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1.
Groundwater is often a critical source of water for municipal, industrial and agricultural uses, especially in arid and semi‐arid environments. Songnen Plain, located in the central part of northeast China, is such a region, it being an important productive base of commodity grain in this country. In the past two decades, groundwater quality in the region, especially salinization, has deteriorated under natural changes and human activities, and has become a crucial factor restricting sustainable eco‐environmental and socio‐economic development. In this paper, The Taoer River catchment, situated in the middle of the region, was selected as the study area for the groundwater quality evolution study using hydrochemistry and stable isotopes to obtain a better understanding of the system. Fifty‐two groundwater samples were collected with systematic design during the low‐water and high‐water periods in 2003. A series of comprehensive quality data interpretations, e.g. statistics, ratios of ions and Piper diagrams, together with stable isotope data, have been used to gain an insight into the spatial and temporal variations and evolution laws of groundwater hydrochemistry. The following main hydrochemical processes were identified as controlling the water quality of the groundwater system: weathering–dissolution, evaporation–condensation, ion‐exchange reactions and groundwater salinization. This latter process, salinization, is the most important process and is caused by the leaching of superficial or near‐surface salts from the saline–alkaline soil into shallow groundwater. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

2.
We used hydrochemistry and environmental isotope data (δ18O, δD, tritium, and 14C) to investigate the characteristics of river water, groundwater, and groundwater recharge in China's Heihe River basin. The river water and groundwater could be characterized as Ca2+? Mg2+? HCO3?? SO42? and Na+? Mg2+? SO42?? Cl? types, respectively. Hydrogeochemical modelling using PHREEQC software revealed that the main hydrogeochemical processes are dissolution (except for gypsum and anhydrite) along groundwater flow paths from the upper to middle Heihe reaches. Towards the lower reaches, dolomite and calcite tend to precipitate. The isotopic data for most of the river water and groundwater lie on the global meteoric water line (GMWL) or between the GMWL and the meteoric water line in northwestern China, indicating weak evaporation. No direct relationship existed between recharge and discharge of groundwater in the middle and lower reaches based on the isotope ratios, d‐excess, and 14C values. On the basis of tritium in precipitation and by adopting an exponential piston‐flow model, we evaluated the mean residence time of shallow groundwater with high tritium activities, which was around 50 years (a). Furthermore, based on the several popular models, it is calculated that the deep groundwaters in piedmont alluvial fan zone of the middle reaches and in southern part of the lower reaches are modern water, whereas the deep groundwaters in the edge of the middle reaches and around Juyan Lake in the lower reaches of Heihe river basin are old water. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

3.
Principal component analysis (PCA) was applied to hydrochemical and isotopic data of 34 groundwater samples. This allowed the reduction of 20 variables to four significant PCs that explain 81.9% of the total variance; F1 (47.1%) explains the groundwater mineralization, whereas F2 (17%) shows isotopic enrichment and nitrate pollution. Based on an iso-factor scores map of F1, three water zones were delineated: Zone A (F1 < ?1), with fresh groundwater from the unconfined aquifer; Zone B (1 > F1 > ?1), with moderate mineralization from the confined–unconfined aquifer boundary; and Zone C (F1 > 1), with the most mineralized hot water from the confined aquifer. The iso-factor scores map of F2 delineates positive values representing samples from the unconfined aquifer, with freshwater and nitrate contamination associated with stable isotope enrichment, whereas negative values represent samples from the confined aquifer. The results clearly demonstrate the usefulness of PCA in groundwater hydrochemistry investigations.  相似文献   

4.
The surface water and groundwater are important components of water cycle, and the interaction between surface water and groundwater is the important part in water cycle research. As the effective tracers in water cycle research, environmental isotope and hydrochemistry can reveal the interrelationships between surface water and groundwater effectively. The study area is the Huaisha River basin, which is located in Huairou district, Beijing. The field surveying and sampling for spring, river and well water were finished in 2002 and 2003. The hydrogen and oxygen isotopes and water quality were measured at the laboratory. The spatial characteristics in isotope and evolution of water quality along river lines at the different area were analyzed. The altitude effect of oxygen isotope in springs was revealed, and then using this equation, theory foundation for deducing recharge source of spring was estimated. By applying the mass balance method, the annual mean groundwater recharge rate at the catchment was estimated. Based on the groundwater recharge analysis, combining the hydrogeological condition analysis, and comparing the rainfall-runoff coefficients from the 1960s to 1990s in the Huaisha River basin and those in the Chaobai River basin, part of the runoff in the Huaisha River basin is recharged outside of this basin, in other words, this basin is an un-enclosed basin. On the basis of synthetically analyses, combining the compositions of hydrogen and oxygen isotopes and hydrochemistry, geomorphology, geology, and watershed systems characteristics, the relative contributions between surface water and groundwater flow at the different areas at the catchments were evaluated, and the interaction between surface water and groundwater was re- vealed lastly.  相似文献   

5.
The groundwater hydrochemical behaviour of the Langueyú creek basin (Argentina) has been evaluated through a systematic survey, followed by application of hydrological and chemometric multivariate techniques. Ten physicochemical parameters were determined in groundwater samples collected from 26 wells during four sampling campaigns (June 2010; October 2010; February 2011 and June 2011), originating a tridimensional experimental dataset X . Univariate statistical and graphical hydrochemical tools (contour maps and Piper diagrams) applied to individual campaigns, allowed to reach some preliminary conclusions. However, a best visualization of the aquifer behaviour was achieved by applying Principal Component Analysis (MA‐PCA) and N‐way PCA procedures, Parallel Factor Analysis and Tucker3. Results were consistent with two‐term models, being Tucker3 [2 2 1] the most adequate, explaining a large amount of the dataset variance (50.7%) with a low complexity. The first Tucker3 [1 1 1] interaction (38.2% of variance) is related with (i) calcium/magnesium versus sodium/potassium ion exchange processes; (ii) an increase of ionic concentration and (iii) a decrease of nitrate pollution, all processes along the direction of the groundwater flow. The second [2 2 1] interaction (12.5% of variance), accounts for the predominant role played by conductivity, bicarbonate and magnesium in the dataset. The seasonal variations are closely related to concentration/dilution phenomena originated by the variations of the phreatic levels, although this point will require additional sampling to establish a definitive hydrochemical model. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

6.
The conceptual hydrogeological model of the low to medium temperature Daying and Qicun geothermal fields has been proposed, based on hydrochemical characteristics and isotopic compositions. The two geothermal fields are located in the Xinzhou basin of Shanxi, China and exhibit similarities in their broad‐scale flow patterns. Geothermal water is derived from the regional groundwater flow system of the basin and is characterized by Cl·SO4‐Na type. Thermal water is hydrochemically distinct from cold groundwater having higher total dissolved solids (TDS) (>0·8 g/l) and Sr contents, but relatively low Ca, Mg and HCO3 contents. Most shallow groundwater belongs to local flow systems which are subject to evaporation and mixing with irrigation returns. The groundwater residence times estimated by tritium and 14C activities indicate that deep non‐thermal groundwater (130–160 m) in the Daying region range from modern (post‐1950s) in the piedmont area to more than 9·4 ka BP (Before Present) in the downriver area and imply that this water belong to an intermediate flow system. Thermal water in the two geothermal fields contains no detectable active 14C, indicating long residence times (>50 ka), consistent with this water being part of a large regional flow system. The mean recharge elevation estimated by using the obtained relationship Altitude (m) = ? 23·8 × δ2H (‰ ) ? 121·3, is 1980 and 1880 m for the Daying and Qicun geothermal fields, respectively. The annual infiltration rates in the Daying and Qicun geothermal fields can be estimated to be 9029 × 103 and 4107 × 103 m3/a, respectively. The variable 86Sr/87Sr values in the thermal and non‐thermal groundwater in the two fields reflect different lithologies encountered along the flow path(s) and possibly different extents of water‐rock interaction. Based on the analysis of groundwater flow systems in the two geothermal fields, hydrogeochemical inverse modelling was performed to indicate the possible water‐rock interaction processes that occur under different scenarios. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

7.
Chahardouly basin is located in the western part of Iran and is characterized by semi‐arid climatic conditions and scarcity in water resources. The main aquifer systems are developed within alluvial deposits. The availability of groundwater is rather erratic owing to the occurrence of hard rock formation and a saline zone in some parts of the area. The aquifer systems of the area show signs of depletion, which have taken place in recent years due to a decline in water levels. Groundwater samples collected from shallow and deep wells were analysed to examine the quality characteristics of groundwater. The major ion chemistry of groundwater is dominated by Ca2+ and HCO3?, while higher values of total dissolved solids (TDS) in groundwater are associated with high concentrations of all major ions. An increase in salinity is recorded in the down‐gradient part of the basin. The occurrence of saline groundwater, as witnessed by the high electrical conductivity (EC), may be attributed to the long residence time of water and the dissolution of minerals, as well as evaporation of rainfall and irrigation return flow. Based on SAR values and sodium content (%Na), salinity appears to be responsible for the poor groundwater quality, rendering most of the samples not suitable for irrigation use. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

8.
Comprehending the recharge of thermal springs is crucial for preserving the water quality of such springs. However, limited groundwater well data in mountainous areas presents a challenge to determining thermal-spring recharge areas. This study analyzes the isotopes (δ2H and δ18O) and major ions in rainwater, streamwater, mountain groundwater and thermal spring water in Jiaoxi, located near Taiwan's largest city, Taipei. The results of the isotope-elevation relationship and GIS recharge analysis indicate that the thermal spring water originated from a remote mountain at elevations of approximately 1170–1480 m, rather than the upstream watershed. The thermal spring water was divided into two groups based on the carbonate saturation index (SI) and isotope composition: the foothill group, which had a positive SI and lower δ value, and the downstream group, which had a negative SI and higher δ value. This study improved the conceptual model of the thermal flow path by demonstrating that the recharge of thermal water is a transboundary regional flow and that the foothill thermal water does not mix with the meteoric water. The revised model also highlights the role of structural lineament trends (faults, fractures and folds) in the movement of regional flow in fractured mountain blocks.  相似文献   

9.
A long‐term study of O, H and C stable isotopes has been undertaken on river waters across the 7000‐km2 upper Thames lowland river basin in the southern UK. During the period, flow conditions ranged from drought to flood. A 10‐year monthly record (2003–2012) of the main River Thames showed a maximum variation of 3‰ (δ18O) and 20‰ (δ2H), although interannual average values varied little around a mean of –6.5‰ (δ18O) and –44‰ (δ2H). A δ2H/δ18O slope of 5.3 suggested a degree of evaporative enrichment, consistent with derivation from local rainfall with a weighted mean of –7.2‰ (δ18O) and –48‰ (δ2H) for the period. A tendency towards isotopic depletion of the river with increasing flow rate was noted, but at very high flows (>100 m3/s), a reversion to the mean was interpreted as the displacement of bank storage by rising groundwater levels (corroborated by measurements of specific electrical conductivity). A shorter quarterly study (October 2011–April 2013) of isotope variations in 15 tributaries with varying geology revealed different responses to evaporation, with a well‐correlated inverse relationship between Δ18O and baseflow index for most of the rivers. A comparison with aquifer waters in the basin showed that even at low flow, rivers rarely consist solely of isotopically unmodified groundwater. Long‐term monitoring (2003–2007) of carbon stable isotopes in dissolved inorganic carbon (DIC) in the Thames revealed a complex interplay between respiration, photosynthesis and evasion, but with a mean interannual δ13C‐DIC value of –14.8 ± 0.5‰, exchange with atmospheric carbon could be ruled out. Quarterly monitoring of the tributaries (October 2011–April 2013) indicated that in addition to the aforementioned factors, river flow variations and catchment characteristics were likely to affect δ13C‐DIC. Comparison with basin groundwaters of different alkalinity and δ13C‐DIC values showed that the origin of river baseflow is usually obscured. The findings show that long‐term monitoring of environmental tracers can help to improve the understanding of how lowland river catchments function. Copyright © NERC 2015. Hydrological Processes © 2015 John Wiley & Sons, Ltd.  相似文献   

10.
Kinmen is located in the south‐west of Mainland China and mainly has two islands, Large Kinmen and Leiyu. Residents in Kinmen have drunk groundwater over several decades. This work characterized the quality of groundwater in Kinmen using factor analysis (FA), cluster analysis (CA) and geochemical simulation. The factor scores were plotted spatially to illustrate the groundwater quality and were used to discuss the grouped relationship using CA. Salinization, redox and organic matter factors are identified from 17 hydrochemical measurements in 18 wells. Acidic and oxidizing groundwater with nitrate‐N pollution is distributed mainly in the west of Large Kinmen. Saline groundwater is distributed to the north‐east of Large Kinmen and in the south of Leiyu. Groundwater with organic matter is present throughout Leiyu. Five groups of the groundwater quality divided by CA can be interpreted according to one to three factors. The grouped characteristics of the groundwater quality help the local government and industries to plan the use and protection of groundwater resources. Furthermore, a geochemical simulation was used to demonstrate the formation processes of the acidic and oxidizing groundwater properties in granitic sediments. A large amount of the precipitation of the kaolinite and magnetite releases concentrations of hydrogen ion and raises the redox potential in the aquifers. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
Based on data from the middle Yellow River basin, a wind-water two-phase mechanism for erosion and sediment-producing processes has been found. By using this mechanism, the extremely strong erosion and sediment yield in the study area can be better explained. The operation of wind and water forces is different in different seasons within a year. During winter and spring, strong wind blows large quantities of eolian sand to gullies and river channels, which are temporally stored there. During the next summer, rainstorms cause runoff that contains much fine loessic material and acts as a powerful force to carry the previously prepared coarse material. As a result, hyperconcentrated flows occur, resulting in high-intensity erosion and sediment yield.  相似文献   

12.
We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO3? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO3?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ18O and δ2H values of groundwater were also different between the two zones. Hydrochemical and δ18O? δ2H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO3?. The 3H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ18O and δ2H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

13.
The strategic project of economic development in the Dornogobi Province in Mongolia is dependent on water supply. Thus a comprehensive hydrogeological characterization was focused on the Upper Cretaceous multi-aquifer system north of Sainshand city. A conceptual model was developed to discover the groundwater flow pattern essential to correct the setting of the numerical model of groundwater flow created using MODFLOW to assess the natural recharge of the aquifer. The conceptualization was based on geological and hydrogeological characterization. However, the evaluation of hydrochemistry proved to be the key factor revealing the principal feature of the groundwater flow pattern, which is the presence of preferential flow zones. These zones allow for intensive transfer of relatively fresh Na(Mg,Ca)?HCO3-dominated groundwater into discharge areas, where it leaks into the Quaternary aquifer. The numerical model suggested an enormous natural recharge of 22 100 m3/d, originating in 64% of the preferential flow zones.  相似文献   

14.
本文在物元分析理论的基础上,将水质量标准、评价指标及其特征值作为物元,并以苏州市第Ⅱ承压地下水为例进行了水质评价。通过建立评价模型,对评价标准及实测数据进行归一化,得到模型的经典域、节域、权系数及关联度,评价结果表明,苏州市大部分第Ⅱ承压地下水水质优良,达到了Ⅰ、Ⅱ类水,未遭受外来物质的污染,评价结果符合实际情况。  相似文献   

15.
Surface water and groundwater in the Heihe river basin of China are interconnected and the pattern of water resources exploitation has a direct effect on the interaction of groundwater and surface water, especially on a downstream oasis. A three‐dimensional groundwater flow simulation model with eight model layers was established to simulate the regional groundwater flow in the multilayered aquifer system and the interaction among the rivers, springs, and groundwater. The model was calibrated not only with historical water levels but also with the investigated baseflow and spring flux. The simulation results of the numerical model match reasonably well with the observed groundwater levels, baseflow to rivers, and spring flux. The numerical simulation also demonstrates that the hydraulic connection between the river and the aquifers has transferred from the coupling to decoupling at some reaches. It is suggested that there is a vital need to reduce groundwater withdrawal and to rationalize the use of both groundwater and surface water in order to maintain sustainable development in the study area. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

16.
The main objective of this study was to use an uncertainty version of a widely used monthly time step, semi-distributed model (the Pitman model) to explore the equifinalities in the way in which the main hydrological processes are simulated and any identifiable linkages with uncertainties in the available observational data. The study area is the Zambezi River basin and 17 gauged sub-basins have been included in the analyses. Unfortunately, it is not generally possible to quantify some of the observational uncertainties in such a data scarce area and mostly we are limited to identifying where these data are clearly deficient (i.e., erroneous or non-representative). The overall conclusion is that the equifinalities in the model are hugely dominant in terms of the uncertainties in the relative occurrence of different runoff generating processes, although water use uncertainties in the semi-arid parts of the basin can contribute to these uncertainties. The identification of landscape features that suggest the occurrence of saturation excess surface runoff provides some information to constrain the model. Improved independent estimates of groundwater recharge is also identified as a key source of observational data that would help a great deal in constraining the model parameter space and therefore reducing some of the model equifinality.  相似文献   

17.
The main purpose of this study is to identify the major factors affecting groundwater quality by means of multivariate statistical analysis of the physico‐chemical compositions. Cluster analysis results show that the groundwater in the study area is classified into four groups (A, B, C and D), and factor analysis indicates that groundwater composition, 81·9% of the total variance of 17 variables, is mainly affected by three factors: seawater intrusion, microbial activity and chemical fertilizers. These results might be related to the geographical characteristics of the study area. The main influence on groundwater in groups B, C and D, which are close to the Yellow Sea and contain reclaimed areas, is the seawater intrusion by the present seawater, the trapped seawater, and microbial activity. Group A, however, has been used for agriculture for a long time, and thus groundwater in this group has been largely affected by chemical fertilizers. As groundwater flows from group A to group D according to its path, the governing factor of the groundwater quality gradually changes from chemical fertilizers to microbial activity and seawater intrusion. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

18.
The planning and management of water resources in the Shiyang River basin, China require a tool for assessing the impact of groundwater and stream use on water supply reliabilities and improving many environment‐related problems such as soil desertification induced by recent water‐related human activities. A coupled model, integrating rule‐based lumped surface water model and distributed three‐dimensional groundwater flow model, has been established to investigate surface water and groundwater management scenarios that may be designed to restore the deteriorated ecological environment of the downstream portion of the Shiyang River basin. More than 66% of the water level among 24 observation wells have simulation error less than 1·0 m. The overall trend of the temporal changes of simulated and observed surface runoff at the Caiqi gauging station remains almost the same. The calibration was considered satisfactory. Initial frameworks for water allocation, including agricultural water‐saving projects, water diversion within the basin and inter‐basin water transfer, reducing agricultural irrigation area and surface water use instead of groundwater exploitation at the downstream were figured out that would provide a rational use of water resources throughout the whole basin. Sixteen scenarios were modelled to find out the most appropriate management strategies. The results showed that in the two selected management options, the groundwater budget at the Minqin basin was about 1·4 × 108 m3/a and the ecological environment would be improved significantly, but the deficit existed at the Wuwei basin and the number was about 0·8 × 108 m3/a. Water demand for domestic, industry and urban green area would be met in the next 30 years, but the water shortage for meeting the demand of agricultural water use in the Shiyang River basin was about 2·2 × 108 m3/a. It is suggested that more inter‐basin water transfer should be required to obtain sustainable water resource use in the Shiyang River basin. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

19.
Jordan is classified as an arid to semi‐arid country with a population according to 1999 estimates of 4·8 millions inhabitants and a growth rate of 3·4%. Efficient use of Jordan's scarce water is becoming increasingly important as the urban population grows. This study was carried out within the framework of the joint European Research project ‘Groundwater recharge in the eastern Mediterranean’ and describes a combined methodology for groundwater recharge estimation in Jordan, the chloride method, as well as isotopic and hydrochemical approaches. Recharge estimations using the chloride method range from 14 mm year?1 (mean annual precipitation of 500 mm) for a shallow and stony soil to values of 3·7 mm year?1 for a thick desert soil (mean annual precipitation of 100 mm) and values of well below 1 mm year?1 for thick alluvial deposits (mean annual rainfall of 250 mm). Isotopically, most of the groundwater in the Hammad basin, east Jordan, falls below the global meteoric water line and far away from the Mediterranean meteoric water line, suggesting that the waters are ancient and were recharged in a climate different than Mediterranean. Tritium levels in the groundwater of the Hammad basin are less than the detection limit (<1·3 TU). However, three samples in east Hammad, where the aquifer is unconfined, present tritium values between 1 and 4 TU. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

20.
A genetic and evolutionary model is established for saline depressions in continental areas. These depressions are located in arid or subarid areas, and are developed on low permeability geological mediums (K<10 mm/day) with a lack of streams reaching the small lakes. The phenomenon of evaporation is fundamental, since it is the basic requirement for the presence or absence of a free water surface in the lake, and also for depression of the phreatic surface, which causes inflow of groundwater towards the lake. With these conditions, the proposed model includes the following stages: (i) initiation of the close depression; (ii) deepening of the depression; (iii) formation of the lake basin and the end of the deepening; and (iv) levelling and lateral extension of the lake basin. The combined effects of groundwater flows and aeolian action offer a coherent explanation for the origin and evolution both of the closed depressions found in the Ebro Valley, and of the salt lakes that subsequently form. The processes described form morphologies of oval shape with the main axis parallel to the direction of the wind, flat floors and evaporitic sedimentation, although they act on geological materials with different lithologies. © 1998 John Wiley & Sons, Ltd.  相似文献   

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