Airborne spectroscopy and spacecraft radiometry of Venus in the far infrared

In March 1979, the spectrum of Venus was recorded in the far infrared from the G.P. Kuiper Airborne Observatory when the planet subtended a phase angle of 62°. The brightness temperature was observed to be 275°K near 110 cm^?1, dropping to 230°K near 270 cm^?1. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO₂, yield results consistently brighter than the observations. Supplementing the spectral data, Pioneer Venus OIR data at similar phase angles provide the constraint that any additional infrared opacity must be contained in the upper cloud, H₂SO₄ to the Pioneer-measured upper cloud structure serves to reconcile the model spectrum and the observations, but cloud microphysics strongly indicates that such a high particle density haze $\text{(N ? 1.6 × 10}{}^7\text{cm}{}^{\mathrm{?3}}\text{)}$ is implausible. The atmospheric environment is reviewed with regard to the far infrared opacity and possible particle distribution modifications are discussed. We conclude that the most likely possibility for supplementing the far-infrared opacity is a population of large particles $\text{(}\text{r}\text{? 1 μm)}$ in the upper cloud with number densities less than 1 particle cm^?3 which has remained undetected by in situ measurements.     

Calculations of the evolution of the giant planets

Evolutionary calculations are presented for spherically symmetric protoplanetary configurations with a homogeneous solar composition and with masses of 10^?3, 1.5 × 10^?3, 2.85 × 10^?4, and 4.2 × 10^?4M_⊙. Recent improvements in equation-of-state and opacity calculations are incorporated. Sequences start as subcondensations in the solar nebula with densities of ～10^?10 to 10^?11 g cm^?3, evolve through a hydrostatic phase lasting 10⁵ to 10⁷ years, undergo dynamic collapse due to dissociation of molecular hydrogen, and regain hydrostatic equilibrium with densities ～1 g cm^?3. The nature of the objects at the onset of the final phase of cooling and contraction is discussed and compared with previous calculations.     

An improved Venus cloud model

A simple radiative-transfer theory that allows for the change in the absorptions of sulfur and carbon dioxide with depth in the atmosphere of Venus can account simultaneously for (1) the spectral reflectance of Venus; (2) the wavelength dependence of contrast in uv cloud features; (3) the CO₂ line profile; (4) the change in slope of the curve of growth from the 7820- to the 10488-Å CO₂ bands; and (5) the rotational temperature near 246°K found for all CO₂ bands. The model cloud consists of 1-μm sulfuric-acid particles, which are well mixed between about 64 km and the 49-km cloud base found by Veneras 9 and 10, plus an overlapping cloud of much larger sulfur particles that extends down to the 35-km cloud base found by Venera 8. The mixing ratios (by number of molecules) below about 64 km are: H₂O, 2 × 10^?4; H₂SO₄, 10^?5; and sulfur, 10^?4. Although the cloud contains an order of magnitude more sulfur than sulfuric acid, the sulfur particles are an order of magnitude larger, and so have only about 1% of the number density of the acid droplets. The “black-white” radiative-transfer model assumes perfectly conservative scattering above the level (which depends on wavelength) where an absorber becomes “black” due to the local temperature and pressure. So-called homogeneous scattering models are inherently self-contradictory, and are inapplicable to planetary atmospheres; the vertical inhomogeneity is an essential feature that must be modeled correctly. The pressure of CO₂ line formation is about half the pressure in the region where uv markings occur.     

Martian isotopic ratios and upper limits for possible minor constituents as derived from Mariner 9 infrared spectrometer data

The Mariner 9 infrared spectrometer obtained data over a large part of Mars for almost a year beginning late in 1971. Mars' infrared emission spectrum was measured from 200 to 2000 cm^?1 with an apodized resolution of 2.4 cm^?1. No significant deviation from terrestrial ratios of carbon (¹²C/¹³C) or oxygen (¹⁶O/¹⁸O; ¹⁶O/¹⁷O) isotopes was observed on Mars. The ¹²C/¹³C isotopic ratio was found to be terrestrial with an uncertainty of 15%. Upper limits have been calculated for several minor constituents. With an effective noise equivalent radiance of 1.2 × 10^?9 W cm^?2 sr^?1/cm^?1, new upper limits in centimeter-atmospheres of 2 × 10^?5 for C₂H₂, 4 × 10^?3 for C₂H₄, 3 × 10^?3 for C₂H₆, 2 × 10^?4 for CH₄, 1 × 10^?3 for N₂O, 1 × 10^?4 for NO₂, 4 × 10^?5 for NH₃, 1 × 10^?3 for PH₃, 7 × 10^?4 for SO₂, and 1 × 10^?4 for OCS have been derived.     

The thermal structure of Jupiter II. Observations and analysis of 8–14 micron radiation

Observations of Jovian limb structure at 8.11 and 8.45 microns are reported. These are used along with other limb structure and spectral data in the 8–14 micron region to derive a model of the thermal and cloud structure within the 1.0-0.01 bar pressure regime. The model is generally consistent with models derived from Pioneer 10 infrared radiometer data reported by Orton (1975b). The temperature is about 165K at 1.00 bar, 108K at 0.01 bar, and 143K at 0.03 bar. In zones, an optically opaque cloud of NH₃ exists near the 143K (0.60 bar) level. A partly transparent haze of solid NH₃ particles overlies the cloud. Belts are free of the cloud and have a much lower abundance of NH₃ haze than the zones. The data are consistent with an NH₃ gas abundance defined by saturation equilibrium, with a mixing ratio of 1.5 × 10^?4 deep in the atmosphere, and with a CH₄ mixing ratio of 2 × 10^?3, about three times the currently accepted value.     

Lightnings and nitric oxide on Venus

In an updating of energy characteristics of lightnings on Venus obtained from Venera-9 and -10 optical observations, the flash energy is given as 8 × 10⁸ J and the mean energy release of lightnings is 1 erg cm^?2 s which is 25 times as high as that on the Earth. Lightnings were observed in the cloud layer. The stroke rate in the near-surface atmosphere is less than 5 s^?1 over the entire planet if the light energy of the stroke exceeds 4 × 10⁵ J and less than 15 s^?1 for (1–4) × 10⁵ J.The average NO production due to lightnings equals 5 × 10⁸ cm^?2 s^?1, the atomic nitrogen production is equal to 7 × 10⁹ cm^?2s^?1,the N flux toward the nightside is 3.2 × 10⁹ cm^?2s^?1, the number densities [N] = 3 × 10⁷cm^?3 and [NO] = 1.8 × 10⁶cm^?3 at 135 km. Almost all NO molecules in the upper atmosphere vanish interacting with N and the resulting NO flux at 90-80 km equals 5 × 10⁵cm^?2s^?1, which is negligibly small as compared with lightning production. If the predissociation at 80–90 km is regarded as the single sink of NO, its mixing ratio, f_NO, is 4 × 10^?8, for the case of a surface sink f_NO = 0.8 × 10^?9 at 50 km. Excess amounts, $\text{f}{}_{\mathrm{<mtext>NO</mtext>}}\text{? 4 × 10}{}^{\mathrm{?8}}$, may exist in the thunderstorm region.     

For infrared spectrophotometry of Jupiter and Saturn

Infrared spectral observations of Mars, Jupiter, and Saturn were made from 100 to 470 cm^?1 using NASA's G. P. Kuiper Airborne Observatory. Taking Mars as a calibration source, we determined brightness temperatures of Jupiter and Saturn with approximately 5 cm^?1 resolution. The data are used to determine the internal luminosities of the giant planets, for which more than 75% of the thermally emitted power is estimated to be in the measured bandpass: for Jupiter L_J = (8.0 ± 2.0) × 10^?10L_⊙ and for Saturn L_S = (3.6 ± 0.9) × 10^?10. The ratio R of thermally emitted power to solar power absorbed was estimated to be R_J = 1.6 ± 0.2, and R_S = 2.7 ± 0.8 from the observations when both planets were near perihelion. The Jupiter spectrum clearly shows the presence of the rotational ammonia transitions which strongly influence the opacity at frequencies ?250 cm^?1. Comparison of the data with spectra predicted from current models of Jupiter and Saturn permits inferences regarding the structure of the planetary atmospheres below the temperature inversion. In particular, an opacity source in addition to gaseous hydrogen and ammonia, such as ammonia ice crystals as suggested by Orton, may be necessary to explain the observed Jupiter spectrum in the vicinity of 250 cm^?1.     

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents of Titan are calculated for solar UV, solar wind protons, interplanetary electrons, Saturn magnetospheric particles, and cosmic rays. The resulting integrated synthesis rates of organic products range from 10²–10³ g cm^?2 over 4.5 × 10⁹ years for high-energy particle sources to 1.3 × 10⁴ g cm^?2 for UV at $\text{λ < 1550}\text{A}\text{?}$, and to 5.0 × 10⁵ g cm^?2 if $\text{λ > 1550}\text{A}\text{?}$ (acting primarily on C₂H₂, C₂H₄, and C₄H₂) is included. The production rate curves show no localized maxima corresponding to observed altitudes of Titan's hazes and clouds. For simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at 2825 km. Such condensates comprise the principal cloud mass, with molecules of greater complexity condensing at higher altitudes. The scattering optical depths of the condensates of molecules produced in the Titanian mesosphere are as great as ～ 10²/(particulate radius, μm) if column densities of condensed and gas phases are comparable. Visible condensation hazes of more complex organic compounds may occur at altitudes up to ～ 3060 km provided only that the abundance of organic products declines with molecular mass no faster than laboratory experiments indicate. Typical organics condensing at 2900 km have molecular masses = 100–150 Da. At current rates of production the integrated depth of precipitated organic liquids, ices, and tholins produced over 4.5 × 10⁹ years ranges from a minimum ～ 100 m to kilometers if UV at $\text{λ > 1550}\text{A}\text{?}$ is important. The organic nitrogen content of this layer is expected to be ～ 10^?1?10^?3 by mass.     

The effect of ammonia ice on the outgoing thermal radiance from the atmosphere of Jupiter

We examine the effects of NH₃ ice particle clouds in the atmosphere of Jupiter on outgoing thermal radiances. The cloud models are characterized by a number density at the cloud base, by the ratio of the scale height of the vertical distribution of particles (H_p) to the gas scale height (H_g), and by an effective particle radius. NH₃ ice particle-scattering properties are scaled from laboratory measurements. The number density for the various particle radius and scale height models is inferred from the observed disk average radiance at 246 cm^?1, and preliminary lower limits on particle sizes are inferred from the lack of apparent NH₃ absorption features in the observed spectral radiances as well as the observed minimum flux near 2100 cm^?1. We find lower limits on the particle size of 3 μm if H_p/H_g = 0.15, or 10μmif H_p/H_g = 0.50 or 0.05. NH₃ ice particles are relatively dark near the far-infrared and 8.5-μm atmospheric windows, and the outgoing thermal radiances are not very sensitive to various assumptions about the particle-scattering function as opposed to radiances at 5 μm, where particles are relatively brighter. We examined observations in these three different spectral window regions which provide, in principle, complementary constraints on cloud parameters. Characterization of the cloud scale height is difficult, but a promising approach is the examination of radiances and their center-to-limb variation in spectral regions where there is significant opacity provided by gases of known vertical distribution. A blackbody cloud top model can reduce systematic errors due to clouds in temperature sounding to the level of 1K or less. The NH₃ clouds provide a substantial influence on the internal infrared flux field near the 600-mbar level.     

The upper Jovian atmosphere aerosol content determined from a satellite eclipse observation

The Galilean satellite eclipse technique for measuring the aerosol distribution in the upper Jovian atmosphere is described and applied using 30 color observations of the 13 May 1972 eclipse of Ganymede obtained with the 5-m Hale telescope. This event probes the South Temperate Zone. The observed aerosol lies above the visible cloud tops, is very tenuous and varies with altitude, increasing rapidly with downward passage through the tropopause. The aerosol extinction coefficient, κ_a (λ1.05 μm), is ～1.1 × 10^?9 cm^?1 in the lower stratosphere and ～1.1 × 10^?8 cm^?1 at the tropopause. The 1σ uncertainty in these values does not exceed 50% The observations require some aerosol above the tropopause but do not clearly determine its structure. The present analysis emphasizes an extended haze distribution, but the alternate possibility is not excluded that the stratospheric aerosol resides in a thin layer. The aerosol extinction increases with decreasing wavelength and indicates the particle radius to be ?0.2 μm. Larger radii are impossible. These overall results confirm Axel's (1972) suggestion of a small quantity of dust above the Jovian cloud tops and the optical depths are consistent with those required to explain the low uv albedo.     

Venera 9, 10: Is there a dust ring around Venus?

Four surveys in which the geometrical parameters were suitable for observations on weak scattering objects were carried out by the Venera 9, 10 orbiters using 3000–8000 Å spectrometers. The results of one survey can be explained by a dust layer at the height of sighting h = 100–700 km. Its absence in other sessions suggests a ring structure. The spectrum of dust scattering is a power function of the wavelength with the index varying from ?2.1 at 100km to ?1.3 at 500km. A method is proposed for obtaining the optical thickness, density and size distribution of dust particles from the scattering spectra. For m > 10^?14 g the number of dust particles with a mass higher than m is proportional to m^?1.3. The radial optical thickness τ is 0.7 × 10^?5 at 5000 Å assuming the geometric thickness δ to be 100 km. The maximum optical thickness along the normal to the plane of the ring is τ_n = 4 × 10^?6. The mass of the ring is 20 tons or 5 × 10^?3 g cm^?1 per unit circumference length; the maximum mass in a column normal to the ring plane is 10^?10g cm^?2; the maximum density (for δ = 100 km) is 10^?17 g cm^?3. A satellite of Venus gradually destroyed by temperature effects and by meteorite streams and plasma fluxes is suggested as the source of dust in the ring. One of 1 km radius could sustain such a ring for a billion years. The zodiacal light intensity near Venus is estimated.     

A physical model of Titan's clouds

We have constructed a model of the physical processes controlling Titan's clouds. Our model produces clouds that qualitatively match the present observational constraints in a wide variety of model atmospheres, including those with low atmospheric pressures (25 mbar) and high atmospheric pressures. We find the following: (1) high atmospheric temperatures (160°K) are important so that there is a large scale height in the first few optical depths of cloud; (2) the aerosol mass production occurs at very low aerosol optical depth so that the cloud particles do not directly affect the photochemistry producing them; (3) the production rate of aerosol mass by chemical processes is probably greater than 3.5 × 10^?14 g cm^?2 sec^?1; (4) and the eddy diffusion coefficient is less than 5 × 10⁶ cm² sec^?1 except perhaps in the top optical depth of the cloud. Our model is not extremely sensitive to particle shape, but it is sensitive to particle density. Higher particle densities require larger aerosol mass production rates to produce satisfactory clouds. Particle densities of unity require a mass production rate on the order of 3.5 × 10^?13 g cm^?2 sec^?1. We also show that an increase in mass input causes a decrease in the mean particle size, as required by J. B. Pollack et al. (1980, Geophys. Res. Lett. 7, 829–832), to explain the observed correlation between the solar cycle and Titan's albedo; that coagulation need not be extremely inefficient in order to obtain realistic clouds as proposed by M. Podolak and E. Podolak (1980, Icarus43, 73–83); that coagulation could be inefficient due to photoelectric charging of the particles; and, that the lifetime of particles near the altitude of unit optical depth is a few months, as required to explain the temporal variability observed by S. T. Suess and G. W. Lockwood and D. P. Cruikshank and J. S. Morgan (1979, Bull. Amer. Astron. Soc.11, 564). Although Titan's aerosols are ottically thick in the vertical direction, the atmosphere is so extended that the horizontal visibility is greater than that found anywhere at Earth's surface.     

Equatorial ozone profiles from the solar maximum mission—a comparison with theory

The u.v. spectrometer polarimeter on the Solar Maximum Mission has been utilized to measure mesospheric ozone vs altitude profiles by the technique of solar occultation. Sunset data are presented for 1980, during the fall equinoctal period within ± 20° of the geographic equator. Mean O₃, concentrations are 4.0 × 10¹⁰ cm^?3at 50 km, 1.6 × 10¹⁰ cm^?3 at 55 km. 5.5 × 10⁹ cm^?3 at 60 km and 1.5 × 10⁹ cm^?3 at 65 km. Som profiles exhibit altitude structure which is wavelike. The mean ozone profile is fit best with the results of a time-dependent model if the assumed water vapor mixing ratio employed varies from 6 ppm at 50 km to 2–4 ppm at 65 km.     

Solar radiation scattered in the Venus atmosphere: The Venera 11,12 data

Results of the scattered solar radiation spectrum measurements made deep in the Venus atmosphere by the Venera 11 and 12 descent probes are presented. The instrument had two channels: spectrometric (to measure downward radiation in the range 0.45 < γ < 1.17 μm) and photometric (four filters and circular angle scanning in an almost vertical plane). Spectra and angular scans were made in the height range from 63 km above the planet surface. The integral flux of solar radiation is 90 ± 12 W m^?2 measured on the surface at the subsolar point. The mean value of surface absorbed radiation flux per planetary unit area is 17.5 ± 2.3 W m^?2. For Venera 11 and 12 landing sites the atmospheric absorbed radiation flux is ～15 W m^?2 for H >; 43 km and ～45 W m^?2 for H < 48 km in the range 0.45 to 1.55 μm. At the landing sites of the two probes the investigated portion of the cloud layer has almost the same structure: it consists of three parts with boundaries between them at about 51 and 57 km. The base of clouds is near 48 km above the surface. The optical depth of the cloud layer (below 63 km) in the range 0.5 to 1 μm does not depend on the wavelength and is ～29 and ～38 for the Venera 11 and 12 landing sites, respectively. The single-scattering albedo, ω₀, in the clouds is very close to 1 outside the absorption bands. Below 58 km the parameter (1 ? ω₀) is <10^?3 for 0.49 and 0.7 μm. The parameter (1 ? ω₀) obviously increases above 60 km. Below 48 km some aerosol is present. The optical depth here is a strong function of wavelength. It varies from 1.5 to 3 at λ = 0.49 μm and from 0.13 to 0.4 at 1.0 μm. The mean size of particles below the cloud deck is about 0.1 μm. Below 35 km true absorption was found at λ < 0.55 μm with the (1 ? ω₀) maximum at H ≈ 15 km. The wavelength and height dependence of the absorption coefficient are compatible with the assumption that sulfur with a mixing ratio ～2 × 10^?8 normalized to S₂ molecules is the absorber. The upper limits of the mixing ratio for Cl₂, Br₂, and NO₂ are 4 × 10^?8, 2 × 10^?11, and 4 × 10^?10, respectively. The CO₂ and H₂O bands are confidently identified in the observed spectra. The mean value of the H₂O mixing ratio is 3 × 10^?5 < F_H2O < 10^?4 in the undercloud atmosphere. The H₂O mixing ratio evidently varies with height. The most probable profile is characterized by a gradual increase from F_H2O = 2 × 10^?5 near the surface to a 10 to 20 times higher value in the clouds.     

Titan: Far-infrared and microwave remote sensing of methane clouds and organic haze

It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N₂, CH₄, and H₂, CH₄ cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N₂ for 1 cm ? λ ? 200 μm,, condensed and gaseous CH₄ for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH₄ clouds: 0.1 g cm^? at a planetocentric radius of 2610–2625 km, 0.3 g cm^?2 at 2590–2610 km, total 0.4 ± 0.1 g cm^–2 above 2590 km; organic haze: $\text{4 ± 2 × 10}{}^{\mathrm{?6}}\text{,}\text{g cm}\text{,}{}^{\mathrm{?2}}$ above 2750 km; tropospheric H₂: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH₄/C₂H₆) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is $\text{?0.6}$ A particle radius $\text{r}\text{? 2 μ}\text{m}$ in the upper portion of the CH₄ cloud is indicated by the apparent absence of scattering effects.     

Mars: Experimental study of albedo changes caused by dust fallout

An experimental study was undertaken to determine how the spectral and photometric properties of representative Martian areas are affected by fallout of atmospheric dust suspended during dust forms. A laboratory apparatus was used to simulate the uniform fallout and deposition of particles 1 to 5 μm in diameter. Spectral measurements from 0.4- to 1.2-μm wavelengths and photometric measurements at several wavelengths were made for a number of Mars-analog materials before and after deposition of 6 × 10^?5 to 1.5 × 10^?3 g/cm² of simulated fallout. These results indicate that the spectral and photometric properties of Martian regions can be affected significantly even by minute amounts of fallout. For instance, the reflectance at 0.56 μm of an average dark area will increase by 35% after deposition of only 9 × 10^?5 g/cm², and by 70% after deposition of 1.5 × 10^?4 g/cm². Thus the fallout from even one dust storm season (～2 × 10^?3 g/cm²) is sufficient to change significantly the spectral and photometric characteristics of the substrate material, if the fallout were ubiquitous over the surface and if no competing processes of dust removal from surface grains occured.     

Infrared photometry of Nova Delphini 2013 (=V339 Del) in the first sixty days after its outburst

The results of JHKLM photometry for Nova Delphini 2013 obtained in the first sixty days after its outburst are analyzed. Analysis of the energy distribution in a wide spectral range (0.36–5 µm) has shown that the source mimics the emission of normal supergiants of spectral types B5 and A0 for two dates near its optical brightness maximum, August 15.94 UT and August 16.86 UT, respectively. The distance to the nova has been estimated to be D ≈ 3 kpc. For these dates, the following parameters have been estimated: the source’s bolometric fluxes ～9 × 10^?7 and ～7.2 × 10^?7 erg s^?1 cm^?2, luminosities L ≈ 2.5 × 10⁵ L _⊙ and ≈2 × 10⁵ L _⊙, and radii R ≈ 6.3 × 10¹² and ≈1.2 × 10¹³ cm. The nova’s expansion velocity near its optical brightness maximum was ～700 km s^?1. An infrared (IR) excess associated with the formation of a dust shell is shown to have appeared in the energy distribution one month after the optical brightness maximum. The parameters of the dust component have been estimated for two dates of observations, JD2456557.28 (September 21, 2013) and JD2456577.18 (October 11, 2013). For these dates, the dust shell parameters have been estimated: the color temperatures ≈1500 and ≈1200 K, radii ≈6.5 × 10¹³ and 1.7 × 10¹⁴ cm, luminosities ～4 × 10³ L _⊙ and ～1.1 × 10⁴ L _⊙, and the dust mass ～1.6 × 10²⁴ and ～10²⁵ g. The total mass of the material ejected in twenty days (gas + dust) could reach ～1.1 × 10^?6 M _⊙. The rate of dust supply to the nova shell was ～8 × 10^?8 M _⊙ yr^?1. The expansion velocity of the dust shell was about 600 km s^?1.     

Das dynamische Verhalten interstellarer Staubteilchen beim Wolkenstoß Teil I. Ohne Berücksichtigung von Masseänderungen

During the collision of interstellar clouds a partial separation between gas and dust occurs. It can be expected that also a separation between heavier and lighter dust particles takes place. To determine the ratio of this dynamical effect the way of dust particles with different values of the product a · ϱ_p (a radius; ϱ_p density of the particles) during the three successive cooling periods is numerically calculated. It is shown that the heavier particles (a · ϱ_p ⪊ 5 · 10⁻⁵ g/cm²) at the end of the collision and the expansion period are gathered in a thin sheet in the inner parts of the new-built cloud whereas the lighter ones (a · ϱ_p 1 · 10⁻⁵ g/cm²) are distributed more or less uniformly among the gas of the cloud. The growth or destruction of the dust particles are not taken into account in this paper.     

Infrared photometry of Venus: Variation during 10 years?

The infrared flux of Venus has been observed with a narrowband filter (λ = 3.6 μm, Δλ = 0.08 μm) from 1982 through 1984, covering a range of the phase angle α from 27 to 94°. Normalized values of flux at the Venus-Earth distance of 1 AU were (4.0–5.4) × 10^?17W/cm²/cm^?1 and the α dependence of the data is rather weak. Furthermore, when the evening terminator of Venus was seen, lower values of flux were obtained in contrast with higher values at the morning terminator. The α dependence is quite different from that of J.V. Martonchik and R. Beer (1975, J. Atmos. Sci.32, 1151–1156). Since we cannot find any significant problem in the two observational methods, the difference might suggest an intrinsic time variation of haze particles during these 10 years in the upper haze layer of the Venus cloud.     

Net thermal radiation in the atmosphere of Venus

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60°N, 31°S, 27°S, and 4°N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus52, 279–300). The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O. B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1984, Icarus57, 143–160), but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5 × 10^?5 near 60°, 2–5 × 10^?4 near 30°, and 5 × 10^?4 near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.