Quasi-conservative behaviour of Be in deep waters of the Weddell Sea and the Atlantic sector of the Antarctic Circumpolar Current

We present the first transect of dissolved ¹⁰Be depth profiles across the Antarctic Circumpolar Current (ACC) in the Atlantic sector. North of the Polar Front the ¹⁰Be concentrations increase continuously from very low values at the surface to values of up to 1600 atoms/g at depth. Deep water ¹⁰Be concentrations of particular water masses are consistent with earlier results obtained further north. South of the Polar Front and in the Weddell Sea the distribution of ¹⁰Be is also characterised by low surface concentrations but below 1000 m depth the concentrations are relatively constant and significantly higher (up to 2000 atoms/g) than further north, probably as a result of mixing and advection of water masses of Pacific origin. Overall the deep water ¹⁰Be distribution is obviously not significantly affected by scavenging processes or ice melt and comparison with the density distribution suggests that ¹⁰Be can be viewed as a quasi-conservative tracer. This provides a tool for an improved understanding of the behaviour of other more particle reactive trace metals in the Southern Ocean such as ²³⁰Th: in deep waters north of the ACC/Weddell Gyre boundary (AWB) ¹⁰Be/²³⁰Th has a relatively constant value (1.7±0.3×10⁹ atoms/dpm) over a wide density range whereas south of the AWB the ratio is significantly lower (1.1±0.2×10⁹ atoms/dpm). This normalisation to ¹⁰Be corroborates that ²³⁰Th is enriched by 50% due to accumulation south of the AWB as a consequence of minimal particulate fluxes. The quasi-conservative behaviour deduced from our results also implies that ¹⁰Be can only be used as a tracer for Southern Ocean particle fluxes in the past if ocean circulation patterns and water mass residence times did not change significantly.     

Distribution ofBe andBe in the Pacific Ocean

The vertical distributions of¹⁰Be and⁹Be at three locations in the Pacific (25°N, 170°E; 17°N, 118°W; 3°S, 117°W) are presented. The results show that both isotopes exhibit nutrient-like profiles. From the surface to the bottom, the increase for¹⁰Be is two- to threefold and that for⁹Be is about fivefold. While the inter-station variations in surface water concentrations may reach a factor of two, deep-water values tend to be much more uniform averaging about 2000 atoms/g for¹⁰Be and 30 pM for⁹Be. A similar situation applies to the¹⁰Be/⁹Be ratio; it varies approximately from 1 to 3 × 10⁻⁷ (atom/atom) at shallow depths but tends toward a value close to 1.1 × 10⁻⁷ in the deep ocean. The variation of¹⁰Be/⁹Be can be viewed as resulting from the fact that¹⁰Be in a given parcel of water consists of two components: recycled and primary. The recycled component is that part of¹⁰Be which has reached tracer equilibrium with⁹Be, as opposed to the primary component which, upon entering the sea from the atmosphere, has yet to equilibrate with⁹Be through particle cycling and mixing processes. It is estimated that 70% to nearly 100% of¹⁰Be at the three stations are being recycled, and the recycled beryllium bears an atomic ratio of¹⁰Be/⁹Be close to 1 × 10⁻⁷. The oceanic residence time of Be is of the order of 1000–4000 years, comparable to or slightly longer than the ocean mixing time.     

Aerosol deposition velocities on the Pacific and Atlantic oceans calculated from7Be measurements

The concentrations of⁷Be have been measured in Pacific and Atlantic ocean water for the past several years to determine the deposition velocity of aerosol particles on the ocean surface.⁷Be is produced at a relatively constant rate in the atmosphere by spallation reactions of cosmic rays with atmospheric nitrogen and oxygen. Immediately after its formation⁷Be becomes attached to aerosol particles, and therefore can serve as tracers of the subsequent behavior of these particles. Isopleths of⁷Be surface water concentrations,⁷Be inventory in the ocean, and deposition velocity have been prepared for the Pacific Ocean from 30°S to 60°N and for the Atlantic Ocean from 10°N to 55°N. The concentrations, inventories and deposition velocities tended to be higher in regions where precipitation was high, and generally increased with latitude. The average flux of⁷Be across the ocean surface was calculated to be 0.027 atoms cm^?2 s^?1 which is probably not significantly greater than the worldwide average⁷Be flux across land and ocean surfaces of 0.022 atoms cm^?2 s^?1 calculated by Lal and Peters. The average deposition velocity was calculated to be 0.80 cm s^?1. This value may be 10–50% too low, since it was calculated using atmospheric⁷Be concentrations which were measured at continental stations. Measurements of atmospheric⁷Be concentrations at ocean stations suggest that the concentrations at the continental stations averaged 10–50% higher than the concentrations over the ocean.     

Importance of vertical geochemical processes in controlling the oceanic profiles of dissolved rare earth elements in the northeastern Indian Ocean

Vertical profiles of dissolved rare earth elements (REEs) were obtained in the Bay of Bengal and the Andaman Sea. The REE concentrations at various depths in the Bay of Bengal are the highest in the Indian Ocean. This is attributable ultimately to the large outflow of the Ganges–Brahmaputra and Irrawaddy rivers, but the dissolved REE flux to surface waters alone cannot explain the large and near-constant REE enrichment throughout the entire water column. The underlying fan sediments serve as not a source but a sink for dissolved REE(III)s. Absence of excess ²²⁸Ra in the deep waters suggests that lateral input of dissolved REEs from slope sediments is also small in these regions. Partial (<0.3%) dissolution of detrital particles, which are carried by the rivers and lateral surface currents and subsequently settle through the water column, appears to be a predominant source for the dissolved REEs. Vertical profiles showing an almost linear increase with depth are common features for the light and middle REEs everywhere, but their concentration levels are variable from basin to basin and from element to element. This suggests that their oceanic distributions respond quickly to the variation of particle flux and its REE composition through reversible exchange equilibrium with suspended and sinking particles much like the case for Th. The relative importance of the vertical geochemical processes of reversible scavenging over the horizontal basin-scale ocean circulation with passive regeneration like nutrients decreases systematically from the light to the heavy REEs. Using a model, the mean oceanic residence times of REEs in the Bay of Bengal are estimated to range from 37 years for Ce to 140–1510 years for the strictly trivalent REEs. In the deep water of the Andaman Sea, isolated from the Bay of Bengal by the Andaman–Nicobar Ridge (maximum sill depth of ∼1800 m), the REE concentrations are almost uniform presumably due to rapid vertical mixing. The REE(III) concentrations are similar to that of ∼1250 m depth water in the Bay of Bengal, consistent with other oceanographic properties. However, the REE composition of the deep water appears to be altered slightly by preferential scavenging of the light REE(III) at the bottom boundary of the basin.     

Lead concentrations in the northeast Pacific: evidence for global anthropogenic perturbations

Lead concentrations were determined by isotope dilution mass spectrometry in 34 surface- and deep-water samples collected in the northeast Pacific between Hawaii and California and off the California coast using a deep-water sampler protected against fouling by contamination from the ship and hydrowire. Measured concentrations lie more than one order of magnitude below previously published open ocean values and they show that in most cases 90% or more of the total lead is in a dissolved form. Lead concentrations are about 10-fold higher in surface and thermocline waters than in deep waters; values drop as low as 1 ng/kg (5 pmol/kg) below 3500 m depth. Lead profiles thus appear different compared to those of most trace metals, which show enrichment in deep waters compared to surface concentrations. Lead concentrations in surface waters increase from 5 to 15 ng/kg (25 to 75 pmol/kg) along a transect starting from a location 200 km off the California coast and continuing towards the center of the North Pacific Gyre. This increase is congruent with that observed for²¹⁰Pb concentrations in the same waters sampled at the same time.Lead is supplied to the open North Pacific largely from the atmosphere, at a rate of about 60 ng/cm² yr, which exceeds the prehistoric oceanic output flux of authigenic lead recorded in pelagic sediments about tenfold. This excess originates from emissions from smelters and combustion of leaded gasoline, overwhelming natural lead inputs that entered the ocean during prehistoric time probably largely through rivers. Vertical lead concentration profiles below the surface mixed layer are probably not in steady state. There, concentrations must be increasing in response to the increase of anthropogenic inputs because the estimated lead residence times are more than 20 years in the thermocline and about 80 years in deep waters. Based on an estimated 10-fold input and concentration increase since the mid-eighteenth century in the surface mixed layer in the central northeast Pacific, it is calculated that the 10 ng/kg average concentration between 100 and 900 m is 2 to 5 times larger, and the 1.8 ng/kg average concentration between 900 and 5000 m depth is about 2 times larger than it was in the mid-eighteenth century. Profiles of lead concentrations in the North Atlantic are expected to be shifted generally to larger values by a factor of 2 to 3 compared to those in the North Pacific because of the effects of greater industrial lead contamination, while lead concentration profiles in the South Pacific are expected to be shifted generally to lower values compared to the North Pacific by about this same factor because of the effects of lesser industrial lead contamination.     

Tracing environmental change in southern Patagonia using beryllium isotopes,Laguna Potrok Aike,Argentina

We have examined the relationship between beryllium isotopes and the hydrological record of Laguna Potrok Aike, a maar lake in southern Argentina for the past 16,000 cal BP. Our study shows that sedimentary ¹⁰Be and ⁹Be records of Laguna Potrok Aike are associated with the hydrological balance, when compared to other proxies such as Ca, Ti and total inorganic carbon (TIC). During drier periods, the level of ⁹Be is decreased. ¹⁰Be follows this trend from 16,000 to 8000 cal BP, for younger samples, the concentration of ¹⁰Be increases at about 5000 cal BP and in recent times, but is otherwise relatively constant. At 13,000 cal BP total beryllium (⁹Be) was relatively low, but the ¹⁰Be/⁹Be ratio was the highest for the entire record studied. Our study shows that beryllium isotopes can be used for tracing climatic signals associated with lake level changes, i.e., dry or wet conditions at Laguna Potrok Aike.     

Oxygen isotope fractionation in dissolved oxygen in the deep sea

¹⁸O variations in dissolved oxygen have been measured at five stations from the eastern equatorial Pacific, at the GEOSECS-I and -II intercalibration stations in the North Pacific and North Atlantic, and along an Antarctic-South Pacific section from MONSOON expedition. Relative to atmospheric oxygen, dissolved oxygen in the ocean is enriched in¹⁸O up to a maximum of 14‰, the extreme enrichments occurring in the oxygen-minimum region of the eastern Pacific. The vertical diffusion-advection model has been used to determine the isotopic fractionation of deep-water in-situ oxygen consumption ascribed to bacterial metabolism. The single-stage enrichment, ε, in Pacific Deep Water below 1 km is 10‰ (α = 0.99,¹⁶O consumed preferentially). The model calculations show that the isotopic data cannot be fit without the introduction of a fractionation factor, just as the dissolved oxygen data cannot be fit without an in-situ consumption parameter. The consistency of the positive sign for ε and the negative source term for O₂, observed in all deep Pacific profiles analyzed to date, provide strong evidence that vertical transport and in-situ consumption terms dominate the horizontal tracer flux terms, and indicate the presence of a significant “deep metabolism” in abyssal ocean waters.     

Beryllium-10 in continental sediments

The concentration of¹⁰Be has been measured in 10 samples taken from a transect of surface sediments beginning in the Atchafalaya River and extending across the Bay 136 km into the Gulf of Mexico. If corrected for a lower retentivity of sand for Be, they have a concentration that is constant within 13%. This concentration is about an order of magnitude smaller than that of deep ocean sediments. For comparison, measurements of¹⁰Be in rainwater, in a sample of soil and in a deep ocean core were made.     

A changing nutrient regime in the Gulf of Maine

Recent oceanographic observations and a retrospective analysis of nutrients and hydrography over the past five decades have revealed that the principal source of nutrients to the Gulf of Maine, the deep, nutrient-rich continental slope waters that enter at depth through the Northeast Channel, may have become less important to the Gulf's nutrient load. Since the 1970s, the deeper waters in the interior Gulf of Maine (>100 m) have become fresher and cooler, with lower nitrate (NO₃) but higher silicate (Si(OH)₄) concentrations. Prior to this decade, nitrate concentrations in the Gulf normally exceeded silicate by 4–5 μM, but now silicate and nitrate are nearly equal. These changes only partially correspond with that expected from deep slope water fluxes correlated with the North Atlantic Oscillation, and are opposite to patterns in freshwater discharges from the major rivers in the region. We suggest that accelerated melting in the Arctic and concomitant freshening of the Labrador Sea in recent decades have likely increased the equatorward baroclinic transport of the inner limb of the Labrador Current that flows over the broad continental shelf from the Grand Banks of Newfoundland to the Gulf of Maine. That current system now brings a greater fraction of colder and fresher deep shelf waters into the Gulf than warmer and saltier offshore slope waters which were previously thought to dominate the flux of nutrients. Those deep shelf waters reflect nitrate losses from sediment denitrification and silicate accumulations from rivers and in situ regeneration, which together are altering the nutrient regime and potentially the structure of the planktonic ecosystem.     

Lead in corals: reconstruction of historical industrial fluxes to the surface ocean

Twentieth century environmental lead chronologies for the western North Atlantic, Pacific, and Indian Oceans have been reconstructed from annually-banded scleractinian corals. Measurements of lattice-bound Pb in sequential coral bands reveal temporal changes in surface water Pb concentrations and Pb isotopic distributions. Perturbations are observable in all specimens studied, attesting to global augmentation of environmental Pb by industrialization.In the western North Atlantic, Pb perturbations have occurred in direct response to the American industrial revolution and the subsequent introduction and phasing-out of alkyl Pb additives in gasoline. Surface ocean conditions near Bermuda may be reliably reconstructed from the coral data via a lead distribution coefficient of 2.3 for the species,Diploria strigosa. Based on²¹⁰Pb measurements, a similar distribution coefficient may be characteristic of corals in general. Surface Pb concentrations in the pre-industrial Sargasso Sea were about 15–20 pM. Concentrations rose to near 90 pM by 1923 as a result of metals manufacture and fossil fuel combustion. Beginning in the late 1940's, increased utilization of leaded gasoline eventually led to a peak concentration of 240 pM in 1971, representing an approximate 15-fold increase over background. Surface ocean concentrations are presently declining rapidly (128 pM in 1984) as a result of curtailed alkyl Pb usage. Lead isotopic shifts parallel the concentration record indicating that characteristic industrial and alkyl Pb source signatures have not changed appreciably in time. Industrial releases recorded in the Florida Keys reflect a weaker source and evidence of recirculated Pb (5–6 years old) from the North Atlantic subtropical gyre. An inferred background concentration of 38 pM suggests influence of shelf and/or resuspended inputs of Pb to these coastal waters.In remote areas of the South Pacific and Indian Oceans, industrial signals are fainter and the corals studied much younger than their Atlantic counterparts. Contemporary Pb concentrations implied by coral measurements (assumingK_D = 2.3) are 40–50 pM for surface waters near Tutuila and Galapagos in the South Pacific, and 25–29 pM near Mauritius in the Indian Ocean. A single coral band from Fiji (1920 ± 5yr) implies a pre-industrial surface water concentration of 16–19 pM Pb for the South Pacific. In view of reported surface water measurements and the North Atlantic coral data, the Pacific coral extrapolations may be slightly high. This could be a result of small variations inK_D among different coral genera, or incorporation of diagenetic Pb by corals sampled in coastal environments.     

10Be and Th isotopes in manganese nodules and adjacent sediments: Nodule growth histories and nuclide behavior

The concentration profiles of ⁹Be, ¹⁰Be, ²³⁰Th, ²³²Th, ²³¹Pa (via ²²⁷Th) and ²³⁸U have been measured in three manganese nodules, one each from the North Pacific (A47-16(4)), the South Pacific (TF-5) and the Indian Ocean (R/V Vitiaz). In addition the ¹⁰Be concentration in deep water from the GEOSECS reoccupation station 500 of the North Pacific, and in ? cores raised from the manganese nodule field in the North Pacific have been measured. The ¹⁰Be concentration in nodule and seawater samples was measured by the accelerator masss spectrometric technique employing the Yale Tandem Van de Graaff accelerator.The concentrations of ¹⁰Be, ²³⁰Th_exc and ²³¹Pa_exc and ratios of ¹⁰Be/⁹Be and ²³⁰Th_exc/²³²Th all decrease with depth in the nodules. This decrease, interpreted in terms of nodule growth, yields “average” growth rates of a few millimeters per million years for the nodules. The growth rates of the nodules exhibit temporal variations, both on short time (～ 50,000 years) and long time (several million years) scales. Of the three nodules studied, only in TF-5 is the short-term average growth rate based on ²³⁰Th_exc in the top 0–0.5 mm the same as the long-term average rate based on Be isotope data for the 0.5–17 mm interval. For the other two nodules, the recent average growth rates based on²³⁰Th_exc data differ significantly from the long-term average growth rates based on Be isotopes. In A47-16(4) the ¹⁰Be based rate is less than the ²³⁰Th_exc rate and in R/V Vitiaz the ¹⁰Be based rate is greater than the ²³⁰Th_exc rate. This observation, coupled with measurable changes in growth rates even during the past few hundred thousand years, suggests, but does not prove, that the discordant growth rates deduced from ²³⁰Th_exc and ¹⁰Be profiles document changes in nodule growth rate with time rather than mixing effects on ²³⁰Th_exc profiles.The ¹⁰Be concentration in the GEOSECS North Pacific deep water is 6100±1200 atoms/g. This value coupled with the average surface ¹⁰Be/⁹Be ratio of North Pacific nodules predicts a ⁹Be concentration within the limits of measured values. The inventory of ¹⁰Be and ²³⁰Th_exc in the nodules is only ～ 10% of the total, the remaining being in sediments. The ¹⁰Be concentrations in the upper portions of two adjacent cores studied are nearly the same, but the deposition fluxes of both ¹⁰Be and ²³⁰Th based on ²³⁰Th dating vary by a factor of two. This difference is attributable to local redistribution of sediment at the time of deposition prior to accumulation.     

Cosmogenic isotopes and their role in present-day solar paleoastrophysics

Present-day data on ¹⁴C and ¹⁰Be concentration in natural archives have been statistically analyzed. It has been established that it is difficult to extract information about solar activity variations on long (several Myr and longer) and, especially, short (to 30 years) time scales using radiocarbon data. It has been indicated that beryllium series bear reliable information about short-term, secular, and, probably, 1000-year variations in solar activity. Moreover, ¹⁰Be concentration in polar ice can also be used to study the internal dynamics of solar activity. It has been concluded that beryllium data are more promising than radiocarbon ones from the viewpoint of solar paleoastrophysics.     

The distribution of 210Pb and 210Po in the surface waters of the Pacific Ocean

By modelling the observed distribution of²¹⁰Pb and²¹⁰Po in surface waters of the Pacific, residence times relative to particulate removal are determined. For the center of the North Pacific gyre these are τ_Po = 0.6years andτ_Pb = 1.7years. The surface ocean τ_Pb is determined by particulate transport rather than plankton settling. The fact that it is about two orders of magnitude smaller than τ_Pb for the deep ocean implies a sharp change in the adsorptive quality of particles during descent through the water column.     

Trace metals and radium in the Gulf of Mexico: An evaluation of river and continental shelf sources

Several studies have provided evidence for the enrichment of trace elements in coastal waters, particularly for copper. These enrichments have been attributed to diffusion from continental shelf sediments and to an influx of river water. We attempted to resolve between these sources by undertaking an extensive suite of measurements of trace metals (Cu, Ni, Cd), ²²⁶Ra and ²²⁸Ra in the surface waters of the Gulf of Mexico, along with trace metal profiles at 6 stations (April 1981 and December 1982). These data establish that enrichments of copper, nickel and cadmium occur in the shallow waters of the Gulf of Mexico. On the Mississippi continental shelf, high trace element concentrations (Cu, Ni: ～ 9 nmol/kg; Cd: ～ 200 pmol/kg) in lower-salinity waters (26‰) are similar to those observed in the Mississippi plume at the same salinity. This evidence suggests a river water source. On the other hand, trace element enrichments are also observed in the northern Gulf (Cu: +0.4 nmol/kg; Ni: +0.5 nmol/kg; Cd: +20 pmol/kg) which coincide with an increase in ²²⁸Ra but are not accompanied by decreased salinity. The excess of evaporation over precipitation in this region makes it possible that this water could be evaporated estuarine water; therefore, hydrographic observations cannot distinguish readily between river and shelf sources. A regional flux balance shows that most of the excess copper in the surface waters of the Florida Current can be supplied by the river-borne dissolved copper flux. Within the uncertainties of such calculations, the continental shelf copper flux must be less than or equal to the river flux.     

Neodymium isotopic variations in seawater

New data for the direct measurement of the isotopic composition of neodymium in Atlantic Ocean seawater are compared with previous measurements of Pacific Ocean seawater and ferromanganese sediments from major ocean basins. Data for Atlantic seawater are in excellent agreement with Nd isotopic measurements made on Atlantic ferromanganese sediments and are distinctly different from the observed compositions of Pacific samples. These results clearly demonstrate the existence of distinctive differences in the isotopic composition of Nd in the waters of the major ocean basins and are characteristic of the ocean basin sampled. The average ε_Nd(0) values for the major oceans as determined by data from seawater and ferromanganese sediments are as follows: Atlantic Ocean,ε_Nd(0) ? ?12 ± 2; Indian Ocean,ε_Nd(0) ? ?8 ± 2; Pacific Ocean,ε_Nd(0) ? ?3 ± 2. These values are considerably less than ε_Nd(0) value sources with oceanic mantle affinities indicating that the REE in the oceans are dominated by continental sources. The difference in the absolute abundance of¹⁴³Nd between the Pacific and Atlantic Oceans corresponds to ～10⁶ atoms¹⁴³Nd per gram of seawater. The correspondence between the¹⁴³Nd/¹⁴⁴Nd in seawater and in the associated sediments suggests the possible application of this approach to paleo-oceanography.Distinctive differences in ε_Nd(0) values are observed in the Atlantic Ocean between deep-ocean water associated with North Atlantic Deep Water and near-surface water. This suggests that North Atlantic Deep Water may be relatively well mixed with respect to Nd isotopic composition whereas near-surface water may be quite heterogeneous, reflecting different sources for surface waters relative to deep water. This suggests that it may be possible to distinguish the sources of water masses within an ocean basin on the basis of Nd isotopic composition.The Nd isotopic variations in seawater are used to relate the residence time of Nd and mixing rates between the oceans.     

10Be dating of large manganese nodules from world oceans

The results of ¹⁰Be and ⁹Be measurements in several sections of ten large manganese nodules are presented along with U and Th isotope data on five of them.The ¹⁰Be and ¹⁰Be/⁹Be methods yield growth rates (covering a period of 5–10 Ma) which are in excellent agreement with each other. In three cases, these rates are also in very good agreement with those derived from the ²³⁰Th methods, whereas in the other two the ²³⁰Th-based rates are faster by over a factor of two.Based on the discrepancy between the inventory of ¹⁰Be (as well as ²³⁰Th) in nodules and the overhead seawater column, it is calculated that the former scavenge their Be and Th isotopes from 2–900 m of the overhead water column. The deduced ⁹Be concentrations of ocean water based on its ¹⁰Be contents and the ¹⁰Be/⁹Be ratios of nodule surfaces are found to be in good agreement with the direct ⁹Be measurements of seawater implying that ⁹Be in nodules (like¹⁰Be) is mostly authigenic.     

Land–ocean distribution of allochthonous organic matter in surface sediments of the Chiloé and Aysén interior seas (Chilean Northern Patagonia)

We investigated the relative distribution of allochthonous (i.e., terrigenous) organic matter in the complex, continuous, river–fjord–sound–channel–gulf system of Chile’s North Patagonia (41.5–46.5°S) in order to establish whether this organic matter can reach the open ocean or whether it is largely retained near its fluvial sources. Grain size distribution, total organic carbon and total nitrogen contents, and carbon stable isotope contents (δ¹³C) were quantified in 53 surface sediment samples collected during the CIMAR Fiordos cruises 1, 4, 8, and 10, as were salinity and silicic acid concentrations in the surface waters. A principal component analysis segregated the Chiloé and Aysén interior seas into two zones: (i) the continental fjords, with sediment enriched in allochthonous organic matter, having higher C:N molar ratios (10–14) and lower δ¹³C composition (?23‰ to ?27‰); and (ii) the channels and gulfs, with a prevalent autochthonous marine source, having lower C:N values (6–10) and higher δ¹³C composition (?20‰ to ?23‰). Estuarine waters with low salinity (2–30) and high silicic acid (10–90 μM) were associated with high C:N ratios and low δ¹³C in surface sediments, meaning that terrestrial organic matter was transported up to the mouth of the continental fjords. A two-source mixing model confirmed that allochthonous (terrestrial) organic matter contents (50–90%) associated with local river discharges were present within the continental fjords. On the contrary, autochthonous (marine) organic matter was prevalent (50–90%) at the sites in the marine influenced channels, sounds, and gulfs.     

On the influence of adequate Weddell Sea characteristics in a large-scale global ocean circulation model

Global ocean circulation models usually lack an adequate consideration of high-latitude processes due to a limited model domain or insufficient resolution. Without the processes in key areas of the global thermohaline circulation, the characteristics and flow of deep and bottom waters cannot be modeled realistically. In this study, a high-resolution (~20 km) ocean model focused on the Weddell Sea sector of the Southern Ocean is combined with a low-resolution (2^° × 2^°) global ocean model applying the state estimation technique. Temperature, salinity, and velocity data on two Weddell Sea sections from the regional model are used as constraints for the large-scale model in addition to satellite altimetry and sea-surface temperatures. The differences between the model with additional constraints and without document that the Weddell Sea circulation exerts significant influence on the course of the Antarctic Circumpolar Current with consequences for Southern Ocean water mass characteristics and the spreading of deep and bottom waters in the South Atlantic. Furthermore, a warming trend in the period 1993–2001 was found in the Weddell Sea and adjacent basins in agreement with float measurements in the upper Southern Ocean. Teleconnections to the North Atlantic are suggested but need further studies to demonstrate their statistical significance.     

Barium in the Antarctic Ocean and implications regarding the marine geochemistry of Ba and226Ra

Ba distribution in the ocean correlates linearly with that of ²²⁶Ra, reflecting little fractionation of the two elements in their uptake by marine organisms. The weight ratio of ²²⁶Ra/Ba is estimated to be (0.714 ± 0.08) × 10^?8. A wide range of Ba/Si and Ra/Si values is noted in siliceous plankton collected from different oceans. This corraborates with the observations that, although silica co-varies with Ba and²²⁶Ra, the Ba/Si and²²⁶Ra/Si ratios in seawater vary from one area to another. Sediment pore water contains higher Ba concentrations than the overlying seawater. The resulting diffusive flux of Ba through the sediment-sea interface is estimated to be no more than 20% of the river input. The apparent oversaturation of dissolved Ba in pore fluids with respect to barite supports the idea that complexing of Ba with organic ligands may be important. Box model calculations show that: (1) on a per unit area basis, ²²⁶Ra flux from the continental shelf sediments is higher than that from the deep sea floor; (2) in the deep ocean, the magnitude of diffusive input of ²²⁶Ra from sediments is about equal to the loss due to radioactive decay.     

The thorium isotope content of ocean water

²³²Th concentrations of surface and deep Pacific Ocean waters are 0.01–0.02 dpm/1000 kg (60 pgm/kg). The²³⁰Th activity is 0.03–0.13 dpm/1000 kg in surface waters and 0.3–2.7 dpm/1000 kg in deep waters. Chemical residence times based on in situ production from parent isotopes are about the same for²³⁰Th and²²⁸Th in surface waters (1–5 years) but are ten times greater for²³⁰Th in deep waters (10–100 years). Apparently there are additional sources of²³⁰Th into deep waters. At MANOP site S manganese nodule tops are enriched in Th isotopes by adsorption of Th from seawater and not by incorporation of Th-rich particulates.