福建漳平洛阳铁矿成矿地质特征及找矿前景分析

漳平洛阳铁矿是一个中型铁矿床,共(伴)生有锌、硫、钼矿等,前人认为铁矿床的成因主要有矽卡岩型、沉积-热液改造型、火山沉积-热液改造型、复合-叠加层状型等4种.在综合分析前人资料的基础上,从研究区内铁矿控矿地质条件出发,对其重新总结和认识,认为洛阳铁矿床为层控矽卡岩型矿床,为洛阳铁矿深边部找矿提供依据.     

中国叠生型铁矿床成矿特征探讨

叠生成矿作用主要是指早期成矿作用被晚期成矿作用叠加、复合和改造。晚期成矿作用的性质常与早期成矿作用不同,也就是说,在早先己有矿床(或矿体、矿源层)的基础上,叠加复合了晚期成矿作用,即成矿时间上有先后、空间产出上有重叠、并对早先形成的矿床进行复杂的复合、叠加和改造,使成矿作用具有多样性、复杂性,并可形成大矿、富矿。铁矿床中叠生成矿作用广泛发育。按矿床或矿体产出和形成的地质特征,中国叠生型铁矿床可分为风化淋滤型、热液叠加改造型和热液叠加复合型3个亚类。风化淋滤型铁矿床在中国分布有限,规模不大,工业利用价值不大,因而中国的叠生型铁矿床主要是指热液叠加改造型和热液叠加复合型两个亚类。热液叠加改造型主要是指早期的铁矿床(或矿体、矿源层)经后期热液叠加改造,使早期的较贫铁矿床(或矿体、矿源层)成为较富铁矿床(或矿体),这是中国BIF型铁矿床中最重要的富铁矿类型,以鞍本地区弓长岭二矿区为典型代表。弓长岭二矿区铁矿,早期在新太古代形成条带状磁铁石英岩(2528 Ma,贫矿石),后期在古元古代,含矿热液交代改造贫铁矿形成富铁矿(1840 Ma)。热液叠加复合型主要是指后期脉型铁(或稀土元素等)矿床叠加在早期(沉积或其他成因)铁等矿床上而形成的矿床,如白云鄂博铁-铌-稀土元素矿床和黔西菱铁矿矿床。白云鄂博铁-铌-稀土元素矿床的形成与火成碳酸岩有关,在中元古代(1.3 Ga)左右,区内火成碳酸岩的侵位,在早期主要形成以岩浆熔离作用为主的铁-铌-稀土元素矿,晚期叠加了加里东期稀土-铌矿化热液脉。古陆边缘构造带或陆内活化带是形成叠生型铁矿床的有利构造空间,较大的地球化学块体,为形成多期、多成因的矿床提供物质来源,叠生型铁矿床的形成明显受构造的控制。叠生成矿是复杂地质过程的一种具体表现。热液叠加改造型和热液叠加复合型的叠生型铁矿床的形成是因中国独特的大地构造环境决定的。叠生成矿作用的研究,尚处在初步阶段。加强对叠生成矿作用的研究,了解其形成的地质背景、成矿机制、作用过程、控矿因素等,对发展矿床学研究,认识区域成矿特征和指导地质找矿具有重要的理论和实际意义。     

福建大田琴山铁矿地质特征及成因初探

大田琴山铁矿主矿体呈似层状贮存于晚古生代经畲组中,其形态和产状受地层控制明显,次要矿体以脉状、透镜状居多;岩浆期后热液叠加、改造显著,属沉积-热液改造型矿床.     

论华南层控锡矿的地质特征与形成机制

华南加里东地槽区内存在一类受不同时代地层控制的层控锡矿。这类矿床兼有同生和后生、沉积和热液叠加的双重特点。矿床的形成是在矿源层的基础上经热液叠加改造的结果。根据热浪叠加改造的程度和特点,本文将华南的层控锡矿划分为沉积-改造、沉积-变质和沉积-热浪叠加三种类型,并对这类矿床的成因问题进行了探讨。     

安徽庐江龙桥铁矿床金云母40Ar/39Ar定年:矿床成因的年代学证据

龙桥铁矿床是安徽庐枞盆地中的重要矿床,铁矿体主要赋存在中三叠统东马鞍山组。采集龙桥铁矿井下-355m中段矽卡岩矿体中与磁铁矿共生的金云母进行了40 Ar/39 Ar同位素年代学测试,得到坪年龄(147.13±1.45)Ma,代表了磁铁矿的形成时代。本区在中三叠世沉积了一套富含铁质的矿胚层;晚侏罗世-早白垩世,由于东部岩石圈伸展及郯庐断裂走滑热事件的影响,深部的成矿物质和热液开始上升并叠加改造含铁沉积矿胚层,热液叠加改造成矿作用从147Ma或更早就已经开始,此后矿床经历了区域火山喷发和正长岩体侵入等多次热事件的持续叠加改造成矿作用。龙桥铁矿矿床成因为沉积—热液叠加改造型。     

青海省典型铁矿矿床特征及其成矿系列的浅析

青海省铁矿床(点)成因类型可划分为镁铁-超镁铁岩浆成矿系列的结晶分异型矿床;壳幔型中酸性岩浆成矿系列的热液型、矽卡岩型矿床;火山喷流-沉积成矿系列的层控型矿床;叠加改造成矿系列的层控改造型、改造热液型、沉积变质型矿床;沉积喷流成矿系列的层控型矿床;沉积成矿系列的陆、海相沉积型矿床.通过对这些成矿系列的典型铁矿矿床特征的研究,从其成矿构造地质环境分析,许多铁多金属矿床(点)均具有形成大型以上矿床的成矿地质条件,且多伴生铜、铅、锌、金银等多金属矿产.研究认为,在今后的找矿勘查过程中,应利用成矿系列的规律,并注重对共(伴)生组分的综合评价,这对扩大全省的找矿远景,提高资源综合利用水平,提高铁矿床技术经济价值具有重要的意义.     

福建龙岩马坑铁矿床成因的探讨

马坑铁矿是福建最大的铁矿床。近年来中国地质科学院矿床所、南京地矿所、长春地质学院、南京大学、福州大学、南京地质学校等单位对该矿床分别进行了工作，对其成因则有接触交代成矿说、复合叠生层状矿床说、陆源沉积热液叠加改造成矿说与海相火山沉积热液改造成矿说。     

褶皱构造与层控矿床

层控矿床是指那些成矿物质在同生沉积的基础上经后期地质作用改造而形成的、受一定地层层位、岩性和层状构造控制的矿床.在成因上属复生类矿床.沉积矿床或矿源层由于古地下热水溶液的改造而成层控矿床(沉积-再造型);也可由变质和混合岩化作用而成沉积-变质型;或是在沉积成矿的基础上受后期岩浆热液的叠加所致(沉积或沉积变质-叠加型).     

新疆查岗诺尔铁矿地质特征及成矿机理探讨

查岗诺尔铁矿床位于伊犁地块北缘博罗科努岛弧带.矿区广泛出露石炭纪火山岩.矿区的主要矿物共生组合为磁铁矿+石榴石+阳起石(绿帘石)组合.矿床大致可以分为早、中、晚三个成矿期.矿床是由富铁的安山质岩浆分异形成,并且后期受到热液作用的叠加改造.隐爆作用伴随整个成矿过程.该矿床成因上属于受到热液作用叠加改造的火山岩型铁矿床.     

四川省盐源县烂纸厂铁矿成因浅析

通过对烂纸厂铁矿床矿体特征、含矿层位、矿石组构、磁铁矿的某些化学特征及与其他各类型的铁矿床的对比,探讨了矿床的成因。综合认为烂纸厂铁矿床为与陆缘浅海沉积作用有关的铁矿床,同时遭受了后期火山热液的叠加改造,其成因类型为沉积-热液叠加改造型。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

Petrographic, mineralogy, and geochemistry of coals of Pabedana, Kerman Province, Central Iran

This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.     

Coprecipitation of Ti,Mo, Sn and Sb with fluorides and application to determination of B,Ti, Zr,Nb, Mo,Sn, Sb,Hf and Ta by ICP-MS

We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l^− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO₂.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.