Extended-range luminescence chronologies for the Middle Pleistocene units at the Sima del Elefante archaeological site (Sierra de Atapuerca,Burgos, Spain)

The Sima del Elefante site is located within the Sierra de Atapuerca karst system (Burgos, northern Spain), and forms part of a series of important Early, Middle and Late Pleistocene archaeological complexes that have been dated previously with luminescence techniques (Gran Dolina, Galería Complex, Sima de los Huesos, Galería de las Estatuas). This study focuses on the upper Middle Pleistocene units (TE18 and TE19) at Sima del Elefante, which contain Acheulean and transitional lithic assemblages (Mode 2/3), as well as large and small mammal fossils. Importantly, these uppermost units are associated with a sediment plug located in the cave's interior at Galería Baja, which marks the closure of a significant palaeoentrance to the Atapuerca karst system. Establishing the accumulation history of these related deposits is important for understanding both Lower Palaeolithic technological dynamics via comparisons with similar levels at other Atapuerca sites (i.e., Gran Dolina and Galería Complex), as well as past human occupation patterns and carnivore use of (and accessibility to) the caves. We present single-grain TT-OSL and multi-grain pIR-IR chronologies for the Sima del Elefante upper sequence and the Galería Baja sediment cone, as well as U-series dating results for a stalagmitic crust capping the combined clastic infill sequence. The paired luminescence ages for the upper occupation levels are in agreement with each other and reveal that the host deposits accumulated 576–481 ka for the TE18 stratified scree layers, 266–237 ka for TE19 and 206–250 ka for the Galería Baja upper cone section (weighted mean 2σ age ranges). A concordant U-series age of 202 ± 65 ka is obtained for the overlying stalagmitic crust at Galería Baja. The Sima del Elefante ages are consistent with those previously obtained using U-series and biochronology, confirming that there is an erosional unconformity and complex carbonate deposition phase associated with the upper layers of unit TE18 and that the original cave entrance likely closed by ∼200 ka. Chronological correlation with other Atapuerca sites reveals potential equivalence between TE18 and unit TD8 (at Gran Dolina), and between TE19 and units GIIb–GIIIb (at Galería Complex) and, possibly, TD10.1 and TD10.2 (at Gran Dolina), though more refined dating is required to confirm the latter.     

New radiometric dates on the lowest stratigraphical section (TD1 to TD6) of Gran Dolina site (Atapuerca,Spain)

Ages based on independent methods, such as combined ESR-U series, luminescence, and magnetostratigraphic analyses have been obtained for the upper stratigraphical section of Gran Dolina site (TD6 to TD11 levels). However, the chronostratigraphical framework of this European Paleolithic key site remains incomplete because of its great antiquity and the lack of reliable methods. This paper provides new radiometric dates by electron spin resonance applied to optically bleached quartz grains for the whole stratigraphic sequence. The results agree with the previous chronostratigraphical framework for the upper part of the stratigraphical sequence. The ages for the Homo antecessor remains from TD6 layer range between 800 and 900 ka. The lowest layers attributed to endogenous sediments (TD1) could be contemporaneous with the Sima del Elefante TE9 human bearing layer dated to 1.2 Ma. The results suggest a human occupation of possibly more than 1 Ma at the Gran Dolina site. This study confirms moreover the potential of ESR dating method applied on quartz in karstic environment.     

Insights into TT-OSL signal stability from single-grain analyses of known-age deposits at Atapuerca,Spain

Single-grain thermally transferred optically stimulated luminescence (TT-OSL) dating has recently been applied to a number of the Atapuerca palaeoanthropological sites. As yet, however, there have not been any direct assessments of TT-OSL signal stabilities for specific grains used for dating. In this study, we undertake a series of TT-OSL suitability assessments on known-age samples from Gran Dolina and Sima del Elefante. Our results suggest that the Atapuerca samples contain populations or sub-populations of grains with suitably stable TT-OSL signals for dating over late-Early and Middle Pleistocene timescales. Equivalent dose (D_e) distribution analysis in combination with pulse-annealing assessments provides a useful means of identifying inter-grain and inter-sample differences in TT-OSL signal stabilities. We also show that obtaining D_e values using different preheat conditions may help to identify potentially problematic TT-OSL behaviours. Analyses of multi-grain aliquot TL curves for these samples reveal that 'bulk' TL signal loss experiments may provide limited insights into TT-OSL source trap lifetimes due to averaging effects, the dominance of grain populations that do not produce TT-OSL, and interference from slowly bleaching OSL components. Our results improve the robustness and precision of existing TT-OSL chronologies for units TD6-3 and TE16-TE17 at Gran Dolina and Sima del Elefante, and support the broader suitability of the single-grain TT-OSL approach at the Atapuerca sites.     

ESR chronology of alluvial deposits in the Arlanzón valley (Atapuerca,Spain): Contemporaneity with Atapuerca Gran Dolina site

The Sierra de Atapuerca (Northern Spain) is characterized by a well-developed karst system where several major archaeological sites have been discovered, attesting an almost continuous hominin occupation of the area during the whole Pleistocene period. Previous geomorphological studies showed a connection between genesis of the karst system and the evolution of the nearby Arlanzón river Valley. However, numerical dating results were missing to refine the chronostratigraphical framework of the Arlanzón valley's fluvial incision. To address this, we applied the Electron Spin Resonance (ESR) dating method to sedimentary optically bleached quartz grains from several fluvial terraces. Nine samples were collected from five of the 14 identified terraces. The ESR age results are stratigraphically coherent and in general agreement with both previous geomorphological observations and available palaeomagnetic data. Consequently, an ESR chronology of the geological evolution of the Arlanzón valley is proposed, which can be then correlated to the sedimentary sequence of the palaeoanthropological site of Atapuerca Gran Dolina. Our results provide important information about the chronology of hominid occupation in this area during Early and Middle Pleistocene.     

Luminescence and ESR dating of the sedimentary infill from the multi-level cave system of Alkerdi-Zelaieta (Navarre,N Spain)

The finding of Upper Paleolithic engravings in 2016 triggered a multidisciplinary investigation of the Alkerdi cave system (Urdazubi, N Spain). The study of the speleogenetic processes led to the identification of at least 6 paragenetic cave levels with associated sedimentary infill. In order to unravel the timing of changes in the karst dynamics and to get some insights about sediment origin, two sediment samples were collected from cave levels 4 and 1 for numerical dating purpose, using both Optically Stimulated Luminescence (OSL) and Electron Spin Resonance (ESR) methods. One additional modern-age sample was also taken from the entrance of the karst to evaluate the magnitude of the optical bleaching achieved by the quartz grains before entering the cave system. Last, one sample was collected from a flowstone for U-series dating, providing independent age control.OSL measurements were carried out using small quartz multi-grain (MG) and single-grain (SG) Single Aliquot Regenerative-dose (SAR) protocol. Initial Equivalent Dose (D_e) results show evidence of saturated OSL signal for the sample of the higher level (with ∼60% of saturated aliquots). Unlike SA data, SG analyses do not meet the usual quality criteria (e.g., relatively high recuperation ratios, only a few grains with useable signal), suggesting that corresponding dating results should be treated with caution.Hence, both MG and SG TT-OSL and MG ESR methods were subsequently employed, as the corresponding signals are known to have higher saturation levels than OSL ones. ESR analyses were based on the Multiple Centre (MC) approach using the standard multi-grain multi-aliquot additive (MAA) dose method, while TT-OSL measurements were performed following Demuro et al. (2020). The latter, however, did not return any useful results for both samples. MC ESR data show the usual D_e pattern (D_e(Al)>D_e(Ti op. D)>D_e(Ti–H)) indicating that among the three ESR signals analyzed, the Ti–H most likely provides the closest estimate to the true burial age. However, low measurement repeatability and goodness-of-of fit indicate that the reliability of the ESR results may be reasonably questioned.Results derived from this multi-technique dating approach provide the first chronological constraints for the sedimentary infill of the Alkerdi cave system. In particular, they suggest that sediment deposition in Cave Level 4 (ALK-OSL01) occurred around 130 ka, which is in good agreement with the minimum age constraint given by the speleothem (80.5 ± 9.0 ka). In comparison, the young age obtained for sample ALK-OSL02 (5.0 ± 0.9 ka) suggests recent Holocene formation of the lowest cave level 1.Finally, the MG De value obtained for the modern sample is close to zero (<1 Gy), indicating that the OSL signal is almost fully reset at a multi-grain level before entering the cave. Additionally, despite the large De overdispersion measured in this modern sample, the De values are one to two order of magnitude lower than those obtained with the same model in the other two samples. Therefore, the large OSL D_e overdispersion (OD) values of up to 64% obtained for the two samples from Cave Level 4 and 1 are most likely related to re-sedimentation processes inside the cave system.     

Dating results on sedimentary quartz,bones and teeth from the Middle Pleistocene archaeological site of Coudoulous I (Lot,SW France): A comparative study between TT-OSL and ESR/U-series methods

This study presents palaeodosimetric results from the Middle Pleistocene archaeological site of Coudoulous I (Lot, SW France). Nine sedimentary quartz samples (41–60 μm) have been analyzed using a multiple aliquot protocol based on the measurement of the TT-OSL signal. In addition, 7 teeth and 7 bones have been dated by combining the ESR method with U-series analyses. Both methods gave consistent age results allowing correlation of the Early Middle Paleolithic Human occupation of the site to MIS 6 and part of the Lower Paleolithic tools to MIS 7. Beyond the establishment of a radiometric chronology for the Coudoulous I sequence, this study focuses on the information extracted from the intercomparison of the methods. Our data suggest that 1) the TT-OSL signal is stable over at least the last 230 ka (considering the age range of the studied samples), 2) there are not significant problems of incomplete bleaching leading support to the applicability of the TT-OSL technique for sedimentary deposits associated with karstic contexts. This approach highlights the interest of combining luminescence and ESR/U-series methods to discuss the reliability of the dating results.     

ESR chronology of the fluvial sequence of Cueva del Silo (Sierra de Atapuerca,Spain)

The Cueva del Silo is part of the lower karst level of the Cueva Mayor-Cueva del Silo karst system (Sierra de Atapuerca, Burgos, Spain), whose evolution has preserved an impressive archeo-paleoanthropological sequence since the Early Pleistocene. Cueva del Silo is remarkable for the presence of fluvial deposits that record the entry of the Arlanzón River water in the cave system, providing a key sequence to investigate the fluvio-karstic relationships that give rise to this endokarst system. In order to provide a chronological framework to these fluvial deposits, six sediment samples were dated by Electron Spin Resonance and 16 samples by paleomagnetism, collected from two outcrops: Galería de las Arenas and Sala del Caos. Our results provide maximum mean age of around 1600 ka and a minimum age of 916 ± 136 ka for the deposits in Sala del Caos. The younger date from Sala del Caos might represent the last fluvial input from Arlanzón River in the lower karst level. In contrast, ESR ages estimates of 1268 ± 133 ka and 1262 ± 108 ka were obtained for Galería de las Arenas sequence, which could indicate re-sedimentation processes from the intermediate karst level where similar ages were published. The annual dose might be wrongly assessed due to the re-sedimentation processes inside the karst, hence, ESR ages for these facies should be treated with extreme caution.     

ESR/U-series chronology of the Neanderthal occupation layers at Galería de las Estatuas (Sierra de Atapuerca,Spain)

The Galería de las Estatuas is a Mousterian site located within the Cueva Mayor-Cueva del Silo karstic system at the Sierra de Atapuerca (Burgos, Spain). This site is characterised by an important Upper Pleistocene stratigraphic sequence in which a large number of lithic artefacts exhibiting clear Mousterian affinities and a rich assemblage of faunal remains have been found.Additionally, this site has yielded a foot phalanx of a clear Neanderthal affinities and its sediment has yielded Neanderthal mitochondrial and nuclear DNA.Two test pits, GE-I and GE-II, have been excavated since 2008 which have been divided in 5 and 2 lithostratigraphical units, respectively. A minimum age of 45 ka cal BP for this site was obtained by radiocarbon dating in GE-II. This chronology was refined using single-grain Optically Stimulated Luminescence (OSL: 80–112 ka in GE-I and 70–79 ka in GE-II) and single-grain thermally transferred OSL (TT-OSL). Although in all case TT-OSL ages were systematically older than their single-grain counterparts. The detrital sequence is sealed by a flowstone whose base is dated to 53.7 ± 3.5 ka cal BP using U-series dating.In order to better constrain the age of this site, nine herbivorous teeth were collected from the whole sedimentary sequence to be dated by the ESR/U-series dating method though only seven provided modelled ages. Six of them were collected from levels 2 to 5 of the GE-I test pit while the last tooth was taken from level 2 of the GE-II test pit. Our results, ranging between 80 and 110 ka, are in agreement with those obtained by single grain TT-OSL and suggest that the sedimentological levels containing Mousterian lithic artefacts and faunal and human remains began to be deposited during the second part of the MIS5. These results fill a temporal gap in the chronology of the Atapuerca sites for which no contemporary MIS5 date was obtained until recently.     

Examining sediment infill dynamics at Naracoorte cave megafauna sites using multiple luminescence dating signals

Relatively little is known about the long-term sediment accumulation dynamics of Naracoorte Cave Complex (NCC) solution pipe cavities, and many of the megafauna-bearing infill deposits at this globally significant Australian Pleistocene fossil locality remain partially dated or lack any numerical age control. In this study, we assess the suitability of three different luminescence dating signals for improving existing chronologies at six Late and Middle Pleistocene NCC sites (n = 22 samples), and we undertake multi-site examinations of NCC sediment infill dynamics spanning the last 550 thousand years (ka). Modern analogue samples collected from above and beneath two active cave entrances confirm that single-grain OSL, single-grain TT-OSL and multi-grain pIR-IRSL signals can be reset down to insignificant residual levels (<10⁻¹–10⁰ Gy) when compared with the natural dose ranges of interest for most NCC palaeontological applications. Replicate luminescence dating comparisons performed at six NCC fossil sites (n = 15 samples) reveal consistent ages for twenty-eight out of thirty-one paired OSL–TT-OSL, OSL–pIR-IRSL and TT-OSL–pIR-IRSL datasets. Nineteen of the twenty Middle to Late Pleistocene samples analysed from the NCC sites produce homogeneous OSL, TT-OSL and pIR-IRSL D_e datasets suggesting that the NCC solution pipe deposits considered here are generally not affected by syn-depositional mixing complications that can take place within closed karst cavities (i.e., the remobilisation of unbleached grains from pre-existing cave floor sediments, and their subsequent translocation and incorporation into deposits within deeper parts of the cavity along with externally bleached, allochthonous grain populations). Detailed examination of solution pipe dynamics at Smoke Tortoise Cave (SMT) reveals a complex accumulation history focused on the marine isotope stage (MIS) 9 and MIS 7 interglacial complexes, as well as the MIS 8e interstadial. The SMT case study highlights that NCC solution pipes are not simply associated with short-lived opening and sediment accumulation events, but may involve multiple, discontinuous deposition episodes and reactivation events. An initial multi-site examination of all published NCC infill chronologies (n = 70) appears to suggest statistically significant, preferential solution pipe development during the relatively wet parts of interglacial or interstadial cycles. The non-uniform infill age distribution implies that NCC solution pipe dynamics may have exerted taphonomic biases on fossil accumulation, which should be taken into consideration when reconstructing long-term palaeoecological histories from NCC solution pipe cavities.     

Age of the oldest hominin settlements in Spain: Contribution of the combined U-series/ESR dating method applied to fossil teeth

This paper presents a synthesis of the combined Uranium-Series/ESR age results obtained on fossil teeth from several Early Pleistocene archaeological and/or palaeontological Spanish localities: Atapuerca Gran Dolina TD-6, Fuente Nueva-3, Barranco León, Venta Micena and Vallparadís. While the age results show some scattering, they are nevertheless encouraging and provide a significant contribution to the understanding of the first hominin settlements in Western Europe.These “old” samples are mainly characterised by high ²³⁰Th/²³⁴U activity ratios that may sometimes exceed secular equilibrium, and by high Uranium concentrations (several tens of ppm or more). The modelling of U-uptake is therefore really crucial for the age calculation process. In the case of the combined US–ESR approach, this uptake is derived from the U-series data measured in dental tissues, which seem to be strongly dependant on the hydro-geological context. Consequently, when dating “old” samples, a special attention has to be paid to the accuracy and the meaning of the U-series data collected from the dental tissues, which may be influenced by several factors such as spatial heterogeneity and recent U-uptake overprint. Some rapid scanning procedures should be developed in order to pre-identify the samples that are the most suitable for ESR dating.     

Electron spin resonance dating of quartz from archaeological sites at Victoria Falls,Zambia

When electron spin resonance (ESR) is applied to sedimentary quartz, dealing with the poor bleachability of the signals is particularly challenging. In this study, we used both the single-grain optically stimulated luminescence (OSL) and the single aliquot ESR dating of quartz from deep sand deposits preserving a Stone Age archaeological sequence to combine the advantages of the two methods: good bleaching behaviour and extended age range. Using the youngest samples at each sampling site we were able to calculate the mean ESR residual age from the difference between the OSL ages and the apparent ESR ages. Focusing mainly on the single aliquot regenerative dose (SAR) protocol here, we were able to calculate the mean ESR residual age for the Ti and Al centres, including the non-bleachable signal component for the latter. For the NP site, residual ages of 209 ± 13 ka and 695 ± 23 ka were calculated for the two centres, whereas for the ZS site 268 ± 39 ka and 742 ± 118 ka were determined. These residual ages are significant and cannot be neglected. Thus, the residual age was subtracted from the apparent ESR ages. The validity of the residual subtraction method was tested through a comparison of the oldest OSL age from each site with the residual subtracted ESR age. For both NP and ZS sites, the residual subtracted Ti and Al ages were consistent with the OSL age within 2-σ uncertainty, and therefore confirm the robustness of the subtraction method. Within the NP sequence, we were able to locate the end of the Early Stone Age at 590 ± 86 ka, and this provides a maximum age for the transition to the Middle Stone Age in this part of south-central Africa.     

ESR and OSL dating of fossil-bearing deposits from Naracoorte Cave Complex palaeontological sites,south Australia

Little work has been undertaken on combined dating of sedimentary quartz grains using electron spin resonance (ESR) and optically stimulated luminescence (OSL) techniques in Australia. This study aims to assess the suitability of a combined ESR and OSL dating approach for establishing improved chronologies of Middle-Late Pleistocene deposits within the Naracoorte Cave Complex (NCC), South Australia. Here, we apply ESR and OSL dating in tandem to a series of samples collected from three different NCC sites: Whale Bone, Specimen and Alexandra cave. ESR quartz dating focuses on the multi-centre (MC) approach, which involves comparative evaluations of Al and Ti centre signals, while paired luminescence dating focuses on single-grain OSL analysis and includes examination of multi-grain averaging effects. The comparative ESR-OSL dating results exhibit broad agreement for deposits spanning 50–150 thousand years, with either the Ti–H or Al centre ages overlapping with paired OSL ages at 2σ in nearly all cases. MC ESR evaluations (Al v Ti–Li v Ti–H age assessments) indicate incomplete resetting of the bleachable Al centre signal for a small number of samples. Two-thirds of samples exhibit Ti–Li ages that are significantly older than corresponding Al centre ages, which is unexpected from a bleaching kinetics perspective and may indicate a broader reliability issue for Ti–Li palaeodose evaluation with these particular samples. Our findings: (i) support the applicability of both palaeodosimetric dating methods in this depositional setting; (ii) highlight the merits of applying combined ESR-OSL analyses in tandem, and; (iii) provide one of the first reliable evaluations of quartz ESR MC dating for samples with natural dose ranges as low as only a few tens of Gy. These results show that the Whale Bone, Specimen and Alexandra cave sites are temporally related and can be used to derive multi-site reconstructions of faunal assemblages and palaeoenvironmental history.     

Magnetostratigraphy of Plio–Pleistocene fossiliferous cave sediments in the Bubing Basin,southern China

Our understanding of the chronological sequence of Pleistocene land mammal faunas (including hominids) preserved in caves and fissures in the karstic terrain of subtropical southern China has been greatly impeded by the discontinuous nature of the strata yielding the fossils. A contributory issue is the lack of suitable elements for numerical dating, especially for the Early Pleistocene cave sediments. Here we present new magnetostratigraphic dating results for five cave sedimentary sequences in the Bubing Basin, Guangxi Zhuang Autonomous Region, which contain the typical Pleistocene Gigantopithecus fauna and Ailuropoda–Stegodon fauna of southern China. The five karstic caves are situated at elevations ranging from 252 m to 191 m above sea level. The integrated dating results reveal that the five cave sedimentary sequences span an age range from the late Gauss normal Chron to the early Brunhes normal Chron. The faunas are assigned to >2.6 Ma (Mohui–houshan Cave), 1.95–1.78 Ma (Mohui Cave), 0.99–0.78 Ma (Baolai Cave) and ∼0.7 Ma (Upper Wuyun and Ganxian Caves). Furthermore, by combining our new magnetostratigraphy work with previously published magnetostratigraphic, U–series and electron spin resonance dating results, a chronological sequence of the Plio–Pleistocene mammalian faunas from cave sites in southern China has been established. The chronological sequence contributes to an improved understanding of the evolutionary processes of Plio–Pleistocene land mammals, as well as of early humans in subtropical southern China.     

黄河小浪底水库区断层的ESR年龄测定

为了检验应用ESR方法测定断层运动年龄的可行性,在黄河小浪底水库区内的5个断层剖面上采集了13个样品进行ESR年龄测定。结果指出;研究区内的断层活动大致发生于距今0.154—0.183Ma及0.374—0.532Ma两个时期。并对一些有关问题作了讨论,指出这是一种很有希望的确定断层活动近似年龄的新方法,在地震地质及工程地质领域中具有良好的应用前景     

Development of the SAR TT-OSL procedure for dating Middle Pleistocene dune and shallow marine deposits along the southern Cape coast of South Africa

Optically stimulated luminescence (OSL) dating is now commonly used to estimate the depositional age of Quaternary landforms along the southern Cape coast of South Africa. Due to the early onset of dose saturation in the quartz-rich sediments from this region, determining the age of deposits much older than the last three glacio-eustatic sea-level high stands has been a challenge. In this study, we explored the feasibility of using the thermally-transferred OSL (TT-OSL) dating method to obtain ages for aeolian and shallow marine deposits at three different localities that hold promise to further illuminate the long and complex Late Quaternary sea-level history of this region. The bleachability and behaviour of both the recuperated OSL (ReOSL) and the basic-transferred OSL (BT-OSL) signals were investigated, and used as independent chronometers to infer (a) the degree of bleaching of the sediments and (b) the stability of the ReOSL signal for dating of older samples. We examined the sensitivity of both signals to varying preheat temperatures and further developed the single-aliquot regenerative-dose procedure for TT-OSL dating of our samples. To verify our procedures, and to understand some of the underlying mechanisms responsible for the problems we observed, modern analogues and known-age Marine Isotope Sub-stage (MIS) 5e samples from the same localities were also measured. The Middle Pleistocene deposits investigated in this study produced statistically consistent ReOSL and BT-OSL ages compatible with sea-level high stands during Marine Isotope Stage 11. This result is of considerable significance, as it may yield new insights into maximum sea-level heights during this period, which is widely considered an appropriate analogue for future environmental conditions.     

A comparison of TT-OSL and post-IR IRSL dating of coastal deposits on Cap Bon peninsula,north-eastern Tunisia

In this study thermally transferred (TT) OSL and post-IR elevated temperature IRSL (290 °C) (pIRIR₂₉₀) dating are applied to deposits covering coastal terraces on the Cap Bon peninsula, Tunisia. Both methods perform well under standard performance tests; dose recovery tests using a modern analogue show that doses relevant to our study can be recovered accurately. Residual signals in the modern analogue for both signals are very small (∼2 Gy). For the younger (<250 ka) deposits reasonable good agreement of the ages is observed between both methods, and in addition with standard quartz OSL dating. Systematic discrepancy in ages is found for the older sediments. The TT-OSL underestimate (compared to the pIRIR₂₉₀ ages) is most likely due to the short lifetime of the TT-OSL trap; we estimate a lifetime of ∼0.7 Ma at 19 °C (mean ambient air temperature of the study area). This is the first time this lifetime has been derived from geological data and it is within the range of previously published laboratory estimates. This result suggests that TT-OSL is not likely to provide a significant extension of the age range beyond that available from other methods. Our preferred pIRIR₂₉₀ ages suggest that the geological setting on Cap Bon is not as simple as previously suggested.     

Evaluating isothermal thermoluminescence and thermally transferred optically stimulated luminescence for dating of Pleistocene sediments in Amazonia

The paleogeography of Amazonia lowlands during the Pleistocene remains hampered by the lack of reliable absolute ages to constrain sediment deposition in the hundred thousand to few million years timescales. Optically stimulated luminescence (OSL) dating applied to quartz has provided important chronological control for late Quaternary sediments, but the method is limited to the last ∼150 ka. In order to extend the age range of luminescence dating, new signals from quartz have been investigated. This study tested the application of isothermal thermoluminescence (ITL) and thermally transferred optically stimulated luminescence (TT-OSL) signals of quartz for dating of fluvial terraces from eastern Amazonia. ITL and TT-OSL signals measured in a modern fluvial sediment sample have shown small residual doses (4 and 16 Gy), suggesting adequate bleached sediments for the target dose range (>150 Gy). This sample responded well to dose recovery test, which showed that the ITL and TT-OSL signals grow to higher doses compared to the doses estimated by the conventional OSL signal. The ITL signal saturated for doses significantly lower than doses reported in the literature. Most dating samples were beyond the ITL saturation doses and only TT-OSL signals were suitable to estimate equivalent doses. Burial ages ranging from 107 to 340 ka were estimated for the fluvial terraces in the lower Xingu River. The main ages uncertainties are related to dose rate changes through time. Despite the uncertainties, these ages should indicate a higher channel base level during the Middle Pleistocene followed by channel incision, possibly due to episodes of increased precipitation in the Xingu watershed.     

On the interest of using the multiple center approach in ESR dating of optically bleached quartz grains: Some examples from the Early Pleistocene terraces of the Alcanadre River (Ebro basin,Spain)

The present work reports the first numerical ages obtained for the two highest fluvial terraces (Qt1 and Qt2) of the Alcanadre River system (Northeastern Spain) representing the earliest remnants of Quaternary morphosedimentary fluvial activity in the Ebro basin. ESR dating method was applied to optically bleached quartz grains and both the Al and Ti centers were measured, in accordance with the Multiple Center approach. The results are overall in good agreement with the existing preliminary chronostratigraphic framework and our interpretation indicate that terraces Qt1 and Qt2 have an ESR age of 1276 ± 104 ka and 817 ± 68 ka, respectively. These data provide some chronological insights on the beginning of the fluvial sedimentary processes in a scenario of incision maintained over Quaternary in the Ebro Basin. These are among the first numerical ages obtained for such high terraces in the Iberian Peninsula.Our results demonstrate the interest of using the Multiple Center approach in ESR dating of quartz, since the two centers provide complementary information, i.e. an independent dose control. The overall apparent consistency between the ESR age estimates and the existing preliminary chronostratigraphic framework may be considered as an empirical evidence that the Ti–Li center may actually work for Early Pleistocene deposits, whereas the Ti–H center shows some clear limitations instead. Finally, these results demonstrate the interest of using ESR method to date Early Pleistocene fluvial terraces that are usually beyond the time range covered by the OSL dating method.     

Testing mathematical uranium migration models in combined ESR/U-series dating of fossil teeth from open-air sites

Several mathematical models have been suggested to describe uranium migration kinetics for ESR dating of fossil tooth. In the present study, different U-uptake models were used to calculate ages for fossil teeth from two open-air Paleolithic sites in Nihewan Basin – Donggutuo and Hougou and compared with independent age control of the sites. For Donggutuo site, the results show that the ages of three teeth calculated by EU and AU models were much younger than magnetostratigraphic age. At Hougou site, two teeth from the top of Nihewan lacustrine deposits give the consistent EU and AU ages within errors but younger than sediment OSL age. This study indicates that mathematical modeling could not always give convincing results for the open-air sites, which may experience dramatic hydrological variations and high erosion rates.     

The Dabie Orogen as the early Jurassic sedimentary provenance: Constraints from the detrital zircon SHRIMP U-Pb dating

The SHRIMP U-Pb ages of detrital zircon from the oldest Mesozoic strata, the Fanghushan Fomation, in the Hefei Basin range from 200 Ma to ca. 2500 Ma, which indicates that the Dabie Orogen as the early Jurassic sedimentary provenance was complex. The composition of the Dabie Orogen includes: the Triassic high pressure-ultrahigh pressure metamorphic rocks, of which the detrital zircon ages are from 234 Ma to 200 Ma; the rocks possibly related to the Qinling and Erlangping Groups representing the southern margin of the Sino-Korean craton in the Qinling and Dabie area, of which the detrital zircon has an age of 481-378 Ma; the Neo-proterozoic rocks originated from the Yangtze croton, of which the detrital zircon ages are 799-721 Ma old; and the rocks with the detrital zircon ages of ca. 2000 Ma and ca. 2500 Ma, which could be the old basement of the Yangtze craton.