Utilization of Shallow Geophysical Sensing at Two Abandoned Municipal/Industrial Waste Landfills on the Missouri River Floodplain

In the past 30 to 40 years, floodplain areas of large rivers, such as the Missouri River, have been extensively used for large industrial and municipal landfills. Many of these sites are now causing varying degrees of ground water contamination. Rapid geophysical characterization techniques have proven useful for delineation of anomalous areas indicative of potential contaminant plumes. These methods have also resulted in a cost effective approach to the location and number of monitoring wells.
An effective technique to initially characterize ground water contamination at such landfills along the Missouri River in northwestern Missouri involved a combination of electrical resistivity and electromagnetic conductivity methods. Resistivity was used to obtain soundings of the alluvium by using a modified Wenner array and to corroborate shallow electromagnetic conductivity measurements by using short Wenner array electrode spacings.
Upon confirmation of similar measurements of the upper soils for the two methods, numerous electromagnetic conductivity traverses were made at each landfill site. The data generated from these surveys were graphed and contoured to delineate anomalous areas. Based on the geophysical study, a ground water monitoring well network was then designed for each landfill.
As a result, a minimal number of wells were required to initially characterize the ground water quality at these two sites. In general, analysis of water samples from these wells displayed good correlation with the geophysical results.     

Elements in Cottonwood Trees as an Indicator of Ground Water Contaminated by Landfill Leachate

Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.
Leaf samples of broad-leafed cottonwood, Populus deltoides , were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or "well plant," functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.
Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.     

Use of a Geo Flowmeter for the Determination of Ground Water Flow Direction

The Geo Flowmeter is manufactured by K.V. Associates of Falmouth, Massachusetts, and is used to determine ground water flow direction and velocity in monitoring wells or open boreholes. It operates by emitting heat pulses and measuring subsequent temperature increases carried by the ground water movement. The meter can be used in wells as small as 2 inches in diameter and only a single well is required for determination of ground water flow direction and rate.
This paper is a case history of the use of the Geo Flowmeter in a complex hydrogeologic setting consisting of a partially above grade landfill located between a navigable waterway and a large storm water impoundment basin. Mounding effects of the landfill, tidal changes in the channel, varying water levels in the impoundment basin and a complex substrate (alternating layers of sand, silt and clay) presented a challenge for ground water interpretation and analysis. The Geo Flowmeter was lowered into existing monitoring wells surrounding the landfill to determine ground water flow direction and rate. Sensitivity of the meter was sufficient to distinguish two separate flow directions in a single well screen. Later investigation involving installation of piezometers, long-term ground water level monitoring and plotting of ground water contours verified initial findings of the meter.
This article presents numerous graphs and pictures to illustrate field use of the instrument and discusses advantages and disadvantages of its use. Actual field data collected is included to provide a basis for evaluating the accuracy of the instrument and identifying situations where it may be used.     

The Geochemistry of Boron in a Landfill Monitoring Program

Ground water monitoring data collected during the past eight years at a permitted municipal solid waste (MSW) disposal facility located in the midwestern United States indicated fluctuations in typical leachate indicator parameter concentrations. Apparent trends in the data inferred leachate outbreak, generating suspicion as to the integrity of the landfill liner. Eight ground water monitoring wells were installed in three distinct geologic units at the landfill facility, including glacial drift, silurian dolomite, and a post-glacial peat fen, which is downgradient from the landfill. Piezometer nests were used to define ground water gradients at the site. Using boron as an indicator, the occurrence of analytes of concern in the downgradient monitoring wells were shown to be indicative of the natural geochemistry of site ground water. This work emphasizes the importance of understanding site hydrogeology during the interpretation of ground water quality data.     

Configuring Detection Wells Near Landfills

A graphical method was devised for designing contaminant detection monitoring networks in aquifers. The approach eliminates bias in detection efficiency among well pairs, thereby improving the overall efficiency of a ground water monitoring network. In the equidistant configurations derived by the graphical approach, all wells are located the same distance from a landfill, but the distance is measured parallel to ground water flow, Measured perpendicular to ground water flow, there is also an equal spacing between wells in an equidistant network. A simulation model was used to compare an equidistant network to a peripheral monitoring configuration, in which wells were spaced evenly along the downgradient boundaries of a landfill. The equidistant network yielded a 12.4% higher detection efficiency and also facilitated earlier release detection. In practice, the graphical approach that yields equidistant configurations can be used to identify candidate monitoring networks to detect potential releases from landfills.     

Decision Analysis for Leachate Control at a Fractured Rock Landfill

The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.     

The Utility of Multiple-Completion Monitoring Wells for Describing a Solvent Plume

At a study site in the midwestern United States, multiple-completion wells demonstrated that a vertical hydraulic gradient was responsible for the contamination pattern exhibited by chlorinated solvent plumes. The typical pattern consisted of little or no contamination in the upper portion of the aquifer with concentrations increasing with depth. When ground water contamination was discovered in an unexpected portion of the site, water level elevations and contaminant distribution data obtained from multiple-completion wells resulted in identification of the source location. The well eventually determined to be located in the source area displayed contaminant levels much higher in the upper zone of the aquifer — the opposite contamination pattern of other on-site wells. Such results indicated that the spill had occurred near this location and that solvent residing along the capillary fringe was continuing to contaminate the aquifer.     

Neutron Moisture Probe Measurements of Fluid Displacement During In Situ Air Sparging

Strawberry Point, located on Hinchinbrook Island, Alaska, is the site of a Federal Aviation Administration air navigation facility that is contaminated with gasoline- and diesel-range hydrocarbons in soil and ground water. An air sparging system was installed to promote bioremediation in the zone of seasonal ground water fluctuation where the contaminant is concentrated. The sparge wells were placed in a homogeneous formation, consisting of fine-grain beach and eolian sands. The system was then evaluated to determine the ground water region of influence and optimum frequency of operation. Neutron probe borehole measurements of percentage; of fluid displacement during sparging at two wells revealed dynamic air distributions defined by an initial and relatively rapid expansion phase followed by a consolidation phase. Air distribution was stable within 12 hours after startup, reaching a peak air saturation of greater than 50 percent. The radius of peak expansion varied with time and depth, with measurable fluid displacement occurring beyond 12 feel from the sparge well near the water table. The percentage of air saturation stabilized within one hour following cutoff of the air flow, leaving pockets of entrapped air near the water table. When air injection was resumed, air saturation levels were found to be repeatable. The observations at this site indicated that the effective region of influence is relatively small and that frequent pulsing is needed to optimize oxygen distribution.     

Assessing background ground water chemistry beneath a new unsewered subdivision

Previous site-specific studies designed to assess the impacts of unsewered subdivisions on ground water quality have relied on upgradient monitoring wells or very limited background data to characterize conditions prior to development. In this study, an extensive monitoring program was designed to document ground water conditions prior to construction of a rural subdivision in south-central Wisconsin. Previous agricultural land use has impacted ground water quality; concentrations of chloride, nitrate-nitrogen, and atrazine ranged from below the level of detection to 296 mg/L, 36 mg/L, and 0.8 microg/L, respectively, and were highly variable from well to well and through time. Seasonal variations in recharge, surface topography, aquifer heterogeneities, surficial loading patterns, and well casing depth explain observed variations in ground water chemistry. This variability would not have been detected if background conditions were determined from only a few monitoring wells or inferred from wells located upgradient of the subdivision site. This project demonstrates the importance of characterizing both ground water quality and chemical variability prior to land-use change to detect any changes once homes are constructed.     

An Integrated Ground Water Monitoring Program Using Multilevel Gas-Driven Samplers and Conventional Monitoring Wells

Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.     

Long-Term Confidence in Ground Water Monitoring Systems

State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.     

A method for evaluating horizontal well pumping tests

Predicting the future performance of horizontal wells under varying pumping conditions requires estimates of basic aquifer parameters, notably transmissivity and storativity. For vertical wells, there are well-established methods for estimating these parameters, typically based on either the recovery from induced head changes in a well or from the head response in observation wells to pumping in a test well. Comparable aquifer parameter estimation methods for horizontal wells have not been presented in the ground water literature. Formation parameter estimation methods based on measurements of pressure in horizontal wells have been presented in the petroleum industry literature, but these methods have limited applicability for ground water evaluation and are based on pressure measurements in only the horizontal well borehole, rather than in observation wells. This paper presents a simple and versatile method by which pumping test procedures developed for vertical wells can be applied to horizontal well pumping tests. The method presented here uses the principle of superposition to represent the horizontal well as a series of partially penetrating vertical wells. This concept is used to estimate a distance from an observation well at which a vertical well that has the same total pumping rate as the horizontal well will produce the same drawdown as the horizontal well. This equivalent distance may then be associated with an observation well for use in pumping test algorithms and type curves developed for vertical wells. The method is shown to produce good results for confined aquifers and unconfined aquifers in the absence of delayed yield response. For unconfined aquifers, the presence of delayed yield response increases the method error.     

Optimizing Ground Water Observation Networks in Irrigation Areas Using Principal Component Analysis

Ground water monitoring networks can provide vital information for sustainable water resources management. This involves the measurement of ground water level, solute concentration, or both. This article deals with the former. It optimizes network distribution of piezometer or data sampling wells to effectively monitor ground water levels under an irrigation region while retaining adequate overall measurement accuracy. This article presents a structured process for applying principal component analysis (PCA) in optimizing a ground water monitoring network in an irrigation area of Australia. The PCA functions, distributed with the MATLAB package, were used to determine relative contributions of individual piezometers in capturing the spatiotemporal variation of ground water levels. Kriging gridding interpolation algorithm was used to render the data surface presentations and determine spatial differences in piezometeric surfaces using different number of data sets. The results show that the overall difference of ground water level between the original piezometer network and the optimized networks after the PCA process was applied is less than 20%, while the total number of piezometers in the optimized network is reduced by 63%, which will save the time and cost to monitor ground water levels in the irrigation area.     

The Detection of Naturally Occurring BTX During a Hydrogeologic Investigation

Benzene, toluene and xylenes (BTX) were detected in ground water during a contaminant hydrogeological investigation of a landfill site. The landfill site was situated on approximately 10m (33 ft) of clay and glacial till overburden soils, which were underlain by a shaly limestone bedrock. The top part of the bedrock was the regional aquifer in the study area. Initial thoughts were that the landfill was the source of the BTX. However, the BTX was detected in ground water a considerable distance from the known extent of the leachate plume. Subsequent detailed analysis of rock cores showed the BTX could be leached from bituminous layers of shale that were interbedded in limestone. Rock core testing included gas chromatograph (GC) analysis of organic free reagent water used for leaching tests, flame ionization detection on a solvent used for leaching tests and thermal desorption analysis of the solid rock. The naturally occurring BTX, along with the presence of brackish ground water in the shaly bedrock, made it difficult to identify ground water contamination emanating from the landfill. Thus, the presence of BTX should not be considered definitive evidence of ground water contamination in certain sedimentary rock aquifers.     

Estimation of hydraulic conductivity in an alluvial system using temperatures

Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.2 degrees C in two wells to approximately 8 degrees C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.     

Application of harmonic analysis of water levels to determine vertical hydraulic conductivities in clay-rich aquitards

A harmonic analysis method was used to determine vertical hydraulic conductivities (Kv) in geologic media between vertically separated piezometers using water level measurements. In this method, each water level time series was filtered and then decomposed using harmonic analysis into a sum of trigonometric components. The phase and amplitude of each harmonic function were calculated. These data were used to estimate Kv values between vertically separated data sets assuming one-dimensional transient flow. The method was applied to water level data collected from nested piezometers at two thick clay-rich till aquitards in Saskatchewan, Canada. At one site, routine water levels were measured in 12 piezometers (installed between 1 and 29 m below ground surface) since installation (1995). At the other site, water levels were measured in seven piezometers (installed between 4 and 53 m below ground surface) since installation (1998-1999). The Kv calculated using harmonic analysis decreased with depth below the water table at both sites, approaching matrix estimates of hydraulic conductivity between 10 and 11 m and between 21 and 43 m below ground surface. These depths reflected the depth of extensive vertical fracturing at the sites and showed that the depth of fracturing may be site specific.     

山西静乐井水位高值异常及其与华北地震活动的关系

静乐井是山西省地下水观测网中的一口地震观测井。从１９８３￣１９９６年的１４ａ观测中,水位动态变化出现过３个高值时段,水位的高值虽有降雨渗入的影响,但主要可能是反映区域应力场加强的变化过程,因此３个水位高值时段与华北地区中强地震的活跃时期基本吻合。     

Detection of Contaminant Plumes by Borehole Geophysical Logging

Two borehole geophysical methods—electromagnetic induction and natural gamma radiation logs—were used to vertically delineate landfill leachate plumes in a glacial aquifer. Geophysical logs of monitoring wells near two land-fills in a glacial aquifer in west-central Vermont show that borehole geophysical methods can aid in interpretation of geologic logs and placement of monitoring well screens to sample landfill leachate plumes.
Zones of high electrical conductance were delineated from the electromagnetic log in wells near two landfills. Some of these zones were found to correlate with silt and clay units on the basis of drilling and gamma logs. Monitoring wells were screened specifically in zones of high electrical conductivity that did not correlate to a silt or clay unit. Zones of high electrical conductivity that did not correlate to a silt or clay unit were caused by the presence of ground water with a high specific conductance, generally from 1000 to 2370 μS/cm (microsiemens per centimeter at 25 degrees Celsius). Ambient ground water in the study area has a specific conductance of approximately 200 to 400 μS/cm. Landfill leachate plumes were found to be approximately 5 to 20 feet thick and to be near the water table surface.     

Poroelasticity: observations of anomalous near surface tilt induced by ground water pumping

Ground tilt signals observed at three different test sites in Germany confirm earlier observations of surface deformation occurences caused by the withdrawal of ground water from nearby wells. The strength of the signals presented here ranges from a few μrad to 230 μrad, whereby ground tilt was measured in shallow boreholes, at depths between 2 and 4 m. Analysis of the tilt signals suggests that local inhomogeneities in the subsoil can have significant impact on several signal parameters, namely its maximum amplitude, its variation in time, and its strike with respect to the direction of the productive well. The observed data emphasize the likelihood of various causes for deviations from the ‘normal’ tilt response that holds for an isotropic poroelastic half-space. In particular, at one site, a reverse well level change, also known as ‘Noordbergum effect’ in hydrogeology, is seen together with a respective response in the tilt signal. The study concludes that near surface deformation in the vicinity of pumped wells bears a wealth of information that may be useful to constrain the conditions of fluid flow at depth; and that there is a need for model calculations to fully understand the involved phenomena.     

Robowell: An Automated Process for Monitoring Ground Water Quality Using Established Sampling Protocols

Robowell is an automated process for monitoring selected ground water quality properties and constituents by pumping a well or multilevel sampler. Robowell was developed and tested to provide a cost-effective monitoring system that meets protocols expected for manual sampling. The process uses commercially available electronics, instrumentation, and hardware, so it can be configured to monitor ground water quality using the equipment, purge protocol, and monitoring well design most appropriate for the monitoring site and the contaminants of interest. A Robowell prototype was installed on a sewage-treatment plant infiltration bed that overlies a well-studied u neon fined sand and gravel aquifer at the Massachusetts Military Reservation, Cape Cod, Massachusetts, during a time when two distinct plumes of constituents were released. The prototype was operated from May 10 to November 13, 1996, and quality-assurance/quality-control measurements demonstrated that the data obtained by the automated method was equivalent to data obtained by manual sampling methods using the same sampling protocols. Water level, specific conductance, pH, water temperature, dissolved oxygen, and dissolved ammonium were monitored by the prototype as the wells were purged according to U.S. Geological Survey (LJSGS) ground water sampling protocols. Remote access to the data record, via phone modem communications, indicated the arrival of each plume over a few days and the subsequent geochemical reactions over the following weeks. Real-time availability of the monitoring record provided the information needed to initiate manual sampling efforts in response to changes in measured ground water quality, which proved the method and characterized the screened portion of the plume in detail through time. The methods and the case study described are presented to document the process for future use.