溢油分散剂的乳化效果及油滴粒径分布影响因素的研究

以GM-2型溢油分散剂和微普紧急泄漏处理液为研究对象,探究不同条件下其处理120#燃料油的乳化效果及对油滴粒径分布的影响。结果表明,提高温度、分散剂与燃料油配比(DOR)以及加强波浪作用均可显著提高溢油分散剂的乳化效果,油滴粒径更小,分布更集中,且液面下较浅处的乳化液浓度较大。GM-2型分散剂乳化效果优于微普分散剂。当温度为25℃,DOR为30%,推波频率为1次/s时,GM乳化效果达到最佳,油滴平均粒径为5.62?m。     

Fate of dispersed marine fuel oil in sediment under pre-spill application strategy

A comparison of the movement of dispersed oil in marine sediment under two dispersant application scenarios, applied prior to and after oil being spilled overboard, was examined. The pre-spill application scenario caused much less oil to be retained in the top sediment than post-spill scenario. The difference in oil retention in the top sediment between pre- and post-spill application scenario increased with increase in fuel oil temperature. For fuel oil above 40 °C, the difference in the effect of pre-spill application strategy under various water temperatures was negligible. When soap water was used as replacement for chemical dispersant, almost one-half as much oil was retained in the top sediment as that when using chemical dispersant. The adsorption of dispersed oil to the top sediment was almost proportionally decreased with doubling of soap dosage.     

Biodegradation of dispersed marine fuel oil in sediment under engineered pre-spill application strategy

Biodegradation of marine fuel oil was studied by monitoring changes in residual oil and populations of microorganisms in marine sediments. Biodegradation rates for dispersant and soap water were 2.09 and 2.27 g/kg per day, respectively, under pre-application strategy, suggesting that the strategy may promote MFO dispersion and provide with sufficient source of food. The effect of temperature on the effectiveness of pre-application strategy is particularly obvious for the growth of fungi and Pseudomonas maltophilia. The effect of pre-application of soap water on the tolerance of aerobic bacteria, Escherichia coli, and P. maltophilia, was gradually diminished within 25–33 days.     

溢油扩展、漂移及扩散预测技术研究进展

海上溢油灾害会严重破坏中国近海海洋环境,还会直接危害我国经济发展。因此,开展溢油预测预警技术研究是非常有必要的,能够为海上溢油应急响应提供技术支撑。本文综述了溢油扩展、漂移及扩散数值预测技术的发展过程及相关研究成果,包括溢油扩展模型、溢油漂移与扩散模型、溢油预测预警系统,为未来开展溢油应急工作提供了理论依据和参考。     

黏性土淹没射流破土实验研究

海底水力喷射开沟技术在海底管道、光缆埋设等工程中得到广泛应用,然而黏土尤其是硬质黏性土中的水力开沟施工较为困难,为阐明其中的破土机制,开展了二维垂向淹没射流开沟物理模拟实验。通过观察射流破土的过程,发现:软黏土与硬质黏性土中冲坑发展的特点有所不同,破土机制也存在差异。射流对硬质黏性土的破坏中,压力导致的剪切破坏起到很大作用,在土力学原理上近似于地基土整体剪切破坏,据此建立了硬质黏性土射流破土模型,同时提出冲坑颈口直径在硬质黏性土冲坑形态中的重要性,并以此取代原有的冲坑直径作为一个预测指标。     

Three-dimensional numerical simulation for transport of oil spills in seas

This study extends previous two-dimensional research [Wang, S.D., Shen, Y.M., Zheng, Y.H., 2005. Two-dimensional numerical simulation for transport and fate of oil spills in seas. Ocean Engineering 32, 1556–1571] to three dimensions in order to investigate the vertical dispersion/motion of the spilled oil slick, which is a more realistic model of the motion of the spilled oil. To this end, a three-dimensional (3-D) model, based on the particle approach, is developed for simulating oil spill transport and fate in seas. The amount of oil released at sea is distributed among a large number of particles tracked individually. These particles are driven by a combination of water current, wave- and wind-induced speed and move in a 3-D space. Horizontal and vertical diffusion are taken into account using a random walk technique. The model simulates the most significant processes which affect the motion of oil particles, such as advection, surface spreading, evaporation, dissolution, emulsification, turbulent diffusion, the interaction of the oil particles with the shoreline, sedimentation and the temporal variations of oil viscosity, density and surface tension. In addition, the processes of hydrolysis, photo-oxidation and biodegradation are also considered in this model. The model has been applied to simulate the oil spill accident in the Bohai Sea.     

胜利原油和Corexit 9527分散剂对海洋围隔实验生态系中浮游动物的影响

本文分析了Corexit 9527分散剂和中国胜利原油对海洋实验生态系中浮游动物群落的影响,得出的主要结论是:1.单独的Corexit 9527对草食性桡足类的生长发育稍有抑制作用,但种群可得恢复和发展,对肉食性桡足类及其他各类浮游动物没有影响;2.Corexit 9527和原油的混合物对所有类别浮游动物均有极大的抑制作用,它导致种群的迅速缩小且无法得以恢复。     

Experimental and numerical hydrodynamic analysis of a stepped planing hull

This work addresses the experimental and numerical study of a stepped planing hull and the related fluid dynamics phenomena typically occurring in the stepped hull in the unwetted aft body area behind the step. In the last few years, the interest in high-speed planing crafts, with low weight-to-power ratios, has been increasing significantly, and, in such context, naval architects have been orienting toward the stepped hull solution. Stepped planing hulls ensure good dynamic stability and seakeeping qualities at high speeds. This is mainly due to the reduction of the wetted area, which is caused by the flow separation occurring at the step. This paper presents the experimental results of towing tank tests in calm water on a single-step hull model, which is the first model of a new systematic series. The same flow conditions are analyzed via Reynolds Averaged Navier-Stokes (RANS) and Large Eddy Simulations (LES), with different moving mesh techniques (overset/chimera and morphing grid), performed at different model speeds. The numerical results are in accordance with experimental data, and overset/chimera grid is found to be the best approach between the analyzed ones. The flow patterns obtained numerically through LES on a refined grid appear similar to the ones observed in towing tank investigations through photographic acquisitions. These flow patterns are dominated by a rather complex 3D arrangement of vortices originating from air spillage at both sides of the step. The understanding of these phenomena is important for the effectiveness of stepped hull designs.     

Experimental and numerical study on vortex-induced motions of a deep-draft semi-submersible

An experimental study on vortex-induced motions (VIM) of a deep-draft semi-submersible (DDS) was carried out in a towing tank, with the aim to investigate the VIM effects on the overall hydrodynamics of the structure. In order to study the fluid physics associated with VIM of the DDS, a comprehensive numerical simulation was conducted to examine the characteristics of vortex shedding processes and their interactions due to multiple cylindrical columns. The experimental measurements were obtained for horizontal plane motions including transverse, in-line and yaw motions as well as drag and lift forces on the structure. Spectral analysis was further carried out based on the recorded force time history. These data were subsequently used to validate the numerical model. Detailed numerical results on the vortex flow characteristics revealed that during the “lock-in”, the vortex shedding processes of the upstream columns enhance the vortex shedding processes of the downstream columns leading to the rapid increase of the magnitude of VIM. In addition to the experimental measurements, for the two uniform flow incidences (0° and 45°) investigated, comprehensive numerical data of the parametric study on the VIM characteristics at a wide range of current strength will also serve as quality benchmarks for future study and provide guidance for practical design.     

同向流中椭圆喷口射流掺混特性实验研究

采用激光诱导荧光技术(laser induced fluorescence-LIF)对同向流动环境中具有不同喷口高宽比(aspect ratio-AR)、射流比(velocity ratio-VR)的椭圆喷口射流与圆喷口射流的标量物质浓度场进行可视化和定量化研究。系统研究了同向流动环境中椭圆喷口射流浓度场的各种掺混稀释特性:中心线稀释度,射流扩展宽度,下游不同断面上的时均浓度分布和紊动强度分布。采用紊流理论和量纲分析方法对实验数据进行分析讨论,给出同向流动环境中受动量控制的椭圆射流稀释度预报方法,提出该类椭圆射流稀释度预报方法归并到已有圆射流系列预报模型中的实现途径,比较了具有相同出口超值动量Me0的圆射流与椭圆射流的沿程稀释度变化。由于椭圆射流比圆射流具有更高的稀释度增长比率,说明椭圆射流比圆射流具有更好的掺混稀释效果。     

Numerical modelling of boom and oil spill with SPH

The protection of coastal areas against oil pollution is often addressed with the use of floating booms. These bodies are subject to an empirical design always based on physical models. Indeed, the numerical modelling of a two-phase flow (oil and water) with complicated free surface in the vicinity of a floating body is a challenging issue. The Smoothed Particle Hydrodynamics (SPH) Lagrangian numerical method is appropriate to such simulations since it allows the modelling of complex motions and fluid–structure interactions. In this paper we first study the mechanism of oil leakage by entrainment due to combined turbulent production and buoyancy. Then, we present the main features of the SPH method in a turbulent formalism and apply this model to predict the motion of a boom and an oil spill in an open-channel and a wave flume, for three types of oil (heavy, light and emulsion). Numerical results are compared to experiments and used to depict criteria for oil leakage. It appears that oil leakage by entrainment occurs when the surface water velocity upstream the boom exceeds a critical value which was estimated around 0.5 m/s for a light oil under steady current. A more accurate criterion is derived from theoretical considerations and successfully compared to numerical experiments. In the case of wave flume, no validation from experiments could be made. However, it appears that leakage occurs from a critical wave height between 0.5 and 1.0 m, for the tested wave period of 4 s. A more extended panel of numerical tests would allow a better knowledge of the involved mechanisms and critical parameters. An extensive use of this model should extend our knowledge regarding the mechanisms of oil leakage under a boom and allow a better and easier design of booms in the near future.     

Experimental and numerical investigations of monopile ringing in irregular finite-depth water waves

In storm conditions, nonlinear wave loads on monopile offshore wind turbines can induce resonant ringing-type responses. Efficient, validated methods which capture such events in irregular waves in intermediate or shallow water depth conditions are needed for design. Dedicated experiments and numerical studies were performed toward this goal. The extensive experimental campaign at 1:48 scale was carried out for Statoil related to the development of the Dudgeon wind farm, and included both a rigid model and a flexible, pitching-type, single degree-of-freedom model. Twenty 3-hour duration realizations for 4 sea states and 2 water depths were tested for each model. A high level of repeatability in ringing events was observed. Uncertainties in the experimental results were critically examined. The stochastic variation in the 3-hour maximum bending moment at the sea bed was significantly larger than the random variation in repetition tests, and highlighted the need for a good statistical basis in design. Numerical simulations using a beam element model with a modified Morison wave load model and second order wave kinematics gave reasonable prediction of the ringing response of the flexible model, and of the measured excitation forces on the rigid model in the absence of slamming. The numerical model was also used to investigate the sensitivity of the responses with respect to damping and natural period. A simple single degree-of-freedom model was shown to behave similarly to a fully flexible model when considering changes in natural frequency and damping.     

Experimental study on hydrodynamic performance of SWATH vessels in calm water and in head waves

An extensive experimental investigation on four SWATH hull forms has been conducted in calm water and in regular waves at University of Naples Federico II. Calm water tests have been analyzed in the range of Froude number Fr_T from 0.1 to 0.6. For all four SWATH configurations at the speed, corresponding to Fr_T 0.32, the behaviour in regular waves has been tested. The results of heave, pitch and vertical accelerations are presented in nondimensional form as RAO. For the “most promising” SWATH #4 configuration, a set of stabilizing fins have been designed and an active stabilization system has been developed. The developed SWATH#5 has been tested in calm water on three displacements in the range of Fr_T from 0.1 to 0.65. The dynamic wetted surface has been identified and the residual resistance coefficient C_R as well as R_T/Δ are reported. Seakeeping tests have been performed in regular head sea and in head and following irregular sea at Fr_T = 0.50. The conditions for the occurrence of dynamic longitudinal instabilities have been identified. The results allows to comment the effect of slenderness of struts and SWATH’s immersed bodies on resistance and seakeeping and concerns the applicability of SWATH concept to small craft.     

Dynamic response of a monopile wind turbine in waves: Experimental uncertainty analysis for validation of numerical tools

The responses of a monopile offshore wind turbine subjected to irregular wave loads are investigated numerically and experimentally, considering a range of sea states. An extensive experimental campaign was carried out on a fully flexible model, representative of a 5 MW offshore wind turbine, at 1:40 scale. An assessment of the experimental results for the response amplitude operator for regular waves and the 90th percentile seabed bending moment in long-crested irregular waves is carried out using two models (analytical and numerical) for uncertainty propagation, suggesting that bias errors in the model properties and in the wave elevation contribute the most to the total uncertainty. The experimental results are also compared to a numerical model using beam elements and Morison-type wave loads with second order wave kinematics. The numerical model does not capture all of the responses within the level of uncertainty of the experiments, and possible reasons for the discrepancies are discussed.     

Effects of oil and a dispersant on intertidal organisms in field experiments with a Mesocosm,the Bremerhaven Caisson

Three medium-scale field experiments on the effects of oil, a dispersant and an oil/dispersant mixture were carried out in an intertidal mud flat ecosystem of the Wadden Sea (German Bight). For six successive tides each contaminant was added to the water enclosed in a mesocosm during submersion of the flat. The fate of the oil in the sediment and effects on phytobenthos, bacteria and macrozoobenthos were studied. Penetration of the oil into the sediment was mainly observed at the surface layer. were present when oil was chemically dispersed. Sublethal effects were found in some macrofauna species (reduced feeding activity) and in phytobenthic organisms (increased activity); oil degrading bacteria increased. No major effects were observed when the dispersant alone was added.     

Development of oil formation theories and their importance for peak oil

This paper reviews the historical development of both biogenic and non-biogenic petroleum formation. It also examines the recent claim that the so-called “abiotic” oil formation theory undermines the concept of “peak oil,” i.e. the notion that world oil production is destined to reach a maximum that will be followed by an irreversible decline. We show that peak oil is first and foremost a matter of production flows. Consequently, the mechanism of oil formation does not strongly affect depletion. We would need to revise the theory beyond peak oil only for the extreme — and unlikely — hypothesis of abiotic petroleum formation.     

The effects of bunker c oil and an oil dispersant: Part 2—effects on the accumulation of chlorine-labelled bunker c oil in various fish tissues

Chlorine-labelled Bunker C oil was used to measure the differential accumulation in various fish tissues between a hydrocarbon and a hydrocarbon/oil dispersant mixture. There is an increased movement of the emulsified oil across the gill structure although accumulation by this tissue is similar for both test conditions. The liver and kidney showed significantly higher levels of the oil/dispersant mixture whereas muscle accumulations were less dramatic. The amounts of Bunker C found in the gills, liver and kidney were considerably higher than that found in the muscle. Consideration was given to the varying capability of the blood to carry polar, compared with non-polar, compounds.     

Environmental crime and judicial rectification of the Prestige oil spill: The polluter pays

The enforcement of institutional rules requires the judicial system to perform well. In the case of oil spills, courts are key actors in determining the allocation of liabilities according to international and national norms. In 2002, the Prestige oil spill led to a major environmental disaster on the coasts of Spain, France and Portugal. The limitations of liability provided by the International Regime of Civil Liability and Compensation for Oil Pollution Damage have prevented the polluters from fully compensating injured parties for the damage the spill produced. In 2013, the Spanish Provincial Court of A Coruña condemned the captain of the tanker for disobedience, but no environmental crime was found; therefore, no further civil liabilities were incurred. Nevertheless, in 2016, the Spanish Supreme Court overruled the ruling of the provincial court and proclaimed the existence of an environmental crime. This judicial rectification changed the allocation of liabilities, extended the application of the polluter-pays principle, and opened a different stage for estimating and covering the costs of the damage. This paper presents a highly relevant case study that analyses the new situation involving oil spills and the distribution of liabilities within the current international regime.     

Acute sublethal toxicity of MV Rena contaminants (heavy fuel oil,oil dispersant and cryolite) to finfish and rock lobster

ABSTRACT

The wreck of the MV Rena in October 2011 discharged large quantities of potentially toxic materials in the coastal marine environment of the Bay of Plenty, New Zealand. We evaluated sublethal effects of the water soluble fractions of physically and chemically dispersed heavy fuel oil (HFO) and the water soluble fraction of cryolite on the haematology of subadult or adult snapper (Chrysophrys auratus), spotted wrasse (Notolabrus celidotus) and red rock lobster (Jasus edwardsii). Small but transient effects occurred, the most significant of which were changes in circulating immune cell populations in fish and lobster that recovered by the conclusion of a 96-h exposure period. No post-exposure effects were observed during a 10-day recovery in toxicant-free seawater. Corexit 9500 oil dispersant increased polycyclic aromatic hydrocarbon (PAH) uptake from HFO in fish and lobster by around two-fold and four-fold, respectively, and caused a larger change in immune cell abundance in snapper than exposure to HFO alone. While depuration of PAHs was more rapid in fish than lobster, significantly elevated PAH levels were still evident after 10 days of depuration.