Improved understanding of dynamic water and mass budgets of high-alpine karst systems obtained from studying a well-defined catchment area

Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO₂ sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.     

Hydrogeological characterization of groundwater storage and drainage in an alpine karst aquifer (the Kanin massif,Julian Alps)

The Kanin massif is an important trans‐boundary aquifer, which stretches between Slovenia and Italy. The groundwater is only partially exploited, mainly for water supply, but the aquifer exhibits great potential for future exploitation. Since no consistent regional overview of the hydrogeological functioning of the Kanin massif was available, the decision was made to perform a study of this area, using a pragmatic approach based on 3D geological and hydrogeological modelling. The so‐called KARSYS approach was applied, with the aim of characterizing the groundwater reserves within this karst massif and of locating the main drainage axes that carry groundwater from the recharge areas to the respective springs. Delineation of the catchment areas of the corresponding springs was carried out, and some new explanations were obtained, especially with regard to the Mo?nica spring, which is located in Slovenia and forms a potential source of drinking water. It was found that this spring's catchment area extends as far as the Italian ski resort of Sella Nevea. The conceptual model also provides a possible explanation about the underground drainage towards the Boka spring and waterfall, which has been a challenge for decades. This new explanation is based on the existence of a perched groundwater body that feeds the Boka spring via a system of conduits. Despite some limitations, the results, which consist of a visualization of the underground drainage and groundwater storage within the Kanin massif, can be used as a basis for planning the sustainable management of karst waters in the studied area. Copyright © 2014 John Wiley & Sons, Ltd.     

Springflow hydrographs: eogenetic vs. telogenetic karst

Matrix permeability in the range of 10(-11) to 10(-14) m(2) characterizes eogenetic karst, where limestones have not been deeply buried. In contrast, limestones of postburial, telogenetic karst have matrix permeabilities on the order of 10(-15) to 10(-20) m(2). Is this difference in matrix permeability paralleled by a difference in the behavior of springs draining eogenetic and telogenetic karst? Log Q/Q(min) flow duration curves from 11 eogenetic-karst springs in Florida and 12 telogenetic-karst springs in Missouri, Kentucky, and Switzerland, plot in different fields because of the disparate slopes of the curves. The substantially lower flow variability in eogenetic-karst springs, which results in the steeper slopes of their flow duration curves, also makes for a strong contrast in patterns (e.g., "flashiness") between the eogenetic-karst and telogenetic-karst spring hydrographs. With respect to both spring hydrographs and the flow duration curves derived from them, the eogenetic-karst springs of Florida are more like basalt springs of Idaho than the telogenetic-karst springs of the study. From time-series analyses on discharge records for 31 springs and published time-series results for 28 additional sites spanning 11 countries, we conclude that (1) the ratio of maximum to mean (Q(max)/Q(mean)) discharge is less in springs of eogenetic karst than springs of telogenetic karst; (2) aquifer inertia (system memory) is larger in eogenetic karst; (3) eogenetic-karst aquifers take longer to respond to input signals; and (4) high-frequency events affect discharge less in eogenetic karst. All four of these results are consistent with the hypothesis that accessible storage is larger in eogenetic-karst aquifers than in telogenetic-karst aquifers.     

A high‐altitude temporary spring in a compartmentalized carbonate aquifer: the role of low‐permeability faults and karst conduits

The aim of this research was to refine the actual conceptual model related to the activation of high‐altitude temporary springs within the carbonate Apennines in southern Italy. The research was carried out through geophysical, hydrogeological, hydrochemical and isotopic investigations at the Acqua dei Faggi experimental site during five hydrologic years. The research demonstrated that, in carbonate aquifers where low‐permeability faults cause the aquifer system to be compartmentalized, high‐altitude temporary springs may be recharged by groundwater. In such settings, neither surface water infiltration in karst systems nor perched temporary aquifers play a role of utmost importance. The rare (once or a few time a year) activation of such springs is due to the fact that groundwater unusually reach the threshold head that allows the spring to flow. The activation of the studied high‐altitude temporary spring also depended on relationships between a low‐permeability fault core and a karst system that locally interrupts the low‐permeability barrier. In fact, when the hydraulic head did not reach the karst system, the concentrated head loss within the fault core did not allow the spring to flow, because the groundwater entirely flowed through the fault towards the downgradient compartment. Copyright © 2009 John Wiley & Sons, Ltd.     

Interpretation of groundwater level monitoring results in karst aquifers: examples from the Dinaric karst

The paper presents an attempt to determine the characteristics of karst aquifers using information on groundwater level (GWL) in natural holes and boreholes with different data quantity and time resolution of GWL measurements. In this paper the particulars of karst aquifers were analysed for four examples from the Dinaric karst. In all four study areas, aquifers are formed in bare, deep and well‐developed Dinaric karst consisting of Cretaceous limestones. The first example represents a wide area of Imotsko polje in the karst. The aquifer was analysed on the basis of infrequent water level monitoring in natural karst water features (jamas, lakes, wells) and discharges of springs and rivers. The karst aquifer in this example is complex, non‐homogenous and variable in space and time, which is frequent in the Dinaric karst. Regardless of the aforementioned it was possible to determine its elementary characteristics. The second example represents 10 wells used for the water supply for the city of Pula. The GWL and salinity were measured once a week in the period between 1981 and 1996. Even though these measurements were relatively infrequent in space and time, they served as bases for assessment of average and maximum aquifer conditions as well as boundaries of saltwater intrusion. In the third example only a portion of aquifer of the karst spring Blaz, which is in the contact with the Adriatic Seas, has been analyzed. It is a spring with an intrusion of salt water. For purposes of study of saltwater intrusion, 26 piezometers were drilled in its vicinity in which GWL, salinity and temperature were measured once a day during 168 days, a period comprising one complete cycle of seawater intrusion and retreat. These measurements proved the existence of dispersed discharge from the aquifer into the sea and its non‐homogeneity in space. In the fourth example GWL was measured continuously in 10 deep (up to 300 m) piezometers in the hinterland of the Ombla Spring catchment. The measurement period lasted 2 years (January 1988 to December 1989). The analyses are made with hourly data. The results made it possible to determine numerous characteristics of the karst aquifer and a significant non‐homogeneity of groundwater distribution in karst aquifers, depending more on the underground karst phenomena than the surface karst forms. Copyright © 2000 John Wiley & Sons, Ltd.     

Identification of a karst hydrological system in the Dinaric karst (Yugoslavia)

Abstract

The construction of a reservoir on the Neretva River resulted in the flooding of three springs which now function as ponors (swallow-holes). In the first phase, they discharged 28 m³ s^?1 of water from the full reservoir. All the water that was lost through these ponors appeared some 1 km downstream from the dam in a group of springs. Most of these springs were, in the natural state, only temporary, and during the dry period their discharge was approximately 1 m³ s^?1. In order to reduce the losses from the reservoir, some reclamation works were carried out resulting in a decrease of the losses by only 6 m³ s^?1. Detailed hydrogeological and hydrological analyses were performed with the objective of identifying the karst system, i.e. to determine the position of the karst channels. The definition of the position and dimensions of the karst channels through which the greatest quantities of water are lost from the reservoir was carried out according to the definition of the hydrograph recession curves and the discharge curves of a group of downstream springs. The recession part of the hydrograph was defined by applying a new expression for the Maillet formula. Thus, it became possible to define not only the transport characteristics of the karst mass but also its retention characteristics.     

萍-乐坳陷带之岩溶发育规律及岩溶水富集特征

萍-乐坳陷带为江西省最主要的隐伏岩溶发育区带之一,岩溶地层发育,地表水、地下水循环交替强烈,地质构造复杂,为岩溶的发育、岩溶地下水的富集提供了良好的条件。查明岩溶发育规律及岩溶水的富集特征,可为地下水资源合理开发与地质环境保护提供科学依据。     

Validating the KAGIS black‐box GIS‐based model in a Mediterranean karst aquifer: Case of study of Mela aquifer (SE Spain)

Karst Aquifer GIS‐based model (KAGIS model) is developed and applied to Mela aquifer, a small karst aquifer located in a Mediterranean region (SE Spain). This model considers different variables, such as precipitation, land use, surface slope and lithology, and their geographical heterogeneity to calculate both, the run‐off coefficients and the fraction of precipitation which contributes to fill the soil water reservoir existing above the aquifer. Evapotranspiration uptakes deplete water, exclusively, from this soil water reservoir and aquifer recharge occurs when water in the soil reservoir exceeds the soil field capacity. The proposed model also obtains variations of the effective porosity in a vertical profile, an intrinsic consequence of the karstification processes. A new proposal from the Nash–Sutcliffe efficiency index, adapted to arid environments, is presented and employed to evaluate the model's ability to predict the water table oscillations. The uncertainty in the model parameters is determined by the Generalized Likelihood Uncertainty Estimation method. Afterwards, when KAGIS is calibrated, wavelet analysis is applied to the resulting data in order to evaluate the variability in the aquifer behaviour. Wavelet analysis reveals that the rapid hydrogeological response, typical of a wide variety of karst systems, is the prevailing feature of Mela aquifer. This study proves that KAGIS is a useful tool to quantify recharge and discharge rates of karst aquifers and can be effectively applied to develop a proper management of water resources in Mediterranean areas.     

Simulation of spring flows from a karst aquifer with an artificial neural network

In China, 9·5% of the landmass is karst terrain and of that 47,000 km² is located in semiarid regions. In these regions the karst aquifers feed many large karst springs within basins of thousands of square kilometres. Spring discharges reflect the fluctuation of ground water level and variability of ground water storage in the basins. However, karst aquifers are highly heterogeneous and monitoring data are sparse in these regions. Therefore, for sustainable utilization and conservation of karst ground water it is necessary to simulate the spring flows to acquire better understanding of karst hydrological processes. The purpose of this study is to develop a parsimonious model that accurately simulates spring discharges using an artificial neural network (ANN) model. The karst spring aquifer was treated as a non‐linear input/output system to simulate the response of karst spring flow to precipitation and applied the model to the Niangziguan Springs, located in the east of Shanxi Province, China and a representative of karst springs in a semiarid area. Moreover, the ANN model was compared with a previous time‐lag linear model and it was found that the ANN model performed better. Copyright © 2007 John Wiley & Sons, Ltd.     

广西武鸣盆地岩溶泉口浮游生物群落对水环境变化的响应

近年来我国西南岩溶地区一些岩溶泉出现水生生态系统由草型向藻型转变的问题,但水化学监测却显示泉水水质依旧良好.岩溶泉的水质变化与水生生态系统退化不同步,故探寻岩溶泉水环境的变化以及浮游生物群落的响应,对全面掌握和客观评价泉水的健康状况具有重要意义.于2016年7月、2020年7月两个时期对广西武鸣盆地内4个岩溶泉进行了浮...     

Estimating mean residence time of karst groundwater in mountainous catchments of Western Himalaya,India

The mean residence time (MRT) of karst groundwater in three mountainous catchments of the Western Himalaya was estimated using multiple approaches: the tritium method, the sine wave model and tracer tests. Water samples were collected from precipitation, glacier melt, streams and karst springs for δ²H and tritium analysis during 2012 and 2013. High tritium values were observed in winter precipitation and low values in summer precipitation. The variation of tritium in karst springs was similar to that of the streams, whereas glacier melt showed lower tritium values. The MRT of cold karst springs was shorter than that of warm karst springs. The tracer breakthrough curves (TBC) retrieved for different springs suggested a short travel time for groundwater and possibly conduit flow. Deterioration of water quality and variation in flux magnitude are the two main practical consequences of the short travel time of karst groundwater in the region.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal     

Anomalous behaviour of specific electrical conductivity at a karst spring induced by variable catchment boundaries: the case of the Podstenjšek spring,Slovenia

Anomalous behaviour of specific electrical conductivity (SEC) was observed at a karst spring in Slovenia during 26 high‐flow events in an 18‐month monitoring period. A conceptual model explaining this anomalous SEC variability is presented and reproduced by numerical modelling, and the practical relevance for source protection zoning is discussed. After storm rainfall, discharge increases rapidly, which is typical for karst springs. SEC displays a first maximum during the rising limb of the spring hydrograph, followed by a minimum indicating the arrival of freshly infiltrated water, often confirmed by increased levels of total organic carbon (TOC). The anomalous behaviour starts after this SEC minimum, when SEC rises again and remains elevated during the entire high‐flow period, typically 20–40 µS/cm above the baseflow value. This is explained by variable catchment boundaries: When the water level in the aquifer rises, the catchment expands, incorporating zones of groundwater with higher SEC, caused by higher unsaturated zone thickness and subtle lithologic changes. This conceptual model has been checked by numerical investigations. A generalized finite‐difference model including high‐conductivity cells representing the conduit network (“discrete‐continuum approach”) was set up to simulate the observed behaviour of the karst system. The model reproduces the shifting groundwater divide and the nearly simultaneous increase of discharge and SEC during high‐flow periods. The observed behaviour is relevant for groundwater source protection zoning, which requires reliable delineation of catchment areas. Anomalous behaviour of SEC can point to variable catchment boundaries that can be checked by tracer tests during different hydrologic conditions. Copyright © 2011 John Wiley & Sons, Ltd.     

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas,Kansas, Missouri and Oklahoma,USA

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.     

Variation of karst spring discharge in the recent five decades as an indicator of global climate change: A case study at Shanxi,northern China

As one of the largest international scientific pro- grams in geoscience and environmental science, global change studies were initiated in the early 1980s[1,2]. Noticeable achievements have been made in the stud- ies using indicators such as loess, marine sediment, permafrost, vermicular red earth, and even magmatic activity[2―6]. In recent years, the importance of ground- water as a new type of global change indicators has caused wide attention[7]. Stochastic, isotopic and hy- drochemical st…     

Characterizing the heterogeneity of karst critical zone and its hydrological function: An integrated approach

Spatial heterogeneity in the subsurface of karst environments is high, as evidenced by the multiphase porosity of carbonate rocks and complex landform features that result in marked variability of hydrological processes in space and time. This includes complex exchange of various flows (e.g., fast conduit flows and slow fracture flows) in different locations. Here, we integrate various “state‐of‐the‐art” methods to understand the structure and function of this poorly constrained critical zone environment. Geophysical, hydrometric, and tracer tools are used to characterize the hydrological functions of the cockpit karst critical zone in the small catchment of Chenqi, Guizhou Province, China. Geophysical surveys, using electrical resistivity tomography (ERT), inferred the spatial heterogeneity of permeability in the epikarst and underlying aquifer. Water tables in depression wells in valley bottom areas, as well as discharge from springs on steeper hillslopes and at the catchment outlet, showed different hydrodynamic responses to storm event rainwater recharge and hillslope flows. Tracer studies using water temperatures and stable water isotopes (δD and δ¹⁸O) could be used alongside insights into aquifer permeability from ERT surveys to explain site‐ and depth‐dependent variability in the groundwater response in terms of the degree to which “new” water from storm rainfall recharges and mixes with “old” pre‐event water in karst aquifers. This integrated approach reveals spatial structure in the karst critical zone and provides a conceptual framework of hydrological functions across spatial and temporal scales.     

Analysis of methods to estimate spring flows in a karst aquifer

Hydraulically and statistically based methods were analyzed to identify the most reliable method to predict spring flows in a karst aquifer. Measured water levels at nearby observation wells, measured spring pool altitudes, and the distance between observation wells and the spring pool were the parameters used to match measured spring flows. Measured spring flows at six Upper Floridan aquifer springs in central Florida were used to assess the reliability of these methods to predict spring flows. Hydraulically based methods involved the application of the Theis, Hantush-Jacob, and Darcy-Weisbach equations, whereas the statistically based methods were the multiple linear regressions and the technology of artificial neural networks (ANNs). Root mean square errors between measured and predicted spring flows using the Darcy-Weisbach method ranged between 5% and 15% of the measured flows, lower than the 7% to 27% range for the Theis or Hantush-Jacob methods. Flows at all springs were estimated to be turbulent based on the Reynolds number derived from the Darcy-Weisbach equation for conduit flow. The multiple linear regression and the Darcy-Weisbach methods had similar spring flow prediction capabilities. The ANNs provided the lowest residuals between measured and predicted spring flows, ranging from 1.6% to 5.3% of the measured flows. The model prediction efficiency criteria also indicated that the ANNs were the most accurate method predicting spring flows in a karst aquifer.     

Groundwater interaction assessment based on the large-scale mapping of geological and hydrogeological conditions in Moscow

Assessing the interaction between aquifers is crucial for estimating the extent of protection of the aquifer in Carboniferous limestone (which is the main source of potable water supply to Moscow area) against contaminants penetrating from the overlying aquifers. The presented approach to assessing groundwater interaction and protection is based on large-scale mapping of the geological and hydrogeological conditions in Moscow. The obtained results may be used for solving the problem of groundwater protection against contamination, as well as for planning the engineering activities in the city.     

Hydrodynamic behaviour of karstic aquifers in Boroujerd,western Iran

Abstract

Considering the geological conditions of the southwest of Boroujerd and northwest of Doroud, Iran, karst development is analysed with respect to the hydrodynamic behaviour of the main draining springs of the units and the karstic aquifers are classified as either those developed in Cretaceous limestone or those developed in Oligomiocene limestone. For this purpose, the yields of the main karstic springs of the region—Absardeh and Zoorabad (Cretaceous karstic limestone aquifer), Kalamsooz and Azizabad (Oligomiocene karstic limestone aquifer)—were measured and analysed. Analysis of the recession curve is used for hydrodynamical analysis and to construct the conceptual model for estimation of karst development in the selected aquifers. Based on the results, the dynamic storage capacity of the saturated zone in Cretaceous limestone is evaluated as low to medium and that in Oligomiocene limestone as medium to high. The dynamic storage capacity of the unsaturated zone in Cretaceous limestone is evaluated as high and that in Oligomiocene limestone as low to medium. Moreover, the contribution of quickflow in karstic aquifers developed in the Cretaceous limestone drained by the Absardeh and Zoorabad springs is 23.5 and 82.2%, respectively, and that for the Kalamsooz and Azizabad springs (Oligomiocene limestone) is 5.7 and 22.5%, respectively. Flow in the Cretaceous limestone aquifer drained by the Zoorabad Spring is of concentrated type and the main flow occurs in the well-developed karstic conduits. The main flow in the Oligomiocene limestone aquifer, drained by the Kalamsooz Spring, occurs in a network of joints and fractures and the contribution of concentrated flow is very low. The transmissivity of the saturated zone in the karstic aquifer drained by the Zoorabad and Absardeh springs is medium to high and that for the Kalamsooz and Azizabad springs is found to be low.     

Hydrogeology of the sasso Lungo group,a dolomitic reef stock in the alpine dolomites of North Italy

The Sasso Lungo group forms an isolated mountain mass in the Italian Dolomites in the SE Alps. The group has an area of ± 9 km² and its elevation ranges from ± 2000–3000 m. The central part consists of an exhumed, dolomitized reef of Triassic age, which has subsided by gravity tectonics partly into the surrounding and underlying plastic Permian and Triassic formations. The hydrogeological characteristics of the formations are discussed. The central reef mass forms the main aquifer, and it is embedded in impervious formations. The discharge of the snowmelt water and rain takes mainly place through a few large springs around the group at some distance from the reef. The springs are hydraulically connected with low subterranean overflow points in the impervious rim of the reef through natural conduits of permeable moraines and Quaternary valley fills. The central lolomite aquifwe shows no signs of karst drainage. The water moves through a dense network of fractures and joints and it has probably a free, fluctuating water table, subdivided by groundwater divides which coincide in most cases with surface drainage divides. All springs and surface waters were mapped and sampled during the summer and fall periods from 1966 through 1968. The chemical composition of the spring waters was very useful in tracing the origin of the spring waters.     

Using periodic hydrologic and geochemical sampling with limited continuous monitoring to characterize remote karst aquifers in the Kaweah River Basin,California, USA

Hydrogeologic field work in remote settings is often challenging: assessing spring behaviour and aquifer characteristics can be expensive in both time commitment and resources needed to assess these systems. In this study, we document the hydrology and geochemistry of 47 perennial karst springs in the Kaweah River, a mountain river basin in the Sierra Nevada, California. After preliminary hydrogeochemical characterization and grouping, selected springs were continuously monitored to further assess aquifer characteristics in each group. Later, in areas without previous dye‐tracing work, traces were conducted to establish connections between large sinking streams and springs. The springs have a wide range of inter‐spring and intra‐spring variability in discharge and geochemistry. We assessed this variability by performing statistical comparisons with spring chemistry and principal components analysis of all measured variables. Results show that springs can be divided into two distinct groups: high elevation springs of the Mineral King Valley and lower elevation springs throughout the rest of the basin. Continuous discharge, temperature and specific conductivity data from four springs (two from each group) were then used to characterize the hydrograph recession behaviour of springs in each group. Both groups showed statistically similar baseflow recession slopes, suggesting that both groups contain baseflow storage compartments with similar hydrogeologic properties. The biggest difference between each group is the variability in amount of water remaining in the aquifer during baseflow conditions. High elevation springs have lower baseflow discharges, relative to peak flow, than lower elevation springs, despite the fact that more precipitation falls at higher elevation. This is likely caused by differences in the amount of soil and epikarst storage, which are related to recent geomorphic events: high elevation aquifers were glaciated as recent as 41 thousand years ago (kya), while there is no evidence that low elevation aquifers were glaciated. As a result, lower elevations have developed thicker soils, weathered bedrock and epikarst. Copyright © 2016 John Wiley & Sons, Ltd.