Hydrogeological conditions for the forming and quality of mineral waters in Serbia

In the past researches conducted on the territory of Serbia, 5 regional geotectonic units have been distinguished with registered occurrences of 230 mineral springs. Recent analyses of the bottled mineral waters quality have not included systematic examinations of micro-components present in these waters. Based on the analyses of the bottled mineral waters (EuroGeoSurveys Geochemistry Expert Group), it has been observed that the water quality is greatly influenced by the chemical composition of igneous intrusions, regardless of the fact that the analyzed waters have been taken from different aquifers (Neogene sediments, limestone, flysch, schist).     

Radiochemical separation and determination of radium-228 in bottled mineral waters by low level gamma spectrometry and its committed effective dose

?The gross beta and ²²⁸Ra radioactivity measurements in mineral waters were performed by proportional counter and gamma spectrometry, respectively, in this study. The natural mineral water samples were collected from various regions of Turkey for this study. Gross beta activities have been determined according to the United States Environmental Protection Agency standard method (EPA 900). In the case that the gross beta activity was determined to be greater than 1 Bq/L, then the ²²⁸Ra activity concentration in the related mineral water sample was specifically measured. ²²⁸Ra activity in mineral water samples was determined by high-purity germanium (HPGe) detector. The photopeak efficiencies were calculated by modeling the sample geometry and the detector in Canberra software LabSOCS. The gross beta activities in the eight of 32 bottled mineral water samples were greater than 1 Bq/L. ²²⁸Ra activity concentrations in bottled mineral waters were determined within 0.100–1.04 Bq/L. The committed effective doses were calculated for three different scenarios according to mineral water consumption rates.     

Classification of natural mineral and spring bottled waters of Portugal using Principal Component Analysis

Considering its area, Portugal is one of the world's richest countries in mineral and spring waters. There are 33 different types of bottled water, 18 of which are classified as natural mineral water and the remaining as spring water. The majority of these waters are of low mineralisation in comparison to most European bottled waters.     

Mineral and thermal waters of Western Bohemia

Mineral and thermal waters are a special kind of ground-water, distinguished by specific chemical or physical properties such as higher mineralization, concentration of certain constituents, dissolved gas, radioactivity, or temperature. Hydrologically, they are a part of ground-water system. Mineral or thermal waters are usually connegted with specific and unique geological and tetuunic structure.. The classical territory of mineral and thermal waters is Europe, where these waters have been used for medicinal purposes since ancient times. The development of spas and increased demands for mineral water for spa operation necessitated increased knowledge of spring structures and the development of optimal balneotechnical works. These problems are discussed on the examples of the Karlovy Vary Spa (Karlsbad) and Jàchymov Spa (St. Jachimstha) in W Bohemia. The location of mineral springs in the Karlovy Vary Spa, the largest spa in Czechoslovakia, in a highly urbanized area required a thorough investigation and unique methods for capturing thermal water at a greater depth to provide a steady supply of thermal water and to protect the springs against pollution from the surface. The Jachymov radioactive thermal springs, which were accidentally discovered in a deep, subsurface uranium mine, present a unique problem of protecting the stability of spring's regime in a mining environment.     

A survey of the inorganic chemistry of bottled mineral waters from the British Isles

The inorganic chemistry of 85 samples of bottled natural mineral waters and spring waters has been investigated from 67 sources across the British Isles (England, Wales, Scotland, Northern Ireland, Republic of Ireland). Sources include boreholes, springs and wells. Waters are from a diverse range of aquifer lithologies and are disproportionately derived from comparatively minor aquifers, the most represented being Lower Palaeozoic (10 sources), Devonian Sandstone (10 sources) and Carboniferous Limestone (9 sources). The waters show correspondingly variable major-ion compositions, ranging from Ca–HCO₃, through mixed-cation–mixed-anion to Na–HCO₃ types. Concentrations of total dissolved solids are mostly low to very low (range 58–800 mg/L). All samples analysed in the study had concentrations of inorganic constituents well within the limits for compliance with European and national standards for bottled waters. Concentrations of NO₃–N reached up to half the limit of 11.3 mg/L, although 62% of samples had concentrations <1 mg/L. Concentrations of Ba were high (up to 1010 μg/L) in two spring water samples. Such concentrations would have been non-compliant had they been classed as natural mineral waters, although no limit exists for Ba in European bottled spring water. In addition, though no European limit exists for U in bottled water, should a limit commensurate with the current WHO provisional guideline value for U in drinking water (15 μg/L) be introduced in the future, a small number of groundwater sources would have concentrations close to this value. Two sources had groundwater U concentrations > 10 μg/L, both being from the Welsh Devonian Sandstone. The highest observed U concentration was 13.6 μg/L.     

Chemical composition of bottled mineral waters in Estonia

Five commercially available in Estonia brands of bottled water have been analysed for 59 chemical elements by ICP-QMS and ICP-AES techniques to assess the quality of domestic mineral waters in scope of the European Groundwater Geochemistry Project initiated by the Geochemistry Expert Group of EuroGeoSurveys. Contents of 9 cations and anions, pH and electrical conductivity (EC) were measured in the bottled mineral waters by IC, titration and photometric methods. The data showed a significant difference between natural undiluted mineral water (Värska Originaal) characterised by the highest values of pH, EC and majority of trace elements studied, and other domestic waters sold in Estonia.     

Some features of mineral waters in Russia

 The Russian Federation has many aquifers and these possess a wide range of chemical compositions. In Russia about 300 mineral water sources have been developed as spas and health resorts. More than 150 of them produce bottled mineral water. A brief historical revue is given. The study of mineral waters in Russia began as far back as the reign of Peter the Great (1682–1725). It has been prolonged by works of many Russian scientists. The details of the chemical composition of the different types of Russian mineral waters and some geological aquifer peculiarities are described. The most widely used classification of mineral waters in Russia is presented. The present condition of these waters and the government standards laid down for their use are described. Examples of different mineral waters are given. Received: 14 April 1998 / Accepted: 8 December 1998     

Composition and variation of major and trace elements in Croatian bottled waters

Within the framework of the Pan-European project about the geochemistry of bottled mineral waters in Europe launched in 2007 by the European Geological Surveys (EGS) Geochemistry Expert Group fourteen brands of bottled natural waters from Croatia of both mineral and spring types were evaluated for getting more coherent spatial information about the natural variation of element concentration in bottled waters found at the European market. Results of chemical analysis show that not a single one out of fourteen analyzed bottled waters from Croatia exceeds the Croatian water standards sanctioning thereby their suitability for human consumption. Also, statistical tests performed for 41 analytes (including pH and EC) clearly show that the water chemistry is in a high degree of conformity with regional geology, depending on structural, stratigraphic and, above all, lithological diversity of aquifers. Thus Dinaric and Pannonian parts of Croatia differ largely with regard to their water types: Dinaric region is completely lacking mineral water types while, on the other side, in the Pannonian region even the spring waters show stronger mineralization in comparison with their Dinaric counterparts. Typically, all natural waters from Croatia bear the bicarbonate (HCO₃) signature. However, Ca–Mg cation pair combination is characteristic of spring waters while Na–K dominates in the mineral waters.     

Technical considerations in extracting and regulating springwater for public consumption

Many states within the United States as well as many other countries have promulgated regulations addressing public health, consumer protection, and truthin-labeling aspects of the extraction, bottling, and labeling of commercially bottled springwater intended for public consumption. Many of these regulations are inconsistent, suggesting a need for more uniform standards in acceptable extraction methods and legal/technical definitions of spring and springwater. An objective of the extraction or collection method is protecting the quality and integrity of the springwater, especially against microbial contamination. A summary of microbiological issues associated with groundwater and springwater is presented. Acceptable extraction methods can be either surface collection boxes/houses at the discharge point of the spring or a subsurface borehole or gallery interception system. Although extraction wells can provide total protective isolation of the water, a potential concern with that method is providing assurance that the extracted water is in fact the same water that feeds the adjacent spring. Criteria for testing this requirement are suggested in the paper.     

Chemistry of springwater in Almora, Central Himalaya, India

 A field study was conducted to assess variations in physico-chemical characteristics of water of the springs located within the boundary of a Central Himalayan town where the springwater is used for drinking purposes. Monitoring of 12 springs was carried out for three seasons (winter, summer and monsoon). The results indicate direct influence of unplanned sewage disposal on the springwater quality as reflected by significant regional variations in the concentration of nitrates, chlorides, sulfates, sulfides and electrical conductivity. Population density varies within the town from 3110 to 14 137 persons/km^–2 and has direct relationship with water quality. Springs located in the densely populated area had higher concentrations of all these compounds. Concentrations of nitrates up to 60 ppm were observed in some springs, making water unsuitable for human consumption. No significant changes were observed in springwater quality during different seasons. Received: 3 February 1995 · Accepted: 27 February 1996     

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.     

MINERAL WATERS OF BOHEMIA

Mineral waters of Bohemia are characterized by a considerable variety of chemical gaseous composition. They may be subdivided chemically into: calcium bicarbonate, sodium bicarbonate, magnesium sulfate, sodium sulfate, and ferruginous sulfate. Carbonated-water springs are chiefly developed along the periphery of the Bohemian massif. The conditions of formation of such springs in Karlovy Vary, Frantiskovy Lázně and Mariánské Lazne and Luga?evice are highly distinctive. Hydrogen-sulfide waters are widespread along the eastern margin of the region, forming part of an extensive zone of oil-bearing waters stretching from Austria into Czechoslovakia and Poland. The principal chemical types of hydrogen sulfide waters are the sodium bicarbonate and calcium bicarbonate varieties. Waters of Bohemia are distinguished according to the degree of radioactivity, low-, mean-, and high-radioactive. The greatest number of radioactive springs has been found on Rudná Hora, the Sudeten, the Slavkov Forests, Central Bohemia and Bohemian Moravian Hills.

Bohemia's mineral waters are widely used for medicinal purposes. — Auth. English Summary     

Investigation of the hydrogeochemistry of some bottled mineral waters in Hungary

Bottled drinking water constitutes a significant part of total water consumption in developed countries and national and EU legislation regulates their market production. In the framework of an international project carried out by the EuroGeoSurveys Geochemistry Expert Group 36 bottled waters were obtained from public markets in Hungary in order to determine their hydrogeochemical composition. The objective of this study is to investigate the possible relationship between groundwater aquifer lithology and the processed and marketed bottled waters, and to develop a classification of bottled waters, based on their dissolved mineral content. Analytical results of this study are compared with the composition shown on bottle labels, and with archive hydrochemical data from the producing wells. Results show that, while processing of original groundwater, such as oxygen addition, iron or hydrogen-sulphide removal can significantly alter water composition, bottled water composition can be used for selection of sites for detailed hydrogeochemical and hydrogeological characterization. A simple and useful classification of bottled water quality is also presented that is based on natural groups of sampled waters derived by means of statistical data analysis methods.     

Combined tracer tests in the karst aquifer of the artesian mineral springs of Stuttgart,Germany

Chlorinated solvents have been detected at low concentrations in some of the mineral and medicinal springs (spas) of Stuttgart since 1984. These springs discharge from a confined karst aquifer. In order to investigate both the properties of the aquifer and the mechanisms of contaminant transport, two multi-tracer tests were carried out in 1998 and 1999. Both fluorescent tracers (naphthionate, eosin, pyranine) and particle tracers (clubmoss spores, microspheres) were used. All available wells and springs were sampled for at least 12 months. In these experiments naphthionate produced the best results. Maximum flow velocities were established to be within the range of 53 and 230 m/day. The breakthrough curves demonstrated a heterogeneous aquifer. The results identified flow to the springs from the west and south-west. It was possible to prove an assumed boundary between the northern zone of low mineralised water and the southern zone of highly mineralised water.     

Bottled natural mineral waters in Romania

Different from drinking water supplied by the municipal network or from other bottled waters, all of which undergo some kind of prior treatment in order to become potable, the natural mineral water is an ecologically pure product, that by virtue of its composition may induce beneficial health effects. According to the EC Directive 80/777, the main criteria used for defining the natural mineral water refer to its original purity and its adequate protection against any pollution hazard. In Romania, mineral water consumption is an old tradition. The geological setting and the existence of unpolluted areas favored the development of mineral water sources of an outstanding quality, many of which include also carbon dioxide in natural state. The present work presents the main sources of bottled mineral water in Romania, classified as a function of total mineral content, ionic composition and carbon dioxide content. There are also forwarded forecasts concerning the medium term evolution of the structure of the bottled mineral water market in Romania.     

Geochemical survey of Slovenian bottled waters

The geochemistry of the major components and trace elements in Slovenian bottled water available on the market in 2004 and 2008 was studied. The waters were predominantly from the Radenska and Rogaška Slatina mineral water source region. In this paper, a comparison of two data sets from two time periods was performed based on the Kolmogorov–Smirnov independent two-sample test. The bottled waters in the data sets were in agreement with drinking water and mineral water standards. Discrepancies were only present for B and Ni in highly mineralised waters. Analyses of the labels on the bottle packaging showed that the analytical results were in general agreement with the values reported on the labels. At the same time, the values reported on the labels by the producers showed that the chemical compositions of products available on the market for longer time periods vary. Slovenian bottled waters are predominantly controlled by a CaCO₃–CO₂–H₂O system where Na, Cl⁻ and SO₄²⁻ are present as the major components, in different combinations.     

Unfilterable "geoaerosols", their use in the search for thermal, mineral and mineralized waters, and their possible influence on the origin of certain types of mineral waters

 Many articles describing the unusual mobility of solid particles in the subsurface layers of the Earth's crust have been published in the last decades, especially in the geological literature. In an attempt to explain this phenomenon, several hypotheses have been developed. The one closest to the behavior observed in nature is based on quantum mechanics. Based on this phenomenon, a new geological prospecting method called Molecular Form of Elements (MFE) was developed in former Czechoslovakia during the 1970s. It has been widely applied since for various types of prospecting, including the search for thermal and mineral waters. When using the MFE method for prospecting, the relationship between the ascending mineral springs and the four directions of structural faults was discovered. The possibility of whether a process, similar to the one acting during the absorption of elements when using the MFE method, can be a source of dissolved solid particles during the creation of mineral waters is also discussed. Received: 3 March 2000 · Accepted: 11 July 2000     

Thermal mineral water springs in Karlovy Vary

In the western part of the Czech Republic about 130–180 km west of the capital of Prague, in an area of about 300 sq km, several dozen mineral springs occur from various origins, with water of different chemical characteristics, temperatures, and levels of carbonation and radioactive intensity. Mineral waters are widely utilized, in particular for spa treatment of a broad range of ailments as well as for bottling (curative and table waters), industrial uses of carbon dioxide, evaporation for the salts dissolved in them and, in regard to thermal waters, for local heating.     

Major and trace elements in German bottled water,their regional distribution,and accordance with national and international standards

The market for mineral water has been growing steadily over the last few years. Germany is the country with the highest number of bottled mineral water brands (908 bottled water samples from 502 wells/brands were analyzed). The per capita consumption of mineral water in Germany in 2003 was 129 L. A wide range of values of one to seven orders of magnitude was determined for 71 elements in the bottled water samples analyzed by ICP-QMS, ICP-AES, IC, titration, photometric, conductometric and potentiometric methods. A comparison of the element concentrations and the legal limits for both bottled and tap water (EU, Germany, US EPA, WHO) shows that only 70% of the 908 mineral water samples fulfill the German and EU drinking water (i.e., tap water) regulations for all parameters (not including pH) for which action levels are defined. Nearly 5% of the bottled water samples not fulfill the German and EU regulations for mineral and table water. Comparison of our results with the current German and European action levels for mineral and table water shows that only 42 of the bottled water samples exceed the limits for one or more of the following elements: arsenic, nitrate, nitrite, manganese, nickel and barium concentrations. Ten of the bottled water samples contain uranium concentrations above the 10 μg/L recommended limit.