Near-infrared spectrophotometry of the satellites and rings of Uranus

New spectrophotometry from 1.5 to 2.5 μm is reported for the Uranian satellites Titania, Oberon, and Umbriel. A spectrum of the rings of Uranus from 2.0 to 2.4 μm is also reported. No evidence is found for frost covering the surface of the ring material, consistent with the low albedo of the rings (P_K = 0.03) previously reported by Nicholson and Jones (1980). The surfaces of the satellites are found to be covered by dirty water frost. Assuming albedos of the frost and gray components covering the Uranian satellites to be the same as the light and dark faces of Iapetus, radii are derived that are roughly twice those inferred from the assumption of a visual albedo of 0.5.     

Four-color photometry of the Galilean satellites

Photometry obtained in 1973 on the uvby system yields high-precision rotational light curves for Io, Europa, and Ganymede at a mean phase angle of ～6°. By combining our observations with photometry obtained by others over a broader range of phase angle, we alsi derive improved values for the phase coefficients and opposition surges of the four Galilean satellites. The values of V(1, 0) obtained by linear extrapolation to zero phase are accurate to ±0.03 magnitudes. We also derive the colors of the sun of the uvby system and use these to obtain albedos of the satellites in four colors.     

Near-infrared spectra of the Galilean satellites: Observations and compositional implications

We have obtained reflectivity spectra of the trailing and leading sides of all four Galilean satellites with circular variable filter wheel spectrometers operating in the 0.7- to 5.5-μm spectral interval. These observations were obtained at an altitude of 41,000 ft from the Kuiper Airborne Observatory. Features seen in these data include a 2.9-μm band present in the spectra of both sides of Callisto; the well-known 1.5-μm and 2.0-μm combination bands and the previously more poorly defined 3.1-μm fundamental of water ice observed in the spectra of both sides of Europa and Ganymede; and features centered at 1.35 ± 0.1, 2.55 ± 0.1, and 4.05 ± 0.05 μm noted in the spectra of both sides of Io. In an effort to interpret these data, we have compared them with laboratory spectra as well as synthetic spectra constructed with a simple multiple-scattering theory. We attribute the 2.9-μm feature of Callisto's spectra primarily to bound water, with the product of fractional abundance of bound water and mean grain radius in micrometers equaling approximately 3.5 × 10^?1 for both sides of the satellite. The fractional amounts of water ice cover on the trailing side of Ganymede, its leading side, and the leading side of Europa were found to be 50 ± 15, 65 ± 15, and 85% or greater, respectively. The bare ground areas on Ganymede have reflectivity properties in the 0.7- to 2.5-μm spectral region comparable to those of Callisto's surface and also have significant quantities of bound water, as does Callisto. Interpretation of the spectrum for the trailing side of Europa is complicated by magnetospheric particle bombardment which causes a perceptible broadening of strong bands, but the ice cover on this side is probably comparable to that on the leading side. These irradiation effects may be responsible for much of the difference in the visual geometric albedos of the two sides of Europa. Minor, but significant, amounts of ferrous-bearing material (either ferrous salts or alkali feldspars but not olivines or pyroxenes) account for the 1.35-μm feature of Io. The two longer wavelength bands are most likely attributable to nitrate salts. Ferrous salts and nitrates can jointly also account for much of the spectral variation in Io's visible reflectivity, thereby eliminating the need to postulate large quantities of sulfur. The absence of noticeable features near 3-μm wavelength in Io's spectra leads to upper bounds of 10% on the fractional cover of water and ammonia ice and 10^?3 on the relative abundance of bound water and hydroxylated material on Io. The two sides of Io have similar compositions. We suggest that the systematic increase in fractional water ice cover from Callisto to Ganymede to Europa is bought about by variations in efficiencies of recoating the satellite's surface by interior water brought to the surface, and by the deposition of extrinsic dust. The most important component of the latter is debris, derived from the outer irregular satellites of Jupiter, which impacts the Galilean satellites at relatively low velocities. Europa has the largest water ice cover because its crust is thinnest and thus the frequency of water recoating is the greatest, and because it is farthest from the sources of low-velocity dust. While models which depict Io's surface as consisting primarily of very fine-grained ice are no longer viable, we are unable to definitively distinguish between the salt assemblage and alkali feldspar models. The salt model can better account for Io's reflectivity spectrum from 0.3 to 5 μm, but the absence of appreciable quantities of bound water and hydroxylated material may not be readily understood within the context of that model.     

Galilean satellites: 1976 radar results

Radar observations of the Galilean satellites, made in late 1976 using the 12.6-cm radar system of the Arecibo Observatory, have yielded mean geometric albedos of 0.04 ± , 0.69 ± 0.17, 0.37 ± 0.09, and 0.15 ± 0.04, for Io, Europa, Ganymede, and Callisto, respectively. The albedo for Io is about 40% smaller than that obtained approximately a year earlier, while the albedos for the outer three satellites average about 70% larger than the values previously reported for late 1975, raising the possibility of temporal variation. Very little dependence on orbital phase is noted; however, some regional scattering inhomogeneities are seen on the outer three satellites. For Europa, Ganymede, and Callisto, the ratios of the echo received in one mode of circular polarization to that received in the other were: 1.61 ± 0.20 1.48 ± 0.27, and 1.24 ± 0.19, respectively, with the dominant component having the same sence of circularity as that transmitted. This behavior has not previously been encountered in radar studies of solar system objects, whereas the corresponding observations with linear polarization are “normal.” Radii determined from the 1976 radar data for Europa and Ganymede are: 1530 ± 30 and 2670 ± 50 km, in fair agreement with the results from the 1975 radar observations and the best recent optical determinations. Doppler shifts of the radar echoes, useful for the improvement of the orbits of Jupiter and some of the Galilean satellites, are given for 12 nights in 1976 and 10 nights in 1975.     

Spectral geometric albedos of the Galilean satellites from 0.24 to 0.34 micrometers: Observations with the international ultraviolet explorer

We present the results of an 8-year program of spectrophometry of the Galilean satellites of Jupiter that was undertaken using the International Ultraviolet Explorer (IUE) Spacecraft. The ultraviolet geometric albedos of all four satellites are low. This is consistent with the hypothesis that sulfurous materials escaping from the surface of Io are being distributed by magnetospheric processes to the surfaces of the other three objects. Although iron bearing silicates may also cause UV darkening, these materials also have spectral features in the visible region of the spectrum which are not found in the spectra of the Galilean satellites. For Io, we find that the ultraviolet geometric albedo is very low (P_uv ∼ 0.04). The trailing hemisphere has an albedo that is higher than that of the leading hemisphere. This is opposite of what is observed at visual wavelengths. The decrease of albedo shortward of 0.33 μm is consistent with groundbased observations (Nelson and Hapke, 1978) and the laboratory reflection spectrum of sulfur dioxide frost. The hemispheric albedo asymmetry is consistent with a variable distribution of the frost, it being present in greater abundance on Io's leading hemisphere. The strenght of this feature has not changed with respect to longitude over the8 years of this study. The phase coefficients and opposition surges at ultraviolet wavelenghts indicate that Io's surface regolith is very porous. Europa has the highest ultraviolet albedo of all the Galilean satellites (P_uv ∼ 0.2). This not inconsistent with the hypothesis of recent resurfacing. However, this albedo is not high enough to be consistent with a surface of pure water ice. We confirm a previously reported ultraviolet spectral asymmetry between Europa's leading and trailing hemispheres. The new data are consistent with the previous analyses which interpreted this as the spectral signature of sulfur ions from the Jovian magnetosphere which had been embedded preferentially on the trailing side of Europa's predominately water ice.surface. The opposition surge observed for Europa's trailing side is greater than that for the leading side. This implies that the trailing side is less compact than the leading side, perhaps due to gardening from the ion implantation process. Ganymede's ultraviolet albedo (P_uv ∼ 0.10) is lower than Europa's. Ganymede has an ultraviolet spectral asymmetry that is similar to Europa's for wavelenghts longer than 0.28 μm. However, at wavelengths shorter than 0.28 μm, the two objects have different opposite hemispherical spectral ratios, indicating that the same mechanism cannot be used to explain the ultraviolet spectral albedo of both objects. One possible explanation is that ozone is present in addition to sulfur embedded on Ganymede's surface. The ultraviolet albedo and opposite hemispherical spectral ratio of Calisto is spectrally flat, indicating that the surface is covered by a material that is spectrally absorbing in the ultraviolet but has no change in absorption at the ultraviolet wavelenghts. The orbital phase variation in the ultraviolet indicates that the absorber is assymmetrically distributed in longitude.     

Spectral reflectivities of the Galilean satellites and Titan, 0.32 to 0.86 micrometers

A spectrophotometric observational study of the Galilean satellites and Titan was carried out at 0.004-μm (40-Å) resolution over the spectral range 0.32 to 0.86 μm. A standard lunar area was used as a primary spectroscopic standard to establish the relative reflection spectra of the objects by ratioing the sky-corrected satellite spectra to the standard area on the Moon. J1 (Io) is found to have a spectral edge at 0.33 μm that has not been previously reported. The increase in reflectivity from 0.4 to 0.5 μm and the band at 0.56 μm are confirmed. A weak band at 0.56 μm is probable on J2 (Europa) and possible on J3 (Ganymede). J4 (Callisto) shows no spectral features that have not been previously reported. On Titan, no temporal variations in the methane bands greater than 2% were found, indicating that the effective path length in the Titan atmosphere did not change over the 3-month period of this study. A new absorption band of methane at 0.68 μm was found on Titan. We propose an extension of the evaporite model of Fanale et al. (1974, 1977) and the sulfur mixing models of Wamsteker et al. (1974) in which the primary constituent of the surface of J1 is elemental sulfur sublimated onto the surface by photodissociation of hydrogen sulfide outgassing from the interior. The sulfur is continually renewed by sublimation, sputtering, and redeposition. At low temperatures irradiation produces stable S₂, S₃, S₄, S₆, and long chain polymers. Some of these allotropes have an edge at 0.33 μm, a rising reflectance between 0.4 and 0.5 μm a band at 0.56 μm. All of these features are found in the spectrum of J1. We conclude that the lunar ratioing technique used in this study is well suited for determining the relative reflection spectra of solar system objects.     

The Galilean satellites: New near-infrared spectral reflectance measurements (0.65–2.5 μm) and a 0.325–5 μm summary

New near-infrared (0.65–2.5 μm) reflectance spectra of the Galilean satellites with 1.5% spectral resolution and ≈2% intensity precision are presented. These spectra more precisely define the water ice absorption features previously identified on Europa, Ganymede, and Callisto at 1.55 and 2.0 μm. In addition, previously unreported spectral features due to water ice are seen at 1.25, 1.06, 0.90, and 0.81 μm on Europa, and at 1.25, 1.04, and possibly 0.71 μm on Ganymede. Unreported absorption features in Callisto's spectrum occur at 1.2 μm, probably due to H₂O, and a weak, broad band extending from 0.75 to 0.95 μm, due possibly to other minerals. The spectrum of Io has only weak absorption features at 1.15 μm and between 0.8 and 1.0 μm. No water absorptions are positively identified in the Io spectra, indicating an upper limit of areal water frost coverage of 2% (leading and trailing sides). It is found for Callisto, Ganymede, and Europa that the water ice absorption features are due to free water and not to water bound or absorbed onto minerals. The areal coverage of water frost is ≈ 100% on Europa (trailing side), ≈65% on Ganymede (leading side), and 20–30% on Callisto (leading side). An upper limit of ≈5% bound water (in addition to the 20–30% ice) may be present on Callisto, based on the strong 3-μm band seen by other investigators. A summary of spectra of the satellites from 0.325 to about 5 μm to aid in laboratory and interpretation studies is also presented.     

On the surface composition of Io

The wavelength dependence of the reflectivity of Io indicates the presence of two materials on the surface of this satellite of Jupiter. These materials are sulfur and an unspecified material (R₁) which shows a wavelength dependence of its reflectivity for 0.3 μm < λ < 1.0 μm similar to the non-H₂O frost spectrum of the rings of Saturn. A 60/40 admixture of these two spectra matches the observed reflection spectrum of Io from 0.3μm–3 μm, if the spectrum of R₁ is featureless for λ > 1 μm. Sulfur will give rise to a posteclipse brightening. The variation with wavelength of the temperature dependence of the reflectivity of sulfur will allow an observational confirmation of the presence of sulfur on Io. The material R₁ should show a large geometrical albedo. The translucency of sulfur is consistent with the polarization-phase curve to Io. The material R₁ is also required to be translucent. The thermal conductivity of a cooled sulfur powder under vacuum was measured and found to agree with the value determined for the upper layer of Io from observations at 10 μm. It is shown that this agreement is not necessarily meaningful.     

New observations of surface markings on Jupiter's satellites

Visual and photographic observations of the Galilean satellites of Jupiter made in September 1973 with the 108 cm reflector at Pic-du-Midi Observatory are presented. A method of estimating the contrasts and albedos of surface markings on the satellites during transit by comparing them with the adjacent surface of Jupiter is described. Results for Io, Europa, and Ganymede give albedo ranges of 0.28 to 0.67, 0.45 to 0.67, and 0.22 to 0.47, respectively. These are geometric albedos for a phase angle of 5°. The percentages of the disks covered by high albedos are consistent with the conclusions of previous workers regarding the fraction of exposed water ice on the surface.     

Keck Adaptive Optics Images of Uranus and Its Rings

We present adaptive optic images of Uranus obtained with the 10-m W. M. Keck II telescope in June 2000, at wavelengths between 1 and 2.4 μm. The angular resolution of the images is ∼0.06-0.09″. We identified eight small cloud features on Uranus's disk, four of which were in the northern hemisphere. The latter features are ∼1000-2000 km in extent and located in the upper troposphere, above the methane cloud, at pressures between 0.5 and 1 bar. Our data have been combined with HST data by Hammel et al. (2001, Icarus153, 229-235); the combination of Keck and HST data allowed derivation of an accurate wind velocity profile. Our images further show Uranus's entire ring system: the asymmetric ? ring, as well as the three groups of inner rings (outward from Uranus): the rings 6+5+4, α+β, and the η+γ+δ rings. We derived the equivalent I/F width and ring particle reflectivity for each group of rings. Typical particle albedos are ∼0.04-0.05, in good agreement with HST data at 0.9 μm.     

Cassini/VIMS observation of an Io post-eclipse brightening event

During the Cassini-Jupiter flyby, VIMS observed Io at different phase angles, both in full sunlight and in eclipse. By using the sunlight measurements, we were able to produce phase curves in the visual through all the near infrared wavelengths covered by the VIMS instrument (0.85-5.1 μm). The phase angle spanned from ∼2° to ∼120°. The measurements, done just after Io emerged from Jupiter's shadow, show an increase of about 15% in Io's reflectance with respect to what would be predicted by the phase curve. This behavior is observed at wavelengths >1.2 μm. Moreover, just after emergence from eclipse an increase of about 25% is observed in the depth of SO₂ frost bands at 4.07 and 4.35 μm. At 0.879<λ<1.04 μm the brightening is 10-24%. Below λ=0.879 μm the brightening, if present, should be less than the precision of our measurements (∼5%). Apparently, these observations are not explained neither by a diverse spatial distribution of SO₂ on the Io' surface nor by atmospheric SO₂ condensation on the surface during the eclipse.     

Observations of Centaur 8405 Asbolus: Searching for Water Ice

Near-infrared spectra of Centaur 8405 Asbolus have been obtained, covering the whole rotational period. Complementary photometry and visible spectroscopy have also been performed. The aim of this project was to confirm or refute the water ice detection on one side of Asbolus reported by Kern et al. (2000 Astrophys. J.542, L155-L159). We found no absorption feature at any rotational phase of Asbolus. Our study is the first in-depth investigation of a centaur over a complete rotational period. Our results seem also to indicate that a change in the slope from 0.8 to 1.0 μm may occur in Asbolus spectrum.     

Influence of the coorbital resonance on the rotation of the Trojan satellites of Saturn

The Cassini spacecraft collects high resolution images of the Saturnian satellites and reveals the surface of these new worlds. Tiscareno et?al. succeeded to determine the Epimetheus rotation from the Cassini Imaging Science Subsystem data, initiating studies on the rotation of Epimetheus and its companion Janus (Tiscareno et?al., Icarus 204:254?C261, 2009; Noyelles, Icarus 207:887?C902, 2010; Robutel et?al., Icarus 211:758?C769, 2011). Especially, Epimetheus is characterized by its horseshoe shape orbit and the presence of the swap has to be introduced explicitly into rotational models. During its journey in the Saturnian system, Cassini spacecraft accumulates the observational data of the other satellites and it will be possible to determine the rotational parameters of several of them. To prepare these future observations, we built rotational models of the coorbital (also called Trojan) satellites Telesto, Calypso, Helene, and Polydeuces, in addition to Janus and Epimetheus. Indeed, Telesto and Calypso orbit around the L ₄ and L ₅ Lagrange points of Saturn-Tethys while Helene and Polydeuces are coorbital of Dione. The goal of this study is to understand how the departure from the Keplerian motion induced by the perturbations of the coorbital body, influences the rotation of these satellites. To this aim, we introduce explicitly the perturbation in the rotational equations by using the formalism developed by érdi (Celest Mech 15:367?C383, 1977) to represent the coorbital motions, and so we describe the rotational motion of the coorbitals, Janus and Epimetheus included, in compact form.     

Eclipse reappearances of Io: Time-resolved spectroscopy (1.9-4.2 μm)

We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO₂ frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO₂ induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO₂ bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν₁ + ν₃]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO₂ bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm⁻¹) 4ν₁ band of SO₂ frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO₂ bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO₂ in the vertical column above Io’s surface was ∼4 × 10⁻⁵ g cm⁻².     

Radar observations of the icy Galilean satellites

We report 12.6-cm-wavelength radar observations of Europa, Ganymede, and Callisto made at the Arecibo Observatory in November 1977 and February 1979. When combined with previous observations, our results establish firmly the distinguishing radar properties of these satellites: (i) high geometric albedos, α; (ii) circular polarization ratios, μ_C, which anomalously exceed unity; (iii) linear polarization ratios, μ_L, which are approximately 0.5; and (iv) diffuse scattering which varies as cosⁿθ, where θ is angle of incidence and 1 ? n ? 2. We tabulate weighted-mean values of α, μ_C, μ_L, and n derived from observations between 1975 and 1979. The values of μ_C for Ganymede and Europa are nearly identical and significantly larger than that for Callisto. The values of n for Ganymede and Callisto are nearly identical and significantly smaller than that for Europa. Although significant albedo and/or polarization features are common in the radar spectra, the fractional rms fluctuation in disk-integrated properties is only ～10%. No time variation in the radar properties has been evident during 1976–1979.     

Temporal behavior of the SO 1.707 μm ro-vibronic emission band in Io's atmosphere

We report observations of the ro-vibronic a¹Δ→X³Σ⁻ transition of SO at 1.707 μm on Io. These data were taken while Io was eclipsed by Jupiter, on four nights between July 2000 and March 2003. We analyze these results in conjunction with a previously published night to investigate the temporal behavior of these emissions. The observations were all conducted using the near-infrared spectrometer NIRSPEC on the W.M. Keck II telescope. The integrated emitted intensity for this band varies from 0.8×¹⁰²⁷ to 2.4×¹⁰²⁷ photons/s, with a possible link to variations in Loki's infrared brightness. The band-shapes imply rotational temperatures of 550-1000 K for the emitting gas, lending further evidence to a volcanic origin for sulfur monoxide. An attempt to detect the B¹Σ→X³Σ⁻ transition of SO at 0.97 μm was unsuccessful; simultaneous detection with the 1.707 μm band would permit determination of the SO column abundance.     

Molecular dynamics estimates for the thermodynamic properties of the Fe–S liquid cores of the Moon,Io, Europa,and Ganymede

A molecular dynamics (MD) simulation is performed for the physical and chemical properties of solid and liquid Fe–S solutions using the embedded atom model (EAM) potential as applied to the internal structure of the Moon, Io, Europa, and Ganymede under the assumption that the satellites' cores can be described by a two-component iron–sulfur system. Calculated results are presented for the thermodynamic parameters including the caloric, thermal, and elastic properties (specific heat, thermal expansion, Grüneisen parameter, density, compression module, velocity of sound, and adiabatic gradient) of the Fe–S solutions at sulfur concentrations of 0–18 at %, temperatures of up to 2500 K, and pressures of up to 14 GPa. The velocity of sound, which increases as pressure rises, is weakly dependent on sulfur concentration and temperature. For the Moon’s outer Fe–S core (~5 GPa/2000 K), which contains 6–16 at % (3.5–10 wt %) sulfur, the density and the velocity of sound are estimated at 6.3–7.0 g/cm³ and 4000 ± 50 m/s, respectively. The MD calculations are compared with the interpretation of the Apollo observations (Weber et al., 2011) to show a good consistency of the velocity of P-waves in the Moon’s liquid core whereas the thermodynamic density of the Fe–S core is not consistent with the seismic models with ρ = 5.1–5.2 g/cm³ (Garcia et al., 2011; Weber et al., 2011). The revision the density values for the core leads to the revision of its size and mass. At sulfur concentrations of 3.5–10 wt %, the density of the Fe–S melt is 20–30% higher that the seismic density of the core. Therefore, the most likely radius of the Moon’s outer core must be less than 330 km (Weber et al., 2011) because, provided that the constraint on the Moon’s mass and moment of inertia is satisfied, an increase in the density of the core must lead to a reduction of its radius. For Jupiter’s Galilean moons Io, Europa, and Ganymede, constraints are obtained on the size, density, and sound velocity of the Fe–S liquid cores. The geophysical and geochemical characteristics of the internal structure of the Moon and Jupiter’s moons are compared. The calculations of the adiabatic gradient at the P–T conditions for the Fe–S cores of the Moon, Io, Europa, and Ganymede suggest the top-down crystallization of the core (Fe-snow scenario).     

Visible spectral reflectance measurements (0.33–1.1 μm) of the Galilean satellites at many orbital phase angles

One hundred eighty-seven reflectance spectra (0.33–1.10 μm) of the Galilean satellites have been obtained. Solar phase angle color correction coefficients were derived and the spectra corrected to a solar phase of 6°. Solar phase angle coefficients beyond 0.55 μm are presented for the first time. The spectra as a function of orbital phase angle are presented in the form of images to display hemispheric spectral variations. Io and Europa are redder on their trailing hemispheres while Callisto is redder on its leading hemisphere. Ganymede shows small longitudinal color variations despite the complex albedo structure visible in Voyager images. Comparisons of these data with previous measurements reveal that most differences can be attributed to the solar calibration. Reflectance measurements of Io at 0.73 μm observed 8.5 years apart show a 6% global reflectance decrease. However, it is difficult to unambigously attribute this particular decrease in reflectance to a change in Io's surface composition.     

A spectroscopic study of the surfaces of Saturn's large satellites: H2O ice, tholins, and minor constituents

We present spectra of Saturn's icy satellites Mimas, Enceladus, Tethys, Dione, Rhea, and Hyperion, 1.0-2.5 μm, with data extending to shorter (Mimas and Enceladus) and longer (Rhea and Dione) wavelengths for certain objects. The spectral resolution (R=λ/Δλ) of the data shown here is in the range 800-1000, depending on the specific instrument and configuration used; this is higher than the resolution (R=225 at 3 μm) afforded by the Visual-Infrared Mapping Spectrometer on the Cassini spacecraft. All of the spectra are dominated by water ice absorption bands and no other features are clearly identified. Spectra of all of these satellites show the characteristic signature of hexagonal H₂O ice at 1.65 μm. We model the leading hemisphere of Rhea in the wavelength range 0.3-3.6 μm with the Hapke and the Shkuratov radiative transfer codes and discuss the relative merits of the two approaches to fitting the spectrum. In calculations with both codes, the only components used are H₂O ice, which is the dominant constituent, and a small amount of tholin (Ice Tholin II). Tholin in small quantities (few percent, depending on the mixing mechanism) appears to be an essential component to give the basic red color of the satellite in the region 0.3-1.0 μm. The quantity and mode of mixing of tholin that can produce the intense coloration of Rhea and other icy satellites has bearing on its likely presence in many other icy bodies of the outer Solar System, both of high and low geometric albedos. Using the modeling codes, we also establish detection limits for the ices of CO₂ (a few weight percent, depending on particle size and mixing), CH₄ (same), and NH₄OH (0.5 weight percent) in our globally averaged spectra of Rhea's leading hemisphere. New laboratory spectral data for NH₄OH are presented for the purpose of detection on icy bodies. These limits for CO₂, CH₄, and NH₄OH on Rhea are also applicable to the other icy satellites for which spectra are presented here. The reflectance spectrum of Hyperion shows evidence for a broad, unidentified absorption band centered at 1.75 μm.     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.