从西藏扎仓茶卡Ⅱ湖提取Li2CO3的简化工艺

藏北高原恶劣的自然地理条件使扎仓茶－卡珍贵的锂资源的开发极为困难,必须采用尽可能简化的提取工艺才能降低成本,本文提出了一种经ＣａＯ,（ＮＨ４）２Ｃ２Ｏ４和Ｎａ２ＣＯ３三步沉积得到粗Ｌｉ２ＣＯ３的简化工艺,其产品纯度可达８５．６２％,总回收率约２０％,卤旦回收率约为７６％。     

从西藏扎仓茶卡Ⅱ湖提取Li_2CO_3的简化工艺

藏北高原恶劣的自然地理条件使扎仓茶卡珍贵的锂资源的开发极为困难,必须采用尽可能简化的提取工艺才能降低成本。本文提出一种经CaO、（NH_4）_2C_2O_4和Na_2CO_3三步沉淀得到粗Li_2CO_3的简化工艺,其产品纯度可达85.62％,总回收率约20％,卤旦回收率约为76％。     

喜马拉雅西构造结及邻区岩石圈演化三维有限元数值模拟

用数值模拟的方法探讨了自10 Ma以来喜马拉雅弧形造山带的西构造结及邻区岩石圈的形变和位移变化特征,并采用不同的流变参数和流变结构模拟了前2 Ma内的形变和应力场的演化过程,通过对不同黏性系数、本构关系和初始地壳厚度的改变在演化过程中所起的作用研究表明：（1）采用黏弹性模型时,西构造结区黏性参数的选取对西构造结及邻区隆升高度和隆升范围有重要影响,计算结果给出西构造结区地壳黏性系数应小于1023Pa·s;（2）相对刚性的塔里木盆地采用弹性结构时,对整个西构造结区域的应力和应变场均能引致明显变化;（3）力学性质稳定块体的存在并没有使应力场的传播出现明显的解耦现象.     

Spatiotemporal patterns of carbon sequestration in a large shallow lake,Chaohu Lake: Evidence from multiple-core records

Lake sediment can sequestrate large amounts of carbon and this issue has become a research hotspot. However, most of research on carbon burial in lakes is based on a single (or a few) sediment core records and so may underestimate the variability of carbon burial features within a single lake. In this study, therefore, Chaohu Lake, a typical large shallow lake in the middle and lower reaches of the Yangtze River, was selected to conduct multiple, high resolution sediment core studies to elucidate that variability. Overall 18 sediment cores are analyzed according to paleolimnological proxies (including ²¹⁰Pb/¹³⁷Cs for 3 master cores); sediment accumulation rate, total organic carbon, grain size and loss of ignition is measured or estimated for most cores. The spatiotemporal variations of organic carbon burial rate (OCBR), carbon storage and their driving factors were examined. Results show: 1) There was a clear temporal difference in carbon burial during the past 150 years, with OCBR varying from 1.1 g C/m²/y to 25.6 g C/m²/y (mean 9.8 g C/m²/y). OCBR began to increase after around 1900, a rapid increase followed after 1950s and a downward trend after 1970s. Total carbon burial amount (OCBA) in the lake since the 1850s is 1.11 x 10¹⁰ g. 2) The average OCBR of six sediment cores in the northwest lake area is 13.4 g C/m²/y, significantly higher than that for sediment cores in other areas (9.6 g C/m²/y). 3) TOC, OCBR, OCBA in all 18 cores exhibited similar temporal patterns (i.e. marked increase since 1950s in most of the cores) but with significant differences in several lake locations. 4) During the last 150 years, carbon burial in Chaohu Lake appears to be greatly affected by changes in regional temperature and population size, according to their significant correlations. OCBR also has a significant correlation with the average lake level in the past 50 years, indicating human activity (notably dam building). This has imposed an important impact on OCBR in Chaohu Lake. This multi-sediment core study reveals the spatiotemporal characteristics of carbon burial in the lake and provides an important basis for increasing the accuracy of calculating carbon storage in large shallow lakes.     

太湖的泥沙与演变

历史时期,太湖是不断扩展的,其平均扩展速率为0.37km~2/a。据沙量平衡分析与计算表明。因湖岸崩塌和太湖水系的输沙作用,近期太湖的泥沙淤积量为9.28×10~5t/a.泥沙数量虽然不大,但经过长期的积累,对太湖演变具有深刻影响。就自然演变趋势而言,近期太湖面积仍以0.168km~2/a的速率扩大,容积则以3.95×10~5m~3/a的速率减小,太湖正进一步向浅平方向演变。然而,因围湖造田,建国以来,太湖的面积则以4.58km~2/a的速率在减小。     

Macrozoobenthic community structure in a large shallow lake: Disentangling the effect of eutrophication and wind-wave disturbance

Biological communities in shallow lakes are often subject to the combined effects of eutrophication and wind-wave disturbance. However, their relative importance in regulating macrozoobenthic community assembly has not been well addressed. In the present study, a monthly sampling of macrozoobenthos and environmental parameters was conducted at ten sites from December 2012 to November 2013 in Lake Hongze, the fourth largest freshwater lake in China, which has undergone serious water quality deterioration over the past few decades. A total of 30 taxa were recorded during the 12 sampling occasions, including 6 chironomids, 6 bivalves, 4 gastropods, 4 oligochaetes, 4 polychaetes, 4 crustaceans and 2 other aquatic insects. The mean abundance and biomass of total macrozoobenthos varied greatly among the ten sites and presented distinctive taxonomic composition between the protected bays and the offshore zone. Three eutrophication parameters (including permanganate index (COD_Mn), chlorophyll a, and total phosphorus in surficial sediments) and three wind-wave variables (including Secchi depth, turbidity, and mean effective fetch) were highly related to spatial variation of macrozoobenthic assemblages. When eutrophication variables were controlled, there was a significant correlation between community similarity and wind-wave disturbance condition, and vice versa. Variation partitioning showed that wind wave disturbance explained 15.9% of the variation in benthic community composition, slightly lower than that explained by eutrophication (17.9%). These results indicate that wind-wave disturbance is as important as eutrophication in regulating benthic community structure in this large shallow lake. Wind-wave disturbance imposed opposite effects on benthic community relative to eutrophication, and were more prominent in the offshore zone weakening the role of eutrophication.     

浅水湖泊湖沼学与太湖富营养化控制研究

自2007年无锡暴发饮用水危机事件以来,太湖经历了前所未有的高强度、大规模治理,各种治理措施累计投资已经超过千亿元.监测显示,在治理初期太湖的氮、磷浓度下降明显,水质有所好转,但最近几年关键水质指标总磷与浮游植物叶绿素α浓度出现了波动,蓝藻水华有所反弹.研究表明,太湖的外源负荷并没有减少,这与城镇用水量增加、污水排放标准偏低、面源污染削减不足有很大的关系;同时,内源负荷也因为蓝藻水华的持续而加重,浅水湖泊水深浅、扰动强的特点强化了磷的循环利用效率,加剧了内源负荷对湖泊富营养化和蓝藻水华的影响.气候变暖叠加营养盐富集的复合效应、流域风速下降以及暴雨事件频次和强度增加等气象水文条件变化,都促进了太湖蓝藻水华的暴发;蓝藻水华的时空分布特征则受湖泊水动力的决定性影响.太湖治理的曲折过程,凸显了大型浅水湖泊湖沼学研究的不断深入与发展,未来需要继续加强多学科交叉研究,特别是基于湖泊-流域系统的气象水文、生物地球化学和生物生态学的学科交叉.对于太湖生态环境的综合治理和管理,既要注重湖泊与流域相结合,更需要重视自然科学和人文科学的有机融合,才能真正达到控制太湖富营养化、维护流域水环境安全与社会经济可持...     

浅水湖泊底栖-敞水生境耦合对富营养化的响应与稳态转换机理:对湖泊修复的启示

浅水湖泊中的初级生产者主要由分布在底栖生境中的底栖植物和生活在敞水生境中的浮游植物组成.底栖植物主要包括维管束沉水植物和底栖藻类等,浮游植物则主要为浮游藻类.贫营养浅水湖泊湖水营养盐浓度低,透明度高,底栖植物因能直接从沉积物中获取营养盐,往往是浅水湖泊的优势初级生产者.随着外源营养盐负荷的增加,湖水中的营养盐浓度不断升高,浮游植物受到的营养盐限制作用减小,加上其在光照方面的竞争优势,逐步发展成为湖泊的优势初级生产者,湖泊逐步从底栖植物为优势的清水态转变为浮游植物为主的浑水态,即稳态转换.在稳态转换过程中,浅水湖泊生态系统结构与功能发生了一系列变化,本文综述了浅水湖泊沉积物性质和生物(浮游植物、底栖植物、底栖动物和鱼类等)群落结构的变化,分析了这些变化对底栖植物、浮游植物之间竞争优势和底栖-敞水生境间磷交换的影响,探讨了富营养化驱动的底栖-敞水生境耦合过程变化和稳态转换机理.了解浅水湖泊底栖-敞水生境耦合过程与稳态转换机理对富营养化浅水湖泊修复有重要意义.富营养化浅水湖泊修复实际就是重建其清水态,在制定修复目标时应该关注评价清水态的指标,如透明度、浮游植物生物量、底栖植物的覆盖度或优势度...     

Environmental changes reflected by the lake sediments of the South Hongshan Lake, Northwest Tibet

The 1.07-m long lake core with 1 cm interval cutting, which was obtained by drilling in the South Hongshan Lake of Northwest Tibet, was dated by the 210Pb and 137Cs methods, and a 150-year consecutive lake sedimentary sequence (1840─1997) with 1.4 year resolution was obtained. Some environmental proxies, such as the total organic carbon (TOC), total nitrogen (TN), ratio of TOC to TN (TOC/TN), trace chemistry elements (TCE), CaCO3, grain size, richness of ostracoda etc. showed that they are of well coincidence. These results implied that the environmental background varied from the cold-wet period in the late 19th century, to the warm-wet period from the end of the 19th century to the 1920s and to the warm-dry period since the 1920s. There were sub-variations since the 1920s: the cold-dry/warm-wet fluctuation from 1922 to 1960, the intensively warm-dry period since 1960 with a short cold-wet period in the mid-1970s to the end of the 1980s. The humid period from the mid-1970s to the end of the 1970s and the dry period beginning from the early 1980s were well documented by climatic data of the nearby weather station records while the grain size was well correlated to the annual precipitation. Compared with the records from Guliya ice core in the same area, the TOC proxy in the lake core indicating warm/cold conditions well corresponded to the ( 18O records representing temperature variations in the ice core. However, the proxies with dry/wet significance in the lake core were different from the variations of snow accumulation reflected by the ice core. It can be concluded that the chosen environmental proxies have clear environmental significance and the lake sediments can reflect climatic and environmental changes at high-resolution.     

1973-2018年青海湖岸线动态变化

青海湖独特的地理位置使得其不仅对环湖周边区域气候起着天然调节器的作用,而且还拥有丰富的湖岸线资源,准确、及时地掌握青海湖岸线动态变化对保护沿湖生态环境有重要意义.因此本文基于1973-2018年Landsat MSS/TM/OLI遥感影像和1961-2017年实测水位资料,对青海湖岸线动态变化及对鸟类栖息地的影响进行研究,同时结合面积、水位及气象数据讨论了影响岸线变化的主要因素.研究表明：1）近45年来青海湖岸线发生变化最大的区域是东岸的沙岛,西岸的鸟岛、铁布卡湾及北岸沙柳河入口区域.尤其自2004年以来,鸟岛地区岸线后退距离最大（5.52 km）,鸟类栖息地扩张约97.94 km²,为鸟类提供了较好的栖息环境.（2）1973-2018年青海湖岸线长度以0.88 km/a的速率逐渐延长.1997年之前岸线长度呈较为平稳的上升趋势,1997-2004年呈波动下降趋势,2004年之后呈剧烈波动增加趋势,岸线曲折性也表现出相同的变化趋势.（3）总体上岸线长度和曲折性受水位和面积的影响并不显著,但在不同的水位情况下,二者对青海湖动态变化做出不同的响应.尤其当水位小于3193.3 m或面积小于4249.3 km²时,岸线曲折性会随着水位和面积变化呈现相同的变化趋势,而水位高于3193.3 m时,岸线曲折性一直在增加,且水位上升速率越大则曲折性年际变化越大.（4）1973-2004年间青海湖水位下降和土地沙漠化是造成湖岸线变化的直接成因,人类活动及草场退化加速了湖泊岸线的变迁.2004年之后,随着青海湖水位回升与面积扩张,岸线逐渐后退,尤其在2017-2018年岸线后退距离最大.     

大型浅水湖泊中浮游细菌群落的空间格局及其驱动机制——以太湖为例

浮游细菌在驱动湖泊物质循环、指示湖泊水环境质量等方面发挥重要作用,探明其在湖泊中的空间分布格局及其驱动机制,是揭示湖泊物质循环过程及水环境状况的关键。浅水湖泊具有水动力扰动强烈的生境特点,其中的浮游细菌群落空间格局的形成机制尚未明晰。本研究以大型浅水湖泊——太湖为研究对象,通过对全湖开展系统的野外调查,结合高通量测序技术、多元统计分析方法及生态学模型构建,系统探明太湖浮游细菌的空间分布格局,并揭示格局形成的驱动机制。结果显示：（1）太湖西北部湖区（藻型湖区）与东南部湖区（草型湖区）之间浮游细菌群落结构存在显著差异,而这两个区域内各湖区间及湖心区与周边湖区间之间的浮游细菌群落结构差异不显著,太湖浮游细菌群落结构整体上呈现较弱的距离衰减规律;（2）太湖草、藻型湖区及湖心区中浮游细菌群落结构分别与叶绿素a、透明度及总悬浮物显著相关,总体上环境变量对太湖浮游细菌群落空间格局的相对贡献率大于空间变量;（3）尽管确定性过程中的异质化选择、随机过程中的非主导性过程以及扩散限制对太湖浮游细菌空间格局的形成均产生重要影响,但总体上随机过程对格局形成的相对贡献更大;（4）太湖无序风场驱动的水力混合作用导致...     

大型浅水湖泊水体对流混合速率分析

湖泊水体的对流混合是最基本的物理过程,其能显著影响湖泊生态系统温室气体等循环,但浅水湖泊水体对流混合的研究鲜有报道.本研究基于太湖(面积2400 km2,平均水深1.9 m)中尺度通量网的原位、高频、连续和多点的观测数据,分析该大型浅水湖泊水体对流混合速率w*的时空特征.结果表明太湖水体w*的均值为2.49 mm/s,因太湖的风速、水温和辐射等物理参数无空间变化,w*也无明显的空间变化.但是研究表明w*呈现显著的昼夜变化和季节变化,且昼夜变化幅度强于季节变化.总体上夜间w*是白天的4倍多,冬季w*(均值1.79 mm/s)明显低于春季(均值2.42 mm/s)、夏季(均值2.91 mm/s)和秋季(均值2.82 mm/s).太湖w*主要受风速和能量收支影响,白天风速是主要驱动因子,夜晚能量收支是主要驱动因子.     

Basic limnological characteristics of the shallow eutrophic lake Grimnitzsee (Brandenburg, Germany)

The medium shallow lake Grimnitzsee (maximum depth: 9.9 m; mean depth: 4.6 m; area: 7.7 · 10⁶ m²) which is situated in the biosphere reserve “Schorfheide-Chorin” in northern Brandenburg (Germany) was studied in 1994 and 1995. A bathymetric map of Grimnitzsee is given for the first time. The lake is usually polymictic although in 1994 and 1995 relatively long summer stratification was observed due to very high global radiation input. Nutrient concentration, light climate, oxygen status, phytoplankton biomass and the species composition of littoral diatoms characterize the lake as eutrophic. Special features deducible from the lake's polymictic character were the multiple development of aerobic or anaerobic strata above the sediment, the fast recovery of silicon concentration in the water column after diatom sedimentation, the importance of resuspension for the success of planktonic diatom populations, and an only moderate correlation between chlorophyll a concentration and light attenuation as well as seston dry weight probably due to the influence of suspended particles.