Geomorphological and seismostratigraphic evidence for multidirectional polyphase glaciation of the northern Celtic Sea

High-resolution seismic and bathymetric data offshore southeast Ireland and LIDaR data in County Waterford are presented that partially overlap previous studies. The observed Quaternary stratigraphic succession offshore southeast Ireland (between Dungarvan and Kilmore Quay) records a sequence of depositional and erosional events that supports regional glacial models derived from nearby coastal sediment stratigraphies and landforms. A regionally widespread, acoustically massive facies interpreted as the ‘Irish Sea Till’ infills an uneven, channelized bedrock surface overlying irregular mounds and deposits in bedrock lows that are probably earlier Pleistocene diamicts. The till is truncated and overlain by a thin, stratified facies, suggesting the development of a regional palaeolake following ice recession of the Irish Sea Ice Stream. A north–south oriented seabed ridge to the north is interpreted as an esker, representing southward flowing subglacial drainage associated with a restricted ice sheet advance of the Irish Ice Sheet onto the Celtic Sea shelf. Onshore topographic data reveal streamlined bedforms that corroborate a southerly advance of ice onto the shelf across County Waterford. The combined evidence supports previous palaeoglaciological models. Significantly, for the first time, this study defines a southern limit for a Late Midlandian Irish Ice Sheet advance onto the Celtic Sea shelf. © 2020 John Wiley & Sons, Ltd.     

Diurnal and semidiurnal tidal currents in the deep mid-Arabian Sea

Current meter records from two depths, approximately 1000 and 3000 m, at three moorings in the deep mid-Arabian Sea were used to study tidal components. Tidal ellipses for the semi-diurnal (M₂, S₂ and K₂) and the diurnal (K₁, and P₁) tidal constituents have been determined using the currents recorded at hourly intervals during May 1986–May 1987. The clockwise rotating M₂ tidal currents were the strongest. The maximum horizontal velocities due to M₂,₂ and K₁ tides were 2.2 cm/s, l.0cm/s and 0.89 cm/s respectively. The amplitudes of the other two constituents (P₁, and K₂) were much smaller. The barotropic M₂ ellipses have been estimated by averaging the M₂ tidal currents at the upper and lower levels. Although the amplitudes of computed ellipses are lower than those that have been predicted using numerical models of global tidal model, their orientations are the same.     

Seismic stratigraphic analysis of non-marine Lower Cretaceous strata in the Wessex and North Celtic Sea Basins

Non-marine strata of Early Cretaceous age ('Wealden facies') are found at outcrop in the type localities of the Wessex Basins, southern England (and adjacent subsurface) and in extensive and thick successions filling the North Celtic Sea Basin. Sedimentology, paleontology, petrology and geochemistry have traditionally been used as evidence in determining the climatic, tectonic and sea level controls on Wealden facies, sedimentary processes and stratigraphy. Analysis of seismic data, through seismic facies and sequence stratigraphic analysis, allows direct comparison of the Wealden in these basins and new interpretations to be made of the tectonic and depositional influences. In the north-eastern end of the North Celtic Sea Basin, tectonic controls on seismic facies can be demonstrated and are related to coarse-grained fan-delta horizons documented in core. In the south-western North Celtic Sea Basin, adjacent to the Cretaceous proto-Atlantic, tectonic controls are less apparent, and changes in relative sea level were probably more important in controlling the preservation of stratigraphic sequences. Where the non-marine Lower Cretaceous succession is imaged clearly, the stratigraphic similarity between parts of the North Celtic Sea and the Weald and Channel Basins suggests a wider control by relative sea-level fluctuations. However, important variations in seismic facies within the basins indicate localized, dominant tectonic control. The recognition of a very distinctive 'lower' Wealden seismic facies, observed as undulatory (?channelized) and downlapping reflections, is contrasted with either the parallel or synsedimentary fault-dominated 'upper' Wealden facies. These seismic characteristics reflect the previously recognized climatic/tectonic change from Hastings to Weald Clay Group environments. The debate on tectonics versus eustacy is further complicated: palaeoclimate appears to be a third process responsible for stratigraphic variation.     

南海北部陆架海底沙波基本特征及属性

南海北部陆架海底沙波是否为残留沙波长期存在争议。为配合陆丰油田的开发,在LF13-2和LF13-1站位之间进行了详细的地形、地貌和海底底流测量。观测数据显示,本研究区发育两组海底沙波。两组沙波的分布和当今的海底地形密切相关,沙波的波宽、波高,沙脊的长度及延伸的方向也都和现今的水深密切相关。此外,沙波区的底质、沉积物颜色等也随现今水深的变化而变化。跨年度的测量结果显示,从2003年夏季到2005年冬季,海底沙波发生了明显的变化,除有明显的沙波迁移,并有新的沙波生成外,沙波区的水深也整体变深,研究区东南端平均加深了0.29m。由于东沙海底高原的存在,东沙区底流有了复杂的变化。实际的观测结果显示,在9MKII站位,向南的退潮流明显大于向北的涨潮流,但在AEM-HR站位,WNW向的涨潮流则稍稍大于ESE向的退潮流。9MKII站位测得的最大底流速为48cm/s,有22%的底流速大于20cm/s,这是启动海底沉积物并能形成海底沙波的最小底流速。本文指出,东沙隆起后,由于强烈的底流侵蚀,在东沙区的中陆架和外陆架区几乎没有现代沉积。构成海底沙波的沉积物主要来自海底地层的剥蚀。测深结果显示的海底加深可能和海底剥蚀有关。很明显,海底沙波和现今的海底底流体系有很好的吻合关系,从而是在现今底流体系条件下形成的,而非晚更新世末次冰期的残留沙波。     

Morphodynamic evolution and stratal architecture of translating tidal point bars: Inferences from the northern Venice Lagoon (Italy)

The widespread distribution of tidal creeks and channels that undertake meandering behaviour in modern coasts contrasts with their limited documentation in the fossil record, where point‐bar elements arising from the interaction between a mix of both fluvial and tidal currents are mainly documented. The sedimentary products of tidal channel‐bend evolution are relatively poorly known, and few studies have focused previously on specific facies models for tidal point bars present in modern settings. This study improves understanding of tidal channel meander bends through a multi‐disciplinary approach that combines analyses of historical aerial photographs, measurements of in‐channel flow velocity, high‐resolution facies analyses of sedimentary cores and three‐dimensional architectural modelling. The studied channel bend (12 to 15 m wide and 2 to 3 m deep) drains a salt marsh area located in the north‐eastern sector of the microtidal Venice Lagoon, Italy. Historical photographs show that, during the past 77 years, the bend has translated seaward ca 15 m. Results show that the channel bend formed on a non‐vegetated mud flat that was progressively colonized by vegetation. Seaward translation occurred under aggradational conditions, with an overall migration rate of 0·2 to 0·3 m year⁻¹, and was promoted by the occurrence of cohesive, poorly erodible outer bank deposits. Ebb currents are dominant, and translation of the channel bend promotes erosion and deposition along the landward and seaward side of the bar, respectively. Tidal currents show a clear asymmetry in terms of velocity distribution, and their offset pattern provides a peculiar grain‐size distribution within the bar. During the flood stage, sand sedimentation occurs in the upper part of the bar, where the maximum flow velocity occurs. During the ebb stage, the bar experiences the secondary helical flow that accumulates sand at the toe of the bar. Lateral stacking of flood and ebb deposits has caused the formation of localized coarsening‐upward and fining‐upward sedimentary packages, respectively.     

Eustatic and climatic controls on the development of the Wahiba Sand Sea, Sultanate of Oman

Aeolian sand sea accumulations can serve as valuable archives of climate change in continental environments. The Wahiba Sand Sea is situated at the northern margin of the area presently affected by Indian Summer Monsoon Circulation and it records environmental changes associated with this major climatic boundary over the last 160 000 years. The internal stratigraphy and evolution of the sand sea is investigated using a combination of outcrop, borehole, seismic and luminescence data. Proximity to the Indian Ocean means that the sand sea succession shows the influence of sea level changes on the sedimentary architecture and composition of the dune deposits. During the last two glacial periods, low global sea level was associated with a high input of bioclastic grains, reflecting the significance of subaerially exposed shelf areas as one of the main sources of aeolian sediment. The onset of aeolian sediment transport and deposition was related to the breakdown of stabilizing vegetation during arid periods that equate with sea level lowstands. The preservation of aeolian sediments by the formation of supersurfaces and associated palaeosoils took place during times of increased wetness and elevated groundwater tables. This interplay of constructive and destructive periods greatly influenced the sedimentary architecture. Oscillations of wet and dry periods between 160 000 and 130 000 years and 120 000–105 000 years ago are attributed to the evolution of a wet aeolian system. Younger periods of aeolian deposition around and after the last glacial maximum were characterized by dry aeolian conditions. No soil horizons developed during these times.     

东海陆架全新统高分辨率层序地层学研究

在高分辨率14C测年、岩石、生物、化学、同位素、气候及磁性地层学研究成果基础上,通过不同沉积背景典型钻孔的沉积学分析,运用层序地层学理论,对东海陆架全新统进行了高分辨率层序划分及对比;建立了全新世层序地层格架及海平面变化过程;提出了相应的层序成因模式。研究结果表明,东海陆架全新统相当于一个发育中的六级（1~10ka）层序,可进一步划分为3个七级（0.1~1ka）层序和若干个更次级层序。代表1个六级或3个七级周期相对海平面变化过程中叠加有若干更次级的海平面波动,它们与地球旋回谱系中的太阳带、历法带密切相关。七级层序具有与三级层序相近的内部构型和成因格架。在东海陆架全新世沉积演化过程中,长江三角州至少有3次不同程度地越过东海陆架进入冲绳海槽,并滞留有至少3层海侵改造"残积砂"沉积。在东海陆架全新世海平面变化期间,最大海平面时期为约距今6~5ka,大致高于现今海平面2~4m,最低海平面在距今10ka左右,大约低于现今海平面130m。目前,由于温室效应的影响,海平面仍呈小幅度波浪式上升。事实证明,层序地层学不仅丰富了现代海洋沉积学的内容,而且解决了许多海洋沉积学未能解决的问题.     

渤海东部潮流沉积特征及MIS4以来的沉积环境演化

渤海东部发育了典型的潮流沉积,由老铁山水道冲刷槽、辽东浅滩沙脊和渤中浅滩沙席组成。该文基于中国海洋地 质调查最新获取的高分辨率单道地震数据,与水深变化进行对比,将该区的潮流沉积特征与其地震相特征进行精细分析, 同时结合晚第四纪CD5孔的岩性、14C测年和层序地层划分,识别出晚更新世以来的四期层序地层,分别是MIS4以细砂为 主的陆相地层、MIS3以粉砂和黏土为主的滨浅海相沉积地层、MIS2末次盛冰期形成的以粉砂质粘土和细砂质粉砂为主的陆 相沉积地层和全新世（MIS1） 发育的以粉砂质黏土和细砂组成的海相沉积地层。其中全新世地层分别由早期的滨海相沉 积、中期的浅海沉积和晚期的潮流沉积组成。通过这四期层序的研究,揭示了该区MIS4期以来的沉积环境演化。     

南海及邻域砂矿资源分布特征及成矿模式

南海及邻域具有多样的地形地貌和丰富的物源,为海洋固体矿产资源的形成和分布提供了物质来源和堆积环境。为系统查明南海及邻域砂矿资源分布情况,本文通过对南海及邻域2606个站位表层沉积物样品进行粒度测试、碎屑矿物鉴定,以及重矿物的品位计算,分析了南海及邻域有用矿物砂矿资源以及建筑用砂资源分布特征并预测了远景区,总结了砂矿成矿模式。结果表明,南海及邻域具有远景的矿种主要有锆石、钛铁矿、金红石、锐钛矿、独居石和石榴子石等;重矿物高品位矿点主要集中在南海东北陆架、菲律宾海盆、南部陆架,重矿物异常区主要位于周缘陆架浅水区以及越东外陆架浅水海域、菲律宾海盆。锆石品位异常区的范围最大,达到工业品位的面积也最大;其次是磁铁矿、钛铁矿、独居石的异常区;锐钛矿、金红石异常区的面积相当;石榴子石品位异常范围最小。根据砂矿的分布规律、大地构造背景、成矿条件以及成矿元素特征,圈定了24个有用重矿物砂矿成矿远景区和6个成矿带。沉积物中砂（0. 063~2 mm）含量大于50%的建筑用砂的远景区9个,主要分布于海南岛西南面到台湾海峡南部一线以北海域,其次为南海南部礼乐滩、万安滩、曾母暗沙附近海域,其余海域极为罕见。基于南海砂矿资源分布特征,初步建立了近岸型、潮流砂脊型、古河道埋藏型、峡口型、陆架坡折带型等五种砂矿成矿模式,为海砂资源进一步勘查提供方向和建议。     

Fluidization and injection in the deep-water sandstones of the Eocene Alba Formation (UK North Sea)

The Nauchlan Member of the Late Eocene Alba Formation (UK North Sea) consists of a deep‐water channel fill that was extensively modified by post‐depositional sand remobilization and injection. Sandstone textures, facies associations and the geometry of the channel fill were affected. A suite of sand‐rich facies was produced by large‐scale fluidization and injection within the channel fill and above it. These facies, termed here unstratified facies, are characterized by the absence of stratification surfaces and by discordant relationships with bedding in the adjacent succession. They reflect variable degrees of disruption of the primary sedimentary structures caused by escaping pore fluid, the velocity of which is estimated at least in the order of 0·1 ms^?1. Adjacent mudstones were severely disrupted by hydraulic fracturing, and fragments of fractured mudstone were incorporated into the fluidized sand. Average porosity was decreased in the sandstones affected by fluidization. Two main phases of sand injection are inferred to occur at different burial depths. A shallow burial phase (below 100 m) produced thin dykes with ptygmatic folds. The second phase occurred at the boundary between Eocene and Oligocene (≈ 300 m burial depth) and resulted in large‐scale tabular wing‐like dykes that project from the edges of the channel fill. The significant pore‐fluid overpressure, which was required to hydraulically fracture the thick mudstone seal and to fluidize the large volume of sand, was likely to be built up by static liquefaction of the source sand and was possibly enhanced by hydrocarbon gas influx.     

Geological structure of the sedimentary cover and evaluation of the oil and gas potential of the Deryugin Basin (Sea of Okhotsk)

Results of interpretation of the seismic refraction survey in the southern part of the Deryugin Basin are presented. A geological-geophysical model was developed, and a scheme of the sedimentary cover evolution of the basin (Late Cretaceous-Pleistocene) is suggested. The data obtained indicate a high hydrocarbon potential comparable with that of the adjacent oil and gas-bearing shelf of northeastern Sakhalin.     

Physical and biological controls on the formation of carbonate and siliciclastic bedforms on the north-east Brazilian shelf

The continental shelf of the State of Rio Grande do Norte, Brazil, is an open shelf area located 5°S and 35°W. It is influenced by strong oceanic and wind-driven currents, fair weather, 1·5-m-high waves and a mesotidal regime. This work focuses on the character and the controls on the development of suites of carbonate and siliciclastic bedforms, based on Landsat TM image analysis and extensive ground-truth (diving) investigations. Large-scale bedforms consist of: (i) bioclastic (mainly coralline algae and Halimeda) sand ribbons (5–10 km long, 50–600 m wide) parallel to the shoreline; and (ii) very large transverse siliciclastic dunes (3·4 km long on average, 840 m spacing and 3–8 m high), with troughs that grade rapidly into carbonate sands and gravels. Wave ripples are superposed on all large-scale bedforms, and indicate an onshore shelf sediment transport normal to the main sediment transport direction. The occurrence of these large-scale bedforms is primarily determined by the north-westerly flowing residual oceanic and tidal currents, resulting mainly in coast-parallel transport. Models of shelf bedform formation predict sand ribbons to occur in higher energy settings rather than in large dunes. However, in the study area, sand ribbons occur in an area of coarse, low-density and easily transportable bioclastic sands and gravels compared with the very large transverse dunes in an offshore area that is composed of denser medium-grained siliciclastic sands. It suggests that the availability of different sediment types is likely to exert an influence on the nature of the bedforms generated. The offshore sand supply is time limited and originates from sea floor erosion of sandstones of former sea-level lowstands. The trough areas of both sand ribbons and very large transverse dunes comprise coarse calcareous algal gravels that support benthic communities of variable maturity. Diverse mature communities result in sediment stabilization through branching algal growth and binding that is thought to modify the morphology of dunes and sand ribbons. The occurrence and the nature of the bedforms is controlled by their hydrodynamic setting, by grain composition that reflects the geological history of the area and by the carbonate-producing benthic marine communities that inhabit the trough areas.     

南黄海辐射沙脊群形成演变的动力地貌过程数值模拟

江苏沿海辐射沙脊群在国内潮成沙体中较为罕见,有关辐射沙脊形成的动力机制已有定论,但对其形成时间和物质来源说法不一。运用长时间尺度动力地貌过程数学模型复演了辐射沙脊群形成演变过程,结果表明:江苏岸外辐聚辐散的流场不依赖于局部海底地形而独立存在;不同初始地形下只要泥沙供给充足,经过150年左右潮流动力对地形不断塑造,辐射状"水道-沙脊"相间的地貌格局都能基本形成;辐射沙脊群是废黄河北归约150年后,随着废黄河水下三角洲不断被侵蚀,辐聚辐散的潮流对不同来源物质重新塑造的结果,是动力-泥沙-地形相互作用的产物。     

Widespread overspill from a saline density‐current channel and its interaction with topography on the south‐west Black Sea shelf

Seaward of the Bosphorus Strait, the south‐west Black Sea shelf is dominated by the world's largest channel network maintained by a quasi‐continuous saline (ca 35 → 31 psu) underflow. Calculations indicate that >85% of the initial discharge of ca 10⁴ m³s^?1 spills overbank before the shelf edge. This paper documents interaction of the overspill with sea bed topography using multibeam bathymetry, echo‐sounder images of the water column, conductivity–temperature–depth profiles and sediment cores. Overbank spill is widespread, particularly through crevasse channels and on the middle shelf where confinement by channel banks is negligible. Towards the outer shelf, the wind‐driven Rim Current advects mud along the shelf, contributing to levée successions and deposition on stoss sides of elongate transverse ridges. Echo‐sounder profiles reveal metre‐scale eddies over megaflutes, and breaking lee waves and internal hydraulic jumps over ridges. Megaflutes reach 600 m long and 7 m deep, yet form where the underflow, outside the flute, is no thicker than ca 2 to 5 m. Two types of elongate seaward‐facing ridges are recognized. Type 1 ridges, 2 to 5 m high, consist of bivalve‐rich muddy sand in low‐angle (3·5° to 6°) cross‐sets created by the underflow. Type 2 ridges, ca 5 m high, have crests up to 2 km long and a buried wedge‐shaped foundation (the ‘ridge‐core’) comprised of facies similar to Type 1 ridges. These ridge‐cores are blanketed on the landward side by stratified muds, and are capped by obliquely oriented ribs supporting a diverse benthic community. This facies distribution is interpreted to result from stoss‐side and lee‐side velocity and turbulence fluctuations induced by internal hydraulic jumps and breaking lee waves in overspilling portions of the underflow. Experimental results published by W.H. Snyder and co‐workers effectively explain ridge evolution and flow across the ridges, and therefore can be applied with confidence to less easily studied deep‐marine settings swept by turbidity currents.     

南黄海辐射沙脊群表层沉积物中底栖有孔虫埋葬群分布特征及其环境意义

对南黄海辐射沙脊群海域123个表层沉积物样品中的有孔虫埋葬群进行了分析,发现其中浮游有孔虫含量低,平均不到7%,其分布与外海潮流有关,底栖有孔虫以浅水广盐性属种为主。通过对研究区至少在3个样品中含量大于2%的59个底栖有孔虫属种的Q型因子分析,提取了3个底栖有孔虫组合,结合沉积物粒度特征、现代海洋环境要素,将研究区划分成3个环境分区:(1)辐射沙脊群主干沙脊及大型潮流通道区,对应Ammonia beccarii vars.-Nonion akitaense-Cribrononion frigidum组合。该区可再分为两个亚区:辐射沙脊群主干沙脊及大型潮流通道北部亚区,代表受低温沿岸流和潮流影响的强水动力近岸砂质沉积环境;辐射沙脊群南部长江口偏北部亚区,反映强潮流的河口、低盐缺氧环境,兼受外海悬浮泥沙的影响。(2)海州湾及废黄河口区,对应Ammonia compressiuscula-Spiroloculina laevigata-Elphidium advenum组合,代表粉砂、黏土质底质,和水深50 m以浅的浅海环境。(3)辐射沙脊南部近岸浅水区,对应Nonion anomalinoidea-Ammonia maruhasii-Ammonia pauciloculata组合,反映了粉砂及砂质底质的近岸浅水、低盐潮间带和潮下带环境。总之,辐射沙脊群海域底栖有孔虫种群的分布,不仅受海水温盐、水深影响显著,还与此区独特的水动力条件,即外海潮波与内陆河流的共同作用有关。     

中国南海吹填岛礁钙质砂动力特性试验研究

南海对我国经济发展、资源开发与运输、维护国土完整具有战略性意义。目前我国已在南海海域以吹填方式建设了一系列的岛礁,并在其上修建了一系列的结构物（房屋、防波堤、机场等）。作为这些重要结构物的地基材料,珊瑚钙质砂在极端波浪、海底地震等环境荷载作用下的动态响应特性对评价其上结构物的安全稳定性具有重要的意义。以我国南海珊瑚岛礁吹填工程为背景,对取自岛礁吹填体现场的钙质砂样品,以吹填现场实测的颗粒级配和干密度为依据,开展动态三轴循环试验,研究我国南海珊瑚岛礁吹填体钙质砂地基土的动力特性。试验结果表明：岛礁钙质砂受动态循环荷载作用,在排水不通畅的条件下可以达到部分液化状态,在排水通畅的条件下不发生液化;在不排水条件下,岛礁钙质砂归一化的累积孔压u/ 与振次比N/Nf符合Seed提出的反正弦孔压发展模式;在不排水条件下,所有岛礁钙质砂样品的动态变形模量Ed /E0与归一化应变?m /?r之间全部重合在一条双曲线上,表明不排水条件下岛礁钙质砂的Ed /E0与?m /?r之间的关系不受干密度和颗粒级配的影响,具有很好的统一性。     

Late Pleistocene–Holocene deposits of the Rhône inner continental shelf (France): detailed mapping and correlation with previous continental and marine studies

Very-high-resolution seismic data acquired on the Rhône continental shelf were used to address the detailed morphology of Late Pleistocene and post-glacial units (from 18 000 yr BP to the present). Two groups of units can be distinguished. (1) Lower units that are mainly the product of variations in relative sea level. They comprise the last Pleistocene regressive deposits made of alluvial sheets (U0, U1) and, above, transgressive deposits that can be divided into: backstepping transgressive units (U3 and U4a), deposited during the landward retreat of the river mouth and transgressive units (U4b, U4c) laid down during the inundation of the shelf. A prograding littoral/lagoon system (U5/U6) indicating a fluctuation during the rise in sea level caps the transgressive units. This work has emphasized the complexity of these depositional environments, mainly related to a river system situated near the current Petit-Rhône. (2) Upper units that make up the recent Rhône delta and correspond to the current highstand systems tract (HST) developed since the stabilization of relative sea level. Seven prodeltaic lobes have been identified (U7–U13). Two of them are bilobate (U7 and U8) and date from a period when the delta was split as a result of the fluviatile system being progressively divided into several channels. Other prodeltaic lobes (U9, U10) are stacked in front of the distributary's outlet, recording several periods of outflow. The results show a strong correlation with studies on land. The distribution of recent prodeltaic lobes was constrained by canalization of the Rhône river to prevent the effects of climatic crises or other natural disasters.     

Eustatic and tectonic controls on Quaternary Ras Leona marine terraces (Strait of Gibraltar, northern Morocco)

Well-preserved Quaternary staircased marine terraces appear on Ras Leona limestone relief. This is a peculiar sector of the Betic-Rif Cordillera, lying in the four-way junction between the Atlantic and the Mediterranean, and Europe and Africa. The age and altitude correlation of the Ras Leona terraces with travertine-covered lateral equivalent terraces fashioned in the neighbouring Beni Younech area, and comparison with those along the Moroccan Atlantic coasts, would suggest that the Ras Leona terraces were mainly formed by eustatic factors. The importance of the eustasy is supported by further comparisons with Spanish and Moroccan Mediterranean terraces and with different marine terraces developed on passive-margin coasts around the world. A tectonic event occurred mainly during the period between the formation of the Maarifian and the Ouljian terraces (i.e., between 370 and 150 ka). The moderate Quaternary tectonic uplift deduced from the marine terraces and its comparison with uplifted marine terraces developed in active subduction setting disagrees with the model of an active eastwards subduction below the Gibraltar tectonic arc.     

Geochemistry of Holocene salt marsh and tidal flat sediments on a barrier island in the southern North Sea (Langeoog,North‐west Germany)

The barrier islands of the southern North Sea were formed during the Holocene sea‐level rise. These islands form part of a highly dynamic environment whose evolution continues today. Subjected to sea‐level changes, tides and storm events, the sedimentary record reflects processes occurring under varying energy conditions. This article presents geochemical, mineralogical and diatom investigations carried out in the salt marsh of the East Frisian barrier island of Langeoog, which is re‐exposed to a rising sea‐level due to de‐embankment. The major aim of this study is to improve the knowledge of the sedimentological and geochemical development of these deposits under the influence of sea‐level rise, with a special focus on the geochemistry and distribution of heavy mineral‐associated elements. Correlation diagrams between FeO, TiO₂ and MnO, as well as ternary plots (Al₂O₃–SiO₂–Zr or TiO₂), clearly indicate the variable appearance of heavy minerals in different lithological facies, comprising marsh soil, mixed and sand flat, and relocated beach sands. A dominating abundance of ilmenite followed by zircon, garnets and some other heavy minerals is evidenced by Scanning Electron Microscope‐Energy Dispersive X‐ray measurements. The data presented here suggests that these geochemical proxies are useful tools for characterizing depositional energy conditions. Increasing depositional energy is evident for the lithological units in the following order: marsh soil, mixed flat, sand flat and relocated beach sand. The energetic conditions during sediment deposition, as well as the sedimentary history, are confirmed by diatom analyses as an additional independent indicator. Depending on source rock composition, the geochemical parameters used in this study may also help to investigate depositional energy regimes of other siliciclastic sedimentary systems.     

水动力因素对砷在河砂中迁移影响的柱试验与模拟

河岸带作为一种典型的地下水-地表水相互作用带,不同水动力学条件下砷在该作用带中的行为较少有研究报道。基于此,采集河岸带河砂开展室内柱试验,分析不同水动力因素（包括流速和粒径）对砷在河砂中迁移的影响并建立相关模型。结果表明：(1) 0.5 mL/min流速下,河砂对As(V)的吸附速度和达到平衡所需的时间均比As(III)快,且粒径越小,该现象越明显;1.0 mL/min流速下,不同粒径的河砂对As(V)的吸附速度随粒径的增大而增大,对As(III)的吸附则没有明显差异;(2) 相同粒径的填充柱中,河砂对As(III)和As(V)的吸附能力均随流速的增加而降低;(3)不同流速和粒径条件下,As(III)和As(V)在砂柱中的迁移过程均更符合Thomas模型,拟合R2高于相同条件下Yoon-Nelson和Adams-Bohart模型。其中,低流速下,Thomas模型对0.15～0.25 mm粒径中As(III)和As(V)迁移过程拟合的R2（≥0.94）显著优于1.00～2.00 mm的较大粒径;高流速下,该模型对不同粒径中砷迁移过程的拟合R2差异不大。研究有助于加深对地下水-地表水相互作用下水动力因素对砷迁移转化规律影响的认识,并丰富和完善高砷地下水形成的机制理论。