Some problems of Venus' atmospheric dynamics

A brief survey is given of the observational data on wind speeds in the atmosphere of Venus, as well as results of the theory of similitude and of a scale analysis for estimation of the wind speeds and temperature contrasts. It is shown that, in the lower portion of the atmosphere, containing roughly half of the mass, the first method produces results which are in somewhat better agreement with the measurements. Measurements of the wind distribution in the atmosphere are discussed. It is shown that, in the slowly rotating atmosphere of Venus, we should expect the Solberg mechanism of inertial instability of the circulation to be effective with respect to axisymmetrical perturbations. The numerical experiments of G.P. Williams (1968, J. Atmos. Sci., 25, 34–1045; 1970, Geophys. Fluid Dyn., 1, 357–369) indicate that in this case the circulation in the meridional plane can be broken down into a series of forward and reverse cells. The existence of such cells can serve to preserve the angular momentum of the planet with its atmosphere—the total momentum of the atmospheric frictional forces against the surface should on the average equal zero. This supports the hypothesis of G. Schubert et al. (1980, J. Geophys. Res., 85, 8007–8025) concerning the multicellular structure of the meridional circulation. Data are analyzed with regard to the time variability of the circulation. If the angular momentum of Venus′ atmosphere can change by 30% (which is not excluded by the presently available data; in Earth's atmosphere seasonal variations of the momentum reach 50%), then the relative variations in the length of a Venusian day will attain 10^?3, i.e., several hours. The surface boundary layer is considered. It is shown that, due to the small transparency of the atmosphere to thermal radiation, heat transfer between the surface and the atmosphere should basically take place by turbulent heat exchange. The basic parameters of the dynamic and thermal regimes of this layer are estimated. Questions of light refraction in the boundary layer are discussed. A strict theory of refraction, developed for these conditions, confirms the preliminary rough estimates of V.I. Moroz (1976, Cosmic Res., 14, No. 5, 691–692; Space Sci. Rev., 25, 3–127), viz, that the horizon is visible on the panorama at a distance of order 100m, due to a relatively sharp negative gradient near the surface.     

Ionospheric photoelectrons: Comparing Venus, Earth, Mars and Titan

The sunlit portion of planetary ionospheres is sustained by photoionization. This was first confirmed using measurements and modelling at Earth, but recently the Mars Express, Venus Express and Cassini-Huygens missions have revealed the importance of this process at Mars, Venus and Titan, respectively. The primary neutral atmospheric constituents involved (O and CO₂ in the case of Venus and Mars, O and N₂ in the case of Earth and N₂ in the case of Titan) are ionized at each object by EUV solar photons. This process produces photoelectrons with particular spectral characteristics. The electron spectrometers on Venus Express and Mars Express (part of ASPERA-3 and 4, respectively) were designed with excellent energy resolution (ΔE/E=8%) specifically in order to examine the photoelectron spectrum. In addition, the Cassini CAPS electron spectrometer at Saturn also has adequate resolution (ΔE/E=16.7%) to study this population at Titan. At Earth, photoelectrons are well established by in situ measurements, and are even seen in the magnetosphere at up to 7R_E. At Mars, photoelectrons are seen in situ in the ionosphere, but also in the tail at distances out to the Mars Express apoapsis (∼3R_M). At both Venus and Titan, photoelectrons are seen in situ in the ionosphere and in the tail (at up to 1.45R_V and 6.8R_T, respectively). Here, we compare photoelectron measurements at Earth, Venus, Mars and Titan, and in particular show examples of their observation at remote locations from their production point in the dayside ionosphere. This process is found to be common between magnetized and unmagnetized objects. We discuss the role of photoelectrons as tracers of the magnetic connection to the dayside ionosphere, and their possible role in enhancing ion escape.     

A first look at atmospheric dynamics and temperature variations on Titan

Pollack (1973) has used a radiative equilibrium model to match radiometric data for Titan and infers the atmospheric mass, composition, opacity, and gross vertical thermal structure. These results are used to estimate the atmospheric temperature variations by means of scaling analysis, taking into account dynamics both for a baroclinic wave regime and for an axially symmetric circulation regime. Horizontal temperature variations of the atmosphere and surface are found to be very small, and the circulation is found to be weak and probably axially symmetric. The small temperature variations appear to preclude the storage of volatiles in polar caps, so that the present atmospheric methane content may be due to a balance between outgassing and photodissociation.     

Atmospheric dynamics on the outer planets and some of their satellites

A short review of the atmospheric dynamics for the outer planets and some of their satellites with atmospheres is presented. Their physical properties are discussed. A survey of observational data for atmospheric motions on the large planets is presented and similarity parameters are given for all objects. General problems of the vertical structure of atmospheres are then considered with some detailed discussion for rarefied atmospheres on Io and Ganymede. The low densities of these atmospheres make their dynamics similar to those of the thermospheres of the terrestrial planets but with a specific boundary layer. The atmospheric temperature regime must be strongly coupled to that of their surface, and so winds should be of the order of the velocity of sound. Similarities and differences are noted between the dynamics of Titan and possibly of Pluto and the circulation on Venus. For large and rapidly rotating planets, some analogies with the oceans are pointed out. The “soliton” hypothesis is discussed in some detail for circulation perturbations observed on Jupiter's disk. Finally, it is noted that the bimodal rotation period found for Neptune [D.P. Cruikshank, Astrophys. J. 220, 157–159 (1978)] may be interpreted as an indication of an equatorial jet on the planet with a relative velocity of about 140 m sec^?1.     

Structure of the Venus mesosphere and lower thermosphere from measurements during entry of the pioneer Venus probes

Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27°S latitude. Comparison of the midnight sounding with the morning sounding at 31°S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of G. M. Keating, J. Y. Nicholson, and L. R. Lake (1980, J. Geophys. Res., 85, 7941–7956) above 140 km with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are ～ 130°K, somewhat warmer than those reported by Keating et al.     

The spectrum of titan in the far-infrared and microwave regions

The pressure-induced absorptions of gaseous nitrogen (N₂) and methane (CH₄) are computed on the basis of the collisional lineshape theory of G. Birnhaum and E.R. Cohen [Canad. J. Phys.54, 593–602 (1976)]. Laboratory data at 300 and 124°K for N₂ and at 296 and 195°K for CH₄ are used to determine the collisional time constant and their temperature dependence. The spectrum of Titan from the microwave to the far-infrared region (0.1–600 cm^?1) is then modeled using these opacities and a temperature profile of Titan's atmosphere derived from the Voyager 1 radio occultation experiment. The model atmosphere is composed of N₂ and CH₄, their relative proportions being determined by the vapor pressure law of CH₄. A model with gaseous opacity alone is ruled out by the far-infrared observations. An additional opacity, thought to be associated with a methane cloud, is confirmed. The effective temperature of Titan is estimated at T_e = 83.2 ± 1.4°K.     

The D/H Ratio in Methane in Titan: Origin and History

We propose a new interpretation of the D/H ratio in CH₄ observed in the atmosphere of Titan. Using a turbulent evolutionary model of the subnebula of Saturn (O. Mousis et al. 2002, Icarus156, 162-175), we show that in contrast to the current scenario, the deuterium enrichment with respect to the solar value observed in Titan cannot have occurred in the subnebula. Instead, we argue that values of the D/H ratio measured in Titan were obtained in the cooling solar nebula by isotopic thermal exchange of hydrogen with CH₃D originating from interstellar methane D-enriched ices that vaporized in the nebula. The rate of the isotopic exchange decreased with temperature and became fully inhibited around 200 K. Methane was subsequently trapped in crystalline ices around 10 AU in the form of clathrate hydrates formed at 60 K, and incorporated into planetesimals that formed the core of Titan. The nitrogen-methane atmosphere was subsequently outgassed from the decomposition of the hydrates (Mousis et al. 2002). By use of a turbulent evolutionary model of the solar nebula (O. Mousis et al. 2000, Icarus148, 513-525), we have reconstructed the entire story of D/H in CH₄, from its high value in the early solar nebula (acquired in the presolar cloud) down to the value measured in Titan's atmosphere today. Considering the two last determinations of the D/H ratio in Titan—D/H=(7.75±2.25)×10⁻⁵ obtained from ground-based observations (Orton 1992, In: Symposium on Titan, ESA SP-338, pp. 81-85), and D/H=(8.75^+3.25_−2.25)×10⁻⁵, obtained from ISO observations (Coustenis et al. 2002, submitted for publication)—we inferred an upper limit of the D/H ratio in methane in the early outer solar nebula of about 3×10⁻⁴. Our approach is consistent with the scenario advocated by several authors in which the atmospheric methane of Titan is continuously replenished from a reservoir of clathrate hydrates of CH₄ at high pressures, located in the interior of Titan. If this scenario is correct, observations of the satellite to be performed by the radar, the imaging system, and other remote sensing instruments aboard the spacecraft of the Cassini-Huygens mission from 2004 to 2008 should reveal local disruptions of the surface and other signatures of the predicted outgassing.     

A theoretical investigation into the trapping of noble gases by clathrates on Titan

In this paper, we use a statistical thermodynamic approach to quantify the efficiency with which clathrates on the surface of Titan trap noble gases. We consider different values of the Ar, Kr, Xe, CH₄, C₂H₆ and N₂ abundances in the gas phase that may be representative of Titan's early atmosphere. We discuss the effect of the various parameters that are chosen to represent the interactions between the guest species and the ice cage in our calculations. We also discuss the results of varying the size of the clathrate cages. We show that the trapping efficiency of clathrates is high enough to significantly decrease the atmospheric concentrations of Xe and, to a lesser extent, of Kr, irrespective of the initial gas phase composition, provided that these clathrates are abundant enough on the surface of Titan. In contrast, we find that Ar is poorly trapped in clathrates and, as a consequence, that the atmospheric abundance of argon should remain almost constant. We conclude that the mechanism of trapping noble gases via clathration can explain the deficiency in primordial Xe and Kr observed in Titan's atmosphere by Huygens, but that this mechanism is not sufficient to explain the deficiency in Ar.     

An electrodynamic model of the solar wind interaction with the ionospheres of Mars and Venus

The electrodynamic model for the solar wind interaction with non-magnetic planets. (Cloutier and Daniell, Planet. Space Sci.21, 463, 1973; Daniell and Cloutier, Planet. Space Sci.25, 621, 1977) is modified to include the effects of non-ohmic currents in the upper ionosphere. The model is then used to calculate convection patterns induced by the solar wind in the ionospheres of Mars and Venus. For Mars the observations of the neutral mass spectrometer or Vikings 1 and 2 provided the neutral atmosphere. Model calculations reproduced the retarding potential analyzer data and indicate that the ionosphere above about 200 km is probably controlled by convection rather than chemistry or diffusion. For Venus a model atmosphere based on Dickenson and Ridley, J. Atmos. Sci.32, 1219 (1975) and Mayr et al., J. geophys. Res.83, 4411 (1978) was used. The resulting model calculations were compared to radio occultation data from Mariners 5 and 10 and Venera 9 which represent extremes in the variability of the upper Cytherean ionosphere. The model calculations are shown to fall within this variation. These results represent the state of the theory immediately prior to the Pioneer-Venus encounter.     

Comment on absorbing regions in the atmosphere of Venus as measured by radio occultation

Two recent papers, one by A.J. Kliore, C. Elachi, I.R. Patel, and J.B. Cimeno, Icarus37, 51-2- 72, 1979, and one by B. Lipa and G.L. Tyler, Icarus39, 192–208, 1979, reach fundamentally different conclusions concerning microwave absorption in the atmosphere of Venus, even though they are based on the same Mariner 10 radio occultation data. The Lipa and Tyler results are in general agreement with earlier Mariner 5 measurements analyzed by G. Fjeldbo, A.J. Kliore, and V.R. Eshleman, Astron. J.76, 123–140, 1971. We find that in the Kliore et al. treatment: (1) the effects of measurements and analysis uncertainties in the derived values of absorption are underestimated; (2) an incorrect formula is used for computation of the refractive effects needed to determine the absorption; (3) detailed features of a derived profile of absorption would have been created in an optically thin region by known motions of the spacecraft antenna, if its axial direction were biased about 0.5° from the computed directions; and (4) this particular angular bias is consistent with other available information about an apparent residual difference between true and reconstructed antenna pointing directions. We conclude that: (1) there is no credible evidence for measurable microwave absorption in the atmosphere of Venus at heights greater than 55 km for any of the wavelengths that have been used in radio occultation experiments, even though Kliore et al. indicate that there are significant amounts up to at least 70 km for both Mariner 10 wavelengths (13 and 3.6 cm); (2) absorption in the region 35 to 50 km has been reasonably well determined from the two concordant Mariner 5 and 10 analyses, but only at one wavelength (13 cm); and (3) improved instrumentation and careful planning and analysis will be required for the radio occultation technique to realize its potential for the study of absorbing regions in the atmospheres of Venus and the major planets.     

Variability of carbon monoxide in the mars atmosphere

In January of 1982 we measured a microwave spectrum of CO in the Martian atmosphere utilizing the rotational J = 1 → 2 transition of CO. We have analyzed data and reanalyzed the microwave spectra of R. K. Kakar, J. W. Waters, and W. J. Wilson, (Science196, 1090–1091, 1977, measured in 1975) and J. C. Good and F. P. Schloerb, (Icarus47, 166–172, 1981 measured in 1980) in order to constrain estimates of the temporal variability of CO abundance in the Martian atmosphere. Our values of CO column density from the data of Karar et al., Good and Schloerb, and our own are 1.7 ± 0.9 × 10²⁰, 3.0 ± 1.0 × 10²⁰, and 4.6 ± 2.0 × 10²⁰cm^?2, respectively. The most recent estimate of CO column density from the 1967 infrared spectra of J. Connes, P. Connes, and J.P. Maillard, (Atlas de Spectres Infarouges de Venus, Mars, Jupiter, et Saturne, Editions due Centre National de la Recherche Scientifique, Paris, 1969), is 2.0 ± 0.8 × 10²⁰ cm^?2 (L.D.G. Young and A.T. Young, Icarus30, 75–79, 1977). The large uncertainties given for the microwave measurements are due primarily to uncertainty in the difference between the continuum brightness temperature and atmospheric temperatures of Mars. We have accurately calculated the variation among the observations of the continuum (surface) brightness temperature of Mars, which is primaroly a function of the observed aspect of Mars. A more difficult problem to consider is variability of global atmospheric temperatures among the observations, particularly the effects of global dust storms and the ellipticity of the orbit of Mars. The large bars accompanying our estimates of CO column density from the three sets of microwave measurements are primarily caused by an assumed uncertainty of ±10°K in our atmospheric temperature model due to possible dust in the atmosphere. A qualitative consideration of seasonal variability of global atmospheric temperatures among the measurements suggests that there is not strong evidence for variability of the column abundance of CO on Mars, although variability of 0–100% over a time scale of several years is allowed by the data set. The implication for the variability of Mars O₂ is, crudely, a factor of two less. We found that the altitude distribution of CO in the atmosphere of Mars was not well constrained by any of the spectra, although our spectrum was marginally better fitted by an altitude increasing profile of CO mixing ratios.     

Polarization studies of the Venus uv contrasts: Cloud height and haze variability

Polarimetry is able to show direct evidence for compositional differences in the Venus clouds. We present observations (collected during $\text{2}\text{1}\text{2}$ Venus years by the Pioneer Venus Orbiter) of the polarization in four colors of the bright and dark ultraviolet features. We find that the polarization is significantly different between the bright and dark areas. The data show that the “null” model of L. W. Esposito (1980, J. Geophys. Res.85, 8151–8157) and the “overlying haze” model of J. B. Pollack et al. (1980, J. Geophys. Res.85, 8223–8231) are insufficient. Exact calculations of the polarization, including multiple scattering and vertical inhomogeneity near the Venus cloud tops, are able to match the observations. Our results give a straightforward interpretation of the polarization differences in terms of known constituents of the Venus atmosphere. The submicron haze and uv absorbers are anticorrelated: for haze properties as given by K. Kawabata et al. (1980, J. Geophys. Res.85, 8129–8140) the excess haze depth at 9350 Å over the bright regions is Δτ_h = 0.03 ± 0.02. The cloud top is slightly lower in the dark features: the extra optical depth at 2700 Å in Rayleigh scattering above the darker areas is Δτ_R = 0.010 ± 0.005. This corresponds to a height difference of 1.2 ± 0.6 km at the cloud tops. The calculated polarization which matches our data also explains the relative polarization of bright and dark features observed by Mariner 10. The observed differential polarization cannot be explained by differential distribution of haze, if the haze aerosols have an effective size of 0.49 μm, as determined by K. Kawabata et al. (1982, submitted) for the aerosols overlying the Venus equator. We propose two models for the uv contrasts consistent with our results. In a physical model, the dark uv regions are locations of vertical convergence and horizontal divergence. In a chemical model, we propose that the photochemistry is limited by local variations in water vapor and molecular oxygen. The portions of the atmosphere where these constituents are depleted at the cloud tops are the dark uv features. Strong support for this chemical explanation is the observation that the number of sulfur atoms above the cloud tops is equal over both the bright and dark areas. The mass budget of sulfur at these altitudes is balanced between excess sulfuric acid haze over the bright regions and excess SO₂ in the dark regions.     

Dynamics and circulation regimes of terrestrial planets

By the study of simple analogues, either in the form of simplified numerical models or laboratory experiments, considerable insights may be gained as to the likely roles of planetary size, rotation, thermal stratification and other factors in determining the principal length scales, styles of global circulation and dominant waves and instability processes active in the respective climate systems of Earth, Mars, Venus and Titan. In this review, we explore aspects of these analogues and demonstrate the importance of a number of key dimensionless parameters, most notably thermal Rossby and Rhines numbers and a measure of the dominant frictional or radiative timescale, in defining the type of circulation regime to be expected in a prototype planetary atmosphere subject to axisymmetric driving. These considerations help to place Mars, Venus, Titan and Earth into an appropriate context, and may also lay the foundations for predicting and understanding the climate and circulation regimes of (as yet undiscovered) Earth-like extra-solar planets. However, as recent discoveries of ‘super-Earth’ planets around some nearby stars are beginning to reveal, the parameter space determined from axisymmetrically forced prototype atmospheres may be incomplete and other factors, such as the possibility of tidally locked rotation and tidal forcing, may also need to be taken into account for some classes of extra-solar planet.     

Experimental laboratory simulation of Titan’s atmosphere: aerosols and gas phase

The discovery that Titan, the largest satellite of Saturn, has an atmosphere and that methane is a significant constituent of it, was the starting point for a systematic study of Titan’s atmospheric organic chemistry. Since then, the results from numerous ground-based observations and two flybys of Titan, by Voyager I and II, have led to experimental laboratory simulation studies and photochemical and physical modeling. All these works have provided a more detailed picture of Titan. We report here a continuation of such a study performing an experimental laboratory simulation of Titan’s atmospheric chemistry, and considering the two physical phases involved: gases and aerosols. Concerning the gaseous phase, we report the first detection of C₄N₂ and we propose possible atmospheric abundances for 70 organic compounds on Titan’s upper atmosphere. Concerning the solid phase, we have characterized aerosol analogues synthesized in conditions close to those of Titan’s environment, using elemental analysis, pyrolysis, solubility studies and infrared spectroscopy.     

Titan’s rotational state

In Noyelles et al. (Astron. Astrophys. 478, 959–970 (2008)), a resonance involving the wobble of Titan is hinted at. This paper studies this scenario and its consequences. The first step is to build an accurate analytical model that would help to find the likely resonances in the rotation of every synchronous body. In this model, I take the orbital eccentricity of the body into account, as well as its variable inclination with respect to Saturn’s equator. Then an analytical study using the second fundamental model of the resonance is performed to study the resonance of interest. Finally, I study the dissipative consequences of this resonance. I find that this resonance may have increased the wobble of Titan by several degrees. For instance, if Titan’s polar momentum C is equal to 0.355MR _T ² (M and R _T being, respectively, Titan’s mass and radius), the wobble might be forced to 41 degrees. Thanks to an original formula, I find that the dissipation associated with the forced wobble might not be negligible compared to the contribution of the eccentricity. I also suspect that, due to the forced wobble, Titan’s period of rotation may be somewhat underestimated by observers. Finally, I use the analytical model presented in this paper to compute the periods of the free librations of the four Galilean satellites as well as the Saturnian satellite Rhea. For Io and Europa, the results are consistent with previous studies. For the other satellites, the periods of the free librations are, respectively, 186.37 d, 23.38 y and 30.08 y for Ganymede, 2.44 y, 209.32 y and 356.54 y for Callisto, and 51.84 d, 2.60 y and 3.59 y for Rhea.     

Galactic cosmic rays and N2 dissociation on Titan

The electromagnetic and particle cascade resulting from the absorption of galactic cosmic rays in the atmosphere of Titan is shown to be an important mechanism for driving the photochemistry at pressures of 1 to 50 mbar in the atmosphere. In particular, the cosmic ray cascade dissociates N₂, a process necessary for the synthesis of nitrogen organics such as HCN. The important interactions of the cosmic ray cascade with the atmosphere are discussed. The N₂ excitation and dissociation rates and the ionization rates of the principal atmospheric constituents are computed for a Titan model atmosphere that is consistent with Voyager 1 observations. It is suggested that HCN may be formed efficiently in the lower atmosphere through the photodissociation of methylamine. It is also argued that models of nitrogen and hydrocarbon photochemistry in the lower atmosphere of Titan should include the absorption of galactic cosmic rays as an important energy source.     

Infrared limb darkening of the Venus atmosphere

An analysis of the limb darkening component obtained by Ingersoll and Orton [Icarus21 (1974), 121–128] from the thermal infrared maps of Venus published by Murray, Wildey, and Westphal [J. Geophys. Res.68 (1963), 4813–4818] and Westphal, Wildey, and Murray [Astrophys. J.142 (1965), 799–802] shows that the Cytherean cloud tops were close to radiative equilibrium in 1962. A method for obtaining the optical depth, the extinction coefficient, and the extinction scale height from such data is derived and values are extracted from Marov's [Icarus16 (1972), 415–461] standard model of the Venus atmosphere.     

Simulations of Superrotation on Slowly Rotating Planets: Sensitivity to Rotation and Initial Condition

We use a simplified terrestrial general circulation model as a nonlinear process model to investigate factors that influence the extent of equatorial superrotation in statically stable atmospheres on slowly rotating planets such as Titan and Venus. The possibility of multiple equilibria is tested by running the same model to equilibrium from vastly different initial conditions. The final state is effectively independent of initial state, reinforcing the impression that equatorial superrotation is inevitable on slowly rotating planets with stable radiative equilibrium structures. Of particular interest is the fact that at Titan rotation, the model equilibrates with strong prograde winds even when initialized with strong retrograde winds. This suggests that reliable remote sensing inferences of latitudinal temperature gradients on Titan can unambiguously be interpreted as evidence for superrotation. We also demonstrate for the first time that significant equatorial superrotation can be produced at Venus' rotation rate in such models, given sufficient numerical precision. The strength of superrotating zonal winds increases with rotation rate in the slowly rotating regime when other parameters are held fixed. However, the efficiency of superrotation relative to the angular momentum of an atmosphere corotating with the solid planet increases with decreasing rotation rate instead, because the Hadley cell strengthens and expands poleward. This allows for the formation of stronger high latitude jets, which ultimately serve as the source for equatorial superrotation via barotropic instability. Estimates of relevant parameter settings for Triton and Pluto tentatively imply that their atmospheres may marginally be in the superrotating regime, but only if temperature decreases with height near the surface.     

Estimated impact shock production of N2 and organic compounds on early Titan

Bombardment of Titan by Uranus-Neptune planetesimals and/or fragments of a disrupted Hyperion progenitor supplied more than enough energy to drive vigorous atmospheric shock chemistry. Chemical equilibrium modeling of the shock products in simulated atmospheres indicates that impact energy has produced large amounts of N₂ and organic compounds over Titan's history. The mole fraction of organic compounds in the shocked gas mixture (T = 1200−2500°K, P = 10⁻¹−10³bar) reaches a maximum of approximately 3% in a current Titan mixture and 12% in a primordial CH₄, NH₃-rich mixture. Atmospheric water mixing ratio controls the organic yield in shock reactions, but its limiting effect may have been reduced by cold-trapping of water in a cooling atmosphere. Kinetic inhibition of graphite formation in the shocked gas enhanced the yield of radicals and organic. The resulting mixture of carbonaceous soot and condensed hydrocarbons subsequently settled onto the surface; the depth of the generated layer was on the order of hundreds of meters. Impact shock energy was capable of converting massive amounts of NH₃ to N₂ early in Titan history—over twice the present atmospheric and 1.5 times the total ocean-atmospheric inventory of N₂. Shock conversion of NH₃ into N₂ bypasses the difficulties of other schemes of N₂ production and may have been of singular importance in Titan's atmospheric evolution.     

Net thermal radiation in the atmosphere of Venus

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60°N, 31°S, 27°S, and 4°N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus52, 279–300). The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O. B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1984, Icarus57, 143–160), but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5 × 10^?5 near 60°, 2–5 × 10^?4 near 30°, and 5 × 10^?4 near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.