Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Heterogeneity in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream

Spatial and temporal variability in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream was investigated. Four locations in a 150‐m reach of the stream were studied using hydrometric and hydrochemical tracing techniques. A high degree of hydrological connectivity between the riparian hillslope and the stream channel was indicated at two locations, where hydrochemical changes and hydraulic gradients indicated that the hyporheic zone was dominated by upwelling ground water. The chemistry of ground water reflected relatively long residence times and reducing conditions with high levels of alkalinity and conductivity, low dissolved oxygen (DO) and nitrate. At the other locations, connectivity was less evident and, at most times, the hyporheic zone was dominated by downwelling stream water characterized by high DO, low alkalinity and conductivity. Substantial variability in hyporheic chemistry was evident at fine (<10 m) spatial scales and changed rapidly over the course of hydrological events. The nature of the hydrochemical response varied among locations depending on the strength of local ground water influence. It is suggested that greater emphasis on spatial and temporal heterogeneity in ground water–surface water interactions in the hyporheic zone is necessary for a consideration of hydrochemical effects on many aspects of stream ecology. For example, the survival of salmonid eggs in hyporheic gravels varied considerably among the locations studied and was shown to be associated with variation in interstitial chemistry. River restoration schemes and watershed management strategies based only on the surface expression of catchment characteristics risk excluding consideration of potentially critical subsurface processes. Copyright © 2002 John Wiley & Sons, Ltd.     

Contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments

We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.     

Contributing sources to baseflow in pre‐alpine headwaters using spatial snapshot sampling

Mountainous headwaters consist of different landscape units including forests, meadows and wetlands. In these headwaters it is unclear which landscape units contribute what percentage to baseflow. In this study, we analysed spatiotemporal differences in baseflow isotope and hydrochemistry to identify catchment‐scale runoff contribution. Three baseflow snapshot sampling campaigns were performed in the Swiss pre‐alpine headwater catchment of the Zwäckentobel (4.25 km²) and six of its adjacent subcatchments. The spatial and temporal variability of δ²H, Ca, DOC, AT, pH, SO₄, Mg and H₄SiO₄ of streamflow, groundwater and spring water samples was analysed and related to catchment area and wetland percentage using bivariate and multivariate methods. Our study found that in the six subcatchments, with variable arrangements of landscape units, the inter‐ and intra catchment variability of isotopic and hydrochemical compositions was small and generally not significant. Stream samples were distinctly different from shallow groundwater. An upper spring zone located near the water divide above 1,400 m and a larger wetland were identified by their distinct spatial isotopic and hydrochemical composition. The upstream wetland percentage was not correlated to the hydrochemical streamflow composition, suggesting that wetlands were less connected and act as passive features with a negligible contribution to baseflow runoff. The isotopic and hydrochemical composition of baseflow changed slightly from the upper spring zone towards the subcatchment outlets and corresponded to the signature of deep groundwater. Our results confirm the need and benefits of spatially distributed snapshot sampling to derive process understanding of heterogeneous headwaters during baseflow. Copyright © 2015 John Wiley & Sons, Ltd.     

Modelling stream flow for use in ecological studies in a large,arid zone river,central Australia

Australian arid zone ephemeral rivers are typically unregulated and maintain a high level of biodiversity and ecological health. Understanding the ecosystem functions of these rivers requires an understanding of their hydrology. These rivers are typified by highly variable hydrological regimes and a paucity, often a complete absence, of hydrological data to describe these flow regimes. A daily time‐step, grid‐based, conceptual rainfall–runoff model was developed for the previously uninstrumented Neales River in the arid zone of northern South Australia. Hourly, logged stage data provided a record of stream‐flow events in the river system. In conjunction with opportunistic gaugings of stream‐flow events, these data were used in the calibration of the model. The poorly constrained spatial variability of rainfall distribution and catchment characteristics (e.g. storage depths) limited the accuracy of the model in replicating the absolute magnitudes and volumes of stream‐flow events. In particular, small but ecologically important flow events were poorly modelled. Model performance was improved by the application of catchment‐wide processes replicating quick runoff from high intensity rainfall and improving the area inundated versus discharge relationship in the channel sections of the model. Representing areas of high and low soil moisture storage depths in the hillslope areas of the catchment also improved the model performance. The need for some explicit representation of the spatial variability of catchment characteristics (e.g. channel/floodplain, low storage hillslope and high storage hillslope) to effectively model the range of stream‐flow events makes the development of relatively complex rainfall–runoff models necessary for multisite ecological studies in large, ungauged arid zone catchments. Grid‐based conceptual models provide a good balance between providing the capacity to easily define land types with differing rainfall–runoff responses, flexibility in defining data output points and a parsimonious water‐balance–routing model. Copyright © 2004 John Wiley & Sons, Ltd.     

End member and Bayesian mixing models consistently indicate near-surface flowpath dominance in a pristine humid tropical rainforest

The impacts of forest conversion on runoff generation in the tropics have received much interest, but scientific progress is still hampered by challenging fieldwork conditions and limited knowledge about runoff mechanisms. Here, we assessed the runoff generation, flow paths and water source dynamics of a pristine rainforest catchment in Costa Rica using end member mixing analysis (EMMA) and a Bayesian mixing model (MixSIAR). Geochemical tracer data collected over a 4-week field campaign were combined with tritium data used to assess potential deeper groundwater flow pathways to the perennial stream. The streamflow composition was best captured using three end-members, namely throughfall, shallow (5–15 cm) and deeper (15–50 cm) soil water. We estimated the end-member contributions to the main stream and two tributaries using the two mixing approaches and found good agreement between results obtained from EMMA and MixSIAR. The system was overwhelmingly dominated by near-surface sources, with little evidence for deeper and older groundwater as tritium-derived baseflow mean transit time was between 2.0 and 4.4 years. The shallow soil flow pathway dominated streamflow contributions in the main stream (median 39% and 49% based on EMMA and MixSIAR, respectively), followed by the deeper soil (32% and 31%) and throughfall (25% and 19%). The two tributaries had even greater shallow soil water contributions relative to the main stream (83% and 74% for tributary A and 42% and 63% for tributary B). Tributary B had no detectable deep soil water contribution, reflecting the morphology of the hillslope (steeper slopes, shallower soils and lower vegetation density compared to hillslope A). Despite the short sampling campaign and associated uncertainties, this study allowed to thoroughly assess runoff generation mechanisms in a humid tropical catchment. Our results also provide a first comparison of two increasingly used mixing models and suggest that EMMA and MixSIAR yield comparable estimates of water source partitioning in this tropical, volcanic rainforest environment.     

Physically‐based modelling of double‐peak discharge responses at Slapton Wood catchment

Heavy winter rainfall produces double‐peak hydrographs at the Slapton Wood catchment, Devon, UK. The first peak is saturation‐excess overland flow in the hillslope hollows and the second (i.e. the delayed peak) is subsurface stormflow. The physically‐based spatially‐distributed model SHETRAN is used to try to improve the understanding of the processes that cause the double peaks. A three‐stage (multi‐scale) approach to calibration is used: (1) water balance validation for vertical one‐dimensional flow at arable, grassland and woodland plots; (2) two‐dimensional flow for cross‐sections cutting across the stream valley; and (3) three‐dimensional flow in the full catchment. The main data are for rainfall, stream discharge, evaporation, soil water potential and phreatic surface level. At each scale there was successful comparison with measured responses, using as far as possible parameter values from measurements. There was some calibration but all calibrated values at one scale were used at a larger scale. A large proportion of the subsurface runoff enters the stream from three dry valleys (hillslope hollows), and previous studies have suggested convergence of the water in the three large hollows as being the major mechanism for the production of the delayed peaks. The SHETRAN modelling suggests that the hillslopes that drain directly into the stream are also involved in producing the delayed discharges. The model shows how in the summer most of the catchment is hydraulically disconnected from the stream. In the autumn the catchment eventually ‘wets up’ and shallow subsurface flows are produced, with water deflected laterally along the soil‐bedrock interface producing the delayed peak in the stream hydrograph. Copyright © 2007 John Wiley & Sons, Ltd.     

Experimental evidence of fast groundwater responses in a hillslope/floodplain area in the Black Forest Mountains,Germany

Analysis of water flow pathways from hillslopes to streams is essential for the optimal protection of water resources as well as for ecohydrological studies. This study addresses runoff generation processes at a hillslope and near‐stream shallow groundwater system in the Black Forest Mountains, southwestern Germany. The changing spatial and temporal flow patterns during differing hydrological situations were examined using a combined hydraulic and hydrochemical approach. Groundwater levels at 10 wells, discharge at a near‐stream saturated area, and several natural tracers (deuterium, dissolved silica, and major anions and cations) were observed at different locations during high and low flows. The importance of the groundwater component during flood formation was clearly demonstrated: its contribution was about 80% during a double peak flood event at the saturated area. In addition, a rapid change of the shallow groundwater levels was observed along two transects of groundwater wells in the floodplain. This led to an enhanced groundwater discharge into the saturated area located at the end of one study transect. The amount of groundwater additionally activated during the event was about 30% of total discharge recorded at the outlet of the saturated area. Two alternative hypotheses are discussed to explain this phenomenon: the establishment of locally confined conditions and the development of a pressure wave (hypothesis A), or the significant change of the three‐dimensional groundwater flow lines that caused a large increase of the groundwater catchment at the saturated area during the investigated event (hypothesis B). Even if the exact flow paths and mechanisms could not be clearly identified, the importance of rapid responding hillslope groundwater was undoubtedly demonstrated by a combination of tracer and hydrometric methods. Copyright © 2004 John Wiley & Sons, Ltd.     

A case study in catchment hydrochemistry: Conflicting interpretations from hydrological and chemical observations

Soil water, stream water, groundwater and rain water were sampled through a storm event in a moorland catchment. Samples were analysed for major ions and deuterium. Chloride and deuterium are used as tracers to enable separation of the stream runoff hydrograph into three components: rain, soil and groundwater. The results indicate that rain water arrives in the stream quickly during the event and contributes a significant volume to the runoff peak. The chemical signal in the rain water is, however, significantly damped, apparently due to mixing with soil water held in the catchment before the event. This is further modified before reaching the stream, apparently through mixing with a deeper groundwater component. Interpretation of tracer, chemistry and hydrological data to present an integrated picture of catchment hydrochemical response is difficult due to problems in the chemical and conceptual definition of the flow components.     

Does hillslope trenching enhance groundwater recharge and baseflow in the Peruvian Andes?

As Andean glaciers rapidly retreat due to climate change, the balance of groundwater and glacial meltwater contributions to stream discharge in tropical, proglacial watersheds will change, potentially increasing vulnerability of water resources. The Shullcas River Watershed, near Huancayo, Peru, is fed only partly by the rapidly receding Huaytapallana glaciers (<20% of dry season flow). To potentially increase recharge and therefore increase groundwater derived baseflow, the government and not‐for‐profit organizations have installed trenches along large swaths of hillslope in the Shullcas Watershed. Our study focuses on a nonglacierized subcatchment of the Shullcas River Watershed and has 2 objectives: (a) create a model of the Shullcas groundwater system and assess the controls on stream discharge and (b) investigate the impact of the infiltration trenches on recharge and baseflow. We first collected hydrologic data from the field including a year‐long hydrograph (2015–2016), meteorological data (2011–2016), and infiltration measurements. We use a recharge model to evaluate the impact of trenched hillslopes on infiltration and runoff processes. Finally, we use a 3‐dimensional groundwater model, calibrated to the measured dry season baseflow, to determine the impact of trenching on the catchment. Simulations show that trenched hillslopes receive approximately 3.5% more recharge, relative to precipitation, compared with unaltered hillslopes. The groundwater model indicates that because the groundwater flow system is fast and shallow, incorporating trenched hillslopes (~2% of study subcatchment area) only slightly increases baseflow in the dry season. Furthermore, the location of trenching is an important consideration: Trenching higher in the catchment (further from the river) and in flatter terrain provides more baseflow during the dry season. The results of this study may have important implications for Andean landscape management and water resources.     

Isotope hydrology and water sources in a heavily urbanized stream

Complex networks of both natural and engineered flow paths control the hydrology of streams in major cities through spatio-temporal variations in connection and disconnection of diverse water sources. We used spatially extensive and temporally intensive sampling of water stable isotopes to disentangle the hydrological sources of the heavily urbanized Panke catchment (~220 km²) in the north of Berlin, Germany. The isotopic data enabled us to partition stream water sources across the catchment using a Bayesian mixing analysis. The upper part of the catchment streamflow is dominated by groundwater (~75%) from gravel aquifers. In dry summer periods, streamflow becomes intermittent in the upper catchment, possibly as a result of local groundwater abstractions. Storm drainage dominates the responses to precipitation events. Although such events can dramatically change the isotopic composition of the upper stream network, storm drainage only accounts for 10%–15% of annual streamflow. Moving downstream, subtle changes in sources and isotope signatures occur as catchment characteristics vary and the stream is affected by different tributaries. However, effluents from a wastewater treatment plant (WWTP), serving 700,000 people, dominate stream flow in the lower catchment (~90% of annual runoff) where urbanization effects are more dramatic. The associated increase in sealed surfaces downstream also reduces the relative contribution of groundwater to streamflow. The volume and isotopic composition of storm runoff is again dominated by urban drainage, though in the lower catchment, still only about 10% of annual runoff comes from storm drains. The study shows the potential of stable water isotopes as inexpensive tracers in urban catchments that can provide a more integrated understanding of the complex hydrology of major cities. This offers an important evidence base for guiding the plans to develop and re-develop urban catchments to protect, restore, and enhance their ecological and amenity value.     

A hillslope-based hydrological model using catchment area and width functions

Abstract

A flow-interval hillslope discretization scheme is proposed for catchment hydrological modelling. By this scheme, a two-dimensional catchment is simplified into a one-dimensional cascade of flow intervals linked by the main stream. Each flow interval comprises a set of parallel hillslopes. The hillslope is the fundamental computational unit in the hydrological model providing lateral inflow to the main stream. The size of hillslope is determined by the catchment area and width functions. Catchment runoff is the total of hillslope responses through the river routing. Tests in four Japanese catchments showed that the model performed well on simulating the overall water balance, general flow pattern, and daily and hourly hydrographs of a whole catchment, as well as simultaneous simulation in different subcatchments. Characteristics of catchment hydrological responses and model applicability are discussed.     

Response time and water origin in a steep nested catchment in the Italian Dolomites

In this study, we investigate the surface flow time of rise in response to rainfall and snowmelt events at different spatial scales and the main sources originating channel runoff and spring water in a steep nested headwater catchment (Rio Vauz, Italian Dolomites), characterized by a marked elevation gradient. We monitored precipitation at different elevations and measured water stage/streamflow at the outlet of two rocky subcatchments of the same size, representative of the upper part of the catchment dominated by outcropping bedrock, at the outlet of a soil‐mantled and vegetated subcatchment of similar size but different morphology, and at the outlet of the main catchment. Hydrometric data are coupled with stable isotopes and electrical conductivity sampled from different water sources during five years, and used as tracers in end‐member mixing analysis, application of two component mixing models and analysis of the slope of the dual‐isotope regression line. Results reveal that times of rise are slightly shorter for the two rocky subcatchments, particularly for snowmelt and mixed rainfall/snowmelt events, compared to the soil‐mantled catchment and the entire Rio Vauz Catchment. The highly‐variable tracer signature of the different water sources reflects the geomorphological and geological complexity of the study area. The principal end‐members for channel runoff and spring water are identified in rainfall and snowmelt, which are the dominant water sources in the rocky upper part of the study catchment, and soil water and shallow groundwater, which play a relevant role in originating baseflow and spring water in the soil‐mantled and vegetated lower part of the catchment. Particularly, snowmelt contributes up to 64 ± 8% to spring water in the concave upper parts of the catchment and up to 62 ± 11% to channel runoff in the lower part of the catchment. These results offer new experimental evidences on how Dolomitic catchments capture and store rain water and meltwater, releasing it through a complex network of surface and subsurface flow pathways, and allow for the construction of a preliminary conceptual model on water transmission in snowmelt‐dominated catchments featuring marked elevation gradients.     

Seasonal changes in runoff generation in a small forested mountain catchment

This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.     

Using hysteretic behaviour and hydrograph classification to identify hydrological function across the “hillslope–depression–stream” continuum in a karst catchment

In cockpit karst landscapes, fluxes from upland areas contribute large volumes of water to low-lying depressions and stream flow. Hydrograph hysteresis and similarity between monitoring sites is important for understanding the space–time variability of hydrologic responses across the “hillslope–depression–stream” continuum. In this study, the hysteretic feature of hydrographs was assessed by characterizing the loop-like relationships between responses at upstream sites relative to subsurface discharge at the outlet of a small karst catchment. A classification of hydrograph responses based on the multi-scale smoothing Kernel -derived distance classifies the hydrograph responses on the basis of similarities between hillslope and depression sites, and those at the catchment outlet. Results demonstrate that the temporal and spatial variability of hydrograph hysteresis and similarity between hillslope flow and outlet stream flow can be explained by the local heterogeneity of depression aquifer. Large depression storage deficits emerging in the highly heterogeneous aquifer produce strong hysteresis and multiple relationships of upstream hydrographs relative to the outlet subsurface discharge. In contrast, when depression storage deficits are filled during consecutive rainfall events, depression hydrographs at the high permeability sites are almost synchronous or exhibit a monotonous function with the hydrographs at the outlet. This reduced hydrograph hysteresis enhances preferential flow paths in fractured rocks and conduits that can accelerate the hillslope flow to the outlet. Therefore, classification of hydrograph similarities between any upstream sites and the catchment outlet can help to identify the dominant hydrological functions in the heterogeneous karst catchment.     

Spatial and temporal variability of groundwater dynamics in a sub‐Mediterranean mountain catchment

The temporal and spatial dynamics of groundwater was investigated in a small catchment in the Spanish Pyrenees, which was extensively used for agriculture in the past. Analysis of the water table fluctuations at five locations over a 6‐year period demonstrated that the groundwater dynamics had a marked seasonal cycle involving a wetting‐up period that commenced with the first autumn rainfall events, a saturation period during winter and spring and a drying‐down period from the end of spring until the end of the summer. The length of the saturation period showed great interannual variability, which was mainly influenced by the rainfall and evapotranspiration characteristics. There was marked spatial variability in the water table, especially during the wetting‐up period, which could be related to differences in slope and drainage area, geomorphology, soil properties and local topography. Areas contributing to runoff generation were identified within the catchment by field mapping of moisture conditions. Areas contributing to infiltration excess runoff were correlated with former cultivated fields affected by severe sheetwash erosion. Areas contributing to saturation excess runoff were characterized by a marked spatial dynamics associated with catchment wetness conditions. The saturation spatial pattern, which was partially related to the topographic index, was very patchy throughout the catchment, suggesting the influence of other factors associated with past agricultural activities, including changes in local topography and soil properties. The relationship between water table levels and stream flow was weak, especially during the wetting‐up period, suggesting little connection between ground water and the hydrological response, at least at some locations. The results suggest that in drier and human‐disturbed environments, such as sub‐Mediterranean mountains, saturation patterns cannot be represented only by the general topography of the catchment. They also suggest that groundwater storage and runoff is not a succession of steady‐state flow conditions, as assumed in most hydrological models. Copyright © 2013 John Wiley & Sons, Ltd.     

Identifying and linking source areas of flow and P transport in dairy‐grazed headwater catchments,North Island,New Zealand

We examined the applicability of the critical‐source area (CSA) concept to the dairy‐grazed 192‐ha Upper Toenepi catchment and its 8·7‐ha Kiwitahi sub‐catchment, New Zealand. We evaluated if phosphorus (P) transport from land into stream is dominated by saturation‐excess (SE) and infiltration‐excess (IE) runoff during stormflow and by sub‐surface (<1·5 m depth) flows during baseflow. We measured stream flow and shallow groundwater levels, collected monthly stream, tile drain (TDA) and groundwater samples, and flow‐proportional stream samples from the Kiwitahi sub‐catchment, and determined their dissolved reactive phosphorus (DRP) and total phosphorus (TP) concentrations. In the Kiwitahi sub‐catchment, during storm events, IE contributions were significant. Contributions from SE appeared significant in the Upper Toenepi catchment. However, in both catchments, sub‐surface contributions dominated stormflow and baseflow periods. Absence of water table at the surface and the water table gradient towards the stream indicated that P transport during events was not limited to surface runoff. The dynamics of the groundwater table and the occurrence of SE areas were influenced by proximity to the stream and hillslope positions. Baseflow accounted for 42% of the annual flow in the Kiwitahi sub‐catchment, and contributed 37 and 52% to the DRP and TP loads, respectively. The P transport during baseflow appeared equally important as P losses from CSAs during stormflow. The close resemblance in P levels between groundwater and stream samples during baseflow demonstrates the importance of shallow groundwater for stream flow. In the Upper Toenepi catchment, contributions from effluent ponds (EFFs) dominated P loads. Management strategies should focus on controlling P release from EFFs, and on decreasing Olsen P concentrations in soil to minimize leaching of P via sub‐surface flow to streams. Research is needed to quantify the role of sub‐surface flow as well as to expand management strategies to minimize P transfers during stormflow and baseflow conditions. Copyright © 2010 John Wiley & Sons, Ltd.     

Quantifying aggregation and change in runoff source in accordance with catchment area increase in a forested headwater catchment

There has been a great deal of research interest regarding changes in flow path/runoff source with increases in catchment area. However, there have been very few quantitative studies taking subscale variability and convergence of flow path/runoff source into account, especially in relation to headwater catchments. This study was performed to elucidate how the contributions and discharge rates of subsurface water (water in the soil layer) and groundwater (water in fractured bedrock) aggregate and change with catchment area increase, and to elucidate whether the spatial variability of the discharge rate of groundwater determines the spatial variability of stream discharge or groundwater contribution. The study area was a 5‐km² forested headwater catchment in Japan. We measured stream discharge at 113 points and water chemistry at 159 points under base flow conditions. End‐member mixing analysis was used to separate stream water into subsurface water and groundwater. The contributions of both subsurface water and groundwater had large variability below 1 km². The contribution of subsurface water decreased markedly, while that of groundwater increased markedly, with increases in catchment area. The specific discharge of subsurface water showed a large degree of variability and decreased with catchment area below 0.1 km², becoming almost constant above 0.1 km². The specific discharge of groundwater showed large variability below 1 km² and increased with catchment area. These results indicated that the variabilities of stream discharge and groundwater contribution corresponded well with the variability of the discharge rate of groundwater. However, below 0.1 km², it was necessary to consider variations in the discharge rates of both subsurface water and groundwater. Copyright © 2016 John Wiley & Sons, Ltd.     

Using stable isotopes to identify major flow pathways in a permafrost influenced alpine meadow hillslope during summer rainfall period

Global warming has leaded to permafrost degradation, with potential impacts on the runoff generation processes of permafrost influenced alpine meadow hillslope. Stable isotopes have the potential to trace the complex runoff generation processes. In this study, precipitation, hillslope surface and subsurface runoff, stream water, and mobile soil water (MSW) at different hillslope positions and depths were collected during the summer rainfall period to analyse the major flow pathway based on stable isotopic signatures. The results indicated that (a) compared with precipitation, the δ²H values of MSW showed little temporal variation but strong heterogeneity with enriched isotopic ratios at lower hillslope positions and in deeper soil layers. (b) The δ²H values of middle-slope surface runoff and shallow subsurface flow were similar to those of precipitation and MSW of the same soil layer, respectively. (c) Middle-slope shallow subsurface flow was the major flow pathway of the permafrost influenced alpine meadow hillslope, which turned into surface runoff at the riparian zone before contributing to the streamflow. (d) The slight variation of δ²H values in stream water was shown to be related to mixing processes of new water (precipitation, 2%) and old water (middle-slope shallow subsurface flow, 98%) in the highly transmissive shallow thawed soil layers. It was inferred that supra-permafrost water levels would be lowered to a less conductive, deeper soil layer under further warming and thawing permafrost, which would result in a declined streamflow and delayed runoff peak. This study explained the “rapid mobilization of old water” paradox in permafrost influenced alpine meadow hillslope and improved our understanding of permafrost hillslope hydrology in alpine regions.     

Defining hydrochemical evolution of streamflow through flowpath dynamics in Kawakami headwater catchment,Central Japan

The hydrochemical behaviour of catchments is often investigated by inferring stream chemistry through identification of source areas involved in hydrograph separation analysis, yet its dynamic evolution of hydrologic pathways has received little attention. Intensive hydrometric and hydrochemical measurements were performed during two different storms on March 29, 2001 and August 21–22, 2001 to define hydrochemical evolution under the dynamic of flow pathways in a 5·2 ha first‐order drainage of the Kawakami experimental basin (KEB), Central Japan, a forested headwater catchment with various soil depths (1·8 to 5 m) overlying late Neogene of volcanic bedrocks. The hydraulic potential distribution and flow lines data showed that the change in flow direction, which was controlled by rainfall amount and antecedent wetness of the soil profile, agreed well with the hydrochemical change across the slope segment during the storm. Hydrograph separation predicted by end‐member mixing analysis (EMMA) using Ca²⁺ and SiO₂ showed that near surface riparian, hillslope soil water and deep riparian groundwater were important in stream flow generation. The evidence of decrease in solutes concentration at a depth of 1 m in the hillslope and 0·6 m in the near surface riparian during peak storm suggested a flushing of high solutes concentration. Most of the solutes accumulated in the deep riparian groundwater zone, which was due to prominent downward flow and agreed well with the residence time. The distinct flow pathways and chemistry between the near surface riparian and deep riparian groundwater zones and the linkage hillslope aquifer and near surface riparian reservoir, which controls rapid flow and solutes flushing during the storm event, are in conflict with the typical assumption that the whole riparian zone resets flow pathways and chemical signature of hillslope soil water, as has been reported in a previous study. Copyright © 2005 John Wiley & Sons, Ltd.