Influence of heterogeneity on unsaturated hydraulic properties (2) – percentage and shape of heterogeneity

In subsurface porous media, the soil water retention curve (WRC) and unsaturated hydraulic conductivity curve (UHC) are two important soil hydraulic property curves. Spatial heterogeneity is ubiquitous in nature, which may significantly affect soil hydraulic property curves. The main theme of this paper is to investigate how spatial heterogeneities, including their arrangements and amounts in soil flumes, affect soil hydraulic property curves. This paper uses a two‐dimensional variably saturated flow and solute transport finite element model to simulate variations of pressure and moisture content in soil flumes under a constant head boundary condition. To investigate the behavior of soil hydraulic property curves owing to variations of heterogeneities and their arrangements as well, cases with different proportions of heterogeneities are carried out. A quantitative evaluation of parameter variations in the van Genuchten model (VG model) resulting from heterogeneity is presented. Results show that the soil hydraulic properties are strongly affected by variations of heterogeneities and their arrangements. If the pressure head remains at a specific value, the soil moisture increases when heterogeneities increase in the soil flumes. On the other hand, the unsaturated hydraulic conductivity decreases when heterogeneities increase in the soil flumes under a constant pressure head. Moreover, results reveal that parameters estimated from both WRC and UHC also are affected by shapes of heterogeneity; this indicates that the parameters obtained from the WRC are not suitable for predicting the UHC of different shapes in heterogeneous media. Copyright © 2011 John Wiley & Sons, Ltd.     

Modelling the impacts of spatial heterogeneity in soil hydraulic properties on hydrological process in the upper reach of the Heihe River in the Qilian Mountains,Northwest China

Spatial heterogeneity of soil has great impacts on dynamic processes of the hydrological systems. However, it is challenging and expensive to obtain spatial distribution of soil hydraulic properties, which often requires extensive soil sampling and observations and intensive laboratory analyses, especially in high elevation, hard to access mountainous areas. This study evaluates the impacts of soil heterogeneity on hydrological process in a high elevation, topographically complex watershed in Northwest China. Two approaches were used to derive the spatial heterogeneity of soil properties in the study watershed: (1) the spatial clustering method, Full‐Order‐CLK was used to determine five soil heterogeneous clusters (configurations 97, 80, 60, 40 and 20) through large number of soil sampling and in situ observations, and (2) the average values of soil hydraulic properties for each soil type were derived from the coarse provincial soil data sets (Gansu Soil Handbook at 1 : 1 000 000 scale). Subsequently, Soil and Water Assessment Tool model was used to quantify the impact of the spatial heterogeneity of soil hydraulic properties on hydrological process in the study watershed. Results show the simulations by Soil and Water Assessment Tool with the spatially clustered soil hydraulic information from the field sampling data had much better representation of the soil heterogeneity and had more accurate performance than the model using the average soil property values for each soil type derived from the coarse soil data sets. Thus, incorporating detailed field sampling, soil heterogeneity data greatly improve performance in hydrological modelling. Copyright © 2015 John Wiley & Sons, Ltd.     

Assessing the impact of the hydraulic properties of a crusted soil on overland flow modelling at the field scale

Soil surface crusts are widely reported to favour Hortonian runoff, but are not explicitly represented in most rainfall‐runoff models. The aim of this paper is to assess the impact of soil surface crusts on infiltration and runoff modelling at two spatial scales, i.e. the local scale and the plot scale. At the local scale, two separate single ring infiltration experiments are undertaken. The first is performed on the undisturbed soil, whereas the second is done after removal of the soil surface crust. The HYDRUS 2D two‐dimensional vertical infiltration model is then used in an inverse modelling approach, first to estimate the soil hydraulic properties of the crust and the subsoil, and then the effective hydraulic properties of the soil represented as a single uniform layer. The results show that the crust hydraulic conductivity is 10 times lower than that of the subsoil, thus illustrating the limiting role the crust has on infiltration. Moving up to the plot scale, a rainfall‐runoff model coupling the Richards equation to a transfer function is used to simulate Hortonian overland flow hydrographs. The previously calculated hydraulic properties are used, and a comparison is undertaken between a single‐layer and a double‐layer representation of the crusted soil. The results of the rainfall‐runoff model show that the soil hydraulic properties calculated at the local scale give acceptable results when used to model runoff at the plot scale directly, without any numerical calibration. Also, at the plot scale, no clear improvement of the results can be seen when using a double‐layer representation of the soil in comparison with a single homogeneous layer. This is due to the hydrological characteristics of Hortonian runoff, which is triggered by a rainfall intensity exceeding the saturated hydraulic conductivity of the soil surface. Consequently, the rainfall‐runoff model is more sensitive to rainfall than to the subsoil's hydrodynamic properties. Therefore, the use of a double‐layer soil model to represent runoff on a crusted soil does not seem necessary, as the increase of precision in the soil discretization is not justified by a better performance of the model. Copyright © 2005 John Wiley & Sons, Ltd.     

Using a pore‐scale model to quantify the effect of particle re‐arrangement on pore structure and hydraulic properties

A pore‐scale model based on measured particle size distributions has been used to quantify the changes in pore space geometry of packed soil columns resulting from a dilution in electrolyte concentration from 500 to 1 mmol l^?1 NaCl during leaching. This was applied to examine the effects of particle release and re‐deposition on pore structure and hydraulic properties. Two different soils, an agricultural soil and a mining residue, were investigated with respect to the change in hydraulic properties. The mining residue was much more affected by this process with the water saturated hydraulic conductivity decreasing to 0·4% of the initial value and the air‐entry value changing from 20 to 50 cm. For agricultural soil, there was little detectable shift in the water retention curve but the saturated hydraulic conductivity decreased to 8·5% of the initial value. This was attributed to localized pore clogging (similar to a surface seal) affecting hydraulic conductivity, but not the microscopically measured pore‐size distribution or water retention. We modelled the soil structure at the pore scale to explain the different responses of the two soils to the experimental conditions. The size of the pores was determined as a function of deposited clay particles. The modal pore size of the agricultural soil as indicated by the constant water retention curve was 45 µm and was not affected by the leaching process. In the case of the mining residue, the mode changed from 75 to 45 µm. This reduction of pore size corresponds to an increase of capillary forces that is related to the measured shift of the water retention curve. Copyright © 2007 John Wiley & Sons, Ltd.     

Anisotropy and depth‐related heterogeneity of hydraulic conductivity in a bog peat. I: laboratory measurements

Anisotropy and heterogeneity of hydraulic conductivity (K) are suspected of greatly affecting rates and patterns of ground‐water seepage in peats. A new laboratory method, termed here the modified cube method, was used to measure horizontal and vertical hydraulic conductivity (K_h and K_v) of 400 samples of bog peat. The new method avoids many of the problems associated with existing field and laboratory methods, and is shown to give relatively precise measurements of K. In the majority of samples tested, K_h was much greater than K_v, indicating that the bog peat was strongly anisotropic. Log₁₀K_h, log₁₀K_v, and log₁₀ (K_h/K_v) were found to vary significantly with depth, although none of the relationships was simple. We comment on the scale dependency of our measurements. Copyright © 2002 John Wiley & Sons, Ltd.     

The effect of conservation practices in sloped croplands on soil hydraulic properties and root‐zone moisture dynamics

Rain‐induced erosion and short‐term drought are the two factors that limit the productivity of croplands in the red soil region of subtropical China. The objective of this study was to estimate the effects of conservation practices on hydraulic properties and root‐zone water dynamics of the soil. A 3‐year experiment was performed on a slope at Xianning. Four treatments were evaluated for their ability to reduce soil erosion and improve soil water conditions. Compared with no practices (CK) and living grass strips (GS), the application of polyacrylamide (PAM) significantly reduced soil crust formation during intense rainfall, whereas rice straw mulching (SM) completely abolished soil crust formation. The SM and PAM treatments improved soil water‐stable aggregates, with a redistribution of micro‐aggregates into macro‐aggregates. PAM and SM significantly increased the soil water‐holding capacity. These practices mitigated the degradation of the soil saturated hydraulic conductivity (Ks) during intense rainfalls. These methods increased soil water storage but with limited effects during heavy rainfalls in the wet period. In contrast, during the dry period, SM had the highest soil water storage, followed by PAM and CK. Grass strips had the lowest soil water storage because of the water uptake during the vigorous grass growth. A slight decline in the soil moisture resulted in a significant decrease in the unsaturated hydraulic conductivity (Ku) of the topsoil. Therefore, the hydraulic conductivity in the field is governed by soil moisture, and the remaining soil moisture is more important than improving soil properties to resist short‐term droughts. As a result, SM is the most effective management practice when compared with PAM and GS, although they all protect the soil hydraulic properties during wet periods. These results suggest that mulching is the best strategy for water management in erosion‐threatened and drought‐threatened red soils. Copyright © 2014 John Wiley & Sons, Ltd.     

Influence of variation of soil spatial heterogeneity on vegetation restoration

Ecological restoration as a new research field of applied ecology can be traced back to the 1950s, it mainly focuses on the studies of ecological restoration of mine fields, tropical forests, wetlands and indus-try-polluted ecosystems[1-4]. Following the raising of the conception of “restoration ecology”[5], the holding of a series of international conferences and the found-ing of the International Association for Restoration Ecology, the studies of ecological restoration has be-come a quit…     

Anisotropy and depth‐related heterogeneity of hydraulic conductivity in a bog peat. II: modelling the effects on groundwater flow

Anisotropy and heterogeneity of hydraulic conductivity (K) are seldom considered in models of mire hydrology. We investigated the effect of anisotropy and heterogeneity on groundwater flow in bog peat using a steady‐state groundwater model. In five model simulations, four sets of K data were used. The first set comprised measured K values from an anisotropic and heterogeneous bog peat. These data were aggregated to produce the following simplified data sets: an isotropic and heterogeneous distribution of K; an isotropic and homogeneous distribution; and an anisotropic and homogeneous distribution. We demonstrate that, where anisotropy and heterogeneity exist, groundwater flow in bog peat is complex. Fine‐scale variations in K have the potential to influence patterns and rates of groundwater flow. However, for our data at least, it is heterogeneity and not anisotropy that has the greater influence on producing complex patterns of groundwater flow. We also demonstrate that patterns and rates of groundwater flow are simplified and reduced when measured K values are aggregated to create a more uniform distribution of K. For example, when measured K values are aggregated to produce isotropy and homogeneity, the rate of modelled seepage is reduced by 28%. We also show that when measured K values are used, the presence of a drainage ditch can increase seepage through a modelled cross‐section. Our work has implications for the accurate interpretation of hydraulic head data obtained from peat soils, and also the understanding of the effect of drainage ditches on patterns and rates of groundwater flow. Copyright © 2002 John Wiley & Sons, Ltd.     

Meta‐analysis of field‐saturated hydraulic conductivity recovery following wildland fire: Applications for hydrologic model parameterization and resilience assessment

Hydrologic recovery after wildfire is critical for restoring the ecosystem services of protecting of human lives and infrastructure from hazards and delivering water supply of sufficient quality and quantity. Recovery of soil‐hydraulic properties, such as field‐saturated hydraulic conductivity (K_fs), is a key factor for assessing the duration of watershed‐scale flash flood and debris flow risks after wildfire. Despite the crucial role of K_fs in parameterizing numerical hydrologic models to predict the magnitude of postwildfire run‐off and erosion, existing quantitative relations to predict K_fs recovery with time since wildfire are lacking. Here, we conduct meta‐analyses of 5 datasets from the literature that measure or estimate K_fs with time since wildfire for longer than 3‐year duration. The meta‐analyses focus on fitting 2 quantitative relations (linear and non‐linear logistic) to explain trends in K_fs temporal recovery. The 2 relations adequately described temporal recovery except for 1 site where macropore flow dominated infiltration and K_fs recovery. This work also suggests that K_fs can have low hydrologic resistance (large postfire changes), and moderate to high hydrologic stability (recovery time relative to disturbance recurrence interval) and resilience (recovery of hydrologic function and provision of ecosystem services). Future K_fs relations could more explicitly incorporate processes such as soil‐water repellency, ground cover and soil structure regeneration, macropore recovery, and vegetation regrowth.     

Estimation of soil hydraulic properties and their uncertainty: comparison between laboratory and field experiment

Often the soil hydraulic parameters are obtained by the inversion of measured data (e.g. soil moisture, pressure head, and cumulative infiltration, etc.). However, the inverse problem in unsaturated zone is ill‐posed due to various reasons, and hence the parameters become non‐unique. The presence of multiple soil layers brings the additional complexities in the inverse modelling. The generalized likelihood uncertainty estimate (GLUE) is a useful approach to estimate the parameters and their uncertainty when dealing with soil moisture dynamics which is a highly non‐linear problem. Because the estimated parameters depend on the modelling scale, inverse modelling carried out on laboratory data and field data may provide independent estimates. The objective of this paper is to compare the parameters and their uncertainty estimated through experiments in the laboratory and in the field and to assess which of the soil hydraulic parameters are independent of the experiment. The first two layers in the field site are characterized by Loamy sand and Loamy. The mean soil moisture and pressure head at three depths are measured with an interval of half hour for a period of 1 week using the evaporation method for the laboratory experiment, whereas soil moisture at three different depths (60, 110, and 200 cm) is measured with an interval of 1 h for 2 years for the field experiment. A one‐dimensional soil moisture model on the basis of the finite difference method was used. The calibration and validation are approximately for 1 year each. The model performance was found to be good with root mean square error (RMSE) varying from 2 to 4 cm³ cm^?3. It is found from the two experiments that mean and uncertainty in the saturated soil moisture (θ_s) and shape parameter (n) of van Genuchten equations are similar for both the soil types. Copyright © 2010 John Wiley & Sons, Ltd.     

Impact of land use on the hydraulic properties of the topsoil in a small French catchment

The hydraulic properties of the topsoil control the partition of rainfall into infiltration and runoff at the soil surface. They must be characterized for distributed hydrological modelling. This study presents the results of a field campaign documenting topsoil hydraulic properties in a small French suburban catchment (7 km²) located near Lyon, France. Two types of infiltration tests were performed: single ring infiltration tests under positive head and tension‐disk infiltration using a mini‐disk. Both categories were processed using the BEST—Beerkan Estimation of Soil Transfer parameters—method to derive parameters describing the retention and hydraulic conductivity curves. Dry bulk density and particle size data were also sampled. Almost all the topsoils were found to belong to the sandy loam soil class. No significant differences in hydraulic properties were found in terms of pedologic units, but the results showed a high impact of land use on these properties. The lowest dry bulk density values were obtained in forested soils with the highest organic matter content. Permanent pasture soils showed intermediate values, whereas the highest values were encountered in cultivated lands. For saturated hydraulic conductivity, the highest values were found in broad‐leaved forests and small woods. The complementary use of tension‐disk and positive head infiltration tests highlighted a sharp increase of hydraulic conductivity between near saturation and saturated conditions, attributed to macroporosity effect. The ratio of median saturated hydraulic conductivity to median hydraulic conductivity at a pressure of − 20 mm of water was about 50. The study suggests that soil texture, such as used in most pedo‐transfer functions, might not be sufficient to properly map the variability of soil hydraulic properties. Land use information should be considered in the parameterizations of topsoil within hydrological models to better represent in situ conditions, as illustrated in the paper. Copyright © 2010 John Wiley & Sons, Ltd.     

Influence of pore size and geometry on peat unsaturated hydraulic conductivity computed from 3D computed tomography image analysis

In organic soils, hydraulic conductivity is related to the degree of decomposition and soil compression, which reduce the effective pore diameter and consequently restrict water flow. This study investigates how the size distribution and geometry of air‐filled pores control the unsaturated hydraulic conductivity of peat soils using high‐resolution (45 µm) three‐dimensional (3D) X‐ray computed tomography (CT) and digital image processing of four peat sub‐samples from varying depths under a constant soil water pressure head. Pore structure and configuration in peat were found to be irregular, with volume and cross‐sectional area showing fractal behaviour that suggests pores having smaller values of the fractal dimension in deeper, more decomposed peat, have higher tortuosity and lower connectivity, which influences hydraulic conductivity. The image analysis showed that the large reduction of unsaturated hydraulic conductivity with depth is essentially controlled by air‐filled pore hydraulic radius, tortuosity, air‐filled pore density and the fractal dimension due to degree of decomposition and compression of the organic matter. The comparisons between unsaturated hydraulic conductivity computed from the air‐filled pore size and geometric distribution showed satisfactory agreement with direct measurements using the permeameter method. This understanding is important in characterizing peat properties and its heterogeneity for monitoring the progress of complex flow processes at the field scale in peatlands. Copyright © 2010 John Wiley & Sons, Ltd.     

Plot‐scale measurement of soil erosion at the experimental area of Sparacia (southern Italy)

Obtaining good quality soil loss data from plots requires knowledge of the factors that affect natural and measurement data variability and of the erosion processes that occur on plots of different sizes. Data variability was investigated in southern Italy by collecting runoff and soil loss from four universal soil‐loss equation (USLE) plots of 176 m², 20 ‘large’ microplots (0·16 m²) and 40 ‘small’ microplots (0·04 m²). For the four most erosive events (event erosivity index, R_e ≥ 139 MJ mm ha^?1 h^?1), mean soil loss from the USLE plots was significantly correlated with R_e. Variability of soil loss measurements from microplots was five to ten times greater than that of runoff measurements. Doubling the linear size of the microplots reduced mean runoff and soil loss measurements by a factor of 2·6–2·8 and increased data variability. Using sieved soil instead of natural soil increased runoff and soil loss by a factor of 1·3–1·5. Interrill erosion was a minor part (0·1–7·1%) of rill plus interrill erosion. The developed analysis showed that the USLE scheme was usable to predict mean soil loss at plot scale in Mediterranean areas. A microplot of 0·04 m² could be used in practice to obtain field measurements of interrill soil erodibility in areas having steep slopes. Copyright © 2003 John Wiley & Sons, Ltd.     

Runoff generation and sediment yield on homogeneous dune slopes: scale effect and implications for analysis

Data concerning runoff and sediment yield in arid zones is of prime importance for hydrologists, geomorphologists, pedologists, ecologists and landscape engineers. For data comparison and extrapolations, runoff and sediment yield are often presented in mass per unit area. Runoff and sediment yield collected on dune slopes over a wide range of plot sizes during 1990–1994 in the Negev Desert, Israel, showed that the contributing area was mainly confined to a narrow belt at the bottom of the slopes. It was therefore hypothesized that the very short rain bursts, capable of runoff generation, may result in a scale effect (SE). Indeed, average duration of duration of consecutive medium and high rain intensities which are potentially above the surface infiltration rate ranged between 2.2 and 3.0 minutes, implying that flow connectivity is largely limited. Based on the intermittent character of the rain spells capable of runoff generation it is argued that SE is an inherent outcome of the rain properties. Yet, it is further argued that the magnitude of the SE is surface‐dependent. As a result, it is argued that the conventional way for runoff and sediment yield presentation as mass per unit area implies theoretical misconceptions and may cause gross overestimation in extrapolation and the presentation of runoff and sediment yield in mass per unit width of the slope is suggested. The accuracy of the two extrapolation methods are compared to the actual runoff and sediment yield collected in the field. The data show that extrapolation based on runoff (or sediment) yield per plot width deviates from the actual amounts collected by a factor of 1·1 to 1·3 only while deviating by a factor of 4·2 to 5·6 and 10·7 to 11·8 if the extrapolation is based on large and small plots, respectively. Theoretical and practical reasons for presentation of runoff and sediment yield as mass per unit width are discussed. Copyright © 2011 John Wiley & Sons, Ltd.     

地震动空间变异性对千米级斜拉桥结构随机地震反应的影响

基于随机振动理论,以苏通长江公路大桥为背景,对超大跨度斜拉桥在随机地震荷载作用下的动力响应展开研究,详细分析地震动空间变化特性对千米级斜拉桥结构动力响应的影响.研究结果表明:相干效应对主梁纵向弯矩影响比较大,尤其是中跨部位;而局部场地效应相对影响较小.对于主梁轴力而言,行波效应影响较为显著,主梁轴力的最大值增大约70%之多,但对竖向剪力并无突出影响.与一致激励比较,行波效应使得跨中竖向位移均方根增大约74%,相干效应为60%,而局部场地效应为13%.对于不同的内力和位移响应,地震动空间变化特性的影响程度和规律不尽相同,必须区别对待,具体问题具体分析.     

Impact of soil moisture heterogeneity length scale and gradients on daytime coupled land‐cloudy boundary layer interactions

Using a coupled large‐eddy simulation–land surface model framework, the impact of two‐dimensional soil moisture heterogeneity on the cloudy boundary layer under varied free‐atmosphere stabilities is investigated. Specifically, the impacts of soil moisture heterogeneity length scale and heterogeneity in terms of soil moisture gradients on micrometeorological states, surface fluxes, boundary layer characteristics, and cloud development are examined. The results show that mesoscale circulations due to surface heterogeneity in soil moisture play an important role in transferring water vapour within the boundary layer and in regulating cloud distribution at the entrainment zone, which, in turn, provides feedbacks on boundary layer/surface energy budgets. The initial domain‐averaged soil moisture is identical for all homogenous and heterogeneous cases; however, the soil moisture heterogeneity in gradient and length scale between dry and wet regions has a significant impact on the estimates of near‐surface micrometeorological properties and surface fluxes, which further affect the boundary layer states and characteristics. Both liquid water potential temperature and liquid water mixing ratio increase with an increasing soil moisture gradient, whereas the amount of specific humidity decreases. Heterogeneity length scale and free atmosphere stability also amplify these impacts on the boundary layer structure and cloud formation. In a low atmospheric stability condition that potentially allows for a deeper boundary layer and a higher entrainment rate, cloud base height and cloud thickness significantly increase as the soil moisture gradient and length scale increase. Analysis to differentiate the influences of surface heterogeneity type (i.e. length scale vs gradient) shows that in general soil moisture gradient provides a larger impact than heterogeneity length scale, although the heterogeneity length scale is large enough to initiate circulation features responsible for differences in the coupled system between homogeneous and heterogeneous soil moisture cases. Copyright © 2012 John Wiley & Sons, Ltd.     

A study of scale effect on specific sediment yield in the Loess Plateau,China

Based on data from 148 hydrometric stations in the Yellow River Basin, an analysis of regional scale relationship, or the relationship between specific sediment yield and drainage basin area, has been undertaken in the study area of the Loess Plateau. For different regions, scale relationship in log-log ordinate can be fitted by two types of lines: straight and parabola, and for each line, a function was fitted using regression analysis. The different scale relationships have been explained in terms of the difference in surface material distribution and landforms. To offset the scale-induced influence, calcu-lation has been done based on the fitted functions, in order to adjust the data of specific sediment yield to a common standard area. Based on the scaled data, a map of specific sediment yield was con-structed using Kriging interpolation. For comparison, a map based on the un-scaled data of specific sediment yield was also constructed using the same method. The two maps show that the basic pattern of specific sediment yield was basically the same. The severely eroded areas (Ys >10000 t km-2a-1) were at the same locations from Hekouzhen to Longmen in the middle Yellow River Basin. However, after the adjustment to a common standard area, the very severely eroded area (Ys >20000 t km-2a-1) became much enlarged because after the adjustment, all the values of Ys in the lower river basin in those regions became much larger than before.     

Effect of mineral reactions on the hydraulic properties of unsaturated soils: Model development and application

The selective radius shift model was used to relate changes in mineral volume due to precipitation/dissolution reactions to changes in hydraulic properties affecting flow in porous media. The model accounts for (i) precipitation/dissolution taking place only in the water-filled part of the pore space and further that (ii) the amount of mineral precipitation/dissolution within a pore depends on the local pore volume. The pore bundle concept was used to connect pore-scale changes to macroscopic soil hydraulic properties. Precipitation/dissolution induces changes in the pore radii of water-filled pores and, consequently, in the effective porosity. In a time step of the numerical model, mineral reactions lead to a discontinuous pore-size distribution because only the water-filled pores are affected. The pore-size distribution is converted back to a soil moisture characteristic function to which a new water retention curve is fitted under physically plausible constraints. The model equations were derived for the commonly used van Genuchten/Mualem hydraulic properties. Together with a mixed-form solution of Richards’ equation for aqueous phase flow, the model was implemented into the geochemical modelling framework PHREEQC, thereby making available PHREEQC’s comprehensive geochemical reactions. Example applications include kinetic halite dissolution and calcite precipitation as a consequence of cation exchange. These applications showed marked changes in the soil’s hydraulic properties due to mineral precipitation/dissolution and the dependency of these changes on water contents. The simulations also revealed the strong influence of the degree of saturation on the development of the saturated hydraulic conductivity through its quadratic dependency on the van Genuchten parameter α. Furthermore, it was shown that the unsaturated hydraulic conductivity at fixed reduced water content can even increase during precipitation due to changes in the pore-size distribution.     

Isotopic fractionation induced by a surface effect influences the estimation of the hydrological process of topsoil

Isotopic heterogeneity in soil water has hindered the application of isotope compositions (δ¹⁸O and δ²H) in soil water dynamics. This heterogeneity has been suggested to be caused by soil properties such as organic matter (OM) and clay content. However, this is yet to be verified in field soil. We sampled the organic layer (O-horizon soil) with highly decomposed organic material and the A-horizon soil in western Sichuan, China, and equilibrated these samples with vapour created by unconfined labelling water. The relationship between soil properties and isotopic fractionation (ε_T/U) between unconfined water and the total soil water was used to determine the line-conditioned excess (lc-excess) and source rain of A-horizon field soil by removing the influence of confined water. Equilibration experiments demonstrated a significant isotopic difference between the ε_T/U levels in the A-horizon and O-horizon soils, indicating that OM plays an important role in isotopic fractionation. In field samples, the lc-excess of the unconfined A-horizon water was, on an average, 2.5‰ higher than that of bulk soil water. The average offsets between the annual rain and the estimated source rain of soil water decreased by 5.0 and 0.5‰ for hydrogen and oxygen after removing the influence of confined water. Isotopic heterogeneity should not be ignored while examining the evaporation of soil water, soil source rain, and hence the recent ‘two water worlds’ hypothesis, which is especially true for cases in which the soils contain high levels of OM.