南海扩张前序岩浆活动:解译华南三水盆地古近纪玄武质岩浆作用过程

华南三水盆地古近纪玄武岩（64～43 Ma）记录了南海扩张前大陆裂解过程中的岩浆-构造活动,但其岩浆演化过程及其动力学机制并不清楚。为此,作者对其开展了详细的岩石学和矿物学研究。三水盆地古近纪玄武岩具有OIB型的微量元素组成特征,由软流圈地幔源区部分熔融形成。该玄武岩中单斜辉石斑晶显示复杂的环带结构,包括正环带、反环带及韵律环带结构,指示了复杂的岩浆作用过程。正环带单斜辉石斑晶为核-边结构,其核部圆化或呈不规则形状,边部自形,指示了早期晶体与晚期演化岩浆混合后发生熔蚀-再生长过程。绝大部分反环带单斜辉石斑晶为核-幔-边结构,其核部相对低Mg,并被部分熔蚀呈不规则状或圆化,幔部相对高Mg,边部自形,反映了相对原始岩浆的补给作用。个别反环带单斜辉石为核-边结构,其核部Al₂O₃、TiO₂含量和Mg^#值明显偏低,为下地壳捕虏晶,表明岩浆从地幔源区上升汇聚到地壳岩浆房的过程中经历了轻微的地壳同化混染作用。韵律环带结构单斜辉石核部常为不规则状,幔部成分呈韵律状变化,边部自形,记录了岩浆对流及多次岩浆演化-补给...     

赣东北晚白垩世橄榄玄粗岩系列火山岩中单斜辉石矿物化学及其地质意义

利用电子探针对广丰-玉山盆地晚白垩世橄榄玄粗岩中单斜辉石进行了详细的矿物学研究,结果表明,所有的单斜辉石都属于普通辉石,表现出低Al,高Ti、Na含量的特征,具有碱性系列特征;单斜辉石斑晶的结晶温度为1 151～1 202℃,压力为0.12～0.58 GPa,可能是相对原始的岩浆上升到浅部(相当于上地壳位置)发生结晶分异作用形成。单斜辉石指示板内构造环境,与寄主岩石指示的构造环境一致。单斜辉石的矿物化学特征与碱性橄榄玄武岩中在浅源结晶的单斜辉石斑晶特征一致,而与碱性橄榄玄武岩中在深源处结晶的单斜辉石斑晶特征存在差异,且明显区别于拉斑玄武岩中单斜辉石斑晶的特征。     

滇西莴中晚始新世高镁富钾火山岩中单斜辉石斑晶环带结构的成因：岩浆补给-混合过程

滇西莴中晚始新世高镁富钾火山岩中单斜辉石斑晶普遍出现正环带结构、反环带结构或韵律环带结构，少量为具绿色核部的单斜辉石(“绿核辉石”)。反环带斑晶和“绿核辉石”的幔部与正环带斑晶的核部具有相似并且相对较窄的成分范围，相对高Mg#（0.83 ~ 0.90）,低TiO2（0.13 % ~ 0.29 %）,Al2O3（0.73 % ~ 1.68 %）和Na2O （0.22 % ~ 0.42 %），为钾质岩浆平衡结晶的产物。反环带斑晶的核部相对低Mg#（0.77 ~ 0.84），但与反环带斑晶的幔部、正环带斑晶的核部均具有相似的Ti/Al比值（0.06 ~ 0.16）；韵律环带结构斑晶的成分变化均在正、反环带斑晶的成分范围之内。莴中高镁富钾火山岩中的这些环带结构单斜辉石斑晶应来源于相似的岩浆体系，反 环带结构表明在岩浆房存在较原始岩浆对较演化岩浆再补给的岩浆混合过程，而韵律环带结构特征揭示曾多次发生这种岩浆混合过程。“绿核辉石”的核部明显低Mg# （0.50 ~ 0.74）,相对富Al2O3（1.66 % ~ 3.63 %）和Na2O（0.87 % ~ 2.17 %），具有明显较低的Ti/Al比值（< 0.05）和较高的AlVI/AlIV比值（0.38 ~ 0.76），为下地壳捕虏晶 来源，证实了在滇西晚始新世富钾岩浆演化过程中存在少量地壳混染作用。     

辽西义县组玄武岩中环带状单斜辉石的成因及其对岩浆演化的约束

辽西四合屯地区早白垩世义县组玄武岩包含大量具环带结构单斜辉石。本文对这些单斜辉石进行了系统的矿物学、主微量元素和原位Sr同位素分析,并探讨了义县组玄武岩的岩浆成因和演化历史。四合屯义县组玄武岩中的单斜辉石主要发育正环带结构,少量为反环带结构。反环带单斜辉石核部主要为透辉石,并具有低的Mg^#(65.5~79.7)和Cr₂O₃(< 0.48%),以及高的Na₂O (0.34%~1.33%)和Al₂O₃(1.02%~3.20%)。它们具有轻稀土元素富集的配分型式,具有明显的Eu和Sr负异常,说明其与斜长石平衡过。在Mg^#-Na₂O/Al₂O₃相关图中,反环带单斜辉石核部总体落入华北古老下地壳麻粒岩中单斜辉石的成分范围,因此其可能是来自下地壳麻粒岩的捕虏晶。反环带单斜辉石幔部和正环带单斜辉石核部主要为普通辉石,它们具有高度一致且变化范围相对窄的化学组成,包括高的Mg^#(84.7~89.2)和Cr₂O₃(0.13%~1.41%),以及低的Na₂O (0.17%~0.48%)和Al₂O₃(1.44%~2.57%)。它们的轻重稀土元素强分馏,与玄武岩全岩组成吻合。利用单斜辉石和基性岩浆之间Fe-Mg及微量元素的分配系数,我们计算了与反环带单斜辉石幔部和正环带单斜辉石核部平衡的岩浆组成,结果表明它们与剔除橄榄石捕虏晶的全岩组成达到平衡,因此这部分单斜辉石是岩浆成因的斑晶。它们相比全岩具有变化范围较宽和整体略高的原位⁸⁷Sr/⁸⁶Sr比值(0.7058~0.7085)。岩浆成因单斜辉石结晶温压计算结果(1171~1221℃、0.54~1.08GPa)表明义县组玄武岩的岩浆演化主要发生在下地壳浅部(18~36km)。四合屯义县组玄武岩具有壳幔双重属性,捕虏晶矿物的同化混染和下地壳榴辉岩的拆沉作用并不能合理解释其大陆下地壳属性。本次研究中反环带单斜辉石核部捕虏晶具有较高的HREE含量,它们可能作为源区残留相记录了华北东部古老下地壳在中生代的部分熔融过程,该过程中对应的熔体相则可以解释义县组玄武岩的下地壳属性。因此,我们认为四合屯义县组玄武岩是壳幔相互作用(岩浆混合)的结果。义县组玄武岩的主体来自受俯冲洋壳改造的岩石圈地幔,在下地壳岩浆房或幔源岩浆上升过程中存在少量下地壳来源酸性熔体的混合作用。

     

赣东北晚白垩世橄榄玄粗岩系列火山岩中单斜辉石矿物化学及其地质意义

利用电子探针对广丰-玉山盆地晚白垩世橄榄玄粗岩中单斜辉石进行了详细的矿物学研究,结果表明,所有的单斜辉石都属于普通辉石,表现出低Al,高Ti、Na含量的特征,具有碱性系列特征;单斜辉石斑晶的结晶温度为1 151～1 202℃,压力为0.12～0.58 GPa,可能是相对原始的岩浆上升到浅部（相当于上地壳位置）发生结晶分异作用形成。单斜辉石指示板内构造环境,与寄主岩石指示的构造环境一致。单斜辉石的矿物化学特征与碱性橄榄玄武岩中在浅源结晶的单斜辉石斑晶特征一致,而与碱性橄榄玄武岩中在深源处结晶的单斜辉石斑晶特征存在差异,且明显区别于拉斑玄武岩中单斜辉石斑晶的特征。     

赣杭构造带龙游地区早白垩世基性岩矿物化学、岩石地球化学特征及其地质意义

通过龙游晚中生代基性岩岩相学观察、全岩主量、微量元素和Sr-Nd同位素及矿物电子探针分析,对岩石成因、岩浆演化和构造环境进行探讨。龙游基性岩岩性为橄榄辉长岩,Sr-Nd同位素显示为幔源特征;主量、微量元素特征显示其经历了以橄榄石、辉石为主的分离结晶作用,且未发生明显的地壳物质混染。橄榄石颗粒具核-边结构,富Mg贫Fe的核部Fo值为90.1～91.8,指示原始岩浆是软流圈地幔,富Fe贫Mg的边部显示橄榄石Fo值为77.4～85.3,且核-边两部分的Fo值相差较大,显示原始橄榄石形成之后受到地幔熔体/流体的交代作用。辉石斑晶大多属于透辉石,在部分斑晶的边部发育少量霓辉石。透辉石斑晶普遍具有核-幔-边结构,从核部到边部的SiO_2含量降低,TiO_2、Al_2O_3含量升高,结晶温度升高,显示原始辉石形成之后受到温度更高的地幔熔体/流体的交代作用。研究认为,古太平洋板块后撤造成岩石圈地幔拉伸作用并形成赣杭构造带深部断裂后,部分软流圈物质受到地幔流体/熔体的交代作用,并沿这些深部断裂向上侵位,经历了以橄榄石和辉石矿物为主的分离结晶作用和微弱的地壳物质混染,最终形成龙游橄榄辉长岩。     

藏北羌塘戈木错渐新世碱性钾质火山岩中绿核辉石的成因:岩浆补给—混合过程

藏北戈木错渐新世碱性钾质火山岩中单斜辉石斑晶普遍出现正环带、反环带和韵律环带结构,多具有"绿核辉石"的结构特征。通过矿物电子探针测得"绿核辉石"的核部有高Mg#和低Mg#两种不同成分,两者都不同程度发育有筛孔状熔蚀结构,环带结构主要发育在辉石的幔部到边部,与绿色核部存在明显的成分间断,幔部环带结构的成分变化范围相对较窄。"绿核辉石"的成分和结构特征反映了同源碱性钾质岩浆在壳内岩浆房中发生了岩浆补给-混合作用,复杂的环带结构记录了混合岩浆的结晶过程。     

冲绳海槽玄武岩中单斜辉石的特征及其意义

冲绳海槽海底玄武岩中存在着三种不同世代的单斜辉石,即斑晶,微晶和基质辉石,它们的平均粒径分别约为400μm,30μm和5μm。斑晶辉石在电子探针下可见到明显的核部与边部之分;微晶辉石无明显的环带构造;基质辉石粒径细小但数量较大。这三个世代的辉石在成分上差异较为明显,从斑晶辉石的核部→边部和微晶辉石→基质辉石,成分从富铁向富镁,钙方向演化,这与封闭体系的辉石成分演化趋势正好相反,辉石的形态和成分特征反映出该玄武岩浆存在岩浆混合的特征,它们也可反演该地幔岩浆的活动过程;源自上地幔的拉斑玄武岩浆,在从源区向浅部岩浆房上升,运移过程中,受到携带相对富铁单斜辉石的较酸性岩浆的注入,混合;在浅部岩浆房中,混合岩浆结晶形成斑晶的边部和微晶辉石;基质辉石则是岩浆喷出洋底后淬冷结晶的结果,冲 槽玄武岩中三个世代的单斜辉石较好的完整记录了地幔岩浆后系列活动过程。     

江西广丰早白垩世碱性橄榄玄武岩中单斜辉石矿物化学及其地质意义

江西广丰早白垩世晚期碱性橄榄玄武岩中含有大、小两类单斜辉石斑晶,它们的主量元素间呈线性相关,且与大斑晶、小斑晶相平衡的岩浆Mg#值均类似于寄主岩石的Mg#值,说明它们与寄主岩石同源。早期的单斜辉石大斑晶粒径达1～1.5cm,SiO2,MgO,TFeO,CaO含量和Mg#值相对较低,Al2O3和TiO2含量相对较高,具有碱性玄武岩中单斜斑晶的矿物学特征;而晚期的单斜辉石小斑晶粒径为0.3～0.5cm,SiO2,MgO,TFeO,CaO含量和Mg#值相对较高,Al2O3和TiO2含量相对较低,也具有碱性玄武岩中斑晶的矿物学特征。单斜辉石大斑晶Wo（硅灰石）相对较高,En（顽辉石）含量相对较低,主要为含钛透辉石、含钛次透辉石,结晶温度为1272～1349℃、压力为1.23～1.93GPa,深度相当于41～64km,可能是原始岩浆绝热底辟上升结晶形成的;单斜辉石小斑晶Wo含量相对较低,En含量相对较高,主要为含钛普通辉石和顽透辉石,结晶温度为1186～1220℃、压力为0.44～0.75GPa,深度相当于15～25km,可能是相对原始的岩浆上升到浅部发生结晶分异作用形成的。     

南秦岭早古生代玄武岩的岩浆源区及演化过程

南秦岭地区早古生代玄武岩中发育的大量单斜辉石斑晶为研究火山岩的深部演化过程及源区属性提供了重要的载体。本文通过对早古生代玄武岩及其中的单斜辉石斑晶进行矿物学、岩石学及地球化学分析,讨论火山岩的演化历程及源区属性。电子探针分析结果表明玄武岩中单斜辉石斑晶属于透辉石,其成分与全岩成分并不平衡,暗示岩石经历了单斜辉石的堆晶作用。通过质量平衡计算得到了与单斜辉石斑晶平衡的熔体并计算了单斜辉石结晶的温压条件,结果显示单斜辉石斑晶结晶压力为7.6~14.0kbar,温度为1201~1268℃。高压下的分离结晶作用导致了单斜辉石成为主要的结晶相。重建后的玄武岩具有高镁、高钙、富钛,富集高场强元素Nb、Ta,亏损Rb、K、Sr和P,Dy/Yb比值高的地球化学特征,指示其源区为含单斜辉石、磷灰石及石榴石的交代岩石圈地幔。同地区发现的玄武质角砾也具高镁及高钙的特征,其富集Ba、Nb、Ta、Ti及低Dy/Yb比值表明源区为含单斜辉石、角闪石及尖晶石的交代岩石圈地幔。

     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.