科拉超深钻：期望与结果

科拉超深钻的钻进和探测首次提供了以前无法达到的深度的有关古老大陆地壳成分和构造的直接资料。岩石密度和它们弹性的各向异性已成为当今地表地质正式描述形式和参考剖面的主要参数。所给出的完整模型的证据是基于科拉超深钻的探测及辅助的地表地质研究。模型认为贝辰加矿区是一个幔源火山岩－侵入岩中心式成矿系统的水平部分。本文还对铜－镍硫化物矿床产出条件给予了新的解释，并有助于理解贝辰加矿区在贝辰加—依曼德—瓦尔朱格缝合带中的位置     

Physical and mechanical properties of selected amphibolite core samples from the Kola Superdeep Borehole KSDB-3

Laboratory tests of physical and mechanical properties were performed on amphibolites representing two units from the Kola Superdeep Borehole KSDB‐3 (Russia) ? the Proterozoic Karelian Complex (depths of 3043 m, 3530 m and 4389 m) and the Archean Kola–Belomorian Complex (depths of 7951 m, 8942 m and 9904 m). Obtained grain density and bulk density values are nearly identical for all tested samples, but porosities increased slowly with depth. Marked differences in strength properties were found between amphibolite samples from the Karelian Complex and amphibolite samples from the Kola–Belomorian Complex. The uniaxial compressive strength of the samples from the lower part of the borehole is significantly smaller than in samples from the upper part; a similar trend was found for triaxial tests. The values of the deformation modulus, Young's modulus and Poisson's ratio obtained from samples of the Karelian Complex are considerably higher than those from the Kola–Belomorian Complex. Observed mechanical properties are explained by the variable grain‐size distribution and by the spatial arrangement of main rock‐forming minerals. These properties are also influenced by recovery of rocks from great depths.     

Petrochemical systematics of amphibolites from the Archean section of the Kola Superdeep Borehole

This paper addresses the problem of the systematization of amphibolites from the Archean part of the section of the SG-3 Kola Superdeep Borehole. It was shown that a combined petrochemical and geochemical approach allows one to classify these rocks with high confidence and to distinguish supposedly Archean and Proterozoic varieties among them. It was found that Proterozoic rocks account for about 50–70% of basic rocks in the Archean section. Homologues of the basic metavolcanics of the Matert Formation were detected among the Proterozoic metaigneous rocks of the Archean section of the SG-3, which casts doubt on the conclusion of some authors on the allochthonous origin of the upper levels of the northern Pechenga section, including its productive horizons. This result has very important metallogenic implications. Original Russian Text N.E. Kozlov, E.V. Martynov, N.E. Kozlova, T.V. Kaulina, Yu.P. Smirnov, 2007, published in Geokhimiya, 2007, No. 2, pp. 150–158.     

The Kola Superdeep Drillhole and the nature of seismic boundaries

The Kola Superdeep Drillhole was drilled through 7 km of Proterozoic rocks of the Pechenga structure and 5 km of the Archean basement in the Baltic Shield to 12 km depth. The results of drilling revealed a significant heterogeneity of physical properties of the crystalline rocks and a surprisingly high porosity and water content throughout the section. Seismic wide-angle reflection data, obtained in the region of the hole, were used to delineate the volcanic-sedimentary layers of the Pechenga structure and the intersecting faults. These studies revealed also a subhorizontal boundary at a depth of 7 km of uncertain origin. Core sampling implies that this boundary is associated with a change in core pressure, with higher porosity and with velocity anisotropy. A change in rock fissuring and in the fluid regime correlates with a velocity inversion zone reached by the hole at a depth of 4.5 km.     

Catagenesis and burial metamorphism of terrigenous and volcanic sequences (section recovered by the En-Yakhinskaya parametric borehole SG-7)

Secondary alterations of Cretaceous, Jurassic, and Triassic terrigenous complexes recovered by borehole SG-7 were studied from the depth of 3620 m to 6920 m (roof of basalts). Down to the depth of ∼6770 m, the section shows a gradual intensification of catagenetic alterations of sandy rocks: the formation of pressure dissolution textures and regeneration of clastic quartz. Intensification of the transformation of clay minerals is not observed in this mineral. Variations in the contents of illite, hydromicas, mixed-layer minerals, smectite, chlorite, and kaolinite at different depths of the recovered section are related to changes in the provenance during the accumulation of sedimentary complexes. The Middle Triassic coarse-grained sandy rocks (suprabasalt sequence) are more intensely transformed: they are marked by microstylolitic textures of pressure dissolution, recrystallization blastesis of clastic quartz grains, and newly formed zoisite. The composition of clay minerals is also characterized by variation: micas are represented by sericite with ΔD = 0; Fe-chlorite and kaolinite are noted. These features suggest the absence of linear positive correlation of T and P with the subsidence depth of sedimentary complexes. Intense heating (up to 200–300°C) of the Middle Triassic suprabasalt rocks is likely caused by trap activity (intense effusion of basalt lavas). Investigation of secondary minerals in basalts recovered by borehole SG-7 revealed that the grade of their transformation matches the medium-temperature subfacies of the greenschist facies.     

Approach to chemical equilibrium in diagenetic chlorites

Electron microprobe analyses were made on diagenetic chlorites in sandstones and mudstones from two deep wells according to the petrographic character of the chlorite occurrence: as pseudomorphic phases, rims on quartz or glauconite or as distinct phases in the clay matrix. Chlorite compositions do not depend upon crystallization site (reacting phases) making it apparent that new chlorites can form in an approach to chemical equilibrium at or near the surface (40° C, 1 km depth). Comparison of this data with that for late diagenetic and early metamorphic chlorites indicates that the compositional range for different grains in the same thin section is similar for the samples throughout the 40°–270° C temperature span. Compositional range decreases upon further metamorphism.Al content appears to be a more reliable indicator of temperature variations than other substitutions in the chlorite structure. The clay mineral assemblage which indicates sedimentary facies affects the trends in composition (Al increase or decrease) as a function of temperature. The octahedral site occupancy show a general increase in going from diagenesis to metamorphic conditions in pelitic rocks. The range of Fe-Mg ratios seems to depend more on the chemistry of each sample than the temperature of formation of the minerals.     

泥岩成岩矿物演化特征与成岩体系划分:以东营凹陷古近系为例

成岩过程中泥岩的成岩矿物会随成岩体系的改变而发生变化,因此有效地识别成岩矿物组合与划分成岩体系,对深刻 理解有机质生烃的差异性具有重要的意义。文章选取东营凹陷古近系不同层段埋深在1200~4500 m的泥岩,通过岩石薄片、 扫描电镜和X射线衍射等检测,有效地区分了外源输入的矿物（如石英）与成岩矿物（亮晶方解石和白云石）等显微特征的差 异,据此建立了定量估算泥岩中成岩转化的黏土矿物含量的方法：C陆源=（C/Q）沙一×Q样品和C成岩=CXRD-C陆源,其中C为黏土矿物含 量,Q为石英含量,更好地反映了泥岩成岩过程中黏土矿物的演化特征。在埋藏演化过程中泥岩中的成岩矿物和组合呈现出 两段性,3000 m以上黏土矿物和白云石的成岩转化较慢,形成了以伊蒙间层+高岭石的成岩矿物组合,推断其经历了酸性成岩 环境和开放成岩体系;3000 m以下黏土矿物和白云石的成岩转化过程加快,形成了以伊利石+绿泥石+白云石的成岩矿物组 合,推断其经历了碱性成岩环境和封闭成岩体系,充分展现了泥岩在深浅层成岩环境和体系的差异性。与前人研究东营凹陷 泥岩中由有机质生烃产生异常压力造成的开放/封闭体系界限基本吻合,表明泥岩中矿物埋藏演化经历的成岩体系与有机质 生烃形成的压力体系具有较好的响应关系,这对认识不同成岩体系下有机质的生烃过程和生烃机理的差异性具有重要的 意义。     

泥岩成岩矿物演化特征与成岩体系划分：以东营凹陷古近系为例

成岩过程中泥岩的成岩矿物会随成岩体系的改变而发生变化，因此有效地识别成岩矿物组合与划分成岩体系，对深刻 理解有机质生烃的差异性具有重要的意义。文章选取东营凹陷古近系不同层段埋深在1200~4500 m的泥岩，通过岩石薄片、 扫描电镜和X射线衍射等检测，有效地区分了外源输入的矿物（如石英）与成岩矿物（亮晶方解石和白云石）等显微特征的差 异，据此建立了定量估算泥岩中成岩转化的黏土矿物含量的方法：C陆源=（C/Q）沙一×Q样品和C成岩=CXRD-C陆源，其中C为黏土矿物含 量，Q为石英含量，更好地反映了泥岩成岩过程中黏土矿物的演化特征。在埋藏演化过程中泥岩中的成岩矿物和组合呈现出 两段性，3000 m以上黏土矿物和白云石的成岩转化较慢，形成了以伊蒙间层+高岭石的成岩矿物组合，推断其经历了酸性成岩 环境和开放成岩体系；3000 m以下黏土矿物和白云石的成岩转化过程加快，形成了以伊利石+绿泥石+白云石的成岩矿物组 合，推断其经历了碱性成岩环境和封闭成岩体系，充分展现了泥岩在深浅层成岩环境和体系的差异性。与前人研究东营凹陷 泥岩中由有机质生烃产生异常压力造成的开放/封闭体系界限基本吻合，表明泥岩中矿物埋藏演化经历的成岩体系与有机质 生烃形成的压力体系具有较好的响应关系，这对认识不同成岩体系下有机质的生烃过程和生烃机理的差异性具有重要的 意义。     

Sm-Nd systematics and petrology of postorogenic granitoids in the northern Baltic Shield

In the northern part of the Baltic Shield, quartz diorites, diorites, and monzodiorites compose massifs of postorogenic granites, in which younger granite phases are restricted to their central parts, and dike rocks (aplites, pegmatites, and granite porphyries) occur in the apical parts. The rocks of the Litsa-Araguba Complex (which is located in the northwestern part of the Kola Peninsula and was examined most thoroughly) compose seven intrusions 850 km² in total area, which were formed in mesoabyssal and hypabyssal depth facies. The massifs consist of quartz diorites and monzodiorites dated at 1774 ± 9 Ma, diorites, diorite porphyries, and lamprophyres, which are distinguished as phase 1. The porphyritic and equigranular granites, granodiorites, quartz monzonites, granites, alaskites and related vein leucogranites, pegmatites, and granite porphyries of phases 2 (main), 3, and 4 have an age of 1772–1762 Ma. Data obtained on the Sm-Nd systematics of the rocks indicate that their ?_Nd(1765) values are close to those for rocks of phases 1, 2, and 3 (from ?6.8 to ?8.8) and vary from ?5.0 to ?11.9 for the leucocratic granites of phase 4. The model age values are, respectively, 2.37–2.62 and 2.58–3.23 Ga. These data suggest that the parental melts were of anatectic genesis and were produced by the melting of mostly metasomatically altered garnet granulites from the lower crust. The leucogranites and alaskites of phase 4, which occur as relatively thin bodies in the rocks of the Archean Complex penetrated by the Kola Superdeep Borehole, were derived from a Neoarchean sialic source or produced by the contamination of the parental melts with the material of the Late Archean upper crust. The SHRIMP-II zircon age of the lower crustal migmatized garnet granulites lies within the range of 1831 ± 23 to 1392 ± 21 Ma in the concordia plot. All dates of the rocks are characterized by a unimodal distribution with most values lying within the range of 1650–1800 Ma and approximated by a discordia with T₁ = 1750 ± 30 Ma, MSWD = 3.1. This age value can be interpreted as an averaged age of the lower crustal granitization and corresponds, within the errors, to the age of postorogenic granite intrusions in the upper crust.     

X射线粉晶衍射仪在大理岩鉴定与分类中的应用

大理岩主要有方解石大理岩、白云石大理岩和菱镁矿大理岩三种。以往大理岩是依据偏光显微镜下观察岩石结构构造及矿物成分进行分类定名,由于方解石、白云石、菱镁矿都属于三方晶系,具有闪突起、高级白干涉色、一轴晶负光性和菱形解理等相同晶体光学特征,偏光显微镜下区分十分困难。为了准确鉴定大理岩中碳酸盐矿物种类及其相对含量,本文利用岩石薄片偏光显微镜和X射线粉晶衍射技术对32件大理岩岩石样品进行分析测试。岩石薄片鉴定结果表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、白云母、黑云母、绿泥石、黏土和金属矿物。根据岩石结构构造及矿物组分特征,可把32件大理岩样品划分为方解石大理岩、长英质方解石大理岩、石英绿泥白云石大理岩、白云石大理岩、云英质白云石大理岩和菱镁矿大理岩等15个类型。X射线粉晶衍射分析表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、钾长石、云母、绿泥石、滑石和蒙脱石。综合分析认为:岩石薄片偏光显微镜鉴定技术很难区分方解石、白云石和菱镁矿等碳酸盐矿物,以及细小的石英、钾长石和斜长石、滑石和白云母等鳞片状硅酸盐矿物;X射线粉晶衍射分析技术不仅能准确检测出大理岩中方解石、白云石和菱镁矿等碳酸盐矿物种类及相对含量(方解石、白云石和菱镁矿的X射线衍射主峰有明显差异,d值分别为0.303 nm、0.288 nm和0.274 nm),而且能够有效鉴别岩石中粉砂级斜长石、钾长石与石英(三种矿物的X射线衍射主峰d值分别为0.319 nm、0.324 nm、0.334 nm);且能区分蒙脱石、绿泥石、云母和滑石等层状硅酸盐矿物(四种硅酸盐矿物的X射线衍射主峰d值分别为1.400 nm、0.705 nm、0.989 nm、0.938 nm)。综合岩石薄片偏光显微镜鉴定和X射线粉晶衍射分析结果,最终确定32件大理岩样品划分为22个岩石类型。研究认为:仅根据岩石薄片偏光显微镜鉴定或X射线粉晶衍射技术其中一种方法不能准确鉴定大理岩岩石,应将大理岩岩石野外观察、岩石薄片鉴定和X射线粉晶衍射技术结合起来,才能准确确定大理岩岩石类型。     

黄河口凹陷渤中27-A构造沙一二段湖相混积岩储层特征及成因

渤海海域黄河口凹陷BZ27-A（渤中27-A）构造沙一二段发育一套湖相混积岩,目前对该储层的特征及成因研究较少.通过岩心观察、铸体薄片、压汞测试等分析,系统阐述了该区混积岩储层的岩石学、储集空间类型、物性等特征,在此基础上探讨了混积岩储层控制因素.结果表明,混积岩岩性复杂多样,由陆源碎屑、黏土矿物、碳酸盐矿物及生物碎屑以多种组合方式混杂构成,发育钙质砂岩、白云质砂岩、陆屑泥晶云岩、泥晶鲕粒云岩、生物碎屑白云岩等类型,剖面上大多呈现夹层或薄互层的特点.多数混积岩储层孔隙度、渗透率低,为致密储层,局部薄层段发育相对较好储层.混积岩储层的发育主要受古地理背景、成岩作用、流体等因素影响,成岩早期大面积碳酸盐胶结是导致储层致密的主要成因,而生屑的贡献、晚期成藏时的油气侵位作用是改善储层物性的重要作用,具有形成相对优质储层的潜力.      

震旦纪灯影组磷块岩及其生成特点

灯影组磷块岩有四种类型,即泥晶磷块岩、内碎屑磷块岩、藻磷块岩和细晶磷块岩。组成磷块岩的主要矿物是磷灰石、白云石、石英和少量伊利石等。磷块岩主要沉积在陆缘海内,它的沉积环境是与深水有联系的浅水地区。深水和浅水环境的地质背景分别为构造拗陷和碳酸盐岩台地。前者提供成矿物质,后者提供有利于磷质成矿的沉积环境。     

Oxygen isotope ratios in magnetite core-and-mantle structures

In a polymetamorphic, felsic, biotite-bearing gneiss, biotite has reacted to form magnetite and microcline. The resulting structure is a magnetite core surrounded by a mantle of feldspar and quartz normally not exceeding 20mm in diameter. Measurements of oxygen isotope ratios disclose disequilibrium between mantle microcline and mantle quartz and also between mantle and matrix minerals of the same species. A clustering of temperature estimates from the oxygen isotope distribution between magnetite and quartz and between magnetite and microcline in the interval 550 to 600°C suggests an approach to oxygen isotope equilibrium. No signs of a re-equilibriation of the reacting biotite can be found.     

A Reconstruction and Discussion of the Effect of Diagenetic Environment on Hydrocarbon Generation Based on Diagenetic Mineral Assemblage in Mudstone

Inorganic minerals in mudstone are composed of clay minerals,carbonate and detrital minerals.Detrital minerals(such as quartz and feldspar)are mainly original deposit.However,clay minerals(kaolinite,illite,and chlorite)and carbonate(calcite and dolomite)are mostly diagenetic minerals.Furthermore,conversion of the four kinds of clay minerals are common.The formation of clay minerals and carbonate is controlled by temperature,pressure,p H,Eh and type of cations during diagenesis.Therefore mineral assemblage can indicate the characteristics and change of diagenetic environment.In addition to inorganic minerals,there are also organic matter of different sources and chemical properties in mudstone.Traditionally,it is considered that evolution of organic matter is controlled by thermal effect.Now studies show that inorganic and organic matter can interact with each other and form clay-organic complexes.This suggest that attention should be paid to the influence of diagenetic mineral assemblage and diagenetic environment on the evolution of organic matter* Samples of mudstone from 1500-4500m of the Palaeogene in the Dongying Depression,China,were collected to investigate the changes of mudstone diagenetic environment.XRD,thin section and SEM were used to detect diagenetic minerals and assemblage characteristics.Results showed that content of detrital minerals,which are floating in mud matrix or preserved as silt laminae,is basically unchanged from shallow to deep strata.Clay minerals which are gathered as argillaceous matrix or preserved as argillaceous laminae have growth and decline relation to carbonate which mainly appear as micropoikilitic ferriferous calcite and ferriferous dolomite.All these characteristics indicate that detrital minerals are exogenetic,whereas carbonate is diagenetic minerals.Based on the SEM analysis of the clay minerals,it was found that smectite present honeycomb and reticulate structure,while illite present filiform and schistose structure and there are growth and decline relationship between them.Nevertheless,hexagonal tabular and stratified kaolinite has the highest content from 2400m to3300m.Rosette and stratified chlorite shows increase trend when the burial depth is deeper than 3300m.These characteristics indicated that clay minerals are diagenetic minerals and there are conversions among the four types.Therefore form shallow to deep,three diagenetic mineral assemblage zones can be divided based on the characteristics of carbonate and clay minerals in mudstone.Namely,smectite+illite/smectite zone in the depth of 2000-2500m;kaolinite+illite/smectite zone in the depth of 2500-3300m and illite+chlorite+carbonate zone below 3300m.Previous studies showed that kaolinite is stable under acidic conditions,while other clay minerals and carbonate are stable under alkaline conditions.Hence according to mineral assemblages feature,it was inferred that diagenetic environment of mudstonehasundergonethechangeof alkaline-acid-alkaline.For the organic matter with different chemical properties in mudstone,the hydrocarbon generation will be different in the acidic and alkaline diagenetic environment even if the conditions of temperature and pressure are the same.Therefore,for hydrocarbon generation we should not only focus on thermal effect,but also pay more attention to the differences of diagenetic environment which have great significance for the understanding of hydrocarbon generation,hydrocarbon expulsion and reservoir formation in mudstone.     

Some aspects of the Krol formation of the Himalaya,India

The Lower Krol sediments consist of intercalations of dolomite with shales in the marginal areas (Solan and Nainital), while limestones are interbedded with marls in the central part of the basin (Massoorie). The Upper Krols are largely composed of dolomites with subordinate limestones and shales.The non-carbonate detrital fraction is dominated by quartz with minor amounts of orthoclase, microcline and plagioclase feldspars. Illite and chlorite constitute the dominant clay minerals, lesser amounts of corrensite and kaolinite are sometimes present. An eastward increase in illite and decrease in chlorite has been ascribed to the supply and distribution of the terrigenum.Zirconium, rubidium, strontium, zinc, nickel and manganese were determined by X-ray fluorescence. Early diagenetic dolomites contain Sr, Zn, Ni and Mn in trace amounts, while the late diagenetic dolomites are characterized by an absence of these elements. The posttectonic dolomites are unusually rich in iron, manganese and sometimes in zinc.Authigenic formation of alkali feldspars, chlorite, illite, quartz and pyrite is not uncommon. The feldspars appear to have formed at early and late diagenetic stages. Potash feldspars dominate over albite in association with dolomite, whereas albite tends to be more common in the limestones.The Krol sedimentation seems to have started in a shallow coastal lagoon behind a barrier beach, upwards changing into tidal-flat deposits.     

钱塘江河口涌潮河段滩槽演替与沉积层序

通过分析时间序列的卫片资料、4 m高的露头剖面的沉积学和元素地球化学特征, 研究钱塘江涌潮河段的滩槽冲淤变化规律、涌潮沉积特征和沉积层序.涌潮河段河道宽浅, 受径流与潮流相互作用强烈, 冲淤频繁且剧烈, 滩槽演替存在约20 a的周期, 与流域年代际洪、枯期转变有关.在滩槽叠置的垂向层序中, 底部为河槽、低潮滩相的厚层块状砂质沉积, 发育各种变形沉积构造, 为典型的涌潮沉积; 顶部为高潮滩相的潮汐韵律沉积, 发育典型的潮汐成因的双黏土层、大小潮周期; 二者之间的中潮滩相呈渐变过渡.C-M图和概率累计曲线可较好地区分涌潮沉积与潮成砂、泥质沉积.涌潮沉积层Si/Al、Zr/Al、Ti/Al等元素比值较高, 而潮汐韵律层Fe/Al、Mn/Al等元素比值较高, 这与它们的赋存方式和水动力分异有关.Si、Zr和Ti主要见于石英和重矿物中, 因此在强水动力沉积层中富集; 而Fe、Mn易被黏土矿物吸附, 在水动力较弱的中高潮滩富集.      

Activity of Silica-Rich Hydrothermal Fluid and Its Impact on Deep Dolomite Reservoirs in the Sichuan Basin, Southern China

Well-developed dissolution pores occur in the dolomites of the Sinian Dengying Formation, which is an important oil and gas reservoir layer in the Sichuan Basin and adjacent areas in southern China. The pores are often filled with quartz, and some dolomites have been metasomatically altered to siliceous chert. Few studies have documented the characteristics, source or origin of silica-rich fluids and their effects on the dolomite reservoir. The peak homogenisation temperatures(T_h) of fluid inclusions in pore-filling quartz are between 150℃ and 190℃, with an average of 173.7℃. Gases in the inclusions are mainly composed of CO_2, CH_4 and N_2. Compared with host dolomite, pore-filling quartz and metasomatic chert contain higher amounts of Cr, Co, Mo, W and Fe, with average concentrations of 461.58, 3.99, 5.05, 31.43 and 6666.83 ppm in quartz and 308.98, 0.99, 1.04, 13.81 and 4703.50 ppm in chert, respectively. Strontium levels are lower than that in the host dolomite, with average concentrations in quartz and chert of 4.81 and 11.06 ppm, respectively. Rare earth element compositions in quartz and chert display positive Eu anomalies with a maximum δEu of 5.72. The δD_(SMOW) values of hydrogen isotopes in water from quartz inclusions vary from-85.1‰ to-53.1‰ with an average of-64.3‰, whereas the δ~(18)O_(SMOW) values range from 7.2‰ to 8.5‰ with an average of 8.2‰. The average ~(87)Sr/~(86)Sr ratios in quartz and chert are 0.711586 and 0.709917, respectively, which are higher than that in the host dolomite. The fluid inclusions, elemental and isotopic compositions demonstrate that the formation of quartz and chert was related to silica-rich hydrothermal fluid and that the fluid was the deep circulation of meteoric water along basement faults. Interactions with silica-rich hydrothermal fluids resulted in densification of dolomite reservoirs in the Dengying Formation through quartz precipitation and siliceous metasomatism. However, it increased the resistance of the host dolomite to compaction, improving the ability to maintain reservoir spaces during deep burial. Evidence for silica-rich hydrothermal activity is common in the Yangtze Platform and Tarim Basin and its influence on deep dolomite reservoirs should be thoroughly considered.     

吉木萨尔凹陷芦草沟组致密油储层初步研究：岩性与孔隙特征分析

通过岩心观察、薄片鉴定、电子探针观测,结合野外剖面及测井和地震等资料,分析吉木萨尔凹陷芦草沟组致密油 储层岩性与孔隙特征。结果表明致密储层段由呈韵律互层产出的白云岩类/粉砂岩类与泥岩类构成,一般由3~5 个韵律组成, 具有一定的非均质性。储层岩石类型主要为白云质粉砂岩/粉砂质白云岩、砂屑白云岩以及泥晶白云岩。其中白云质粉砂岩 / 粉砂质白云岩分布最广,为芦草沟组上、下储层段（“甜点”）最主要储集岩,砂屑白云岩只分布于上储层段,泥晶白云岩 以薄的夹层形式分布于上、下储层段。电子探针微区观测表明,储集空间以溶蚀型孔隙为主,孔径大小从几μm 到30 μm, 可分为粒间/ 晶间溶孔、粒内溶孔以及部分裂缝型孔隙,发生溶蚀作用的矿物以钠长石为主,白云石次之。定量分析表明, 白云质粉砂岩/ 粉砂质白云岩主要由钠长石、白云石以及少量钾长石等矿物组成,砂屑白云岩主要由微晶白云石和少量钠长 石等矿物组成,泥晶白云岩主要由微晶白云石和少量石英、钠长石等矿物组成。     

Mechanisms of isomorphic substitution in quartz

Mechanisms of the incorporation of isomorphic impurities of Al, Ti, and Ge into quartz were studied by EPR techniques. For this purpose, laboratory experiments were carried out on quartz annealing, which allowed us to model the processes of impurity atom introduction into the quartz lattice. The investigation of the kinetics of these processes showed that they are described by diffusion-controlled reactions. In many samples, a proportional relationship was observed between the concentrations of Al and Ti impurities incorporated into the quartz structure during laboratory annealing. A comparison of the experimental results with the character of the natural distribution of isomorphic impurities in quartz revealed their similarity. Based on the analysis of the results of our investigations, two main mechanisms were proposed for isomorphic substitutions in quartz. One of them is referred to as the capture mechanism and corresponds to the incorporation of isomorphic impurities during mineral formation. The second, diffusion mechanism operates after the crystallization of quartz. The isomorphic impurities incorporated into the quartz structure by this mechanism are either formed through the decomposition and transformation of composite complexes or as a result of diffusion from crystalline and gas-liquid inclusions. It was suggested that both mechanisms are responsible for the incorporation of Al and Ge impurities into the mineral lattice, whereas Ti is introduced mainly by the diffusion mechanism. The accounting for the mechanisms of isomorphic substitutions provides a means to significantly increase the reliability of the interpretation of genetic information recorded in the distribution of structural impurities in quartz. Original Russian Text ? L.T. Rakov, 2006, published in Geokhimiya, 2006, No. 10, pp. 1085–1096.     

滇东北巧家县松梁铅锌矿床地质特征及成矿条件分析

巧家松梁铅锌矿床位于小江深断裂和巧家-莲峰大断裂所夹持的"三角地带",矿体产于灯影组中、上段中-厚层硅质白云岩、硅质条带白云岩中。矿体产出严格受构造的控制,F5、F6断裂分别控制着①、②号矿体。矿石矿物简单,主要为闪锌矿、方铅矿和黄铁矿,脉石矿物以白云石为主,次为方解石、石英。文章分析了松梁铅锌矿床的成矿地质特征,认为铅锌成矿的潜力较大,矿床的深部及外围找矿前景良好。在此基础上,总结了成矿预测的标志:上震旦统灯影组强蚀变白云岩、硅质白云岩作为地层岩性标志;NW向压扭性断裂带及其光滑断面是构造标志;白云石化、方解石化等中、低温热液蚀变是地表重要的找矿标志;构造地球化学异常和低电阻、高极化率分别是深部找矿的地球化学和地球物理标志。