13C/12C ratio double cyclicity in a Miocene browncoal: isotopic signals and orbital forcing

A detailed stable carbon isotopic profile of a late Miocene browncoal seam from the Lower Rhine Embayment, Germany, reveals two clear separate cycles of different frequency: this is the first instance of this type of isotopic signature being recognized within coals. The ratio of the two frequencies suggests this isotopic signal possibly resulted from climatic or vegetational responses to orbital forcing. The cyclicity has been enhanced by the application of conventional filtering methods on the data set. An analysis of the seam's palynology indicates a correlation between heavier isotopic compositions and the presence of Sequoiapollenites polyformosus , whose parent plant is believed to have favoured moist climates and higher groundwater tables.     

Carbon isotope variations and fractionation corrections in 14C dating

The formulas for correcting ¹⁴C measurements are explained. The expected ranges of the δ¹³C values for some types of samples are given. It is pointed out that the corrections are approximate because of the choice of correction formula, and that all samples arc normalized to wood samples instead of to carbon dioxide of the air. Some results from the Uppsala laboratory for plant materials and carbonates are given.     

The 14C age of the Toten' mammoth, eastern Norway

A mammoth tusk find from Toten in Oppland, eastern Norway, has been re-dated by the EDTA method. On examining the tusk for heavy metals, the porous parts were found to have the highest concentration. This fact, together with earlier experience from selecting bone samples for ¹⁴C dating, favour the choice of the hard non-porous parts. The influence of possible minor contaminants remaining after pretreatment is discussed. Because of high cosmic-ray intensity the background deviated from the normal stable value. The variations were studied carefully. The final result is that the net activity of the bone is so close to zero that it is questionable whether the age is 'finite'. It is concluded that the tusk is older than 28,000 years.     

An alternative model for positive shifts in shallow-marine carbonate δ13C and δ18O

Abstract Positive shifts in global seawater δ¹³C_DIC are related to changes in the ratio of organic relative to inorganic carbon burial in oceanic basins, whereas factors such as climatic cooling and the accumulation of polar ice are known to cause positive shifts in δ¹⁸O. Here, an alternative model is proposed for the formation of local positive isotope shifts in shallow-marine settings. The model involves geochemically altered platform-top water masses and the effects of early meteoric diagenesis on carbonate isotopic composition. Both mechanisms are active on modern (sub)tropical carbonate platforms and result in low carbonate δ¹³C and δ¹⁸O relative to typical oceanic values. During high-amplitude transgressive events, the impact of isotopically light meteoric fluids on the carbonate geochemistry is much reduced, and ¹³C-depleted platform-top water mixes with open oceanic water masses having higher isotope values. Both factors are recorded as a transient increase in carbonate ¹³C and ¹⁸O relative to low background values. These processes must be taken into consideration when interpreting the geochemical record of ancient epeiric seas.     

Long-term (105) or short-term (103) δ13C excursion near the Palaeocene-Eocene transition: evidence from the Tethys

Expanded sedimentary records from the Tethys reveal unique faunal and isotopic changes across the Palaeocene-Eocene (P-E) transition. Unlike in the open oceans, the Tethys exhibits a gradual decrease of 1.5% in δ¹³C values prior to the rapid δ¹³C excursion. Associated with the 6¹³C excursion is a decrease in calcite burial, increase in detrital content and appearance of a unique opportunistic planktic foraminifera1 assemblage (e.g. compressed acarininids). The existence of a prelude decrease in δ¹³C values in the Tethys suggests that the P-E δ¹³C excursion may have occurred in two steps and over a few hundred thousand years, rather than as one step over a few thousand years as previously suggested. This slower excursion rate is readily explained by changing organic carbon weathering or burial rates and avoids the need of invoking ad hoc scenarios.     

The origin of magnesite deposits from the Polish Foresudetic Block ophiolites: preliminary δ13C and δ18O investigations

Twenty-three magnesite samples from vein deposits, found in ultramafic rocks related to ophiolites in the north-east Bohemian Massif, have been examined for carbon and oxygen isotope ratios. In these rocks two stages of antigorite serpentinization took place prior to magnesite precipitation. δ¹⁸O_SMOW in magnesites ranges from 24.5 to 27.9%o (corrected for acid fractionation factor) which leads us to conclude a meteoric origin of the ore-forming solution. This inference is further supported by δ¹³C values (?18.7 to ?4.4%o) which point to a biogenic origin of carbon in the magnesites.     

Biostratigraphical and palaeoenvironmental implications of isotopic studies (18O, 13C) of middle Miocene (Badenian) foraminifers in the Central Paratethys

The cause of the middle Miocene Badenian salinity crisis in the Central Paratethys is addressed by examining the palaeotemperature evolution of Badenian waters before and after the deposition of evaporites. Selected foraminifer taxa ( Globigerinoides spp., Globigerina bulloides , and Uvigerina ) characterizing, respectively, the near-surface, intermediate, and bottom layers of the water column, were studied in two boreholes of SW Poland. The δ¹⁸O and δ¹³C values for these taxa show distinct differences which can be explained by the temperature difference between surface and bottom waters during deposition. These values also show temporal changes corresponding to the water temperature evolution in the Badenian basin. Different and quickly changing environmental conditions have been inferred from changes in foraminifer assemblages. They explain why biostratigraphic subdivisions based on well-recognized assemblages are the most accurate approach for determining the biostratigraphy of middle Miocene deposits in the Central Paratethys. The results of isotopic studies indicate that evaporites occur in a part of the Badenian section that was characterized by the lowest temperatures in the studied sections.     

Ice sheet extent and early deglacial history of the southwestern sector of the Greenland Ice Sheet

The offshore and coastal geomorphology of southwest Greenland records evidence for the advance and decay of the Greenland Ice Sheet during the Last Glacial Maximum. Regional ice flow patterns in the vicinity of Sisimiut show an enlarged ice sheet that extended southwestwards on to the shelf, with an ice stream centred over Holsteinsborg dyb. High level periglacial terrain composed of blockfield and tors is dated to between 101 and 142 ka using ²⁶Al and ¹⁰Be cosmogenic exposure ages. These limit the maximum surface elevation of the Last Glacial Maximum ice sheet in this part of southwest Greenland to ca 750–810 m asl, and demonstrate that terrain above this level has been ice free since MIS 6. Last Glacial Maximum ice thickness on the coast of ca 700 m implies that the ice sheet reached the mid to outer continental shelf edge to form the Outer Hellefisk moraines. Exposure dates record ice surface thinning from 21.0 to 9.8 ka, with downwasting rates varying from 0.06 to 0.12 m yr⁻¹. This reflects strong surface ablation associated with increased air temperatures running up to the Bølling Interstadial (GIS1e) at ca 14 ka, and later marine calving under high sea levels. The relatively late retreat of the Itilleq ice stream inland of the present coastline is similar to the pattern observed at Jakobshavn Isbræ, located 250 km north in Disko Bugt, which also retreated from the continental shelf after ca 10 ka. We hypothesise that the ice streams of West Greenland persisted on the inner shelf until the early Holocene because of their considerable ice thickness and greater ice discharge compared with the adjacent ice sheet.     

Determination of Total Organic Carbon Content and δ13C in Carbonate-Rich Detrital Sediments

The determination of total organic carbon content and composition in detrital sediments requires careful removal of their carbonate minerals. In detrital sediments containing large amounts of carbonates, including dolomite, this can only be achieved by liquid acid leaching that may solubilise a significant proportion of the organic carbon. For a set of detrital sediments from the Himalayan system and the Amazon River as well as five geological reference materials, we determined the proportion of organic carbon (C_org) solubilised during acid leaching. This proportion is significant for all analysed sediments and generally tends to increase with the organic carbon content. Compared to other types of sediments analysed, clay fractions extracted from river sediments and bed sediments with very low organic carbon content have high and low proportions of acid soluble C_org respectively. In Himalayan and Amazon river sediments, the proportion of C_org solubilised during acid leaching was relatively constant with average values of 14 and 19 % respectively. Thus, it is possible to correct the C_org content for the dissolved organic carbon content measured after decarbonation. Data presented here show that C_org dissolved during liquid acid leaching must be taken into account. After careful calibration, the method presented here should, therefore, be applied to any carbonate-rich detrital sediment.     

Effect of sample pretreatment and size fraction on the δ18O and δ13C values of foraminifera in Arabian Sea sediments

Stable oxygen and carbon isotope ratios (δ¹⁸O and δ¹³C, respectively) of a planktonic foraminiferal species (Globigerinoides sacculifer) and marble carbonate were measured with and without a variety of pretreatments like ultrasonication, soaking in H₂O₂, methanol and roasting under vacuum. Additionally, organic matter - carbonate mixtures were also analysed with and without the above pretreatments. No significant difference was found in the isotope ratios of treated and untreated samples. It appears that most of the pretreatments may not be necessary when dealing with planktonic foraminifera, especially G. sacculifer. Analysis of two different size fractions (> 400 μm and 250–400 μm) of this species reveals that the smaller size fraction is enriched in ¹⁸O and depleted in ¹³C relative to the bigger size fraction. It is therefore necessary to choose a proper size fraction for isotopic analyses.     

40Ar/39Ar Constraints on the tectonic history and architecture of the ultrahigh-pressure Sulu orogen

New ⁴⁰Ar/³⁹Ar ages are presented from the giant Sulu ultrahigh-pressure (UHP) terrane and surrounding areas. Combined with U-Pb ages, Sm-Nd ages, Rb-Sr ages, inclusion relationships, and geological relationships, they help define the orogenic events before, during and after the Triassic collision between the Sino–Korean and Yangtze Cratons. In the Qinling microcontinent, tectonism occurred between 2.0 and 1.4 Ga. The UHP metamorphism occurred in the Yangtze Craton between 240 and 222 Ma; its thermal effect on the Qinling microcontinent was limited to partial resetting of K-feldspar ⁴⁰Ar/³⁹Ar ages. Subsequent unroofing at rates of 5–25 km Myr⁻¹ brought the UHP terrane to crustal levels where it underwent a relatively short amphibolite facies metamorphism. The end of that metamorphism is marked by ⁴⁰Ar/³⁹Ar ages in the 219–210 Ma range, implying cooling at crustal depths at rates of 50–200 °C Myr⁻¹. Ages in the 210–170 Ma range may reflect protracted cooling or partial resetting by Jurassic or Cretaceous magmatism. Jurassic 166–149 Ma plutonism was followed by cooling at rates of c. 15 °C Myr⁻¹, suggesting relatively deep crustal conditions, whereas Cretaceous 129–118 Ma plutonism was succeeded by cooling at rates of c. 50 C Myr⁻¹, suggesting relatively shallow crustal depths.     

Evaluation of bulk carbonate δ13C data from Triassic hemipelagites and the initial composition of carbonate mud

Bulk carbonate samples of hemipelagic limestone–marl alternations from the Middle and Upper Triassic of Italy are analysed for their isotopic compositions. Middle Triassic samples are representative of the Livinallongo Formation of the Dolomites, while Upper Triassic hemipelagites were sampled in the Pignola 2 section, within the Calcari con Selce Formation of the Southern Apennines in Southern Italy. Triassic hemipelagites occur either as nodular limestones with chert nodules or as plane‐bedded limestone–marl alternations which are locally silicified. In the Middle Triassic Livinallongo Formation, diagenetic alteration primarily affected the stable isotopic composition of sediment surrounding carbonate nodules, whereas the latter show almost pristine compositions. Diagenesis lowered the carbon and oxygen isotope values of bulk carbonate and introduced a strong correlation between δ¹³C and δ¹⁸O values. In the Middle Triassic successions of the Dolomites, bulk carbonate of nodular limestone facies is most commonly unaltered, whereas carbonate of the plane‐bedded facies is uniformly affected by diagenetic alteration. In contrast to carbonate nodules, plane‐bedded facies often show compaction features. Although both types of pelagic carbonate rocks show very similar petrographic characteristics, scanning electron microscopy studies reveal that nodular limestone consists of micrite (< 5 μm in diameter), whereas samples of the plane‐bedded facies are composed of calcite crystals ca 10 μm in size showing pitted, polished surfaces. These observations suggest that nodular and plane‐bedded facies underwent different diagenetic pathways determined by the prevailing mineralogy of the precursor sediment, i.e. probably high‐Mg calcite in the nodular facies and aragonite in the case of the plane‐bedded facies. Similar to Middle Triassic nodular facies, Upper Triassic nodular limestones of the Lagonegro Basin are also characterized by uncorrelated δ¹³C and δ¹⁸O values and exhibit small, less than 5 μm size, crystals. The alternation of calcitic and aragonitic precursors in the Middle Triassic of the Dolomites is thought to mirror rapid changes in the type of carbonate production of adjacent platforms. Bioturbation and dissolution of metastable carbonate grains played a key role during early lithification of nodular limestone beds, whereby early stabilization recorded the carbon isotopic composition of sea water. The bulk carbonate δ¹³C values of Middle and Upper Triassic hemipelagites from Italy agree with those of Tethyan low‐Mg calcite shells of articulate brachiopods, confirming that Triassic hemipelagites retained the primary carbon isotopic composition of the bottom sea water. A trend of increasing δ¹³C from the Late Anisian to the Early Carnian, partly seen in the data set presented here, is also recognized in successions from tropical palaeolatitudes elsewhere. The carbon isotopic composition of Middle and Upper Triassic nodular hemipelagic limestones can thus be used for chemostratigraphic correlation and palaeoenvironmental studies.     

AMS 14C measurements and macrofossil analyses of a varved sequence near Pudozh, eastern Karelia, NW Russia

The laminated sediments at Pudozh in eastern Karelia are generally assumed to have been deposited between 13 000 and 16 000 ¹⁴C yr BP and have been used to date the recession of the active ice margin. However, 17 AMS ¹⁴C measurements performed on terrestrial plant macrofossils contained in these sediments show that deposition began during the late Allerφd, when the ice margin had already receded to the northern part of Lake Onega. Based on an age model, we assume that the 1933-year-long varved sequence covers the time period between c. 12 900 and 11 000 calendar years BP. During this period, which comprises the later part of the Late Weichselian and the early Holocene, the local vegetation consisted of open, tree-less dwarf shrub heaths. Increased soil erosion may have occurred before 12 550 calendar years BP.     

Understanding carbonate ramp dynamics using δ13C profiles: examples from the Neoproterozoic Buah Formation of Oman

The Late Neoproterozoic Buah Formation (Nafun Group, Oman) is a carbonate unit outcropping in the Jabal Akhdar and Huqf areas. It is composed mostly of shallow‐water carbonates deposited on a distally steepened carbonate ramp. Correlation of two δ¹³C isotope shifts shows that in the Jabal Akhdar ramp differentiation into fast and slow subsiding areas was followed by lateral progradation. In the Huqf area, however, a uniform scenario of upward shallowing of the facies and lateral progradation is demonstrated by chemostratigraphic timelines cross‐cutting the facies belts. The chemostratigraphic profiles show that the Buah Formation was deposited during sea‐level highstand conditions and that ramp differentiation was due to synsedimentary tectonics. High‐resolution correlation of δ¹³C profiles from the same lithostratigraphic unit (whether Precambrian or Phanerozoic in age) lacking biostratigraphic data can shed light on carbonate systems dynamics, tectonic vs. eustatic controls on depositional sequences and basin subsidence.     

Late Pleistocene glacial history of Jameson Land, central East Greenland, derived from cosmogenic 10Be and 26Al exposure dating

Previous work has presented contrasting views of the last glaciation on Jameson Land, central East Greenland, and still there is debate about whether the area was: (i) ice-free, (ii) covered with a local non-erosive ice cap(s), or (iii) overridden by the Greenland Ice Sheet during the Last Glacial Maximum (LGM). Here, we use cosmogenic exposure ages from erratics to reconcile these contrasting views. A total of 43 erratics resting on weathered sandstone and on sediment-covered surfaces were sampled from four areas on interior Jameson Land; they give ¹⁰Be ages between 10.9 and 269.1 kyr. Eight erratics on weathered sandstone and till-covered surfaces cluster around ∼70 kyr, whereas ¹⁰Be ages from erratics on glaciofluvial landforms are substantially younger and range between 10.9 and 47.2 kyr. Deflation is thought to be an important process on the sediment-covered surfaces and the youngest exposure ages are suggested to result from exhumation. The older (>70 kyr) samples have discordant ²⁶Al and ¹⁰Be data and are interpreted to have been deposited by the Greenland Ice Sheet several glacial cycles ago. The younger exposure ages (≤70 kyr) are interpreted to represent deposition by the ice sheet during the Late Saalian and by an advance from the local Liverpool Land ice cap in the Early Weichselian. The exposure ages younger than Saalian are explained by periods of shielding by non-erosive ice during the Weichselian glaciation. Our work supports previous studies in that the Saalian Ice Sheet advance was the last to deposit thick sediment sequences and western erratics on interior Jameson Land. However, instead of Jameson Land being ice-free throughout the Weichselian, we document that local ice with limited erosion potential covered and shielded large areas for substantial periods of the last glacial cycle.     

Astronomical tuning of the Tortonian 87Sr/86Sr curve in the Mediterranean basin

ABSTRACT This work presents a detailed ⁸⁷Sr/⁸⁶Sr isotope curve for the interval 7.5–9.7 Ma obtained by a high-resolution analysis (sampling spacing of about 40 kyr) of an astronomically calibrated land-based sedimentary sequence exposed in the central Mediterranean area (Gibliscemi section, southern Sicily). The main aim is to verify a synchronous response of the Mediterranean seawater Sr isotope record to the oceanic forcing on the basis of multiple comparisons of the Gibliscemi record with published coeval ⁸⁷Sr/⁸⁶Sr curves. A good correlation with the ⁸⁷Sr/⁸⁶Sr data from the ODP site 926 (equatorial Atlantic ocean), considered to be the Sr chemostratigraphic reference section for the Late Miocene, and from the Pacific DSDP site 590B was registered. Conversely, the comparison of the Gibliscemi Sr isotope data with ⁸⁷Sr/⁸⁶Sr ratios from the coeval segment of the land-based Sardella section (eastern Mediterranean) shows important differences highlighting a local control on the seawater Sr isotope changes in semi-isolated subbasins within the Late Miocene Mediterranean.     

A 3.1 billion year old marble and the 87Sr/86Sr of late-Archean seawater

A marble band in the ≈ 2.75 Gyr old Ramagiri schist belt in the Dharwar craton of south India gave a Pb–Pb age of 3.075 ± 0.095 Gyr. The geochemical data, including high Sr and low Ba and Mn indicate seawater origin for the parent rock, and that there was insignificant geochemical exchange between the marble and the surrounding rocks. The calculated initial Nd isotopic composition and μ₁ indicate an older continental crustal source for the Nd and Pb. The initial ⁸⁷Sr/⁸⁶Sr of the marble is 0.70128, which is higher than the calculated mantle value at ≈ 3 Ga. Although pre-3 Gyr old marine carbonate rocks are thought to be buffered by mantle Sr, the Ramagiri marble contains evolved, crustal Sr. Despite this, the marble has the lowest measured ⁸⁷Sr/⁸⁶Sr among carbonates and represents one of the least radiogenic periods in seawater Sr isotope composition.     

Palaeoproterozoic evaporites in Fennoscandia: implications for seawater sulphate, the rise of atmospheric oxygen and local amplification of the δ13C excursion

This paper addresses global oxygenation and establishment of a marine sulphate reservoir in the Palaeoproterozoic. We report syn-depositional, marine, anhydrite-containing pseudomorphs after Ca-sulphates as widespread throughout the Tulomozero Formation in the SE Fennoscandian Shield, implying that surface waters were oxidized and a large SO marine reservoir was developed as early as 2100 Ma. The Ca-sulphates and associated magnesite and halite precipitated syn-depositionally from oxidized, evolved and modified seawater in coastal playa, sabkha and intertidal flat settings. ⁸⁷Sr/⁸⁶Sr and δ¹³C of associated ¹³C-rich stromatolitic dolostones were environmentally controlled with the highest ratios occurring in playa and sabkha carbonates. The results imply that the Palaeoproterozoic δ¹³C_carb excursion was amplified by 8‰ by local environmental factors and calls into question many observations of putative δ¹³C global signals reported previously from similar Palaeoproterozoic, evaporitic, dolostones. The local environmental amplification can explain a large regional and intercontinental δ¹³C discrepancy observed in synchronous carbonates.     

Diversity of murtoos and murtoo-related subglacial landforms in the Finnish area of the Fennoscandian Ice Sheet

Murtoos are recently discovered triangular-shaped subglacial landforms that form under warm-based ice and in association with significant subglacial meltwater flow. They appear in distinct fields and commonly occur in the area that was covered by the Fennoscandian Ice Sheet during glacial periods. Murtoos potentially represent a transition form from non-channelized to channelized subglacial drainage networks. In the present study, we analyse and classify murtoos and murtoo-related landforms in the Finnish area of the Fennoscandian Ice Sheet based on their characteristics and appearance in LiDAR-based digital elevations models. Combined with morphometric analyses, the observations suggest that five types of murtoos and murtoo-related landforms are common and widespread in Finland: (i) triangle-type murtoos (TTMs), (ii) chevron-type murtoos (CTMs), (iii) lobate-type murtoos (LTMs), (iv) murtoo-related ridges and escarpments (MREs), and (v) other murtoo-related polymorphous landforms (PMRs) that look like small mounds and ridges. The morphometric characteristics of the different types are described here in detail, and it is shown that they are spatially and geomorphologically related. In addition, we provide examples of murtoos other than the TTMs to demonstrate that different murtoo types and murtoo-related landforms are composed of similar sediments and architectural characteristics. The diversity of murtoo landforms and the transition between distinct murtoo types indicate rapid and complicated variations in the configuration of subglacial hydrology at different spatial and temporal scales. This study emphasizes the essential role of subglacial meltwater in the shaping of glacial landscapes and the redistribution of large volumes of sediments during the deglaciation of the Fennoscandian Ice Sheet.