RbSr radiometric age of late Precambrian fossil-bearing and associated rocks from Sinai

Six samples of metamorphic rocks from three essentially coeval stratigraphic units, two of which contain Precambrian microfossils, have been analyzed by the Rb-Sr whole-rock radiometric method. Least-squares regression of the data yields an isochron date of 934 ± 80m.y. with initial ⁸⁷Sr/⁸⁶Sr= 0.7007 ± 0.0011. This date may reflect the approximate age of formation of these rocks or, alternately, a time of major metamorphism. Regardless, the date is significant in that it (a) is in agreement with the 900-m.y. date for rocks containing similar types of fossils from Bitter Springs, Australia, and (b) coupled with structural evidence, supports the time equivalence of these rocks with 1000-m.y. old rocks (“Kibaran cycle”) of Saudi Arabia.     

Inherited isotope systems and the source region pre-history of early Caledonian granites in the Dalradian Series of Scotland

RbSr and UPb isotope analyses are reported for two pre-metamorphic Caledonian granites which intrude Dalradian rocks in the Central Highlands of Scotland. These data indicate that the origin of the granitic magmas involved partial fusion of old crustal material.UPb systems of zircon size and magnetic fractions from the Ben Vuirich granite are strongly discordant. However, U/Pb isotopic ratios precisely define a chord which intersects concordia at 514_?7⁺⁶ m.y. and 1316_?25⁺²⁶ m.y. Geological constraints suggest that the lower intersection records the post-F₂, pre-M₃ emplacement age of the granite. The upper intersection reflects the presence of old zircon xenocrysts incorporated into the granite magma without complete isotopic resetting. The ultimate source of these xenocrysts is probably a metamorphic basement complex which formed about 1320 m.y. ago, but the immediate source region of the granites could have been Dalradian sediments derived therefrom.RbSr whole-rock systems of the Ben Vuirich granite are also strongly discordant, although 8 out of 13 data points scatter about an “errorchron” of 564 ± 24 m.y. with an initial⁸⁷Sr/⁸⁶Sr ratio of about 0.716. This is interpreted as a spurious result due to incomplete homogenization of Sr isotopes in the source region during partial fusion. Initial⁸⁷Sr/⁸⁶Sr ratios at the time of emplacement indicated by the zircon data ranged from 0.7173 to 0.7191. Whole-rock samples from the Dunfallandy Hill granite have Rb/Sr ratios 2–3 times higher than those from Ben Vuirich and define a reasonably good isochron age of 491 ± 15 m.y. with an initial⁸⁷Sr/⁸⁶Sr of 0.7185 ± 0.0008. This may date granite emplacement or subsequent resetting of the high Rb/Sr rocks during Caledonian metamorphism. RbSr systematics indicate that the crustal source regions of these and other Caledonian granites separated from the upper mantle at least ca. 800 m.y. ago and probably ca. 1300 m.y. ago, thus confirming the interpretation of the upper intersection age of the zircon UPb data.     

Isotopic and other geochemical evidence for the origin of the Loch Uisg Granophyre,Isle of Mull,Scotland

Full chemical analyses, including some trace elements and both oxygen and strontium isotope abundance data are presented for samples collected from a traverse across the outcrop of the early Tertiary Loch Uisg Granophyre. Chemically, the body is rhyodacite with very uniform major and trace element composition. In contrast, depleted δ¹⁸O values vary widely from +1.5‰ in the south to ?3.7‰ in the north (a distance of about 21/2 km), a range comparable to that for the intrusive rocks of Mull as a whole. This indicates more extensive groundwater interaction (i.e. higher water/rock ratios and/or higher temperatures of isotope exchange) towards the focus of the central intrusive complex. There is some degree of correlation between δ¹⁸O and iron oxidation ratios but no other evidence that the primary igneous geochemistry of these rocks has been significantly modified by hydrothermal alteration after emplacement of the pluton. Initial⁸⁷Sr/⁸⁶Sr ratios range from 0.71350 ± 9 to 0.71624 ± 6 and correlate with both Rb content and Rb/Sr ratio, the latter correlation yielding a pseudo-isochron of 260 ± 54 Ma at the time of emplacement. These results confirm a major contribution from an old crustal source region, ruling out formation of the granophyre solely from a basic parent magma. However, Rb-Sr data are presented for the Moine schists exposed in Mull and Morvern which also appear to rule out their involvement in the petrogenesis of the granophyre, either as a source region for melting, or as a bulk contaminant for a mantle-derived magma. The only viable hypotheses are assimilation at depth of? Lewisian into a basaltic fractionation sequence or partial melting of a Proterozoic basement such as that involved in the production of Caledonian granites in the Scottish Highlands.     

New isotopic ages and the timing of orogenic events in the Cordillera Darwin,southernmost Chilean Andes

The Cordillera Darwin, a structural culmination in the Andes of Tierra del Fuego, exposes an orogenic core zone that has undergone polyphase deformation and metamorphism. Some of the classic problems of orogenic zones have remained unanswered in the Cordillera Darwin: the age of deformed plutonic rocks, the distinction of structurally reactivated basement and metamorphosed cover rocks, and the timing of orogenic events. This study addresses and partially answers these questions.A well-constrained Rb-Sr isochron age of157±8m.y. and an initial⁸⁷Sr/⁸⁶Sr ratio of 0.7087 obtained from a pre-tectonic granitic suite suggest a genetic relation between this suite and Upper Jurassic silicic volcanic rocks in the cover sequence (Tobifera Formation), and also suggest involvement of continental crust in formation of these magmas. A poorly constrained Rb-Sr isochron age of240±40m.y. obtained from supposed basement schists is consistent with field relations in the area which suggest a late Paleozoic/early Mesozoic metamorphism for these pre-Late Jurassic rocks. However, because of scatter in the data and the uncertainties involved in dating metasedimentary rocks, the significance of the isotopic age is dubious. Compilation of previously published ages in the area [9] with new mineral ages reported here indicate that “early Andean” orogenic events occurred between 100 and 84 m.y. ago, and that subduction-related magmatism has contributed, probably discontinuously, to the crustal evolution of the region throughout the Mesozoic.     

Chronology and chemical history of the parent body of basaltic achondrites studied by the 87Rb-87Sr method

Total-rock ⁸⁷Rb-⁸⁷Sr measurements have been carried out on ten eucrites. Internal “isochrons” were determined for Ibitira, Bereba, Pasamonte, Stannern, Sioux County and Juvinas. Ibitira as well as Juvinas (previously published) give an age of 4.52 ± 0.25 b.y. The corresponding “ages” of Bereba and Sioux County are 4.17 ± 0.26 b.y. and 4.19 ± 0.14 b.y. Stannern and Pasamonte have maximum “ages” of 3.1 and 2.6 b.y., respectively. These last four “ages” are significantly lower than 4.55 b.y.Using the total rocks and the two primitive eucrites Ibitira and Juvinas, we define as the best differentiation age for eucrites 4.57 ± 0.13 b.y. which is better than any previous determination, and (⁸⁷Sr/⁸⁶Sr)_BABI = 0.69899 ± 0.00004. We discuss the early differentiation of the basaltic achondrite parent body by assuming that the parent body started with chondritic composition and had a two-step evolution during the very early history of the solar system.     

87Rb87Sr chronology of H chondrites: Constraint and speculations on the early evolution of their parent body

A precise⁸⁷Rb-⁸⁷Sr whole-rock isochron for H chondrites and an internal isochron for Tieschitz (H3) have been determined. The age and⁸⁷Sr/⁸⁶Sr initial ratio of the whole rocks are4.52 ± 0.05 b.y. and0.69876 ± 0.00040(λ(⁸⁷Rb) = 1.42 × 10^?11yr^?1). For Tieschitz, whereas handpicked separates plot on a well-defined line, heavy liquid separates scatter in the⁸⁷Rb/⁸⁶Sr vs.⁸⁷Sr/⁸⁶Sr diagram. Leaching experiments by heavy liquids indicate that they might have a sizeable effect on Tieschitz minerals. The age and⁸⁷Sr/⁸⁶Sr initial ratio as determined by handpicked separates are4.53 ± 0.06 b.y. and0.69880 ± 0.00020, indistinguishable from the whole-rock isochron.These results are interpreted as “primitive isochrons” dating the condensation of chondrites from the solar nebula. The best value of this event is given by joining both isochrons together at4.518 ± 0.026 b.y. and⁸⁷Sr/⁸⁶Sr= 0.69881 ± 0.00016. The near identity of this initial ratio with the one of Allende white inclusions argues in favor of a sharp isochronism of condensation from a⁸⁷Sr/⁸⁶Sr homogeneous nebula. Data from Guaren?a [11] and Richardton [48] are interpreted as secondary internal isochrons, 100 m.y. after the condensation of the whole rocks.The data are then used to constrain a thermal evolution model of the H chondrite parent body. This body might have a 150–175 km radius, and might have been heated by²⁶Al. An²⁶Al/²⁷Al ratio of 4–6 × 10^?6 is enough for heating such a body. Further tests for this model are proposed.     

Sr–Nd isotopes and geochemistry of the infrastructural rocks in the Meatiq and Hafafit core complexes, Eastern Desert, Egypt: Evidence for involvement of pre-Neoproterozoic crust in the growth of Arabian–Nubian Shield

Abstract Meatiq and Hafafit core complexes are large swells in the Eastern Desert of Egypt, comprising two major tectono‐stratigraphic units or tiers. The lower (infrastructure) unit is composed of variably cataclased gneissose granites and high‐grade gneisses and schists. It is structurally overlain by Pan–African ophiolitic mélange nappes (the higher unit). The two units are separated by a low‐angle sole thrust, along which mylonites are developed. Major and trace element data indicate formation of the gneissose granites in both volcanic arc and within‐plate settings. Nevertheless, all analyzed gneissose granites and other infrastructural rocks, exhibit low initial ratios (Sr_i) (<0.7027), positive ε_Nd(t) (+4.9 to +10.3) and Neoproterozoic Nd model age (T_DM) (592–831 Ma for the gneissose granite samples). Although these values are compatible with other parts of the Arabian– Nubian Shield considered to be juvenile, the ε_Nd(t) values and several incompatible element ratios of the gneissose granites are too low to be derived from a mantle source without contribution from an older continental crust. Our geological, Sr–Nd isotopic and chemical data combined with the published zircon ages indicate the existence of a pre‐Neoproterozoic continent in the Eastern Desert that started to break up at ca 800 Ma. Rifting and subsequent events caused the formation of oceanic crust and emplacement within‐plate alkali basalts in the hinterland domains of the old continent. The emplacement of basaltic magma might have triggered melting of lower crust in the old continent and resulted in emplacement of the within‐plate granite masses between 700 Ma and 626 Ma. The granite masses and other rocks in the old continent have been subjected to deformation during the over‐thrusting of Pan–African nappes, probably because of the oblique convergence between East and West Gondwanaland. Rb–Sr isotopes of the gneissose granites in both Meatiq and Hafafit core complexes defines an isochron age of 619 ± 25 Ma with Sr_i of 0.7009 ± 0.0017 and mean squares of weighted deviates = 2.0. We interpret this age as the date of thrusting of the Pan–African nappes in the Eastern Desert. Continued oblique convergence between East and West Gondwanaland could have resulted in the formation northwest–southeast‐trending Meatiq and Hafafit anticlinoriums.     

The petrogenesis and implications of deformed late Caledonian–early Hercynian granites in the Wuyi area,South China

Precambrian basement rocks have been affected by Caledonian thermal metamorphism. Caledonian‐aged zircon grains from Precambrian basement rocks may have resulted from thermal metamorphism. However, Hercynian ages are rarely recorded. Zircon U–Pb Sensitive High Resolution Ion Microprobe (SHRIMP) dating reveals that zircon ages from the Huyan, Lingdou, and Pengkou granitic plutons can be divided into two groups: one group with ages of 398.9 ±5.3 Ma, 399 ±5 Ma, and 410.2 ±5.4 Ma; and a second group with ages of 354 ±11 Ma, 364.6 ±6.7 Ma, and 368 ±14 Ma. The group of zircon U–Pb ages dated at 410–400 Ma represent Caledonian magmatism, whereas the 368–354 Ma ages represent the age of deformation, which produced gneissosity. The three plutons share geochemical characteristics with S‐type granites and belong to the high‐K calc‐alkaline series of peraluminous rocks. They have (⁸⁷Sr/⁸⁶Sr)_i ratios of 0.710 45–0.724 68 and εNd(t) values of ?7.33 to ?10.74, with two‐stage Nd model ages (T_DM2) ranging from 1.84 Ga to 2.10 Ga. Magmatic zircon εHf(t) values range from ?3.79 to ?8.44, and have T_DMC ages of 1.65–1.93 Ga. The data suggest that these granites formed by partial melting of Paleoproterozoic to Mesoproterozoic continental crust. A collision occurred between the Wuyi and Minyue microcontinents within the Cathaysia Block and formed S‐type granite in the southwest Fujian province. The ca 360 Ma zircon U–Pb ages can represent a newly recognized period of deformation which coincided with the formation of the unified Cathaysia Block.     

Nd isotopic characteristics of S- and I-type granites

The initial Nd and Sr isotopic composition has been determined in S- and I-type granites from the Paleozoic Berridale and Kosciusko Batholiths of southeast Australia. The Nd and Sr isotopic variations form a strongly covariant array with S-types granites having a relatively restricted range inε_Nd values from ?6.1 to ?9.8 but a large range in initial⁸⁷Sr⁸⁶Sr of from 0.7094 to 0.7184. These characteristics are indicative of an～1400-m.y. sedimentary or metasedimentary source for S-types. I-types have variable initial Nd ranging from +0.4 to ?8.9, and a more limited range in initial⁸⁷Sr⁸⁶Sr of from 0.70453 to 0.7119. These isotopic characteristics are consistent with a two-component mixing model whereby a depleted mantle-like component (DMC) withε_Nd = +6 and⁸⁷Sr⁸⁶Sr= 0.703, is mixed with a crustal component (CC) havingε_Nd = ?9 and⁸⁷Sr⁸⁶Sr= 0.720. Although this two-component mixing model satisfies the isotopic constraints the source rock chemistry of the I-types is not compatible with the large proportion (up to 50%) of sedimentary material implied by the isotopic data. This indicates that more than two components are required to account for both the isotopic and chemical data. Both the chemical and isotopic data are consistent with I-type granites having been formed from source rocks of predominantly mantle derivation and obtained progressively from the mantle over a period of 1000 m.y. prior to granite formation.     

Isotopic geochemistry (O,Sr, Pb) of the Golda Zuelva and Mboutou anorogenic complexes,North Cameroun: mantle origin with evidence for crustal contamination

The annular (6–8 km diameter) Golda Zuelva and Mboutou anorogenic complexes of North Cameroun are composed of a suite of alkaline plutonic rocks ranging from olivine gabbro to amphibole and biotite granite. For the Mboutou complex there are two overlapping centres. In the Golda Zuelva complex the plutonic rocks are associated with a later hawaiite to rhyolite volcanic suite. A Rb/Sr whole rock isochron gives an age of 66±3 Ma for the Golda Zuelva granites, with initial⁸⁷Sr/⁸⁶Sr ratio of 0.7020, and demonstrates that plutonism and volcanism were essentially contemporaneous and probably cogenetic. For Golda Zuelva and the north Mboutou centre¹⁸O/¹⁶O (5.6–6.2),⁸⁷Sr/⁸⁶Sr (0.7030–0.7045) and Pb isotopic ratios (²⁰⁷Pb/²⁰⁴Pb: 15.60–15.64) support a mantle origin for the initial magmas. Unlike Sr isotopes, the O isotopic ratios of the granitic end members at Golda Zuelva (～7.5) indicate crustal contamination. Post-magmatic alteration was not significant.For the younger south Mboutou centre the O-, Sr- and Pb-isotopic data indicate more extensive magma-crust interaction and in a different (higher level?) crustal environment with δ¹⁸O granite=3.3‰,⁸⁷Sr/⁸⁶Sr ratios up to 0.706 and Pb isotopic ratios more markedly displaced from the oceanic volcanic field. The low-¹⁸O granites probably record, at least in part, a magmatic process with subsequent minor post-magmatic alteration effects. The major and trace element systematics between the north and south Mboutou centres are directly comparable. The evolution of the magmas were dominated by fractional crystallisation and progressive crustal contamination processes.     

Age relationships between greenstone belts and “granites” in the Rhodesian Archaean craton

Whole-rock Rb-Sr age measurements on rocks from the Rhodesian Archaean craton of Southern Africa demonstrate that (a) the Mashaba area gneisses, which are typical of the Rhodesian Basement Complex, are approximately 3600 m.y. old, (b) volcanic rocks from the main greenstone belts, assigned to the Bulawayan Group, were extruded approximately 2600–2700 m.y. ago, (c) a cross-cutting pluton, the Sesombi tonalite, was emplaced2690 ± 70 m.y. ago, (d) the Gwenoro Dam migmatites, which field evidence suggests could be older than the main greenstone belts, were emplaced2780 ± 30 m.y. ago.The initial⁸⁷Sr/⁸⁶Sr ratios of most of the rock units of groups b, c and d are in close agreement at about 0.701, suggesting that the later granitic (sensu lato) and andesitic rocks so far analysed were not produced by remelting of, or contamination with, ancient gneissic basement.     

Rb-Sr whole-rock age of the contact aureole of the Stillwater Igneous Complex,Montana

Fourteen whole-rock samples from three traverses through the contact aureole of the Stillwater Complex were analyzed for Rb, Sr and⁸⁷Sr/⁸⁶Sr. Twelve of these samples yielded an age of 2750 ± 45m.y.; (⁸⁷Sr/⁸⁶Sr)₀ = 0.705 ± 0.003 (2σ). In addition one whole rock and a biotite separate derived from it gave an age of 2544 m.y.; (⁸⁷Sr/⁸⁶Sr)₀ = 0.714. These data support a minimum age of 2750 m.y. for the intrusion of the complex.     

87Rb-87Sr chronology of enstatite meteorites

A⁸⁷Rb-⁸⁷Sr analysis of some enstatite meteorites has been made. Whole rocks plot on an isochron of age 4.508 ± 0.037b.y. and strontium initial ratio 0.69880 ± 0.00044 (2σ errors; λ⁸⁷Rb= 1.42 × 10^?11yr^?1) . If the Norton County results are joined, we get an age of 4.516 ± 0.029b.y. and initial ratio of 0.69874 ± 0.00022. This result is indistinguishable from the whole rock isochron for H chondrites. It is interpreted as the age of condensation from the solar nebula. The identity of the⁸⁷Sr/⁸⁶Sr initial ratio with the ones for Allende white inclusions shows that this ratio was homogeneous in the solar nebula, and that the Rb-Sr fractionations observed between the different chondrite groups appeared only shortly before or during condensation accretion.Internal studies of the type-I enstatite chondrites Abee and Indarch and the intermediate-type Saint Mark's and Saint Sauveur have been done.Abee data scatter in the⁸⁷Rb-⁸⁷Sr diagram. For Indarch, Saint Mark's and Saint Sauveur, we obtained well-defined straight lines of “age” (T) and “initial ratio” (I): Indarch,T = 4.393 ± 0.043b.y.I = 0.7005 ± 0.0009; Saint Mark's,T = 4.335 ± 0.050b.y.I = 0.69979 ± 0.00022; Saint Sauveur,T = 4.457 ± 0.047b.y.I = 0.6993 ± 0.0014. Our result on Indarch agrees with the former result of Gopalan and Wetherill [5].A careful examination of the data shows that these straight lines are neither due to leaching effects by heavy liquids, nor result from terrestrial weathering. The “isochrons” for Indarch and Saint Sauveur can be mixing lines between enstatite and feldspar. The results are interpreted in terms of cosmochemical secondary effects: type-I and intermediate-type enstatite chondrites have been shocked 60–200 m.y. after their formation. This agrees with the idea of an early generalized bombardment of the inner solar system; this also indicates that type-I enstatite chondrites were rather situated in the outershells of their parent body and might be at the origin of the scatter of I-Xe ages of enstatite meteorites.Whole rock and enstatite from Bishopville, Cumberland Falls and Mayo Belwa have also been analysed. In these three aubrites, the⁸⁷Rb-⁸⁷Sr system is perturbed. Our Bishopsville sample might not be fresh and this makes the significance of our results uncertain. Cumberland Falls and Mayo Belwa probably suffered relatively recent shocks and open-system redistribution of Rb and Sr.     

RbSr total rock isotope studies on Precambrian charnockitic gneisses from South Norway: evidence for isochron resetting during a low-grade metamorphic-deformational event

The quartzo-feldspathic charnockitic orthogneisses within the Bamble sector of the so-called Sveconorwegian (1.2–0.9 b.y.) zone are highly fractionated in K and Rb such that they comprise two chemically contrasting zones — one highly K, Rb-deficient and the other with values of the same order as upper crustal lithologies.Eight series of samples, each collected from single outcrops, have yielded Rb-Sr total rock apparent ages in two distinct groups, at ～1540 and ～1060 m.y. Outcrops in both the K-deficient and normal-K suites have produced examples of each age. The older age relates to the high-grade charnockite event, and the younger to a superimposed low-grade event which occurred at the same time as the intrusion of undeformed granite sheets and pegmatite dikes; one of the granites has yielded an isochron age of 1063 ± 20 m.y. The low-grade event involved only the partial alteration of orthopyroxenes to chlorite and/or serpentine, coupled with some corrosion of biotite; the alterations were initiated along narrow, irregularly spaced, cracks and it was their development which facilitated open system behaviour of the total rock isotopic systems at some localities. The degree of rehomogenisation is a function of the intensity of the secondary alterations.Confirmation of resetting at ～1060 m.y. is given by four mineral + host rock isochrons all yielding ages within error of the age for the intrusive granite; two of these are from outcrops where the rocks retain the older ～1540-m.y. age.The secondary total rock isotopic homogenisation cannot be explained adequately by Rb mobility or by simple mixing with a fluid having its own initial⁸⁷Sr/⁸⁶Sr composition. The primary mineralogy may have determined whether individual localities and/or samples suffered net increases or net decreases in⁸⁷Sr/⁸⁶Sr.An important implication of the results is that in this, or any similar geological situation, there would be a very real possibility of drawing erroneous conclusions from regionally-collected samples, particularly if the full significance of the later, relatively minor P-T event remained undetected and/or the scale of isotopic (re-)homogenisation, were unknown. It is only because of the methods adopted that it can be stated that there is no isotopic evidence for a high grade Sveconorwegian (Grenvillian) event in this part of southern Norway.     

Occurrence of oceanic plagiogranites in the older tectonic zone,Southwest Japan

K, Rb and Sr concentrations and Sr isotopic compositions were determined for the Dai granitic rocks of trondhjemitic composition occurring in a serpentinite mass in the Nagato tectonic zone formed in the Late Paleozoic era, and for the granitic rocks of quartz dioritic composition recently dredged from the seamount of the Kyushu-Palao Ridge. Both granitic rocks are characterized by low abundances of K and Rb, low K₂O/Na₂O ratios, high K/Rb ratios, low Rb/Sr ratios and low initial⁸⁷Sr/⁸⁶Sr ratios. These characteristics suggest that strong similarities may exist between the Dai granitic rocks and the dredged granitic rocks, and that the Dai granitic rocks may be classified as oceanic plagiogranite. These oceanic plagiogranites may plausibly represent single-stage mantle-derived granites, possibly from the suboceanic mantle.     

Strontium isotopic geochemistry of intrusive rocks,Puerto Rico,Greater Antilles

The strontium isotopic geochemistry is given for three Puerto Rican intrusive rocks: the granodioritic Morovis and San Lorenzo plutons and the Rio Blanco stock of quartz dioritic composition. The average calculated initial⁸⁷Sr/⁸⁶Sr ratios are 0.70370, 0.70355 and 0.70408, respectively. In addition, the San Lorenzo data establish a whole-rock isochron of71 ± 2m.y., which agrees with the previously reported K-Ar age of 73 m.y. Similarity of most of the intrusive rocks in the Greater Antilles with respect to their strontium isotopic geochemistry regardless of their major element composition indicates that intrusive magmas with a wide range of composition can be derived from a single source material. The most likely source material, in view of the available isotopic data, is the mantle wedge overlying the subduction zone.     

The evolution of early precambrian crustal rocks at Isua,West Greenland — Geochemical and isotopic evidence

Petrographic and chemical evidence suggests that boulders from a conglomeratic unit in the Isua supracrustal succession were derived by the erosion of an acid volcanogenic sediment. Six samples of the boulders and surrounding matrix yield a Rb-Sr whole rock isochron with a slope corresponding to an age of 3860 ± 240 m.y. (2 sigma error), but consideration of the initial⁸⁷Sr/⁸⁶Sr ratio constrains the possible age of formation of 3710 ± 900 m.y. This is in general agreement with a published Pb/Pb age of 3760 ± 70 m.y. on Isua banded ironstones.Pb isotope compositions as well as highly fractionated, heavy element depleted, rare earth element abundance patterns for the boulders suggest that their igneous precursors were derived from a source region with a similar geochemical history to that of some components of the 3700–3800 m.y. old Ami?tsoq gneisses, involving fractionation of garnet during their evolution.A Pb/Pb whole-rock isochron for Ami?tsoq gneisses from Isua yields an age of 3800 ± 120 m.y. (2σ), in good agreement with previously published Rb-Sr age data on the same rocks. The rock leads are highly unradiogenic and demonstrate substantial U depletion at least 3800 ± 120 m.y. ago. A two-stage model for the U-Pb system yields an average²³⁸U/²⁰⁴Pb (μ₁) value of 9.3 ± 0.2 for the source region, which is significantly different from the published value of 9.9 ± 0.1 for the Isua iron formation. This indicates the existence of U-Pb heterogeneities between the source regions of plutonic and supracrustal rocks by about 3700–3800 m.y. ago. Attempts to apply U-Pb whole-rock dating to the Ami?tsoq gneisses were unsuccessful because of geologically recent U loss, possibly due to groundwater leaching.A Rb-Sr whole-rock isochron on a suite of Ami?tsoq gneiss samples from a different locality in the Isua region has yielded an age of 3780 ± 130 m.y.In contrast to the Godthaab area, there is no geochronological evidence at Isua for major rock-producing or tectonothermal events after about 3700 m.y. ago. The entire gneiss-supracrustal system developed within the approximate interval 3900–3700 m.y. ago.     

“Mantle” Rb/Sr and 87Sr/86Sr ratios for clinopyroxenes from Norwegian garnet peridotites and pyroxenites

Clinopyroxenes separated from garnetiferous ultramafic rocks in the core zone of the Norwegian Caledonides have rubidium concentrations of 0.008 to 0.064 ppm, strontium concentrations of 23.5 to 421 ppm, and ⁸⁷Sr/⁸⁶Sr ratios of 0.7011 to 0.7029. The very low Rb/Sr ratios of the clinopyroxenes (less than 0.0004) suggest that their ⁸⁷Sr/⁸⁶Sr values have not varied significantly over geologic time and may approximate the initial ⁸⁷Sr/⁸⁶Sr of the eclogite-facies ultramafic mineral assemblages at their time of formation. The ultramafic rocks occur in a basement complex that yields Rb-Sr whole-rock and U-Pb zircon ages of about 1800 m.y. Garnetiferous ultramafic rocks are apparently lacking in younger (Sveconorwegian or Caledonian) sialic sequences, raising the possibility that the eclogite-facies metamorphism may have occurred at least 1800 m.y. ago. The Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios of the clinopyroxenes are as predicted for the ancient upper mantle under most evolutionary models. However, the data do not preclude the possibility that the eclogite-facies metamorphism occurred in the crust. The garnetiferous ultramafic rocks are generally enclosed by large volumes of dunite which could have shielded the eclogite-facies assemblages from contamination by fluids from the country rock during metamorphism.     

Geochemistry, K–Ar geochronology and Sr–Nd–Pb isotope compositions of pitchstone in Gohado, southwestern Okcheon Belt, South Korea

Abstract Geochemical and Sr–Nd–Pb isotope characteristics, as well as K–Ar geochronology of a massive pitchstone (volcanic glass) stock erupted into Late Cretaceous lapilli tuff and rhyolite in the Gohado area, southwestern Okcheon Belt, South Korea, are reported. The pitchstones are highly evolved with SiO₂ contents ranging from ～72 to 73 wt%, K₂O/Na₂O ratios of 1.04–1.23 and low MgO/FeO^t values (0.17–0.20). The pitchstones are weakly peraluminous and the ASI (molar Al₂O₃/Na₂O + K₂O + CaO) values are significantly lower than 1.1. The pitchstones also display a general calc‐alkaline nature with significant alkali contents. The rare earth elements (REE) compositions show moderately fractionated nature with (La/Yb)_N ranging from 11 to 16. Chondrite normalized REE patterns show relative enrichment of light REE over heavy REE and moderate Eu anomaly (Eu/Eu* ratio varies from 0.53 to 0.57). A distinct negative Nb anomaly is observed for all pitchstones on a primitive mantle normalized trace element diagram, typical of subduction‐related magmatism and crustal‐derived granites. All these features are characteristic of I‐type granites derived from a continental arc. The pitchstones have Zr contents of 98.5–103.5 ppm with zircon thermometry yielding temperatures of 749–755°C (mean 752°C). The K–Ar analyses of representative pitchstone samples yielded ages of 58.7 ± 2.3 and 62.4 ± 2.1 Ma with a mean age of 61 Ma. The rocks show nearly uniform initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of 0.7104–0.7106 and identical ¹⁴³Nd/¹⁴⁴Nd initial ratio of 0.5120. The rocks display negative εNd (61 Ma) values of ?12. The depleted mantle model ages (T_DM) range from 1.54 Ga to 1.57 Ga. The Pb isotope ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.522–18.552, ²⁰⁷Pb/²⁰⁴Pb = 15.642–15.680 and ²⁰⁸Pb/²⁰⁴Pb = 38.794–38.923. These ratios suggest that the Gohado pitchstones were formed in a continental arc environment by partial melting of a 1.54 Ga to 1.57 Ga parental sources of lower crustal rocks probably of mafic or intermediate compositions.     

The age of the Mistastin Lake crater,Labrador, Canada

⁴⁰Ar/³⁹Ar age determinations have been carried out on eight samples of melt rocks and one of the maskelynite from Mistastin Lake impact crater, Labrador. The observed⁴⁰Ar^* evolution spectra of the impact melts fall into distinct groups which correlate with petrographic variations. The release patterns of six of the melt rock samples define an age plateau in the range 34–41 m.y.; the other two have complex spectra which indicate incomplete equilibration of inclusions. Four of the samples with well-defined plateaux exhibit a high-temperature sag in their⁴⁰Ar/³⁹Ar ratio similar to that observed in some lunar samples. Maskelynite gives a partially overprinted spectrum which rises monotonically to a final age near 700 m.y., approximately half the age of the country rocks. The data from the melt samples are interpreted as indicating an age of 38 ± 4 m.y. for the Mistastin Lake impact event. Previously, it had been considered that this crater was 202 ± 25 m.y. old.