Recovery and concentration of suspended solids in the upper rhone river by continuous flow centrifugation

Six stations along the Rhône River from the Rhône Glacier to Lake Geneva were sampled by continuous flow centrifuge for recovery of suspended sediment. The samples were taken four times in the year in both 1982 and 1983. In addition, the mouth of the river was sampled in a like manner every two weeks during 1982 until August 1983. Concentration of sediment and composition did not vary as a function of depth or location across the river. Concentrations varied in time and as a function of flow and samples showed both increasing concentration in suspension and an increase in the proportion of finer particles moving downstream from source to mouth. Only slight variations in texture could be observed down the river as a function of time and appeared to relate to freezing and melting of the Rhône and other headwater glaciers as the primary sediment source. Little variation was observed annually in the texture and composition of the sediment at the river mouth despite large changes in concentration between the high flow summer and low flow winter discharges. These findings are consistent with a well-mixed system in which the suspended sediments are directly related to the primary supply of material from the glaciers.     

Practical aspects of calibrating and selecting unit hydrograph-based models for continuous river flow simulation

Abstract

A continuous simulation rainfall-streamflow modelling approach that identifies unit hydrographs for total streamflow has been applied to an 11-year record from a national hydrometric monitoring network catchment in the UK. The model is of the parametrically parsimonious conceptual model (PPCM) type that can make efficient use of rainfall, streamflow and air temperature data readily available from established national and regional monitoring networks. A multiple split-sample model calibration and simulation analysis is presented that reveals some guiding principles for calibrating and applying PPCMs generally. The inadequacy of a one-dimensional objective function for calibrating best PPCMs is demonstrated. A two-dimensional objective function approach is superior but is shown to be unreliable in some cases, confirming the need for additional critical inspection of other model performance statistics, model parameters and time series plots as an integral part of the model calibration process. A strong tendency evident from the multiple split-sample analysis is that, for the catchment studied, models that fit relatively well in calibration mode perform relatively poorly in simulation mode.     

Effects of coal contamination on early life history processes of a reef-building coral,Acropora tenuis

Successful reproduction and larval dispersal are important for the persistence of marine invertebrate populations, and these early life history processes can be sensitive to marine pollution. Coal is emerging as a contaminant of interest due to the proximity of ports and shipping lanes to coral reefs. To assess the potential hazard of this contaminant, gametes, newly developed embryos, larvae and juveniles of the coral Acropora tenuis were exposed to a range of coal leachate, suspended coal, and coal smothering treatments. Fertilisation was the most sensitive reproductive process tested. Embryo survivorship decreased with increasing suspended coal concentrations and exposure duration, effects on larval settlement varied between treatments, while effects on juvenile survivorship were minimal. Leachate exposures had negligible effects on fertilisation and larval settlement. These results indicate that coral recruitment could be affected by spills that produce plumes of suspended coal particles which interact with gametes and embryos soon after spawning.     

Examination and parameterization of the root water uptake model from stem water potential and sap flow measurements

A simple field‐based method for directly parameterizing root water uptake models is proposed. Stem psychrometers and sap flow meters are used to measure stem water potential and plant transpiration rate continuously and simultaneously. Predawn stem water potential is selected as a surrogate for root zone soil water potential to examine and parameterize the root water uptake–water stress response functions. The method is applied to two drooping sheoak (Allocasuarina verticillata) trees for a period of 80 days, covering both a dry season and a wet season. The results indicate that the S‐shape function is more appropriate than the Feddes piecewise linear function for drooping sheoak to represent the effect of soil moisture stress on its root water uptake performance. Besides, the water stress function is found to be not only a function of soil moisture but also dependent of the atmospheric demand. As a result, the water stress function is corrected for the effect of atmospheric conditions. Copyright © 2012 John Wiley & Sons, Ltd.     

Mineralogical approach in elucidation of contamination mechanism for toxic trace elements in the environment: Special reference to arsenic contamination in groundwater

Mineralogy and mineral-microbe interactions play a significant role in the environmental contamination of toxic trace elements in groundwater and wetland ecosystems. This review has described the importance of use of TEM that is an essential tool to study the environmental mineralogy and mineral-microbe interactions. Biomineralization process that can advance the succession and evolution of biosphere on the earth has also been summarized briefly. This study explained the role of minerals to control the mechanism of adsorption, desorption, mobility and transport of toxic trace elements, especially arsenic (As) in the groundwater. Finally, this review has explored the evolution of As contamination in groundwater of the Quaternary age deposits including the Holocene and Pleistocene with special reference to groundwater of Bangladesh, West Bengal (India), Vietnam and Inner Mongolia (China).     

Effects of antecedent moisture and macroporosity on infiltration and water flow in frozen soil

Infiltration into frozen soil plays an important role in soil freeze–thaw and snowmelt-driven hydrological processes. To better understand the complex thermal energy and water transport mechanisms involved, the influence of antecedent moisture content and macroporosity on infiltration into frozen soil was investigated. Ponded infiltration experiments on frozen macroporous and non-macroporous soil columns revealed that dry macroporous soil produced infiltration rates reaching 10³ to 10⁴ mm day⁻¹, two to three orders of magnitude larger than dry non-macroporous soil. Results suggest that rapid infiltration and drainage were a result of preferential flow through initially air-filled macropores. Using recorded flow rates and measured macropore characteristics, calculations indicated that a combination of both saturated flow and unsaturated film flow likely occurred within macropores. Under wet conditions, regardless of the presence of macropores, infiltration was restricted by the slow thawing rate of pore ice, producing infiltration rates of 2.8 to 5.0 mm day⁻¹. Reduced preferential flow under wet conditions was attributed to a combination of soil swelling, due to smectite-rich clay (that reduced macropore volume), and pore ice blockage within macropores. In comparison, dry soil column experiments demonstrated that macropores provided conduits for water and thermal energy to bypass the frozen matrix during infiltration, reducing thaw rates compared with non-macroporous soils. Overall, results showed the dominant control of antecedent moisture content on the initiation, timing, and magnitude of infiltration and flow in frozen macroporous soils, as well as the important role of macropore connectivity. The study provides an important data set that can aid the development of hydrological models that consider the interacting effects of soil freeze–thaw and preferential flow on snowmelt partitioning in cold regions.     

Interaction of trace metals with natural particle surfaces: Comparison between adsorption experiments and field measurements

The distribution of the metal ions Zn and Pb between particulate and dissolved phase in river Glatt was studied by field measurements and compared with calculated simulations, using parameters obtained by adsorption experiments with natural suspended particulate material. Differences in distribution coefficients obtained from field data are observed in function of the sampling locations and of the composition of the particulate matter.Experiments in which metal ion solutions are titrated with a suspension of natural particles and analyzed by anodic stripping voltammetry, are interpreted in terms of binding capacities and conditional stability constants of Zn and Pb with the surface sites. Binding constants of a particular metal ion varied very little for all samples. We obtained mean values for the conditional average complex formation constants at pH 8 of: log^cond K _Pb = 9.44 ± 0.18 and log^cond K _Zn = 8.17 ± 0.20. At this pH, binding capacities of 5 10^–3 – 1.7 10^–2 mol/kg of particles were obtained for samples collected at different locations and times; organic material, iron and manganese oxides are considered to be the main components that control the adsorption to the particles.Distribution coefficients are calculated from the experimentally obtained binding capacities and conditional stability constants. Calculated distribution coefficients for Zn agree with those obtained from the field data and are not very sensitive to changes in the composition of the solution. Good agreement was obtained for lead as well; for some samples it was important to take two types of sites with different affinity into consideration.     

自然水体中悬浮物对反硝化影响的研究进展

悬浮物在自然水体（池塘、河流、湖泊等）中普遍存在,相较于上覆水,是微生物更为倾向的附着载体。相较于沉积物,更易获取硝酸盐,是水体反硝化发生的热点微区。悬浮物在水体中经历一系列碰撞、絮凝、溶解、离子交换、吸附解吸等物理化学过程,从而会引起颗粒物粒径、营养盐浓度等发生变化;悬浮物的沉降和再悬浮过程也会引起上覆水和沉积物之间的物质交换,并在好氧缺氧过渡过程中对氮转化造成影响,从而直接或者间接影响水体反硝化速率。本文概括了国内外关于悬浮物影响水体反硝化的研究进展和热点,总结了不同浓度、粒径、组成和种类的悬浮物对反硝化作用的影响,从溶解氧、功能微生物、无机氮、有机碳等环境因素重点归纳了悬浮物影响反硝化的过程,比较和分析了悬浮物反硝化的测定方法。结合当前悬浮物反硝化研究现状,建议未来可以从新兴污染物悬浮物、机理模型、测定方法等方面展开深入研究。     

The effects of ice cover on flow characteristics in a subarctic meandering river

The effects of ice cover on flow characteristics in meandering rivers are still not completely understood. Here, we quantify the effects of ice cover on flow velocity, the vertical and spatial flow distribution, and helical flow structure. Comparison with open‐channel low flow conditions is performed. An acoustic doppler current profiler (ADCP) is used to measure flow from up to three meander bends, depending on the year, in a small sandy meandering subarctic river (Pulmanki River) during two consecutive ice‐covered winters (2014 and 2015). Under ice, flow velocities and discharges were predominantly slower than during the preceding autumn open‐channel conditions. Velocity distribution was almost opposite to theoretical expectations. Under ice, velocities reduced when entering deeper water downstream of the apex in each meander bend. When entering the next bend, velocities increased again together with the shallower depths. The surface velocities were predominantly greater than bottom/riverbed velocities during open‐channel flow. The situation was the opposite in ice‐covered conditions, and the maximum velocities occurred in the middle layers of the water columns. High‐velocity core (HVC) locations varied under ice between consecutive cross‐sections. Whereas in ice‐free conditions the HVC was located next to the inner bank at the upstream cross‐sections, the HVC moved towards the outer bank around the apex and again followed the thalweg in the downstream cross‐sections. Two stacked counter‐rotating helical flow cells occurred under ice around the apex of symmetric and asymmetric bends: next to the outer bank, top‐ and bottom‐layer flows were towards the opposite direction to the middle layer flow. In the following winter, no clear counter‐rotating helical flow cells occurred due to the shallower depths and frictional disturbance by the ice cover. Most probably the flow depth was a limiting factor for the ice‐covered helical flow circulation, similarly, the shallow depths hinder secondary flow in open‐channel conditions. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

潜流湿地中微生物对三峡库区微污染水净化效果的影响

为了探讨潜流湿地对三峡库区微污染河水的净化效果,在野外构建芦竹、菖蒲、空心菜和无植物(空白)水平潜流人工湿地,研究人工湿地系统中微生物基本菌群和功能菌群数量分布,探讨污染物去除与微生物菌群种类和数量的相关性.结果表明:实验湿地系统运行情况良好,植物湿地系统对各污染物指标的去除效果优于空白湿地系统;芦竹、菖蒲、空心菜和空白湿地系统的微生物数量均随温度的降低而减少,其中,植物湿地系统的微生物数量高于空白系统;各湿地系统的微生物数量与水质指标去除率之间的相关性较强,在夏季,不同人工湿地系统的细菌总数与CODMn的去除率之间存在着显著的正相关,真菌、亚硝酸细菌总数与铵氮去除率之间均存在着显著的正相关,在冬季,不同人工湿地系统的反硝化细菌总数与总氮去除率之间存在着显著的正相关.     

Effects of helical flow in one‐dimensional modelling of sediment distribution at river bifurcations

Complex flow processes at river bifurcations and the influence of the layout of a bifurcation make it difficult to predict sediment distribution over the downstream branches in case bedload transport dominates. In one‐dimensional models we need a nodal point relationship that prescribes the distribution of sediment over the downstream branches. We have identified which factors need to be included in such a relationship for the division of bedload transport at bifurcations. Next, irrotational flow theory for idealized geometries has been used to derive a simple physics‐based nodal point relationship that accounts for the effects of helical flow in the situation that a channel takes off under an angle from a straight main channel. This first step towards a complete nodal point relationship is applicable to bedload transport situations if the flow is clearly curved and if there is no pronounced bed topography. The relationship has been tested against data from a unique set of laboratory measurements, numerical data and data from a scale model of the Rhine bifurcation at Pannerden in the Netherlands. We find that the derived model yields a reasonable prediction of the sediment division over the downstream branches, and yields better predictions than the Wang et al. model for the situation considered. Considering the relative complexity and limited accuracy of the nodal point relationship for the effect of helical flow alone, however, we conclude thatderiving a practical physics‐based 1‐D relationship including all relevant processes is not feasible. We therefore recommend 2‐D or 3‐D modelling for all cases in general where morphological evolution depends on the division of bedload transport at bifurcations. Copyright © 2012 John Wiley & Sons, Ltd.     

Distribution of rare earth elements in marine sediments from the Strait of Sicily (western Mediterranean Sea): evidence of phosphogypsum waste contamination

Concentrations of rare earth elements (REE), Y, Th and Sc were recently determined in marine sediments collected using a box corer along two onshore-offshore transects located in the Strait of Sicily (Mediterranean Sea). The REE + Y were enriched in offshore fine-grained sediments where clay minerals are abundant, whereas the REE + Y contents were lower in onshore coarse-grained sediments with high carbonate fractions. Considering this distribution trend, the onshore sediments in front of the southwestern Sicilian coast represent an anomaly with high REE + Y concentrations (mean value 163.4 μg g⁻¹) associated to high Th concentrations (mean value 7.9 μg g⁻¹). Plot of shale-normalized REE + Y data of these coastal sediments showed Middle REE enrichments relative to Light REE and Heavy REE, manifested by a convexity around Sm-Gd-Eu elements. These anomalies in the fractionation patterns of the coastal sediments were attributed to phosphogypsum-contaminated effluents from an industrial plant, located in the southern Sicilian coast.     

Conservative behavior of arsenic and other oxyanion-forming trace elements in an oxic groundwater flow system

Groundwater samples were collected along a flow path in a shallow, fractured tuffaceous aquifer from the Oasis Valley–Beatty Wash region of southern Nevada, USA, and analyzed for a number of oxyanion-forming trace elements including arsenic (As), antimony (Sb), selenium (Se), molybdenum (Mo), and tungsten (W). In addition, ancillary geochemical parameters, including pH, major solute compositions, dissolved silica, dissolved oxygen, and iron and manganese concentrations were quantified in the groundwaters. Arsenic concentrations range from 70 nmol/kg up to 316 nmol/kg in groundwaters of the Oasis Valley–Beatty Wash flow system, and generally exhibit increasing concentrations with flow down-gradient along the flow path. Antimony, W, and to a lesser extent, Mo, exhibit similar increasing concentration trends with flow down-gradient in the aquifer, albeit, at lower concentrations levels (e.g., mean ± SD for Sb, W, and Mo are 2.3 ± 0.9 nmol/kg, 7.4 ± 3.7 nmol/kg, and 101 ± 19 nmol/kg, respectively). Selenium concentration, which range between 4 and 11 nmol/kg, generally decrease in groundwaters with flow down-gradients in the Oasis Valley–Beatty Wash groundwater flow systems. Inverse modeling of groundwater chemistry evolution from the lower reaches of the Oasis Valley flow path using PHREEQC indicate that the groundwater composition is consistent with mixing of nearly equal proportions of groundwater from upper reaches of Oasis Valley and Beatty Wash groundwater, along with dissolution of volcanic glass, potassium feldspar, and gypsum, followed by calcite precipitation, and formation of secondary zeolites (analcime), clay minerals (Ca-montmorillonite), and cristobalite. The geochemical modeling indicates that the concentrations of As and the other oxyanion-forming trace elements are controlled by dissolution of volcanic glass, water–rock interaction with mineralized zones within the aquifer (i.e., sulfide oxidation), desorption from aquifer surface sites, and mixing of Oasis Valley and Beatty Wash groundwaters.     

High‐frequency streamflow acquisition and bed level/flow angle estimates in a mountainous river using shallow‐water acoustic tomography

The acquisition of reliable discharge estimates is crucial in hydrological studies. This study demonstrates a promising acoustic method for measuring streamflow at high sampling rate for a long period using the fluvial acoustic tomography system (FATS). The FATS recently emerged as an innovative technique for continuous measurements of streamflow. In contrast to the traditional point/transect measurements of discharge, the FATS enables the depth‐averaged and range‐averaged flow velocity along the ray path to be measured in a fraction of a second. The field test was conducted in a shallow gravel‐bed river (0.9 m deep under low‐flow conditions, 115 m wide) for 1 month. The parameters (stream direction and bottom elevation) required for calculating the streamflow were deduced by a nonlinear regression to the discharge data from the well‐established rating curve. The cross‐sectional average velocities were automatically calculated from the acoustic data, which were collected on both riverbanks every 30 s. The FATS was connected to the internet so that the real‐time flow data could be obtained. The FATS captured discharge variations at a cut‐off frequency of approximately 70 day^?1. The stream exhibited temporal discharge changes at multiple time scales ranging from a few tens of minutes to days. Copyright © 2016 John Wiley & Sons, Ltd.     

Effect of snow structure on water flow and solute transport

Water flow through a melting snow pack modifies its structure and stability and affects the release of water and nutrients into soils and surface waters. Field and laboratory observations indicate a large spatial variability on various scales of the liquid water content and flow, a dominant system feature currently not included in numerical models. We investigated experimentally water and dye tracer movement through microstructurally different snow pack horizons and the persistence of preferential flow paths. Naturally rounded snow of varying grain size was artificially packed to obtain well known conditions by sieving it into rectangular bins. Surface melt was induced with infrared lamps. The flow paths were visualized with tracers and liquid water content was monitored with time domain reflectometry probes. Vertical cuts through the snow pack were imaged. The dye tracer patterns allowed the two flow regimes ‘matrix flow’ and ‘preferential flow’ to be distinguished. Matrix flow is apparently dominated by film and capillary flow in the unsaturated snow matrix. The capillary barrier effect at a boundary between a fine over a coarse textured layer on matrix flow in snow was confirmed. In contrast, preferential flow appears as well‐defined flow fingers that advance from 0·1 to 1 cm s^?1. During a melt phase, the advancing flow fingers enlarge and are only partially time invariant. It remains to be shown whether the continuum concept, including the Darcy–Buckingham law is apt to describe the extremely non‐linear nature of water flow and the travel time of solutes in snow under conditions of melt water percolation. Probably, snow packs that include faceted crystals and large variations in bulk density, feature more pronounced capillary barriers and preferential flow triggering, but also stronger impeding of fingers by lateral dispersion. Further, triggering and persistence of preferential flow is complicated by the usually transient infiltration rate. Copyright © 2004 John Wiley & Sons, Ltd.     

Permeability and pore-connectivity variation of pumices from a single pyroclastic flow eruption: Implications for partial fragmentation

The relationship between permeability and vesicularity in volcanic rocks has been used to infer the degassing behavior of hydrous magma. Recent data on natural samples from various eruptions show a wide variation, fitting a power–law relationship of the percolation models with low (< 30%) critical vesicularity (Ф_C). In this study, we present data on permeability and pore-connectivity of juvenile rhyolitic pumice clasts in a pyroclastic flow around Onikobe volcano, NE Japan, and investigate their relationship with vesicularity developed in a single eruption event. The permeability of the pumices having a relatively low abundance of microlites and microphenocrysts shows a trend increasing by 4 orders of magnitude (from 10^− 13.8 to 10^− 10.1 m²) in a high and narrow vesicularity range (from 72 to 80%). This trend intersects at a high angle with the fit to the permeability–vesicularity data in the previous studies that has a low Ф_C, and is located on the extension of the trend for the products of isotropic decompression experiments. The two-dimensional (2D) connectivities of pores for the pumices were also measured from thin sections. From the point of view of percolation theory, connectivity provides information about the probability of percolation. They showed a steep increase from ca. 0 to 0.7 in an almost similar vesicularity range, as compared to their permeabilities. We attribute the increase in 2D connectivity to the increasing amount of ruptured bubble walls, which might have provided less-tortuous paths through larger apertures for gas flow. This, in turn, would cause an effective increase in the permeability. Aggregates of bubble-wall-shaped glass shards were found in the pumices, and their amount and degree of welding are higher in the pumices that have a higher abundance of microlites and microphenocrysts. These pumices have relatively high permeability and 2D connectivity at low vesicularity, which is accounted for by the existence of large irregularly shaped pores. These textural characteristics suggest that a series of partial fragmentation processes, including local rupturing of bubble walls and subsequent foam-collapse with permeable gas flow, might have occurred before the ultimate bulk fragmentation, thus resulting in the increase in permeability. We suggest that the 2D connectivity of pores is a useful parameter to quantify the degree of fragmentation of bubble walls and has the potential for use to assess their permeability.     

Nitrate fluctuations at the water table: implications for recharge processes and solute transport in the Chalk aquifer

This study investigates fluctuations in nitrate concentration at the water table to improve understanding of unsaturated zone processes in the Chalk aquifer. Sampling was conducted using a novel multi‐level sampler during periods of water table rise over 5 years at a vertical resolution of 0.05 m. Nitrate concentration increased as the water table seasonally recovered, with similar inter‐annual trends with depth. The rising water table activated horizontal fractures facilitating the delivery of water elevated by up to 10 mg/l of nitrate with respect to the adjacent groundwater below. These fractures are considered to activate via piston displacement of water from the adjoining matrix. Hydrograph analysis identified 16 events which significantly perturbed the water table within 24–48 h of rainfall. Consistent nitrate concentrations indicate recharge through persistent fracture flow from the surface was not generally the primary driver of the rapid water table response during these events. Instead, the response was attributed to the piston displacement of porewater immediately above the water table. However, a single event in November 2012 delivered relatively dilute recharge indicating rapid persistent fracture flow following rainfall was possible to a depth of 14–15 m. Decreases in porewater nitrate concentration around fracture horizons and the dilution of many groundwater samples with respect to porewaters indicate a fresher source of water at depth. This was considered most likely to be a result of near surface water bypassing the matrix because of widespread mineralization on fracture surfaces, which retard water and solute exchange. Therefore, persistent fracture flow maybe considered a frequent process, operating independently of the matrix, and is not necessarily event driven. Copyright © 2015 John Wiley & Sons, Ltd.