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1.
Douglas fir trees and associated soils were sampled from the slopes of a small ( 4 km2) drainage basin in northeastern Washington to investigate the biogeochemical response to locally uraniferous groundwater. Uranium is preferentially incorporated in needles and twigs compared to larger branches or the trunk. The U concentration in needle ash ranges from 0.2 to 5.8 μg g−1 (ppm) and shows no correlation with the U concentration in associated soils. Rather, the distribution of anomalously uraniferous douglas fir (>1.0μg g−1 U in needle ash) appears to be controlled by observed or readily inferred pathways of near-surface groundwater movement in the drainage. These pathways include: (1) general downslope movement of subsurface runoff; (2) increased flux of near-surface groundwater near the toe of an alluvial fan; and (3) emergence of uraniferous (100–150 ng ml−1 [ppb] groundwater in the vicinity of a slope spring. The data also indicate the presence of near-surface uraniferous groundwater along a structurally controlled zone that parallels the north-south strike of the valley, and that includes the slope spring. The results suggest that biogeochemical sampling may be used to supplement more direct, but more limited, measurements of groundwater quality and flow regime in areas of near-surface contaminated groundwater.  相似文献   

2.
Investigation of chemical and physical weathering of bedrock and alluvial sediment in the Anza Borrego Desert, California, sheds light on weathering processes in hot‐arid systems and clarifies interpretations of climate from alluvial sediment. All of the alluvial sediment in the study area emanates from Cretaceous tonalite of the Peninsular Range, enabling exploration of the effects of external variables – climate, transport distance and tectonics – on the physical and chemical properties of the sediment. Chemical weathering in this area is dominated by plagioclase alteration observed in both bedrock outcrops and sediment, evinced most clearly by changes in the Eu anomaly. Biotite chemical weathering, manifested by interlayer K+ loss, is not evident in bedrock, but clearly observed in the sediment. Despite the weak intensity of chemical weathering (Chemical Index of Alteration = 56 to 62), fine‐grained (<63 μm) sediment displays a clear weathering trend in A–CN–K space and contains up to 25% clay minerals. Physical abrasion and grain‐size reduction in biotite during transport predominates in the sediment, whereas physical (insolation) weathering affecting bedrock is inferred from estimates of differential thermal expansion of mineral phases in response to extreme temperature changes in the study area. Chemical alteration and Brunauer–Emmett–Teller surface area both increase within the active Elsinore fault zone at the distal end of the depositional transect, reflecting tectonic‐induced fracturing and associated accelerated weathering. Extensive fracturing, together with a more humid Pleistocene climate, probably facilitated in situ bedrock weathering, preceding arid alluvial deposition in the Holocene. This study demonstrates that both climate and tectonic processes can affect chemical and physical weathering, resulting in alteration of plagioclase, leaching of K+ from biotite in the sediment and formation of clay minerals, even in hot, arid systems.  相似文献   

3.
Korea has suffered from high U concentrations in some groundwater, especially in Daejeon near the central Ogcheon metamorphic belt. However, clear explanation has not been yet reported for the uranium sources in groundwater. This study is focused on identifying the potential uraniferous host rocks and finding the exact U-minerals serving as uranium sources in groundwater near Daejeon, Korea. For this work, we performed an in situ gamma ray spectrometer survey and a laboratory microscopic study with electron micro-probe analysis. The measurements for radioactive element content did not show any prominent K- and Th-anomaly spots, but they did result in several observations of considerable U-anomalies in pegmatite and hydrothermally altered granite, in which uraninite, coffinite and uranophane were found by electron micro-probe analysis. The occurrences of U-minerals are the first such discovery except in the low-grade U deposits of the Ogcheon metamorphic belt in Korea. All observed U-minerals were intimately associated with hydrothermal alteration. The remarkably low Th/U ratios in the studied uraniferous rocks also suggest that the U enrichment was genetically related to a post-magmatic hydrothermal process. However, many of the uraniferous parts were controlled by a reducing environment and occurred near the border between graphite-rich mica-schist and Jurassic leucocratic granite. The findings on these uraniferous rocks can be used in elucidating the source of highly enriched U groundwater in granite aquifers as well as in understanding the occurrence of igneous U-minerals, which has not been previously reported in Korea.  相似文献   

4.
The late Tertiary high ash brown coal (Rr=0.26%) of the Schirnding Seam Zone is mainly composed of huminite. The seam is underlain by a thick saprock (mica saprockkaolinite-mica saprock) some tens of meters thick which gradually developed from phyllitic basement rocks and a thin Footwall Series of coarse-grained clastic sediments which, however, occur only in a few places. The roof rocks ‘ Hanging Wall Series' abruptly appear on top of the seam and consist of massive gray mudstones and arenites, intercalated with some tuffites. These Tertiary series were studied in open-pit mines operated for coal and clay and in bore holes. Chemical investigation involved the analyses of TOC, TSC, Ni, Co, Pb, Zn, Ga, Be, V, Cr, U, Th, P, Zr, REE and organic compounds of extracted organic matter (=OM). Early Tertiary chemical weathering was responsible for the monotonous kaolinite-mica-goethite mineral assemblage in the saprock and the footwall series. In the coal-bearing basin a more variegated mineral association including, pyrite, kaolinite, illite, smectite, illite-smectite mixed layers and siderite was brought about by volcanic processes, intrastratal solution set free in course of coalification and early diagenesis and by meteoric waters infiltrating the coal-bearing series from uplifted parts of the basin, which underwent strong oxidation. The environment of deposition is interpreted in terms of peatswamps that were fed by small streams and crevasse splays of a meandering drainage system grading towards the basin margin into a braided stream system on an alluvial fan plain. Strongly fluctuating water levels were responsible for the pronounced cyclicity to be encountered across the coal-bearing series. The processes of element redeposition and element migration in the Schirnding Basin are operative across the interface coal-saprolite (detrital influx of heavy minerals and intrastratal solution, hydrocarbon infiltration and redistribution of organic matter, reworking of duricrusts), in the saprolite proper (weathering leachats) and across the redox boundaries between the Schirnding Seam Zone and the Hanging Wall Series (input of physils and diagenetic alteration) as well as its strongly oxidized stratigraphic equivalents at the basin edge (volcanic influx, intrastratal solutions). Chemical and mineralogical variations across the coal basin which are directly controlled by the variation in the environment of deposition, weathering and groundwater movements may be directly correlated to changes in the saprock due to the immediate contact between coal and bedrock.  相似文献   

5.
近年来,不少学者开始关注基岩油藏,但有关基岩风化壳的研究尚未有报道.以柴达木盆地东坪地区基岩风化壳为研究对象,结合东坪地区的地质资料、测井资料及地球化学资料,对花岗质基岩风化壳的结构特征及其与油气储集的关系进行了系统的研究.结果表明:(1) 建立了以Al2O3、CaO、Na2O、K2O为主要判别依据的花岗质基岩风化指数,准确的识别出古土壤层、残积层、半风化层、未风化层;(2) 根据成像测井响应特征及常规测井曲线可以很好地识别古风化壳特征;(3) 东坪地区基岩风化壳的主要储集空间有基岩溶蚀孔洞、基质矿物溶孔和基岩裂缝,共3种,为致密储层,风化壳由风化基面向上,孔隙逐渐发育,至半风化岩石中部的孔隙度较大,且以大孔隙为主,由半风化岩石到风化粘土层,孔隙的规模变小,逐渐以微孔隙为主,纵向上,孔隙度与风化程度、构造缝发育情况、埋藏深度及其和应力释放中心的距离具有相关性.风化壳的存在大大的改善了储层物性,扩展了含气面积,增加了含气层系,对花岗质基岩地层油气藏和深层油气勘探具有重要的理论价值和科学意义.   相似文献   

6.
几年来野外实地调查和室内大量的实际资料表明,我国东南部中生代含铀花岗岩体大多数属原来大陆壳硅铝层浅海相陆源沉积岩和火山沉积岩,以及少量的花岗岩等物质在深部增温增压下经受重熔作用而产生的酸性岩浆侵入于距当时地表约为2—4公里深处,经过充分而完善的结晶分异作用和射气  相似文献   

7.
The petrography and geochemistry (major, trace, and rare earth elements) of clastic sedimentary rocks from the Paleogene Dainan Formation (E2 d) in the North Jiangsu Basin, eastern China, are investigated to trace their provenance and to constrain their tectonic setting. The studied samples are characterized by LREE enrichment, flat HREE, and negative Eu anomaly similar to the upper continental crust composed chiefly of felsic components in the source area. Petrographic observation indicates that the sandstones contain predominant metamorphic and sedimentary clasts that were derived from peripheral recycled orogen and intrabasinal materials. The trace element ratios (Co/Th, La/Sc, La/Th, and Th/U) and the La-Th-Sc ternary plot further confirm that the sandstones are derived from granitic gneiss sources from recycled orogen and the intrabasinal mixed sedimentary provenance. The granitic gneiss source rocks may have derived from the Proterozoic granitic gneiss denuded in the eastern Dabie-Sulu orogen; and the intrabasinal provenance may come from the underlying strata during the Late Paleocene Wubao movement. The chemical index of alteration (CIA) and A-CN-K plot show that these source rocks may have experienced weak to medium chemical weathering. Analysis on tectonic setting of the source area suggests an active continental margin, which is intimate with tectonic feature of the Dabie-sulu orogen and the Yangtze block. In summary, we suggest that the North Jiangsu Basin is an ideal site for the study of the coupling between the uplift of the orogen and the subsidence of the foreland basin.  相似文献   

8.
塔里木盆地碳酸盐岩油气聚集带   总被引:14,自引:4,他引:10  
海相碳酸盐岩储层多类型及非均质性强的特点,决定了其油气聚集带与以往陆相盆地碎屑岩油气聚集带的控制因素有显著差异,碳酸盐岩的油气聚集并不是简单地受二级构造带的控制。通过分析塔里木盆地已发现碳酸盐岩油气藏,其储层发育受大气淡水风化淋滤作用、沉积作用及各种成岩作用、深部流体改造作用等因素的控制。据储层成因类型及其横向分布特征,将塔里木盆地碳酸盐岩油气聚集带划分为:不整合与古风化壳型、生物建造礁-滩型、白云岩内幕型及深部流体改造型。不同类型的碳酸盐岩油气聚集带主要分布于塔北隆起、塔中隆起及巴楚断隆等古隆起的不同部位。由于不同碳酸盐岩油气聚集带上储集层成因机制不同,导致其储集空间、储集性能、油气藏类型及分布等均有所不同。  相似文献   

9.
崔雪玉  赵涵滢  潘涛  李明 《探矿工程》2008,35(12):28-34
宝泉抽水蓄能电站引水系统上斜井开挖揭示,在高程668000~651000 m和高程526000~514000 m处,分别穿过古风化壳地层。古风化壳地层岩石极为破碎,夹泥较多,基岩裂隙发育,地下水丰富,透水率较大。古风化壳地层段地层的灌浆处理,成为斜井开挖能否顺利通过该地层的关键,并且直接影响着电站的安全、稳定运行。针对上述问题,通过采取阻水帷幕、高压固结、锥形帷幕灌浆几种方法联合处理,取得了满意的效果。详细介绍了具体的灌浆处理技术措施,分析了处理效果。  相似文献   

10.
藏北羌塘盆地大规模古风化壳的发现及其意义   总被引:1,自引:0,他引:1  
付修根  王剑  吴滔  何江林 《地质通报》2009,28(6):696-700
新的野外油气地质调查发现,在羌塘盆地中央隆起带及其两侧的南、北羌塘坳陷中,那底岗日组及其同沉积地层之下广泛发育了一古风化壳,古风化壳覆盖了石炭系、二叠系和前人已确定的三叠系肖茶卡组,具有区域性展布的特点。研究表明,不同地区古风化壳的形成时代不同:在南羌塘及中央隆起带上,风化剥蚀作用可能于晚二叠世就已开始,并经历了早、中三叠世的进一步演化;北羌塘地区的古风化壳形成时代可能为晚三叠世(或中三叠世),至晚三叠世肖茶卡组沉积期,形成了南北羌塘统一的古风化壳,并被那底岗日组及其同沉积地层超覆。这些新发现对于重新认识羌塘盆地的沉积演化、正确评价羌塘盆地的石油地质条件具有重要意义。  相似文献   

11.
High-mountain basins provide a source of valuable water resources. This paper presents hydrological models for the evaluation of water resources in the high-mountain Zêzere river basin in Serra da Estrela, Central Portugal. Models are solved with VISUAL BALAN v2.0, a code which performs daily water balances in the root zone, the unsaturated zone and the aquifer and requires a small number of parameters. A lumped hydrological model fails to fit measured stream flows. Its limitations are overcome by considering the dependence of the temperature and precipitation data with elevation and the spatial variability in hydrogeomorphological variables with nine sub-basins of uniform parameters. Model parameters are calibrated by fitting stream flow measurements in the Zêzere river. Computed stream flows are highly sensitive to soil thickness, whereas computed groundwater recharge is most sensitive to the interflow and percolation recession coefficients. Interflow is the main component of total runoff, ranging from 41 to 55% of annual precipitation. High interflows are favored by the steep relief of the basin, by the presence of a high permeability soil overlying the fractured low permeability granitic bedrock and by the extensive subhorizontal fracturing at shallow depths. Mean annual groundwater recharge ranges from 11 to 15% of annual precipitation. It has a significant uncertainty due to uncertainties in soil parameters. This methodology proves to be useful to handle the research difficulties regarding a complex mountain basin in a context of data scarcity.  相似文献   

12.
碳酸盐岩的化学风化是岩溶关键带各圈层相互作用的主要形式,风化壳中蕴含重要气候环境和物质循环信息。通过对广西桂林会仙峰丛谷地石灰土的化学风化强度及元素迁移特征的研究,并与滇黔湘和青藏高原的岩溶风化壳的对比分析,结果表明:(1)会仙石灰土化学蚀变指数(CIA)均值为92.14,与贵州兴义岩溶风化壳相当,反映炎热潮湿气候下的强烈化学风化;白云岩风化壳CIA与灰岩风化壳相当,CIA值主要受“不溶物”含量的影响;地形上,从上坡到下坡,从坡地到谷地,垂向剖面从浅部到深部,碳酸盐岩风化壳的CIA值呈减小趋势;(2)包括会仙石灰土在内的中国南方碳酸盐岩风化壳的CIA值与纬度成负相关,青藏高原地区和北方地区碳酸盐岩风化壳的CIA值与纬度不存在相关性,可能受晚第三纪以来印度板块俯冲推挤,青藏高原地区构造抬升和夷平面变形的影响;(3)与硅酸盐风化壳、黄土剖面不同,碳酸盐岩风化壳CIA和Na/K(摩尔比值)不存在相关性,但CIA和K/Al(摩尔比值)则存在显著负相关,可采用K/Al来表征碳酸盐岩剖面的风化程度,其主要是受可溶成分的快速淋失影响;会仙石灰土、贵州兴义风化壳较其他风化壳更接近Al端,化学风化程度更高;(4)会仙石灰土的化学成分与中国其他地区碳酸盐岩风化壳基本一致,剖面上分布均匀;与上陆壳相比,Na、K、Ca、Mg表现为亏损,其他元素为富集;和下伏碳酸盐岩的稳定元素Ti相比,除了Cr、Fe、P、Al富集或不变外,其他元素都发生明显的迁移淋失;会仙风化壳元素的迁移性由强到弱为:Ca ? Mg ? B ? Na ? N ? Cd ? Zn ? As ? K ? Pb ? Si ? Mn ? Al ? Cr ? Fe ? P,高含量Ca、Mg的快速溶失对其他元素的迁移性有重要影响。   相似文献   

13.
Door County, Wisconsin, is a region of karst topography underlain by Silurian dolomite bedrock. Numerous sinkholes intercept much of the surface runoff and act as sites for direct groundwater recharge. The clay-rich and impermeable Upper Ordovician Maquoketa formation separates the dolomite aquifer from the deeper aquifers and appears to be a factor in groundwater circulation and karst formation Thin glacial drift and Quaternary materials overlie the dolomite and are hydrologically connected with it The interactions of surface and groundwater, and the role of solution features in water interchange were studied in a small drainage basin. This basin contains several large sinkholes and a nearby spring complex Mapping identified many additional sinks and swallets in surface drainage routes Water flowing into two sinks was traced and found to have a residence time of several hours. Water flowing into sinkholes and from the spring was sampled to identify the quality and seasonal trends in composition of the shallow groundwater Water quality parameters monitored include magnesium, sodium, potassium, chloride, phosphorous, nitrate and ammonia, nitrogen, alkalinity, pH, turbidity, and specific conductance. Nitrate levels were found to increase 5 to 6 times during periods when there was zero input through sinkhole recharge sites. Nitrate levels approached the 10 mg/l NO3 -N limit set by the U.S. Public Health Service for drinking water In this basin sandy soils are most susceptible to sink development, whereas clay-rich soils have a lesser number of sinks. It appears, however, that a network of bedrock solution features exists under all soils The loss of soil into sinkholes has impacted groundwater quality and reduced agricultural productivity through a reduction in tillable acreage and water retention capacity.  相似文献   

14.
Near the shores of Great Slave Lake, natural sources of heavy metals include gold and base metal deposits, mineralized greenstone belts and sedimentary bedrock, and uraniferous granites. Potential anthropogenic sources of heavy metals (As, Zn, Pb) include large gold and base metal extraction -processing facilities on the shores of the lake. Six sediment cores were collected on a traverse of the lake. Heavy metal concentrations and distributions are related to the regional bedrock geochemistry in the drainage basin. Higher uranium concentrations in the northernmost core are attributed to extensive uraniferous areas north of the lake. More subtle variations of concentration are related to sedimentologic characteristics and processes in the lake. The west basin is a natural sink for most of the heavy metals determined. Two centrally located west basin cores had mean zinc concentrations of 145 ppm, whereas cores closer to the north and south shores had mean concentrations of 80–110 ppm. Mn, Ni, and Pb were enriched in some of the cores from the area of shallower water near the MacKenzie River outlet, rather than in the central west basin. The enrichment is related to Mn-, Ni-, and Pb-rich amorphous coatings on quartz grains. Elevated zinc or lead levels from anthropogenic activities were not detected but elevated levels are suspected for arsenic. In the two cores from the center of the west basin, surface sediment contains up to 12 ppm arsenic, not high in comparison with noncontaminated freshwater lakes elsewhere in Canada but considerably elevated relative to concentrations of 1 ppm found deeper in the same cores. Contribution from the National Water Research Institute, Western and Northern Region. Presented at the 10th International Sedimentological Congress, Jerusalem, Israel, 1978.  相似文献   

15.
徐守立  尤丽  毛雪莲  钟佳  吴仕玖 《地球科学》2019,44(8):2717-2728
研究花岗岩潜山储层特征及控制因素为琼东南盆地下一步潜山勘探提供依据,综合已钻井录井资料、壁心资料、测井资料、薄片资料及地球化学资料,识别风化壳并刻画储层特征.研究结果表明松南低凸起及周缘花岗岩受长期风化影响,纵向分带明显,由表及里依次发育粘土风化带、砂砾质风化带、裂缝带和基岩带.通过元素测井、成像测井、常规测井结合可以很好的识别潜山风化壳及纵向结构特征.纵向上不同风化层储集空间特征显著差异,依次发育孔隙型、裂缝-孔隙复合型、孔隙-裂缝复合型及裂缝型4种储集空间,以裂缝-孔隙型储集为主的砂砾质风化带物性最好,自砂砾质风化带以下,随埋深增加,风化减弱,储层物性依次变差.松南低凸起周缘花岗岩侵入体形成于三叠纪初期,自燕山期构造抬升,长期古隆起暴露、断裂及节理发育是其厚层优质风化壳型潜山储层发育的主要原因.同时,由于潜山后期埋深浅,经过压实、胶结等成岩作用影响弱,是凸起周缘潜山储层发育的重要原因.为下一步潜山领域勘探提供地质支撑.   相似文献   

16.
Palaeomagnetic dates for two sites on the Southern Tablelands of New South Wales, at Bunyan and Bredbo, indicate that basal lake sediments and underlying bedrock were ferruginised during the late Tertiary. The dates provide further evidence of a regional episode of intense weathering and ferruginisation in the late Tertiary.  相似文献   

17.
亚洲主要河流的沉积地球化学示踪研究进展   总被引:5,自引:0,他引:5  
发源于喜马拉雅—青藏高原的亚洲几条大河的河流地球化学研究揭示了高原隆升、流域风化剥蚀、大气CO2消耗和亚洲季风气候变化之间的耦合关系。研究认为南亚主要河流流域的化学风化对全球大气CO2消耗和海洋化学通量变化贡献较大,河流沉积地球化学研究反映的高原阶段性隆升过程、流域剥蚀速率以及亚洲季风演化信息也明显比东亚主要河流的记录清晰;尤其是最近几年运用河流碎屑单矿物化学和年代学方法来示踪流域构造演化、沉积物从源到汇过程以及河流演化历史等,取得了许多重要的研究成果。比较而言,我国的河流在元素地球化学和水化学组成方面虽然开展了大量基础研究工作,但目前急需进一步提炼科学目标,与国际性的研究计划结合,综合多学科的研究力量,在研究思路和关键方法上需要突破和深入,加强研究的广度和深度。长江更可以作为一个突破口和研究平台,来开展深入的沉积地球化学示踪研究。  相似文献   

18.
马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr2+)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr2+的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr2+的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr2+的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。  相似文献   

19.
在吉林东部花岗岩区地下水化学成分和化学类型研究的基础上,以Na作为参比元素,确定了花岗岩风化过程中22种主量元素和微量元素的相对活动顺序。花岗岩区地下水的地球化学类型属低矿化度(变化范围为69.51×10-6~386.49×10-6,平均值为199.48×10-6)的HCO3-Ca和HCO3-Na-Ca型。花岗岩风化过程中元素的活动性顺序(RM)从大到小依次为:B、Ca、Mo、Zn、Sr、Na、Mg、Cr、Cu、Ni、K、Co、Li、V、As、Ba、Si、Y、Fe、Ti、Al、Mn。风化产物中的粘土矿物主要为高岭土、蒙脱石,反映出本区花岗岩的风化淋滤程度较弱的特点。  相似文献   

20.
Chemical relationships among surface waters, soils and rocks were investigated in the drainage basin of the North Fork of the Shoshone River in northwestern Wyoming. The area is underlain entirely by andesitic volcanic rocks. Smectite is the only clay mineral forming in soils over much of the area, although minor kaolinite occurs in a few areas of higher-than-average rainfall.Mass-balance calculations relating stream water chemistry to rock alteration indicate that controls on the chemistry of surface waters take place not in the soil zone but in the altered rock zone. The dominant weathering process which controls the water chemistry is slight alteration of large volumes of rock, rather than development of chemical equilibria involving secondary phases in the soil zone. The altered rock is enriched in feldspars and depleted in ferromagnesian minerals compared to fresh rock. The high rate of physical erosion of the area is enough to remove the residue, reexpose the bedrock, and continue the weathering process.  相似文献   

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