Comparison of paired quartz OSL and feldspar post-IR IRSL dose distributions in poorly bleached fluvial sediments from South Africa

A comparative study using quartz optically stimulated luminescence (OSL) and feldspar post-infrared infrared stimulated luminescence (post-IR IRSL) was undertaken on Quaternary fluvial sediments from an unnamed tributary of the Moopetsi River in South Africa. The aim is to assess whether the post-IR IRSL signal can be used to date incompletely bleached sediments. Several post-IR IRSL signals using varying stimulation and preheat temperatures were investigated; of these the post-IR IRSL₂₂₅ signal was deemed most appropriate for dating because it bleached most rapidly. The feldspar post-IR IRSL₂₂₅ equivalent dose (D_e) values from this site are consistently larger than those from quartz OSL, probably due to differences in the bleaching characteristics of the two signals. Additionally, the post-IR IRSL₂₂₅ D_e values within a sample showed less variation in precision than the quartz D_e data, possibly due to greater averaging between grains in the feldspar small aliquots. The agreement between ages based on the OSL and post-IR IRSL₂₂₅ signals was better for younger samples (<20 ka) than for older ones (>50 ka); the cause of this variation is unclear.     

Optically stimulated luminescence dating of Ocean Drilling Program core 658B: Complications arising from authigenic uranium uptake and lateral sediment movement

Ocean Drilling Program Site 658 lies under the North African summer dust plume, and ought to be an ideal target for optically stimulated luminescence (OSL) dating, since the main clastic input is far-travelled Saharan dust. However, OSL ages for coarse silt-sized quartz (40–63 μm) are systematically lower than independent age estimates when dose rates are calculated using a model which assumes detrital ²³⁸U, ²³²Th and ⁴⁰K and excess ²³⁰Th and ²³¹Pa. Ages which are in good agreement with independent age control are obtained from the coarse silt samples when a correction for authigenic uranium uptake is incorporated into the dose rate model. Authigenic uranium uptake occurs under reducing conditions, which are common at the sediment–water interface, and some degree of authigenic uranium correction may be required for most marine sediments. Using this revised dose rate model, ages produced using fine silt-sized quartz (4–11 μm) are up to 100% older than both independent and coarse silt ages. In addition, the fine silt ages show a consistent pattern of age decrease with depth over 1.5 m of core. ²³⁰Th data from Site 658 indicate that this site receives 3 times more sediment laterally than vertically. It is concluded that the fine silt at Site 658 contains a substantial reworked component, making it unsuitable for dating. Conversely the coarse silt fraction, which settles through water at ∼40 times the rate of fine silt, appears to be derived from dust input over the site at the time of deposition. Since prominent nepheloid (cloudy) layers occur in various deep ocean basins, and the material suspended in these layers often consists of reworked fine silt-sized sediments, coarser material should be dated where possible.     

Luminescence dating of Weichselian interstadial sediments from the German Baltic Sea coast

A cliff outcrop called Kluckow, in the Baltic Sea area, with a (glacio-) fluvial to (glacio-) lacustrine succession, provides a unique opportunity to resolve uncertainties in the timing and extent of several poorly constrained Weichselian ice advances. Based on a detailed lithofacies analysis, we selected four sampling horizons for luminescence dating to determine a depositional chronology. We measured both coarse-grain quartz and potassium-rich feldspar for age determination using optically stimulated luminescence (OSL) and post-IR infrared stimulated luminescence (pIRIR). Furthermore we addressed potential problems such as incomplete bleaching and quartz saturation effects. The resulting luminescence-chronology, supported by one radiocarbon age, illustrates a depositional time interval of the investigated sequence between ∼62 and ∼22 ka. Within this sequence a mussel-bearing fluvial sand indicate interstadial climate conditions at approximately 46 ka. The upper part of the section is composed of a 4 m thick glaciolacustrine silty clay and an overlying glaciofluvial sand; the latter yielded an OSL age of ∼22 ka. Shortly after these sequences formed, the subsequent ice advance (indicated by the overlying till sheet) reached the study area. Based on our new chronology and lithofacies analysis, we conclude that the Scandinavian Ice Sheet did not reach the study area between ∼62 and ∼22 ka.     

A revised burial dose estimation procedure for optical dating of youngand modern-age sediments

The presence of genuinely zero-age or near-zero-age grains in modern-age and very young samples poses a problem for many existing burial dose estimation procedures used in optical (optically stimulated luminescence, OSL) dating. This difficulty currently necessitates consideration of relatively simplistic and statistically inferior age models. In this study, we investigate the potential for using modified versions of the statistical age models of Galbraith et al. [Galbraith, R.F., Roberts, R.G., Laslett, G.M., Yoshida, H., Olley, J.M., 1999. Optical dating of single and multiple grains of quartz from Jinmium rock shelter, northern Australia: Part I, experimental design and statistical models. Archaeometry 41, 339–364.] to provide reliable equivalent dose (D_e) estimates for young and modern-age samples that display negative, zero or near-zero D_e estimates. For this purpose, we have revised the original versions of the central and minimum age models, which are based on log-transformed D_e values, so that they can be applied to un-logged D_e estimates and their associated absolute standard errors. The suitability of these ‘un-logged’ age models is tested using a series of known-age fluvial samples deposited within two arroyo systems from the American Southwest. The un-logged age models provide accurate burial doses and final OSL ages for roughly three-quarters of the total number of samples considered in this study. Sensitivity tests reveal that the un-logged versions of the central and minimum age models are capable of producing accurate burial dose estimates for modern-age and very young (<350 yr) fluvial samples that contain (i) more than 20% of well-bleached grains in their D_e distributions, or (ii) smaller sub-populations of well-bleached grains for which the D_e values are known with high precision. Our results indicate that the original (log-transformed) versions of the central and minimum age models are still preferable for most routine dating applications, since these age models are better suited to the statistical properties of typical single-grain and multi-grain single-aliquot D_e datasets. However, the unique error properties of modern-age samples, combined with the problems of calculating natural logarithms of negative or zero-Gy D_e values, mean that the un-logged versions of the central and minimum age models currently offer the most suitable means of deriving accurate burial dose estimates for very young and modern-age samples.     

Investigation of the applicability of standardised growth curves for OSL dating of quartz from Haua Fteah cave,Libya

The establishment of standardised growth curve (SGC) for equivalent dose (D_e) determination can substantially reduce the amount of instrument time required for OSL measurements. In this study, we investigated the applicability of SGC for the optically stimulated luminescence (OSL) signal from single grains and small aliquots of sedimentary quartz from Haua Fteah cave, in Libya. The samples exhibit large inter-grain and inter-aliquot variation in the shape of their single grain and small aliquot dose response curves (DRCs) constructed from a range of sensitivity-corrected regenerative dose signals (L_x/T_x), which prevents the establishment of a single common SGC among different grains or small aliquots. Instead, the DRCs for the small aliquots can be divided into a minimum of three groups using the Finite Mixture Model, with the DRC saturating at a different dose level for each group. In order to establish a common DRC, or SGC, for each group, we propose a new normalisation method, the so-called least-squares normalisation procedure (‘LS-normalisation’), which largely reduces the variation between aliquots within the same group and allows the establishment of a common DRC, or SGC, for each group. In order to apply the SGC method for these samples, two regenerative dose points are needed for each aliquot to attribute it to one of the groups based on the ratio of the L_x/T_x signals for two sensitivity-corrected regenerative dose points. Equivalent dose (D_e) values for each aliquot can be estimated using the fitting parameters calculated for the SGC of the relevant group to which it belongs, together with measurements of the natural signal (L_n), one regenerative dose signal (L_x1) and their corresponding test dose signals (T_n, T_x1). For the samples investigated from Haua Fteah, we found that D_e estimates obtained from the SGCs are consistent with those obtained using a full SAR procedure. Our results suggest that small single-aliquot and single-grain D_e values obtained from application of the SGC may be underestimated if there is a significant proportion of early-saturating grains present in the sample; such grains or aliquots are mostly rejected due to saturation when analysed using the full SAR procedure. In this case, it is necessary to calculate the D_e values based only on those grains or aliquots that have relatively high saturation levels.     

Luminescence dating of cobbles from Pleistocene fluvial terrace deposits of the Ara River,Japan

Constraining the ages of fluvial terraces is essential to understanding fluvial responses to climate and sea-level changes and estimating uplift/incision. Luminescence dating of sand or silt grains from fluvial terrace deposits in Japan is difficult because sand layers are often absent from gravelly deposits, quartz grains are typically dominated by medium/slow components and/or contaminated by feldspars, and short transport distances and short residence times in riverbeds result in poor bleaching of luminescence signals. Luminescence dating of cobbles may overcome these difficulties, but few studies have applied this technique to fluvial terrace deposits. Here, we examine the utility of luminescence dating applied to three granodiorite cobbles from a late Pleistocene fluvial terrace deposit of the Ara River, Japan. We investigated variations of the infrared stimulated luminescence (IRSL) and post-IR IRSL signals with depth in each cobble. The IRSL and post-IR IRSL signals generally increase with depth, indicating that the cobbles were not completely bleached before deposition. Nonetheless, the IRSL ages of the cobble surfaces (19–17 ka) are consistent with the age of a tephra layer (16–15 ka) at the base of loess deposits overlying the terrace. In contrast, IRSL ages of sand-sized feldspar grains overestimate the depositional age because of incomplete bleaching, whereas silt-sized quartz grains greatly underestimate the depositional age, likely because of the thermal instability of the medium component. Our results demonstrate that luminescence dating of cobbles could provide a better understanding of fluvial systems in which luminescence dating of sand grains is difficult.     

Luminescence dating of the late Quaternary sediments in Hangzhou Bay,China

Coastal plain of Hangzhou Bay, to the south of the present Yangtze Estuary, is closely linked to the evolution of the Yangtze River delta. However, absolute age of Pre-Holocene sediments is limited, which hinders the understanding of this area's environmental evolution. In this study, using optically stimulated luminescence (OSL), single aliquots and single grains of quartz and K-feldspar were used to date the late Quaternary sediments in coastal plain on the southern Hangzhou Bay. The vertical difference in particle size composition render either silt- or sand-sized quartz for dating. Cross-checking of multiple OSL dating methods indicated that the upper ∼65 m recorded the Holocene part of the succession; sediment from a depth of 136.6 m was dated to ∼180 ka. It was found that the single-grain method was more reliable in comparison to single-aliquot age, the former minimized the effect of signal components. Single-grain quartz and K-feldspar luminescence yielded consistent ages at sample depth of 136.6 m (∼160–180 ka), while the latter gave robust age at depth of 115.5 m (∼150 ka). This chronology is in general in accordance with neighbouring cores and can constrain paleomagnetic dating results in those cores. Taking together, the study site has thickest Holocene deposits in comparison to the highland centered around Taihu Lake on the southern Yangtze delta. Moreover, the luminescence characteristics of quartz from different sample depths, behaved differently with respect to luminescence sensitivity, signal components and saturation level, perhaps reflecting varied provenance and weathering characteristics caused by climate change.     

Luminescence dating of canal sediments from Angkor Borei, Mekong Delta, Southern Cambodia

Work to apply luminescence dating to archaeological sites in the Lower Mekong Delta has continued with a programme aimed at dating ancient canal sediments and brick monuments in the vicinity of ancient city of Angkor Borei. Following the successful application of OSL dating to the Paris 2 canal near Angkor Borei further fieldwork and analysis has been undertaken. The infill and substrate of the larger Paris 4 canal connecting Angkor Borei to Oc Eo, some 80 km to the south in Vietnam has been sampled and subjected to luminescence analysis. Field spectroscopy and underwater bleaching experiments were also conducted in the Baray and Angkor Borei in 2004. The results show that both illumination intensities and spectral distributions are severely altered by as little as 1.5 m of turbid water, and that OSL bleaching rates for both quartz and feldspars are reduced. Since quartz resetting is heavily dependant on the UV components in daylight, which have preferentially attenuated the effects of turbid water on OSL zeroing rates are especially marked. The new data from the Paris 4 canal, which has been dated by OSL to be between the first millenium BC and the late first millenium AD are significant to understanding the archaeological development of the Fu Nan state in the Lower Mekong Delta, and the sequence of development of the canal network linking inland agrarian sites and coastal trading centres.     

A Bayesian hierarchical age model for optical dating of single grains of quartz

In optical dating, the last time that a sample of sediment was exposed to sunlight is determined by dividing its equivalent dose (D_e) by the dose rate. For single-grain dating, the sample D_e is based on the statistical analysis of the distribution of D_e values estimated for individual grains, whereas the dose rate is usually determined from measurements of the environmental radioactivity of the bulk sample, together with allowances for radiation sources internal to the grains and cosmic rays. Conventionally, the D_e and dose rate are measured and analysed separately to produce an estimate of the depositional age of a sample, but this approach may result in loss of information because distributions of single-grain D_e values are influenced by several factors. Existing statistical models do not incorporate all the key information contributing to age estimation, such as the pattern and scale of dispersion of single-grain D_e values and dose rates, the associated measurement uncertainties, the effect of natural variability among grains, and the outlier probabilities of D_e and dose rate estimates. Here we propose an empirical Bayesian hierarchical age model (BHAM) for optical dating of quartz samples that incorporates the above information to estimate their depositional ages. The BHAM is based on the implementation of standardised growth curve and L_nT_n methods to integrate information on the full distribution of single-grain D_e values, sources of measurement uncertainty, beta-dose heterogeneity (observed or modelled), and detection of outliers. We present the results of validation tests using data sets of optically stimulated luminescence measurements and dose rates obtained for quartz samples dated previously from Denisova Cave (Russia) and for simulated samples. We conclude that the BHAM represents a robust and flexible approach to dealing with data for single grains of quartz within a Bayesian hierarchical framework and is suitable for application to sediments deposited in a variety of depositional settings.     

Reliability of equivalent-dose determination and age-models in the OSL dating of historical and modern palaeoflood sediments

The challenge of accurately estimating the deposition age of incompletely-bleached samples in luminescence dating has motivated developments in the analysis of single grain dose distributions, and a number of statistical approaches have been proposed over the last few years. In this study, we compare the behaviour of the arithmetic average, so-called ‘robust statistics’, the Central Age Model (CAM), the Minimum Age Model (MAM) and the Internal–External Consistency Criterion (IEU) and lowest 5% method, when applied to single-grain dose distributions from a sequence of eight recent (40–1000 years) flash-flood deposits. These sediments are expected to be incompletely bleached, but all have age control from historical records. Modifications were made to allow the use of the standard CAM and MAM models with dose distributions containing near zero and negative dose values. An assessment of minimum over-dispersion (OD) is based on dose recovery tests based on gamma-irradiated samples. We then present a detailed analysis of the effect of an additional uncertainty added to the individual dose estimates on the burial dose estimates from the MAM and the IEU approach. The results of the various models are discussed in terms of the accuracy of the resulting age, and we conclude that, overall, the IEU approach generates the most accurate ages. We also demonstrate that accurate doses can be obtained for those older samples for which uncertainties of ∼40 years are unimportant by applying the IEU model to small aliquot (∼30 grains) dose distributions. From our study we conclude that these and similar young slack-water flood deposits can be accurately dated using quartz OSL, opening up the possibility of establishing time series of flood discharge in catchments for which no instrumental or historical record exists.     

Bayesian analysis of individual and systematic multiplicative errors for estimating ages with stratigraphic constraints in optically stimulated luminescence dating

Many dating techniques include significant error terms which are not independent between samples to date. This is typically the case in Optically Stimulated Luminescence (OSL) dating where the conversion from characteristic equivalent doses to the corresponding ages using the annual dosimetry data includes error terms that are common to all produced datings. Dealing with these errors is essential to estimate ages from a set of datings whose chronological ordering is known. In this work, we propose and we study a Bayesian model to address this problem. For this purpose, we first consider a multivariate model with multiplicative Gaussian errors in a Bayesian framework. This model relates a set of characteristic equivalent doses to the corresponding ages while taking into account for the systematic and non-systematic errors associated to the dosimetry. It thus offers the opportunity to deal properly with stratigraphic constraints within OSL datings, but also with other datings possessing errors which are independent from systematic errors of OSL (e.g. radiocarbon). Then, we use this model to extend an existing Bayesian model for the assessment of characteristic equivalent doses from Single Aliquot and Regenerative (SAR) dose measurements. The overall Bayesian model leads to the joint estimation of all the variables (which include all the dose–response functions and characteristic equivalent doses) of a sequence of, possibly heterogeneous, datings. We also consider a more generic solution consisting in using directly the age model from a set of characteristic equivalent dose estimates and their associated standard errors. We finally give an example of application on a set of five OSL datings with stratigraphic constraints and observe a good adequacy between the two approaches.     

Investigating the amount of zeroing in modern sediments of River Danube, Austria

Sediments attributed to flooding events of River Danube concerning the bleaching of the optical stimulated luminescence (OSL) signal were investigated. It is demonstrated that the OSL signal in both quartz and feldspar is not completely but differentially bleached in the sediment grains. Partial bleaching of the samples is clearly indicated by the scatter of equivalent dose determined for several individual single aliquots. It is also shown that residual ages in feldspars are significantly higher than those calculated for quartz. It is furthermore demonstrated that analysing measurement-time dependent equivalent dose estimates is not a suitable method to identify partial bleaching in the investigated sediment grains. However, the transport and deposition process of the investigated samples was probably disturbed by an artificial input of sediment, and this case study may thus not be representative of undisturbed high flood events in the past.     

Testing the applicability of standardised growth curves (SGCs) for OSL signals of quartz grains from the Yangtze Delta,China

The standardised growth curve (SGC) technique has the potential to save instrument time for equivalent dose (D_e) determination when applying single-aliquot regenerative-dose (SAR) protocol during optically stimulated luminescence (OSL) measurements. In this study, we test the applicability of two commonly used SGC procedures for OSL signals of quartz grains from aqueous deposits of the Yangtze Delta in China, which have been reported for weak luminescence signals and suffering from partial bleaching. Multiple silt-sized and sand-sized fractions of quartz samples from eight cores are used to construct SGCs by test dose standardisation (TD-SGC) and least-squares normalisation (LS-SGC), respectively. Three strategies, i.e. region-specific (SGC_R), region with core-specific (SGC_R + C) and core-specific (SGC_C), are adopted to categorise these normalised data into different SGC datasets. The large variability of dose response signals is substantially reduced by the SGC procedures for most of these datasets. Hence, common SGCs for a variety of samples from the Yangtze Delta can be established, irrespective of their distinctive particle sizes and luminescence characteristics. The D_e values are then estimated using both TD-SGC and LS-SGC procedures for samples from a specific core. Comparing to the full SAR protocol, the TD-SGC procedure roughly gives reproducible D_e estimates lower than ∼100 Gy while the LS-SGC procedure derives generally consistent D_e estimates of up to ∼230 Gy. Although LS-SGC_C and LS-SGC_R + C procedures replicate the most consistent D_e values, the LS-SGC_R procedure performs better in efficiency with a slightly less accuracy. In addition to careful comparison of LS-SGC and full SAR procedures, we suggest that a synchronous ratio derived by the chosen regenerative dose and its response signal for re-normalisation can be used to predict the LS-SGC D_e reliability on samples from similar sedimentary environments.     

Problems associated with luminescence dating of Late Quaternary glacial sediments in the NW Scottish Highlands

Linking the timing of glacial episodes and behaviour to climatic shifts that are documented in ice and marine sedimentary archives is key to understanding ocean-land interactions. In the NW Scottish Highlands a large number of closely spaced (‘hummocky’) moraines formed at retreating glacier margins. Independent age control on one palaeo-glacier limit is consistent with the timing of Younger Dryas (YD) glaciation in the area, but adjacent glacier lobes have remained undated due to the lack of sites and material for ¹⁴C dating. Direct dating of ice-marginal moraines using optically stimulated luminescence (OSL) techniques has never been attempted before in Scotland, but if successful, they may be the most appropriate methods for constraining the age of sediment deposition in the absence of organic material. Coarse-grained quartz and K-feldspar minerals from supraglacial sheet flow deposits and glacilacustrine sediments within ice-marginal moraines were analysed using the single-aliquot regenerative-dose (SAR) protocol. Independent age control and clear geomorphological relationships indicate that all samples should yield YD or post-Last Glacial Maximum (LGM) ages. Quartz OSL shine down curves showed low luminescence sensitivity, significant medium-to-slow components, a weak fast component, and scattered SAR data; Linearly Modulated-OSL (LM-OSL) measurements confirmed that the fast component was weak or absent. In contrast, feldspar infrared stimulated luminescence (IRSL) was highly sensitive with excellent SAR data. However, SAR data from 3 mm diameter aliquots of feldspar (200 grains) give higher than expected equivalent doses (D_e) by an order of magnitude. SAR measurements of small clusters of feldspar grains (ranging from 1–8) considerably broaden the apparent D_e distribution, but even the lowest value is about 2–3 times the expected D_e. Two possibilities arise to explain the quartz and feldspar data: (1) that glacial sequences in the NW Highlands re-work inherited (older) glacial deposits and that some of the pre-Devensian existing glacial landforms have only been modified during Devensian glaciation; or (2) that the sedimentary processes operating in these ice-marginal environments are not conducive to adequate bleaching of quartz and feldspar grains. Our study implies that ice-proximal supraglacial sediments from this region in NW Scotland reflect older ages of deposition, but dating YD sediments has not been possible.     

Optical dating of a Paleolithic site near the eastern coastal region of Shandong,northern China

Many archaeological sites were excavated in China, but rarely in the adjacent coastal areas. An archaeological site at Huangniliang in the coastal area of Shandong Province, northern China was excavated in 2013. Abundant stone artifacts including hammers, cores, flakes, chunks, and retouched tools are found in the silty aeolian sediments. In this study, optically stimulated luminescence (OSL) technique was employed to establish the chronological framework of the site. Medium-grained (45–63 μm) quartz was extracted from six sediment samples for dating. The equivalent doses obtained with the single-aliquot regenerative-dose (SAR) protocol are shown to increase with depth. Three samples from the stone-tool containing layer yield OSL ages ranging from 54 ka to 59 ka, providing the earliest geochronological evidence for the presence of humans in the eastern coast of Shandong peninsula during the early period of Marine Isotope Stage (MIS) 3.     

毛乌素沙地东南缘全新世湖相地层石英和钾长石释光测年对比

采集来自毛乌素沙地东南缘巴图湾、大沟湾和三岔河等3处典型湖相地层出露点的3个样品,分别提取石英和钾长石矿物组分,采用小片技术(样品直径2 mm)进行释光年代测试,并将两种矿物年代结果进行对比研究.应用单片再生剂量(SAR)流程测试了石英样品的等效剂量(预热温度选为260℃).剂量恢复实验和光释光特性显示,SAR流程测试条件选择合适,样品沉积前光释光信号晒退完全,说明石英年代结果可靠.另外,应用两步红外激发(激发温度分别为50℃和150℃)的单片再生剂量流程(post-infrared infrared-stimulated luminescence,简写为p IRIR流程)测试钾长石样品的等效剂量,剂量恢复实验和释光特性等各项检验均符合要求,剩余剂量在-0.2~0.026 Gy之间,可忽略不计.钾长石的p IRIR150信号异常衰减速率为0.55~1.71(%/decade),因造成的误差较小,故无需对年代结果进行校正.3处湖相地层的石英年代分别为11.3±0.9、6.5±0.6、2.7±0.2 ka BP,钾长石p IRIR150年代分别为10.0±0.7、6.9±0.5、2.4±0.2 ka BP,两者在误差范围内一致,说明毛乌素沙地东南缘的全新世湖相沉积物适合用钾长石p IRIR150流程进行释光测年.本研究为毛乌素沙地部分样品因石英信号较弱而无法测年问题提供了解决办法,也为该区域全新世,尤其是历史时期(近2000年)以来的环境变化研究提供了年代学支撑.     

The potential of cryptotephra and OSL dating for refining the chronology of open-air archaeological windblown sand sites: A case study from Mirkowice 33, northwest Poland

The discovery of a cryptotephra (nonvisible volcanic horizon) in a windblown sand archaeological site in Poland highlights how luminescence and tephrostratigraphy may combine to better refine the chronology of such sites. In this study we identify a cryptotephra horizon which on the basis of major and minor element geochemistry and an OSL age of 2.3 ± 0.1 ka is correlated to the Glen Garry tephra. The different methodological strengths of OSL and tephrostratigraphy may be harnessed to counter the limitations of a single approach to produce a more secure chronology. Although in this study the tephra deposition event is shown to post-date the archaeological activity, the methodological approach is clearly demonstrated. Further investigations will reveal if cryptotephra layers are commonly preserved in such environmental settings. If this is so then future applications of this approach may prove to be more widely applicable.     

Investigating the potential of HCl-only treated samples using range-finder OSL dating

Rapid sample preparation and measurement protocols for optically stimulated luminescence (OSL) dating have been investigated as a method of increasing the throughput of samples (e.g. Roberts et al. 2009). Here, we investigate the potential of dating samples treated using only hydrochloric acid (HCl) for providing accurate range-finder ages for quartz. The equivalent dose (D_e) is underestimated for older samples using a standard single-aliquot regenerative-dose (SAR) protocol, but measurement of the post-IR OSL signal (e.g. Roberts and Wintle, 2003) provides D_e estimates within 15% of the ‘target fully prepared D_e’ for two-thirds of samples. The application of a standardised growth curve (SGC) is also investigated. For these dune samples, the most efficient preparation and measurement procedure from which accurate D_e estimates can be obtained is treatment with HCl-only, measurement of the natural and regenerative post-IR OSL signal, and calculation using a region-independent SGC. A slightly longer protocol incorporating an additional preparation stage of heavy liquid density separation can be used to improve D_e estimates in samples where feldspar-contamination is thought to be particularly problematic. In practice, these time savings of days to weeks in the preparation and measurement protocols mean that a large number of samples can first be rapidly treated with HCl, the post-IR blue OSL signal measured using a shortened double-SAR protocol, and D_e calculated by applying an independent SGC before then deciding which samples require full preparation and measurement, rather than the inefficiency of committing time and resources to all samples if this is unnecessary for the context of a particular suite of samples. The potential of this rapid preparation and measurement protocol is discussed in relation to sand dune dating studies.     

On the interest of using the multiple center approach in ESR dating of optically bleached quartz grains: Some examples from the Early Pleistocene terraces of the Alcanadre River (Ebro basin,Spain)

The present work reports the first numerical ages obtained for the two highest fluvial terraces (Qt1 and Qt2) of the Alcanadre River system (Northeastern Spain) representing the earliest remnants of Quaternary morphosedimentary fluvial activity in the Ebro basin. ESR dating method was applied to optically bleached quartz grains and both the Al and Ti centers were measured, in accordance with the Multiple Center approach. The results are overall in good agreement with the existing preliminary chronostratigraphic framework and our interpretation indicate that terraces Qt1 and Qt2 have an ESR age of 1276 ± 104 ka and 817 ± 68 ka, respectively. These data provide some chronological insights on the beginning of the fluvial sedimentary processes in a scenario of incision maintained over Quaternary in the Ebro Basin. These are among the first numerical ages obtained for such high terraces in the Iberian Peninsula.Our results demonstrate the interest of using the Multiple Center approach in ESR dating of quartz, since the two centers provide complementary information, i.e. an independent dose control. The overall apparent consistency between the ESR age estimates and the existing preliminary chronostratigraphic framework may be considered as an empirical evidence that the Ti–Li center may actually work for Early Pleistocene deposits, whereas the Ti–H center shows some clear limitations instead. Finally, these results demonstrate the interest of using ESR method to date Early Pleistocene fluvial terraces that are usually beyond the time range covered by the OSL dating method.     

Multiple phases of North African humidity recorded in lacustrine sediments from the Fazzan Basin, Libyan Sahara

The Fazzan Basin of south-west Libya is at present arid with less than 20 mm of rainfall per annum. However, regionally extensive limestones, lacustrine sands and coquina (fossiliferous carbonate rock) deposits show that the Fazzan Basin previously contained a large palaeolake, indicating that the climate in the past was more humid. Optically stimulated luminescence (OSL) dating techniques have been applied to key lacustrine deposits within the basin in an attempt to provide an internally consistent chronology for this humidity record. Results indicate that palaeolake sediments within the Fazzan Basin record a very long history of palaeohydrological change, ranging from present day arid conditions to humidity capable of sustaining a lake with an approximate area of 76,250 km². The existence of humid periods in mid oxygen isotope stage 5 and the early Holocene is confirmed. An older lacustrine event, tentatively correlated to oxygen isotope stage 11, is also recognized. In addition, evidence is presented for at least two humid phases beyond the age range over which the conventional OSL dating technique is applicable. This study demonstrates that OSL dating of palaeolake sediments within the Fazzan Basin offers the potential to provide a detailed record of North African humidity spanning several glacial–interglacial cycles.