults that have been quiescent and non-hazardous for millennia could re-enter an enduring period of recurrent hazardous earthquakes with little warning. Likewise, the Reelfoot fault also reveals evidence of temporal clustering of earthquakes on short-term cycles (months), as well as evidence for longer-term reactivation cycles (10⁴–10⁶ years). This introduces the possibility that temporal clustering could be hierarchical on some continental-interior faults.     

The response of the Lower Mississippi River to river engineering

An examination of the response of the Lower Mississippi River (LMR) to a variety of engineering activities is presented through the discussion of: (a) a brief history of engineering investigations and activities on the LMR; (b) the impact of artificial cutoffs on the channel geometry and water surface profiles of adjacent reaches; (c) the impact of channel alignment activities on channel morphology; and (d) the apparent impact of all of the LMR engineering activities on sediment dynamics in the channel.

Investigations by many agencies reflect over 150 years of study of the hydraulics and hydrology of the LMR, which have contributed significantly to our understanding of large alluvial rivers. In an effort to provide for flood control and navigation on the largest river in North America, private landowners and the US Army Corps of Engineers have performed a wide range of river engineering activities, including construction of levees, floodways, artificial cutoffs, bank revetment, training dikes, dredging, channel alignment, and reservoirs on the major tributaries. This unprecedented program of river engineering activities on the river during the last 100 years has resulted in the evolution of a freely meandering alluvial river to a highly trained and confined meandering channel. The LMR has increased its overall gradient and average top-bank width and generally increased its channel depth. The immediate response of the river to increased gradient as a result of the construction of artificial cutoffs was dampened in some locations by local geological controls.

Examination of the trends in sediment dynamics of the LMR reveals that the suspended load of the river has decreased during the 20th century. Conversely, a trend in the bed load transport in the channel for the years 1930 and 1989 cannot be determined with confidence because of the difficulty in acquiring representative samples. The highly trained river now responds to channel forming flows by attempting to build mid-channel bars rather than natural cutoffs of meanders.

The LMR should maintain a relatively stable plan form in the intermediate future, barring a very large and unprecedented flood. The river will continue to adjust its channel geometry and its local gradients as a response to variations in significant discharges. Continued channel maintenance and occasional dredging will insure the present state of sediment and water transport efficiency.     

Effects of rainfall,geomorphological and geometrical variables on vulnerability of the lower Mississippi River levee system to slump slides

This study investigated the importance of rainfall and various geomorphological and geometrical factors to the vulnerability of earthen levees to slump slides. The study was performed using a database including 34 slump slides that occurred in the lower Mississippi River levee system from 2008 to 2009. The impact of rainfall within the six months prior to slide occurrence was studied for 23 slides for which an accurate occurrence date was available. Several variables were used to develop a logistic regression model to predict the probability of slump slide occurrence. The proposed model was verified for both slide and non-slide cases. The regression analysis depicts the impact of channel width, river sinuosity index, riverbank erosion, channel shape condition and distance to river. Excluding the sinuosity index, the impact of the other independent variables examined was found to be significant. Occurrence of riverbank erosion around the slide locations was the most significant predictor factor. A channel width of less than 1000?m was ranked as the second most significant variable. The proposed model can aid in locating high-risk areas on levees in order to take prompt protective measures, increase monitoring efforts and enable early response under emergency conditions.     

Sources of elevated salinity in the Mississippi River Alluvial Aquifer, south-central Louisiana, USA

Salinization is a process impacting groundwater quality and availability across much of southern Louisiana, USA. However, a broad divergence of opinion exists regarding the causes of this elevated salinity: updip-migrating marine waters from the Gulf of Mexico, saline fluids migrating up fault planes, movement of water from salt domes, and/or remnant seawater from the last major marine transgression. The Mississippi River Alluvial Aquifer (MRAA) in south-central Louisiana is recharged by the Mississippi River, and there are discharge zones to the west and east. Recharge waters from the Mississippi River are fresh, but Cl⁻ levels in the western portions of the aquifer are as high as 1000 mg/L. The aquifer is an important source of water for several municipalities and industries, but prior to this study the source(s) of the elevated salinity or whether the salinization can be remediated had not been determined.The low Br/Cl ratios in the groundwaters are consistent with a saline endmember produced by subsurface dissolution of salt domes, not a marine source. The H and O isotopic systematics of the aquifer waters indicate meteoric sources for the H₂O, not marine waters or diagenetically-altered deep brines. The westward salinization of aquifer water represents a broad regional process, instead of contamination by point sources. Mapping of spatial variations in salinity has permitted the identification of specific salt domes whose subsurface dissolution is producing waters of elevated salinity in the aquifer. These include the Bayou Choctaw and St. Gabriel domes, and possibly the Bayou Blue dome. Salinization is a natural, on-going process, and the potential for remediation or control is slight, if not non-existent.     

Sediment-water interactions in the metal-contaminated floodplain of the Clark Fork River,Montana, USA

The distribution and concentration of metals and metalloids in the floodplain of the Clark Fork River of western Montana, USA, are mainly controlled by post-depositional diagenetic mechanisms of metal fractionation. Due to the influx of wastes into the river's headwaters from mining processes around the turn of the century, extensive amounts of contaminated material were deposited onto the floodplain. Tailings were deposited as widespread overbank deposits and point bars adjacent to abandoned channels, and are characterized by orange and gray mottled sediment, which is devoid of vegetation and covered by a blue metal sulfate precipitate during dry periods. Examination of stratigraphic profiles of floodplain sediment indicates three periods of deposition: 1) pre-mining, represented by coarse sand and organic overbank deposits under reducing conditions; 2) syn-mining, characterized by transition sediments and tailings deposits under oxidizing conditions; and, 3) post-mining, distinguished by grass-bound topsoil.Sites were established where sediments and water throughout the stratigraphic section were collected and analyzed. Chemical analyses indicate enriched concentrations of cadmium, copper, manganese, and zinc in sediments and porewater, and arsenic in groundwater, in areas contaminated by tailings deposits. Vertical trends in concentrations of metals show that they are distributed based on apportionment of metal phases between reducing-oxidizing environments and pH fluctuations.     

Surface complexation modeling for predicting solid phase arsenic concentrations in the sediments of the Mississippi River Valley alluvial aquifer, Arkansas, USA

The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6 m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6 m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory.     

Arsenic in groundwater of the Red River floodplain, Vietnam: Controlling geochemical processes and reactive transport modeling

The mobilization of arsenic (As) to the groundwater was studied in a shallow Holocene aquifer on the Red River flood plain near Hanoi, Vietnam. The groundwater chemistry was investigated in a transect of 100 piezometers. Results show an anoxic aquifer featuring organic carbon decomposition with redox zonation dominated by the reduction of Fe-oxides and methanogenesis. Enhanced P_CO2 pressure causes carbonate dissolution to take place but mainly in the soil and unsaturated zone. The concentration of As increases over depth to a concentration of up to 550 μg/L. Most As is present as As(III) but some As(V) is always found. Arsenic correlates well with NH₄, relating its release to organic matter decomposition and the source of As appears to be the Fe-oxides being reduced. Part of the produced Fe(II) is apparently reprecipitated as siderite containing less As. Results from sediment extraction indicate most As to be related to the Fe-oxide fractions. The measured amount of sorbed As is low. In agreement, speciation calculations for a Fe-oxide surface suggest As(III) to constitute only 3% of the surface sites while the remainder is occupied by carbonate and silica species. The evolution in water chemistry over depth is homogeneous and a reactive transport model was constructed to quantify the geochemical processes along the vertical groundwater flow component. A redox zonation model was constructed using the partial equilibrium approach with organic carbon degradation in the sediment as the only rate controlling parameter. Apart from the upper meter a constant degradation rate of 0.15 C mmol/L/yr could explain the redox zonation throughout the aquifer. Modeling also indicates that the Fe-oxide being reduced is of a stable type like goethite or hematite. Arsenic is contained in the Fe-oxides and is first released during their dissolution. Our model further suggests that part of the released As is adsorbed on the surface of the remaining Fe-oxides and in this way may be retarded.     

Hydrogeochemistry of two river main floodplain lakes,Hessia, FR Germany

Two lakes, Lake Gänseweiher (LGW) and Lake Fechenheimer Weiher (LFW) occupy groundwater filled abandoned gravel pits which serve as fishing grounds and are part of recreational areas, respectively.Both lakes are cut into a near-surface groundwater aquifer, which is located in the pleistocene River Main gravel terrace t₆. They are sealed at the base by miocene clays and above by overlying flood deposits of the River Main. The latter provide protection from pollutants derived from wet and dry deposition of atmospheric contaminants.Groundwater chemistry determines the pool of dissolved constituents in lake water. The temporal and spatial distribution patterns of chemical compounds in lake water are brought about by endo-biogenic processes, of which the indicators are nitrate-nitrogen and dissolved silica. The latter illustrates an instantaneous response to pulses of diatom blooms.Both lakes are eutrophic (polytrophic) according to the classification guidelines presented in literature.     

Geochemical and isotopic evidence for upward flow of saline fluid to the Mississippi River Valley alluvial aquifer,southeastern Arkansas,USA

Hydrogeology Journal - Groundwater from the Quaternary Mississippi River Valley Alluvial (MRVA) aquifer in southeastern Arkansas (SE AR), USA, has higher salinity compared to other MRVA...     

Measured river leakages using conventional streamflow techniques: the case of Souhegan River, New Hampshire, USA

Multiple streamflow measurements were made at coupled discharge measurement stations to quantify rates of aquifer recharge and discharge on two reaches of the Souhegan River, New Hampshire, USA, flowing within a glacial-drift river-valley aquifer. The reaches included a predominantly losing (aquifer recharge) reach and a variable (aquifer recharge and discharge) reach located downstream of the former reach. River leakage, the differential between coupled upstream and downstream streamflow measurements along a reach, varied by almost 30 cubic feet per second (ft³/s) (0.85 m³/s) along the two reaches. The upper reach averaged 3.94 ft³/s (0.11 m³/s) loss whereas the lower reach averaged 4.85 ft³/s (0.14 m³/s) gain. At the upper reach, 13 losses were measured out of 19 coupled measurements. At the lower reach, ten out of 13 coupled measurements indicated gains in flow and suggest that this reach is primarily a gaining river reach. An important factor in river leakage appears to be antecedent trends in river stage. At the upper reach, gains were measured only during periods of declining river stage. Conversely, at the lower reach, streamflow loss was measured primarily during periods of rising river stage. Although some tendencies exist, several factors complicate the analysis of river leakage, most notably the inaccuracies in computed stream discharge.     

Hydrochemical evidence for mixing of river water and groundwater during high-flow conditions, lower Suwannee River basin, Florida, USA

 Karstic aquifers are highly susceptible to rapid infiltration of river water, particularly during periods of high flow. Following a period of sustained rainfall in the Suwannee River basin, Florida, USA, the stage of the Suwannee River rose from 3.0 to 5.88 m above mean sea level in April 1996 and discharge peaked at 360 m³/s. During these high-flow conditions, water from the Suwannee River migrated directly into the karstic Upper Floridan aquifer, the main source of water supply for the area. Changes in the chemical composition of groundwater were quantified using naturally occurring geochemical tracers and mass-balance modeling techniques. Mixing of river water with groundwater was indicated by a decrease in the concentrations of calcium, silica, and ²²²Rn; and by an increase in dissolved organic carbon (DOC), tannic acid, and chloride, compared to low-flow conditions in water from a nearby monitoring well, Wingate Sink, and Little River Springs. The proportion (fraction) of river water in groundwater ranged from 0.13 to 0.65 at Wingate Sink and from 0.5 to 0.99 at well W-17258, based on binary mixing models using various tracers. The effectiveness of a natural tracer in quantifying mixing of river water and groundwater was related to differences in tracer concentration of the two end members and how conservatively the tracer reacted in the mixed water. Solutes with similar concentrations in the two end-member waters (Na, Mg, K, Cl, SO₄, SiO₂) were not as effective tracers for quantifying mixing of river water and groundwater as those with larger differences in end-member concentrations (Ca, tannic acid, DOC, ²²²Rn, HCO₃). Received, March 1999 / Revised, July 1999 / Accepted, July 1999     

Chemical and mineralogical composition of Amazon River floodplain sediments,Brazil

The total and exchangeable concentration of major elements and the mineralogical composition of sediments collected along the Amazon River floodplain (várzea) were determined. Average elemental composition (wt%) decreased in the order: Si>Al>Fe>Na>Ca>K>Mg>Ti. There was some spatial variability: the concentration of Al, Na and Mg decreased downstream; the concentration of Fe, K and Ti remained constant; the Si concentration increased toward the Amazon River mouth. Mineralogically, there was a downriver increase in the concentration of quartz and kaolinite, and a concurrent decrease in the concentration of Na- and Ca-plagioclases. On the other hand smectite-vermiculite clay minerals increased and the mica (illite) concentration remained constant. A mass balance indicated that, except for illite, downriver changes in the other minerals were not caused solely by mixing of Amazon River water with water from the major tributaries, which have a distinctly different composition. Therefore, the mass balance indicated that plagioclases and smectite-vermiculite had been lost in the várzea, while kaolinite was formed there.     

Correction: Geochemical and isotopic evidence for upward flow of saline fluid to the Mississippi River Valley alluvial aquifer,southeastern Arkansas,USA

Hydrogeology Journal - A Correction to this paper has been published: https://doi.org/10.1007/s10040-021-02350-y     

Hohokam Canal Irrigation and the Formation of Irragric Anthrosols in the Middle Gila River Valley,Arizona, USA

Irragric anthrosols form as a result of prolonged deposition of fine sediments from irrigation water. Ancient irragric soils centuries to millennia old occur in several world regions, especially in arid environments of Asia and the Americas. This article presents evidence for an ancient irragric anthrosol in the North American Southwest, along the Snaketown Canal System in the Middle Gila River Valley, Arizona. This pedostratigraphic unit was formed as a result of a millennium of irrigation by Hohokam farmers from A.D. 450 to 1450. The irragric soil consists of a mantle of silty‐to‐loamy textures with minimal soil formation overlying a natural argillic horizon on a Pleistocene stream terrace. A soil mapped independently by the United States Department of Agriculture‐Natural Resources Conservation Service with these horizons corresponds closely with the canal system. Soil within the canal system tends to be lower in salt, sodium, and pH compared with external soils. This suggests that the irragric process improved soil for crop production through long‐term leaching and additions of fresh sediments with the irrigation water. This anthropogenic process of canal sedimentation has had a long‐lasting impact on the sedimentary record and soils in this arid environment.     

Interpreting temporal variations in river response functions: an example from the Arkansas River,Kansas, USA

Groundwater/surface-water interactions can play an important role in management of water quality and quantity, but the temporal and spatial variability of these interactions makes them difficult to incorporate into conceptual models. There are simple methods for identifying the presence of groundwater/surface-water interactions; however, identifying flow mechanisms and pathways can be challenging. More complex methods are available to better identify these mechanisms and pathways but are often too time consuming or costly. In this work, a simple method for interpreting and identifying flow mechanisms and sources using temporal variations of river response functions is presented. This approach is demonstrated using observations from two sites along the Arkansas River in Kansas, USA. A change in flow mechanisms between the rising and falling limbs of river hydrographs was identified, along with a second surface-water source to the aquifer, a finding that was validated with stable isotope analyses.     

The fate and transport of nitrate in shallow groundwater in northwestern Mississippi, USA

Agricultural contamination of groundwater in northwestern Mississippi, USA, has not been studied extensively, and subsurface fluxes of agricultural chemicals have been presumed minimal. To determine the factors controlling transport of nitrate-N into the Mississippi River Valley alluvial aquifer, a study was conducted from 2006 to 2008 to estimate fluxes of water and solutes for a site in the Bogue Phalia basin (1,250 km²). Water-quality data were collected from a shallow water-table well, a vertical profile of temporary sampling points, and a nearby irrigation well. Nitrate was detected within 4.4 m of the water table but was absent in deeper waters with evidence of reducing conditions and denitrification. Recharge estimates from 6.2 to 10.9 cm/year were quantified using water-table fluctuations, a Cl^– tracer method, and atmospheric age-tracers. A mathematical advection-reaction model predicted similar recharge to the aquifer, and also predicted that 15% of applied nitrogen is leached into the saturated zone. With current denitrification and application rates, the nitrate-N front is expected to remain in shallow groundwater, less than 6–9 m deep. Increasing application rates resulting from intensifying agricultural demands may advance the nitrate-N front to 16–23 m, within the zone of groundwater pumping.     

Localized zones of denitrification in a floodplain aquifer in southern Wisconsin, USA

A floodplain aquifer within an agricultural watershed near Madison, Wisconsin (USA), was studied to determine whether denitrification was occurring below the surface organic layer. Groundwater levels and concentrations of O₂, Cl^?, NO ₃ ^? , SO ₄ ^2? , dissolved organic carbon (DOC), and major cations were monitored over a 1-year period along a 230-m transect between an agricultural field and a stream discharge point. Seventeen groundwater samples were analyzed for δ¹⁵N_NO3 and δ¹⁸O_NO3 composition. Samples in which NO ₃ ^? was too low for stable isotope analysis were analyzed for excess dissolved N₂. Groundwater NO ₃ ^? concentrations declined between the agricultural field and the discharge point. Chloride and δ¹⁵N_NO3/δ¹⁸O_NO3 data indicated that the drop in NO ₃ ^? was caused primarily by dilution of shallow NO ₃ ^? -rich water with deeper, NO ₃ ^? -depleted groundwater. Two localized zones of denitrification were identified in the upland-wetland transition by their δ¹⁵N_NO3 and δ¹⁸O_NO3 signatures, and two in the stream hyporheic zone by the presence of excess dissolved N₂. The combined stratigraphic, hydrologic, and geochemical data in these locations correspond to groundwater mixing zones where NO ₃ ^? is delivered to subsurface layers that support denitrification fueled by dissolved (e.g. DOC or dissolved Fe(II)) and/or solid-phase (e.g. particulate organic carbon, solid-associated Fe(II), or pyrite) electron donors.