Interstellar absorptions at λ=3.2 μm and 3.3 μm

Unidentified interstellar absorption bands at =3.2 m and 3.3 m might be due to amino-acids in bacterial grains.     

Modeling the atmospheric limb emission of CO2 at 4.3 μm in the terrestrial planets

The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO₂ atmospheric fluorescence emission at 4.3‐μm from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of ν₃ quanta of high-energy CO₂ states by CO₂ itself could reduce the model-data discrepancy if increased by a factor 2-4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities.     

Optical constants of amorphous and crystalline H2O-ice in the near infrared from 1.1 to 2.6 μm

Using new laboratory spectra, we have calculated the real and imaginary parts of the index of refraction of amorphous and crystalline H₂O-ice from 20 to 150 K in the frequency range 9000-3800 cm⁻¹ (1.1-2.6 μm) at a spectral resolution of 1 cm⁻¹. These optical constants can be used to create model spectra for comparison to spectra from Solar System objects. We also analyzed the differences between the amorphous and crystalline H₂O-ice spectra, including weakening of bands and shifting of bands to shorter wavelength in amorphous H₂O-ice spectra. We have also observed two spectrally distinct phases of amorphous H₂O-ice.     

FGK 22 μm excess stars in LAMOST DR2 stellar catalog

Since the release of the Large Sky Area Multi-Object Fiber Spectroscopic Telescope(LAMOST)catalog, we have had the opportunity to use the LAMOST DR2 stellar catalog and the WISE All-Sky Data Release catalog to search for 22 μm excess candidates. In this paper, we present 10 FGK candidates which show an excess in the infrared at 22 μm. All the 10 sources are newly identified 22 μm excess candidates.Of these 10 stars, five stars are F type and five stars are G type. The criterion for selecting candidates is Ks[22].387. In addition, we present the spectral energy distributions covering wavelengths from the optic-≥0al to mid-infrared band. Most of them show an obvious excess from the 12 μm band and three candidates even show excess from 3.4 μm. To characterize the amount of dust, we also estimate the fractional luminosity of10 22 μm excess candidates.     

10 μm Imaging of the Blue Compact Galaxy HE 2–10

We present the first results of a survey of Blue Compact Galaxies with a 10 m array. Blue Compact Galaxies (BCGs) are dwarf galaxies experiencing an intense burst of star formation. As dwarf systems, their main characteristics is a low heavy-elements abundance. Although dust is thought to be less abundant in these galaxies than in normal spirals, the presence of a compact starburst region favors a detection in the infrared, and 10 m imaging is perfectly suited to star formation studies in BCGs since it focuses on the hottest dust inside the star-forming regions.     

A determination of Jovian ammonia abundance based on a 2 μm spectrum

A spectrum of Jupiter in the two micron region has been analyzed to determine the Jovian ammonia abundance. The result is a ?4 cm - amagat, assuming an airmass factor η = 2.5 and a single effective reflecting layer for this wavelength. This is compared with the abundances observed at other wavelengths.     

A Model of The 2–4 μm Spectrum of Comet Halley

Recent observations of Halley's Comet show a broad absorption band centred at 3.4 μm and which can be explained on the basis of a bacterial grain model. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mid-IR (8–13 μm) images of the 21 μm,carbon rich proto-planetary nebulae

We present 9.7 and 11.8 m narrow band (/=10%) images of three carbon (C-) rich proto-planetary nebulae with an unusual 21 m feature: IRAS 07134+ 1005, IRAS 22272+5435, and IRAS 04296+3429. The images were taken at UKIRT using the Berkeley/IGPP/LEA mid-IR camera. All three objects have a bipolar shape adding to the existing evidence that C-rich PPNe are by nature bipolar. Furthermore, we find the same bipolar morphology in a previous study of the C-rich, young planetary nebula, IRAS 21282+5050. We believe these four objects form an evolutionary sequence which links the C-rich asymptotic giant branch (AGB) stars with the C-rich planetary nebulae (PNe). From this evolutionary sequence, we conclude that bipolarity in C-rich PNe begins on the AGB and that the dynamical ages of these PPNe are in fair agreement with theoretical ages for a 0.6 M hydrogen burning core star.     

First observation of 628 CO2 isotopologue band at 3.3 μm in the atmosphere of Venus by solar occultation from Venus Express

The new ESA Venus Express orbiter is the first mission applying the probing technique of solar and stellar occultation to the atmosphere of Venus, with the SPICAV/SOIR instrument. SOIR is a new type of spectrometer used for solar occultations in the range 2.2-4.3 μm. Thanks to a high spectral resolving power R∼15,000-20,000 (unprecedented in planetary space exploration), a new gaseous absorption band was soon detected in the atmospheric transmission spectra around 2982 cm⁻¹, showing a structure resembling an unresolved Q branch and a number of isolated lines with a regular wave number pattern. This absorption could not be matched to any species contained in HITRAN or GEISA databases, but was found very similar to an absorption pattern observed by a US team in the spectrum of solar light reflected by the ground of Mars [Villanueva, G.L., Mumma, M.J., Novak, R.E., Hewagama, T., 2008. Icarus 195 (1), 34-44]. This team then suggested to us that the absorption was due to an uncatalogued transition of the ¹⁶O¹²C¹⁸O molecule. The possible existence of this band was soon confirmed from theoretical considerations by Perevalov and Tashkun. Some SOIR observations of the atmospheric transmission are presented around 2982 cm⁻¹, and rough calculations of line strengths of the Q branch are produced, based on the isotopic ratio measured earlier in the lower atmosphere of Venus. This discovery emphasizes the role of isotopologues of CO₂ (as well as H₂O and HDO) as important greenhouse gases in the atmosphere of Venus.     

2.8–3.6 μm Spectra of Micro-Organisms with Varying H2O Ice-Content

The extinction curves of bacterial grains on which variable mass fractions of water-ice are condensed are calculated. Because the ice band at 3.07 μm is stronger by a factor of about thirty than the OH and CH stretching bands in organic materials even a small mass fraction of ice condensed inside or on the surface of the particles modifies and tends to obscure the characteristic biological signature at ∼ 3.4 μm. This revised version was published online in July 2006 with corrections to the Cover Date.     

N2 2P Fluorescence from scattering of N22σg photoelectrons

N₂ 2P fluorescent intensity was monitored as a function of incident photon energy from 40 to 70 eV. A structure was seen near 52.2 eV. This feature is attributed to the scattering of photoelectrons originating from the N₂ 2σ_g molecular orbital with a binding energy of about 37.7 eV. The kinetic energy of these photoelectrons corresponds to the peak of the 2P excitation cross section at 14.5 eV.     

Silicon monoxide and the 10 μm interstellar feature

Laboratory spectra of SiO particles of 1 m radius show a broad structureless extinction peak at 9.6m. The wavelength dependence of extinction from SiO, an amorphous silicon oxide, provides a good match to that of interstellar dust.     

8–13 μm spectrophotometry of Comet Kohoutek

Spectrophotometry of Comet Kohoutek (1973f) covering the wavelength range 8–13 μm is presented. The spectral shape of the derived flux excess above a blackbody closely resembles that seen in circumstellar and interstellar dust and generally attributed to metallic silicates.     

Correlation of simultaneous ultraviolet (0.36 μm) and infrared (8 to 14 μm) images of Venus

We present evidence for a correlation between features observed in simultaneous infrared (8 to 14 μm) and ultraviolet (0.36 μm) images obtained during Venus' 1975 and 1977 apparitions. The sense of the observed correlation is such that bright uv markings correspond to bright (warm) ir features, and similarly, dark uv markings correspond to dark (cool) ir features.     

2.4 μm emission from the galactic centre region

It is shown that the 2.6 mm CO emission profile in the regions of two unidentified 2.4 m features observed near the galactic centre is consistent with an explanation of these features in terms of inhomogeneities in interstellar extinction. From our observations we estimate the mass to luminosity ratio of the galactic central bulge to beM/L _v=4.     

Identification of a new band system of isotopic CO2 near 3.3 μm: Implications for remote sensing of biomarker gases on Mars

We present the discovery of a new vibrational band system of isotopic CO₂ (carbon dioxide) near 3.3 μm, with multiple strong P, Q and R lines in the prime spectral region used to search for Mars CH₄ (methane). The band system was discovered on Mars using high-resolution spectrometers (λ/δλ>40,000, CSHELL and NIRSPEC) at telescopes (NASA-IRTF and Keck-2) atop Mauna Kea, HI. The observed line intensities and frequencies agree very well with values predicted by a vibrational band model that we developed using known parameters for the molecular levels involved. Using this model, we synthesized spectra for different observing conditions (from Space and ground-based telescopes) and for different spectral resolving powers (5000 to 40,000). Although the total atmospheric burden on Mars is more than 150 times smaller than on Earth, the greater mixing ratio of CO₂ ensures that its column abundance on Mars is almost 20 times greater than on Earth. Thus, weak telluric CO₂ band systems appear much stronger on Mars. Many molecules of possible biological and geothermal interest have strong signatures at these wavelengths, in particular hydrocarbons owing to their strong ro-vibrational CH stretching modes. For example, the new isotopic CO₂ band-system encompasses lines of CH₄, C₂H₆ (ethane), CH₃OH (methanol) and H₂O (water). Implications for previous and future searches of biomarker gases are presented.     

Infrared spectrum of Io, 2.8–5.2 μm

The reflectance spectrum of Io is presented from 2.8 to 5.2 μm, extending the earlier results of D. P. Cruikshank, T. J. Jones, and C. B. Pilcher (1978, Astrophys. J. 225, L89–L92), and demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 μm. Laboratory spectra of nitrates and carborates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on the recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds as reported in a companion paper (F. P. Fanale, R. H. Brown, D. P. Cruikshank, and R. N. Clark, 1979, Nature280, 761–763).     

The Galilean satellites: New near-infrared spectral reflectance measurements (0.65–2.5 μm) and a 0.325–5 μm summary

New near-infrared (0.65–2.5 μm) reflectance spectra of the Galilean satellites with 1.5% spectral resolution and ≈2% intensity precision are presented. These spectra more precisely define the water ice absorption features previously identified on Europa, Ganymede, and Callisto at 1.55 and 2.0 μm. In addition, previously unreported spectral features due to water ice are seen at 1.25, 1.06, 0.90, and 0.81 μm on Europa, and at 1.25, 1.04, and possibly 0.71 μm on Ganymede. Unreported absorption features in Callisto's spectrum occur at 1.2 μm, probably due to H₂O, and a weak, broad band extending from 0.75 to 0.95 μm, due possibly to other minerals. The spectrum of Io has only weak absorption features at 1.15 μm and between 0.8 and 1.0 μm. No water absorptions are positively identified in the Io spectra, indicating an upper limit of areal water frost coverage of 2% (leading and trailing sides). It is found for Callisto, Ganymede, and Europa that the water ice absorption features are due to free water and not to water bound or absorbed onto minerals. The areal coverage of water frost is ≈ 100% on Europa (trailing side), ≈65% on Ganymede (leading side), and 20–30% on Callisto (leading side). An upper limit of ≈5% bound water (in addition to the 20–30% ice) may be present on Callisto, based on the strong 3-μm band seen by other investigators. A summary of spectra of the satellites from 0.325 to about 5 μm to aid in laboratory and interpretation studies is also presented.     

New 8–13 μm Si:Ga/DRO hybrid arrays for very large telescopes

Since 1984, the CEA-LETI-LIR (Infrared Laboratory) has been involved in development of Si:Ga/DRO hybrid detector arrays dedicated to imaging of astronomical sources in the 8–13 m range. Successively, 32×32 element arrays were successfully manufactured for the ISOCAM camera and 64×64 arrays were fabricated for ground-based imaging. The latter detectors have been integrated in 3 cameras (C10, CAMIRAS and TIMMI for ESO) and have led to excellent astrophysical results since 1990.To equip instruments to be mounted on very large telescopes such as the European VLT at ESO, manufacture of new arrays has been undertaken and is currently under way at CEA-LETI-LIR. These new arrays will have a 128×192 format and will present the outstanding essential feature that their storage capacity will be able to be changed according to observation conditions (2 capacities will be implemented in the pixel).The main characteristics of these new detectors will be presented in this paper.     

Observations of Jupiter and Saturn at 5–8 μm

Moderate-resolution spectrophotometry (Δλ/λ～0.015) has shown the effects of known atmospheric constituents (NH₃, CH₄, C₂H₆) on the 5–8 μm spectrum of Jupiter. Broadband observations of Saturn at 6.5 μm are also reported.