In quest of lunar regolith breccias of exotic provenance: a uniquely anorthositic sample from the Fra Mauro (Apollo 14) highlands

Polymict samples can be used to establish mass-balance constraints regarding the bulk composition of the lunar crust, and to gauge the degree of regional heterogeneity in the composition of the lunar crust. The most ideally polymict type of sample is finely-mixed regolith (lunar soil), or its lithified equivalent, regolith breccia. Fortunately, lunar regolith breccias can occasionally be found at great distances from their points of origin — most of the known lunar meteorites are regolith breccias. We are searching for examples of exotic regolith samples among the Apollo regolith breccia collection. Most of the 21 Apollo regolith breccias analyzed for this study strongly resemble the local soils over which they were collected. Nine regolith breccias from Apollo 16 are surprisingly mature compared to previously-analyzed Apollo 16 regolith breccias, and six of the seven from Apollo 16 Station 5 have lower, more local-soil-like,mg ratios than previously analyzed regolith breccias from this station. Several of the Apollo 14 regolith breccias investigated show significantly highermg, and lower Al, than the local soils.The most interesting sample we have investigated is 14076,1, from a lithology that constitutes roughly half of a 2.0-g pebble. The presence of spherules indicates a regolith derivation for 14076,1, yet its highly aluminous (30 wt.% Al₂O₃) composition is clearly exotic to the 1.6-km traverse surface over which the Apollo 14 samples were collected. This sample resembles soils from the Descartes (Apollo 16) highlands far more than it does any other polymict sample from the Fra Mauro (Apollo 14) region. The I/_sFeO maturity index is extremely low, but this may be a result of thermal annealing. A variety of siderophile elements occur in 14076,1 at typical regolith concentrations. The chemistry of the second most aluminous regolith sample from Apollo 14, 14315, can only be roughly approximated as a mixture of local regolith and 14076,1-like material. However, the low a priori statistical probability for long-distance horizontal transport by impact cratering, along with the relatively high contents of incompatible elements in 14076,1 (despite its high Al content), suggest that this regolith breccia probably originated within a few hundred kilometers of the Appollo 14 site. If so, its compositional resemblance to ferroan anorthosite tends to suggest that the regional crust is, or originally was, far richer in ferroan anorthosite than implied by the meager statistics for pristine rocks from this site. Thus, 14076,1 tends to strengthen the hypothesis that ferroan anorthosite originated as the flotation crust of a global magmasphere.     

Ancient solar wind in lunar microbreccias

The Apollo 11 soil breccias are samplers of the ancient lunar environment due to their history in the regolith and their efficient closure to addition of recent solar wind upon compaction. These breccias contain the lowest¹⁵N/¹⁴N isotopic ratio yet reported for any lunar sample (in fact, for any natural sample). This extends the range of variation of¹⁵N/¹⁴N of the solar wind to greater than 30%, from a δ¹⁵N of ?190‰ in the past to +120‰ at present. No mechanism is yet known that is capable of accounting for such a large change in the¹⁵N/¹⁴N ratio without producing a substantial concomitant change in the¹³C/¹²C ratio, although some sort of nuclear reaction in the sun appears to be required. Apollo 11 soil breccias and 15086 are all formed by meteoritic impacts which compact the lower regolith against the basement rock without much heating. Rock 15086 formed from the layer of regolith between 100 and 200 cm depth, as shown by the close agreement between the nitrogen content and isotopic ratios of 15086 and those of the Apollo 15 deep drill core. Cosmic ray exposure ages, based on spallation-produced¹⁵N, are 2.3 ± 0.4 b.y. for Apollo 11 breccias. This age is much greater than the estimate from cosmogenic²¹Ne, presumably due to diffusive loss of neon.     

Influence of (FeO+TiO2) abundance on the microwave thermal emissions of lunar regolith

One of the essential controls on the microwave thermal emissions (MTE) of the lunar regolith is the abundance of FeO and TiO₂, known as the (FeO+TiO₂) abundance (FTA). In this paper, a radiative transfer simulation is employed first to study the change in the brightness temperature (T_B) with FTA under a range of frequencies and surface temperatures. Then, we analyze the influence of FTA on the MTE of the lunar regolith using microwave sounder (CELMS) data from the Chang’E-2 lunar orbiter, Clementine UV-VIS data, and lunar samples recovered from the Apollo and Surveyor projects. We conclude that: (1) FTA strongly influences the MTE of the lunar regolith, but it is not the decisive control, and (2) FTA decreases slightly with depth. This research plays an essential role in appropriately inverting CELMS data to obtain lunar regolith parameters.     

Pre-4.2 AE mare-basalt volcanism in the lunar highlands

The concept that the plutonism of the lunar highlands and the mare-type volcanism are two separate problems in both time (> 4.4 AE versus < 3.95 AE) and space is seriously questioned by the discovery of a 4.23-AE low-Ti mare basalt from Fra Mauro Formation.Apollo 14 breccia 14305 contains a clast (,122) which is an olivine gabbronorite that is texturally and mineralogically similar to several Apollo 12 basalts (e.g., 12005, 12035, 12040). It consists of cumulus olivine (40 modal %; Fo 62–70) and Ti-chromite (2.5 modal %); post-cumulus phases include low-Ca pyroxene (29 modal %; Wo 7–13 En 68–75), augite (10 modal %; Wo 31–40 En 47–50), plagioclase (15 modal %, An 82–93), and ilmenite (4 modal %, 5–7 MgO). The TiO₂ content of this rock = 4.3%; CaO/Al₂O₃ ? 1.0, CaO = 5.1%; MgO/FeO ? 1.0, MgO = 21.9%. The REE pattern, normalized to chondritic abundances, is approximately 30 × Ch and “hump-shaped” with a pronounced Eu depletion and a non-KREEPy signature. A four-point Rb-Sr isochron reveals an age of 4.23 ± 0.05 AE. The sample has a low initial ⁸⁷Sr/⁸⁶Sr= 0.69911 ± 3.The data presented here show that non-KREEPy, mare-type volcanism commenced at least as early as 4.2 AE in the Fra Mauro region and probably across much of the lunar surface. Massive bombardment during the “terminal cataclysm” and the subsequent veneer of younger mare basalts has obliturated most of the evidence for these ancient volcanic events. These old, mare-type volcanics may be related to basin-forming events such as made Procellarum (i.e., impact-triggered igneous activity).     

The effect of interstitial gaseous pressure on the thermal conductivity of a simulated Apollo 12 lunar soil sample

The thermal conductivity of a simulated Apollo 12 lunar soil sample was measured with a needle probe under vacuum. The result showed that the sample, with bulk densities of 1.70–1.85 g cm^?3 held in a vertical cylinder (2.54 cm in diameter and 6.99 cm long) has a thermal conductivity ranging from 8.8 to 10.9 mW m^?1 K^?1. This is comparable to the lunar regolith's thermal conductivity as determined in situ. Besides the dense packing of the soil particles, an enhanced intergranular thermal contact, due to the self-compression of the sample, is necessary to raise the sample's thermal conductivity from the level of loose soil (< 5 mW m^?1 K^?1) to that of the lunar regolith deeper than 35 cm (～ 10 mW m^?1 K^?1). A model of the lunar regolith, a thin layer of loose soil resting on a compacted self-compressed substratum, is consistent with the lunar regolith's surface structure as deduced from an observation of the lunar surface's brightness temperature. Martian regolith surface structure is similar, except that its surface layer may be missing in places because of aeolian activity. Measurements of thermal conductivity under simulated martian surface conditions showed that the thermal properties of loose and compacted soils agreed with the two peak values of the martian surface's thermal inertia as observed from “Viking” orbiters, suggesting that drifted loose soil and exposed compacted soil are responsible for the bimodal distribution of the martian surface's thermal inertia near zero elevation. For compacted soil exposed to the martian surface to have the same thermal conductivity as that buried under the surface layer, a cohesion of the soil particles must be assumed.     

Analyses of nitrogen and argon in single lunar grains: towards a quantification of the asteroidal contribution to planetary surfaces

We performed nitrogen and argon isotopic analyses in single 200-μm-sized ilmenite grains of lunar regolith samples 71501, 79035 and 79135. Cosmogenic and trapped components were discriminated using stepwise heating with a power-controlled CO₂ laser. Cosmogenic ¹⁵N and ³⁸Ar correlate among different ilmenite grains, yielding a mean ¹⁵N_c/³⁸Ar_c production ratio of 14.4±1.0 atoms/atom. This yields a ¹⁵N production rate in bulk lunar samples of 3.8-5.6 pg (g rock)⁻¹ Ma⁻¹, which agrees well with previous estimates. The trapped δ¹⁵N values show large variations (up to 300‰) among different grains of a given soil, reflecting complex histories of mixing between different end-members. The ³⁶Ar/¹⁴N ratio, which is expected to increase with increasing contribution of solar ions, varies from 0.007 to 0.44 times the solar abundance ratio. The trapped δ¹⁵N values correlate roughly with the ³⁶Ar/¹⁴N ratios from a non-solar end-member characterized by a ³⁶Ar/¹⁴N ratio close to 0 and variable but generally positive δ¹⁵N values, to lower δ¹⁵N values accompanied by increasing ³⁶Ar/¹⁴N ratios, supporting the claim of Hashizume et al. (2000) that solar nitrogen is largely depleted in ¹⁵N relative to meteoritic or terrestrial nitrogen. Nevertheless, the ³⁶Ar/¹⁴N ratio of the ¹⁵N-depleted (solar) end-member is lower than the solar abundance ratio by a factor of 2.5-5. We explain this by a reprocessing of implanted solar wind atoms, during which part of the chemically inert rare gases were lost. We estimate that the flux of non-solar N necessary to account for the observed δ¹⁵N values is comparable to the flux of micrometeorites and interplanetary dust particles estimated for the Earth. Hence we propose that the variations in δ¹⁵N values observed in lunar regolith can be simply explained by mixing between solar wind contributions and micrometeoritic ones infalling on the Moon. Temporal variations of δ¹⁵N values among samples of different antiquities could be due to changes in the micrometeoritic flux through time, in which case such flux has increased by up to an order of magnitude during the last 0.5 Ga.     

Apollo 16 neutron stratigraphy

The Apollo 16 soils have the largest low energy neutron fluences (up to 10¹⁷ n/cm², E < 0.18eV) yet observed in lunar samples. Variations in the isotopic ratios ¹⁵⁸Gd/¹⁵⁷Gd and ¹⁵⁰Sm/¹⁴⁹Sm (up to 1.9% and 2.0% respectively) indicate that the low energy neutron fluence in the Apollo 16 drill stem increases with depth throughout the section sampled. Such a variation implies that accretion has been the dominant regolith “gardening” process at this location. The data may be fit by a model of continuous accretion of pre-irradiated material at a rate of ～70 g/(cm² · 10⁸yr) or by models involving as few as two slabs of material in which the first slab could have been deposited as long as 10⁹ yr ago.The ratio of the number of neutrons captured per atom by Sm to the number captured per atom by Gd is lower than in previously measured lunar samples, which implies a lower energy neutron spectrum at this site. The variation of this ratio with chemical composition is qualitatively similar to that predicted by Lingenfelter, Canfield and Hampel.Variations are observed in the ratio ¹⁵²Gd/¹⁶⁰Gd which are fluence correlated and probably result from neutron capture by¹⁵¹Eu.     

Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples

Abundances and isotopic compositions of all the stable noble gases have been measured in 19 different depths of the Apollo 15 deep drill core, 7 different depths of the Apollo 16 deep drill core, and in several surface fines and breccias. All samples analyzed from both drill cores contain large concentrations of solar wind implanted gases, which demonstrates that even the deepest layers of both cores have experienced a lunar surface history. For the Apollo 15 core samples, trapped⁴He concentrations are constant to within a factor of two; elemental ratios show even greater similarities with mean values of⁴He/²²Ne= 683±44,²²Ne/³⁶Ar= 0.439±0.057,³⁶Ar/⁸⁴Kr= 1.60±0.11·10³, and⁸⁴Kr/¹³²Xe= 5.92±0.74. Apollo 16 core samples show distinctly lower⁴He contents,⁴He/²²Ne(567±74), and²²Ne/³⁶Ar(0.229±0.024), but their heavy-element ratios are essentially identical to Apollo 15 core samples. Apollo 16 surface fines also show lower values of⁴He/²²Ne and²²Ne/³⁶Ar. This phenomenon is attributed to greater fractionation during gas loss because of the higher plagioclase contents of Apollo 16 fines. Of these four elemental ratios as measured in both cores, only the²²Ne/³⁶Ar for the Apollo 15 core shows an apparent depth dependance. No unambiguous evidence was seen in these core materials of appreciable variations in the composition of the solar wind. Calculated concentrations of cosmic ray-produced²¹Ne,⁸⁰Kr, and¹²⁶Xe for the Apollo 15 core showed nearly flat (within a factor of two) depth profiles, but with smaller random concentration variations over depths of a few cm. These data are not consistent with a short-term core accretion model from non-irradiated regolith. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. The lack of large variations in solar wind gas contents across core layers is also consistent with appreciable pre-accretion irradiation. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmogenic gases below ～65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper ～70 cm of the core. Cosmogenic gas concentrations of several Apollo 16 fines and breccias are consistent with ages of North Ray Crater and South Ray Crater of ～50·10⁶ and ～2·10⁶ yr, respectively.     

Depth profile of53Mn in the lunar surface

Measurements of cosmic-ray produced⁵³Mn are reported for a series of lunar surface samples down to a depth of 416 g/cm². These results clearly illustrate the decrease in activity with depth as the incident galactic cosmic rays are absorbed. Below 60 g/cm² the production rate decreases exponentially with a mean length, λ, of about 220 g/cm². These results indicate that, at the Apollo 15 site, the lunar regolith has been unmixed, on a meter scale, for the last 5 my. The neutron activation technique for⁵³Mn, which allowed samples smaller than 200 mg to be used for these measurements, is described.     

Neutron capture effects in lunar gadolinium and the irradiation histories of some lunar rocks

The Gd isotopic composition in 19 lunar rock and soil samples from three Apollo sites is reported. The analytical techniques and the high precision mass spectrometric measurements are discussed. Enrichments in¹⁵⁸GdO/¹⁵⁷GdO due to neutron capture range up to 0.75%. Integrated ‘thermal’ neutron fluxes derived from the isotopic anomalies of Gd are compared with spallation Kr data from aliquot samples to construct a model which gives both average cosmic-ray irradiation depths and effective neutron exposure ages (T_n) for some rocks. In the case of rock 12053, this yields an average sample location of ∼300 g/cm² below the lunar surface and an effective irradiation age of ∼230 my, compared to 99 my obtained by the⁸¹Kr-Kr method. Rock 14310 is the first lunar sample where Kr anomalies due to resonance neutron capture in Br are observed. A⁸¹Kr-Kr exposure age of 262 ± 7 my is calculated for this rock.     

Production de26Al dans Fe et Si par protons de 0.6 et 24 GeV

A total of 139 breccia and crystalline rock fragments in the size range 2–4 mm from four Apollo 15 soil samples have been examined. Two of the sample stations are on the mare surface (4 and 9A) and two are on the Apennine Front (2 and 6). Approximately 90% of the fragments from the Apennine Front are brown-glass “soil” breccias, but those from the mare surface are 60%–70% basalt. Several textural varieties of mare basalt have been recognized, but within experimental error there is no difference in their⁴⁰Ar-³⁹Ar ages. The major non-mare (Pre-Imbrian) crystalline rock types in the Apennine Front regolith are KREEP basalt, anorthositic rocks, recrystallized norite (including anorthositic norite) and recrystallized polymict breccias; however, such crystalline rocks are rare in the samples examined. Apparently, the near surface Imbrium ejecta below the regolith has not been thermally recrystallized, and probably there are no outcrops of crystalline rocks upslope from the sample stations.     

Textural remanence: A new model of lunar rock magnetism

In reexamining the accumulated magnetic data on lunar rocks, several common patterns of magnetic behavior are recognized. Their joint occurrence strongly suggests a new model of lunar rock magnetism, which appeals only to partial preferred textural alignment of the spontaneous moments of magnetic grains, without requiring the existence of ancient lunar magnetic fields. This magnetic fabric, mimetic to locally oriented petrofabric, gives rise to an apparent “textural remanent magnetization” (TXRM). In order to account for the observed intensity of “stable remanence” in lunar rocks, only a minute fraction (10^?3 to 10^?5) of the single-domain iron grains present need be preferentially aligned. Several mechanisms operating on the lunar surface, including shock and diurnal thermal cycling, appear adequate for producing the required type and degree of magnetic alignment in all lunar rock classes. The model is supported by a wide variety of direct and indirect evidence and its predictions (e.g. regarding anisotropic susceptibility and remanence acquisition) can be experimentally tested.     

A Monte Carlo model for the exposure history of lunar dust grains in the ancient solar wind

The theoretical motion of individual dust grains in the lunar regolith is analyzed by using a Monte Carlo statistical code where the variables are the mass and speed distribution of meteorites at the lunar surface and the geometrical shape of impact craters. From these computations the detailed irradiation history of the grains in the ancient solar wind is traced back, over a period of 4 billion years, as a function of the grain size. Then by combining this irradiation scheme with the result of solar wind simulation experiments, the time and depth dependent accumulation of solar wind effects in the theoretical grains (solar wind maturation) is inferred. Finally, the validity of these predictions is tentatively checked by discussing a variety of physical and chemical solar wind effects which are registered in the surface layers of lunar dust grains. Therefore these studies give a tentative scenario for the “maturation” of the lunar regolith with respect to solar wind effects, but they also reveal useful guidelines to deduce meaningful information from such effects. In particular, they suggest a “lunar skin” sampling technique for extracting dust grains in lunar core tubes which could help in deciphering the past activity of the ancient solar wind over a time scale of several billion years.     

Constraints on the origins of lunar magnetism from electron reflection measurements of surface magnetic fields

Apollo 15 and 16 subsatellite measurements of lunar surface magnetic fields by the electron reflection method are summarized. Patches of strong surface fields ranging from less than $\text{1}\text{4}$° to tens of degrees in size are found distributed over the lunar surface, but in general no obvious correlation is observed between field anomalies and surface geology. In lunar mare regions a positive statistical correlation is found between the surface field strength and the geologic age of the surface as determined from crater erosion studies. However, there is a lack of correlation of surface field with impact craters in the mare, implying that mare do not have a strong large-scale uniform magnetization as might be expected from an ancient lunar dynamo. This lack of correlation also indicates that mare impact processes do not generate strong magnetization coherent over ～ 10 km scale size. In the lunar highlands fields of >100 nT are found in a region of order 10 km wide and >300 km long centered on and paralleling the long linear rille, Rima Sirsalis. These fields imply that the rille has a strong magnetization (>5 × 10^?6 gauss cm³ gm^?1 associated with it, either in the form of intrusive, magnetized rock or as a gap in a uniformly magnetic layer of rock. However, a survey of seven lunar farside magnetic anomalies observed by the Apollo 16 subsatellite suggests a correlation with inner ejecta material from large impact basins. The implications of these results for the origin of lunar magnetism are discussed.     

Nitrogen isotopes in lunar highlands breccias

Some breccias from the lunar highlands have probably trapped solar wind gases at a very early epoch in the history of the moon, as implied by their high contents of parentless fissiogenic xenon and sometimes, of parentless radiogenic¹²⁹Xe. Four samples of this type, on which noble gas data already exist, have been selected for analysis of nitrogen contents and isotopic composition, by using step-wise heating techniques: 14047, 14055, 14307, 60255. Since uncertainties in the evolution of the solar wind¹⁵N/¹⁴N ratio with time are due in part to uncertainties in the measurement of the epoch of exposure, those samples provided the opportunity to measure the isotopic composition of nitrogen which has been trapped in the remote past, avoiding the problems inherent in the use of spallogenic nuclides. Results show that, in the samples studied from the Apollo 14 landing site, nitrogen is not particularly light, and has not been acquired, as a whole, in very ancient times. The conflicting presence of both parentless xenon and nitrogen of relatively “recent” isotopic signature can be explained if the hypothetical light nitrogen is diluted by more abundant, heavier nitrogen. Accordingly, the very ancient soil components which are implied in these objects by the presence of excess fission xenon have been re-exposed at a much later epoch, or mixed with some younger soil components, before the compaction event. The present data do not question the hypothesis of a secular isotopic variation of lunar trapped nitrogen, but cannot prove that very light nitrogen was trapped together with parentless fission xenon in the soil components of the highlands soil breccias. The very unusual release pattern of nitrogen in breccia 60255 can result from nitrogen isotopic homogenization with gas loss.     

In-situ measurement of the rate of235U fission induced by lunar neutrons

The depth profile of the neutron-induced fission rate of²³⁵U was directly measured to a depth of 350 g/cm² by the Apollo 17 Lunar Neutron Probe Experiment. The fission rate rises sharply from the surface to a broad maximum from 110 to 160 g/cm² and drops off at greater depths. The shape of theoretical depth profile of Lingenfelter et al. fits the measured capture rates well at all depths. The absolute magnitude of the experimental fission rates are (11±17)% lower than those calculated theoretically. The excellent agreement between theory and experiment implies that conclusions drawn previously by interpreting lunar sample data with the theoretical capture rates will not require revision. In particular lunar surface processes, rather than uncertainties in the capture rates, are required to explain the relatively low neutron fluences observed for surface soil samples compared to the fluences expected for a uniformly mixed regolith.     

Chemistry and structure of lunar and synthetic armalcolite

A study of the chemical trends displayed by lunar armalcolites has been made in conjunction with single-crystal X-ray structure refinements of lunar and synthetic armalcolite in order to assess the possible importance of Ti³⁺ in lunar armalcolite and to characterize the effects of cation substitutions on the structure. The apparent cation deficiencies found in lunar armalcolites analyzed with the electron microprobe most likely reflect the presence of Ti³⁺, although the existence of vacancies cannot be ruled out. Structure refinements of an Apollo 17 armalcolite are consistent with either interpretation. These results support experimental evidence suggesting the presence of Ti³⁺ in armalcolite and indicate that virtually all lunar armalcolites probably contain ～4–11 mol.% Ti₂³⁺Ti⁴⁺O₅ component in solid solution. The cation distribution in lunar armalcolite is essentially completely ordered. However, synthetic crystals quenched from near 1200°C have been found to retain significant cation disorder.     

Early lunar differentiation: 4.42-AE-old plagioclase clasts in Apollo 16 breccia 67435

We report on a⁴⁰Ar-³⁹Ar study of the Apollo 16 breccia 67435 and present ages of five samples representing matrix, lithic clasts and plagioclase clasts. While the matrix age spectrum does not have a well-defined plateau, the two lithic clasts gave plateau ages of 3.96 and 4.04 AE. Since all samples had apparent ages of ～1 AE in the fractions ≤600°C extraction temperature, the breccia might have been assembled in a rather mild process at about that time or even more recently out of material with different metamorphic ages. The two plagioclase samples, of which one was a single 9-mg mineral clast and the other a 15-mg composite of several clasts, also have ages of ～1 AE in the low-temperature release fractions, but are apparently undisturbed by any ～4-AE events since they both have well-defined plateaux at 4.42 AE. The age of these strongly calcic plagioclase clasts, believed to be remnants of the anorthositic lunar crust, establishes a lower age limit to the end of the early lunar differentiation and thus places a strong constraint to the lunar evolution.     

Isotopic and REE studies of lunar basalt 12038: implications for petrogenesis of aluminous mare basalts

We report Sr, Nd, and Sm isotopic studies of lunar basalt 12038, one of the so-called aluminous mare basalts. A precise internal Rb-Sr isochron yields a crystallization age of 3.35±0.09 AE and initial⁸⁷Sr/⁸⁶Sr=0.69922?2 (2σ error limits, 1AE=10⁹ years, λ(⁸⁷Rb)=0.0139AE^?1). An internal Sm-Nd isochron yields an age of 3.28±0.23AE and initial¹⁴³Nd/¹⁴⁴Nd=0.50764?28. Present-day¹⁴³Nd/¹⁴⁴Nd is less than the “chondritic” value, i.e. ?(Nd, 0)=?2.3±0.4 where ?(Nd) is the deviation of¹⁴³Nd/¹⁴⁴Nd from chondritic evolution, expressed as parts in 10⁴. At the time of crystallization ?(Nd, 3.2AE)=1.5±0.6.We have successfully modeled the evolution of the Sr and Nd isotopic compositions and the REE abundances within the framework of our earlier model for Apollo 12 olivine-pigeonite and ilmenite basalts. The isotopic and trace element features of 12038 can be modeled as produced by partial melting of a cumulate mantle source which crystallized from a lunar magma ocean with a chondrite-normalized REE pattern of constant negative slope. Chondrite-normalized La/Yb=2.2 for this hypothetical magma ocean pattern. A plot of I(Sr) versus ?(Nd) for the Apollo 12 basalts clearly shows the influence of varying proportions of olivine, clinopyroxene, orthopyroxene, and plagioclase in the basalt source regions. A small percentage of plagioclase (～5%) in the 12038 source apparently is responsible for low I(Sr) and ?(Nd) in this basalt. Aluminous mare basalts from Mare Crisium (Luna 24) and by inference Mare Fecunditatis (Luna 16) occupy locations on the I(Sr)-?(Nd) plot similar to that of 12038, implying that some basalts from three widely separated lunar regions came from plagioclase-bearing source regions. A summary of model calculations for mare basalts shows a record of lunar mantle solidification during the period when REE abundances in the lunar magma ocean increased from ～20× chondritic to >100× chondritic. Although there is a general trend from olivine to clinopyroxene-dominated source regions with progressive magma ocean evolution, significant mineralogical heterogeneities in mantle composition apparently formed at any given stage of evolution, as evidenced in particular by the three Apollo 12 magma types.     

A new type of chondritic meteorite found in lunar soil

A fragment found in soil from the Apollo 12 site (12037, from the rim of Bench Crater) appears to be a unique type of chondrite, petrologically and chemically distinct from other chondrites and lunar rocks. Inclusions consisting of shocked pyroxene rimmed by euhedral troilite crystals are set in a black aphanitic matrix. Abundant magnetite in the matrix exhibits microscopic morphologies (framboids and plaquets) characteristic of C1 chondrites. The bulk composition of this sample has high Mg/Si and low Fe/Si relative to other chondrites, and P and S are strongly enriched. Most compositional differences between this meteorite and other chondrites may be explained by fractionation of Fe phases, such as magnetite and troilite. Low refractory element contents preclude mixing with lunar materials. This sample may be a surviving fragment of the meteoritic component present in the lunar regolith. Its characteristics suggest that ancient meteoritic debris sampled by the moon may be significantly different from that captured by the present-day earth.