Radionuclide ratios in wet and dry deposition samples from June 1976 through December 1977

²³⁸Pu,²³⁹Pu and¹³⁷Cs in rain and dry fallout and⁹⁰Sr in rain samples were measured at Woods Hole, Massachusetts, from June 1976 through December 1977. The dry fallout was estimated to be about 7.8% of the total deposition of²³⁹Pu and¹³⁷Cs.²³⁹Pu/¹³⁷Cs ratios, almost constant at about 0.011 in rain or dry fallout, February through December 1977, suggested that fractionation between the refractory and volatile radionuclides is insignificant in stratospheric fallout. This supports the idea of regional homogeneity of radionuclide ratios in fallout.     

Atmospherically-derived radionuclides as tracers of sediment mixing and accumulation in near-shore marine and lake sediments: Evidence from7Be,210Pb,and239,240Pu

Cosmogenic⁷Be(t_1/2 = 53.3days) has been used to estimate particle-mixing rates in the upper layers of lacustrine and near-shore marine sediments. Excess²¹⁰Pb and/or^239,240Pu have provided limits on rates of sediment accumulation in these environments and indices of the efficiency of the sediments as collectors of reactive nuclides over longer time scale.In sediment cores from Long Island Sound (marine) and Lake Whitney (fresh-water)⁷Be was measurable in the top 2–3 cm. Diffusion-analog particle-mixing coefficients calculated from these data are in the range of 10^?7 cm²/s. For Long Island Sound the coefficients are lower by factors of 3–6 than those estimated from the depth distributions of excess²³⁴Th at the same stations [14]. For Lake Whitney the calculated mixing coefficient is an upper limit because of the possibility of a sampling artifact.Measurements of total (wet + dry) atmospheric deposition of⁷Be in New Haven give an average flux of 0.07 dpm/cm² day during March-November, 1977; this is equivalent to a steady-state inventory of 5.4 dpm/cm² in a perfect collector. Sediment cores from Long Island Sound contain about half this⁷Be inventory, consistent with either a mean residence time for⁷Be in the water column of about one half-life or with post-depositional loss of⁷Be from Long Island Sound sediments. The Lake Whitney cores contain about 5 dpm/cm², much nearer the atmospheric delivery. A higher inventory of⁷Be in fresh-water, as compared to marine, sediments could be due either to a shorter mean residence time for⁷Be in fresh water or to lateral transport processes in the lake or its catchment. High inventories of excess²¹⁰Pb and^239,240Pu in Lake Whitney sediments demonstrate the importance of lateral transport on longer time scales at least.     

Fallout240Pu and239Pu in Atlantic marine samples

Mass spectrometric analyses of low levels of global fallout plutonium separated from Atlantic marine samples have differentiated fallout²³⁹Pu and²⁴⁰Pu in aquatic samples for the first time. The results show no single characteristic²⁴⁰Pu/²³⁹Pu ratio in marine samples; the observed range is from 0.11 to 0.24 on an atom basis. There are indications that differences exist in the chemical or physical form of plutonium from atmospheric fallout in Atlantic surface water and that selective concentration in surface organisms is occurring. No single²⁴⁰Pu/²³⁹Pu value is found in pelagic sediments collected from different depths and locations. Discounting sources other than fallout, our results show that the plutonium deposited at any given time since atmospheric testing began may have carried a unique²⁴⁰Pu/²³⁹Pu tag. This label may be extremely useful to trace fallout plutonium through biogeochemical cycles.     

Plutonium,radiocesium and radiocobalt in sediments of the Hudson River estuary

Anthropogenic radionuclides have reached the Hudson estuary as global fallout from nuclear weapons testing and through local releases from commercial nuclear reactors. Significant activities of²³⁸Pu and^239,240Pu (fallout-derived),¹³⁴Cs and⁶⁰Co (reactor-released), and¹³⁷Cs (derived from both sources), have accumulated in the sediments throughout the estuary, with the primary zone of accumulation near the downstream end of the system in New York harbor. The estuary appears to have trapped nearly all of the^239,240Pu delivered as fallout, and consequently, ocean dumping of dredged harbor sediment is currently the primary means for the net transport of these nuclides to coastal waters. In contrast, only 10–30% of the¹³⁷Cs,¹³⁴Cs and⁶⁰Co delivered to the estuary have been retained on the fine particles which accumulate at a rapid rate in the harbor.The primary factors which have governed the distribution of anthropogenic radionuclides in Hudson sediments are: (1) spread of fine particles labeled with both fallout and reactor nuclides throughout the axis of the estuary, (2) differences in timing of the peak fallout years (1962–1964) and years of maximum reactor releases (1971–1972), (3) large variations in sediment accumulation rates, ranging from a few millimeters per year or less to many tens of centimeters per year, (4) appreciable desorption of¹³⁷Cs and¹³⁴Cs from particles at higher salinities, and (5) possible enhanced desorption of⁶⁰Co at higher salinities (relative to¹³⁴Cs and¹³⁷Cs) which may be associated with the release of reduced manganese from the harbor sediments.     

Fallout radionuclides in the Pacific Ocean: Vertical and horizontal distributions,largely from GEOSECS stations

From GEOSECS stations, largely, the 1974 distributions of Pu and of¹³⁷Cs are described in the Pacific Ocean north of about 20°S latitude. Changes in some of these distributions are described from 1978 cruises by the authors.The Pacific exhibited, everywhere, a shallow subsurface layer of Pu-rich water with its concentration maximum at about 465 m in 1974; over a large portion of the central North Pacific a second layer of Pu-labelled water, less concentrated than the shallow layer, lay just above the bottom. Similar features were not observed in the case of¹³⁷Cs.The inventories of both Pu and¹³⁷Cs in the water column at most 1974 stations are substantially greater than those to be expected from world-wide fallout alone; these inventory excesses appear to be attributable to close-in fallout, but only if the ratio Pu/¹³⁷Cs in this source was much higher than in world-wide fallout. The North Pacific mean ratio of the inventories is 2.2 times that observed in world-wide fallout.Resolubilization of Pu both from sinking particles and from sediments explains peculiarities of its depth distributions.There is little evidence for tracer movement by sliding downward along density surfaces;¹³⁷Cs appears to have moved to depth by downmixing at the edge of the Kuroshio, and then moved horizontally and upward alongσ_t contours. The shallow Pu-rich layer shows no coordination with density, salinity or O₂ isopleths. The deep Pu-rich layer is restricted to a narrow range of O₂ concentrations that confirm its origin in the Aleutian Trench and rapid spread southward and laterally. Near-bottom circulation processes have been much more active than here-to-fore described.     

Pb-derived ages for the reconstruction of terrestrial contaminant history into the Mexican Pacific coast: Potential and limitations

²¹⁰Pb is widely used for dating recent sediments in the aquatic environment; however, our experiences working in shallow coastal environments in the Pacific coast of Mexico have demonstrated that the potential of ²¹⁰Pb for reliable historical reconstructions might be limited by the low ²¹⁰Pb atmospheric fallout, sediment mixing, abundance of coarse sediments and the lack of ¹³⁷Cs signal for ²¹⁰Pb corroboration. This work discusses the difficulties in obtaining adequate sedimentary records for geochronological reconstruction in such active and complex settings, including examples of ²¹⁰Pb geochronologies based on sediment profiles collected in two contrasting areas coastal areas (mudflats associated to coastal lagoons of Sinaloa State and the continental shelf of the Gulf of Tehuantepec), in which geochemical data was used to support the temporal frame established and the changes in sediment supply recorded in the sediment cores which were related to the development of land-based activities during the last century.     

Depositional history of artificial radionuclides in the Ross Ice Shelf,Antarctica

The annual fluxes of artificial radionuclides (²³⁸Pu,^239+240Pu,²⁴¹Am,¹³⁷Cs,⁹⁰Sr and³H) from the atmosphere to the Ross Ice Shelf in Antarctica were determined from measurements in strata dated by²¹⁰Pb. Recognizable sources include the U.S. tests (Mike-Ivy and Castle Hill) in the early 1950s, the U.S.S.R. tests of the early 1960s, the SNAP-9A burnup of 1964 and the French and Chinese tests in the late 1960s and 1970s. There are several problems still awaiting resolution: the differences in atmospheric chemistries of fission products and of transuranics produced in weapons tests and the anomalous fluxes of²³⁸Pu to the ice shelf which do not appear to reflect a one-year stratospheric residence. There is no evidence for a smearing of the fallout record as a consequence of diffusion of these radionuclides in the glacial column.     

TOPICS ON SEISMIC RESEARCH AT THE MONACO OCEANOGRAPHIC MUSEUM *

The author comments the techniques and methods used in continuous seismic profiling by the Monaco Oceanographic Museum during the last five years. Pinger probe give informations on the Mud layering and thickness. On the shelf or in abyssal plains, boomer and sparker are employed and allow to rise various geological conclusions. South coast of France, continental shelf in the Gulf of Lion, abyssal plain of the Ligurian Sea and Lake of Geneva are the areas concerned to with the results.     

241Pu and241Am in sediments from coastal basins off California and Mexico

In sediments deposited in the coastal basins off the western North American continent since the early 1960's, there is more²⁴¹Am activity than one would predict if its presence was solely due to the decay of²⁴¹Pu that was produced during the testing of weapons in 1961–1962 (taken as July 1, 1962 for calculations). This excess can be accounted for by the decay of²⁴¹Pu, if pre-1962 fallout (fallout from the pre-moratorium testing) has been continuously introduced into the recent sediments along with fallout from post-moratorium testing. This hypothesis is supported by the plutonium depth profiles which do not reflect direct fallout from the atmosphere, as characterized by two peaks corresponding to the two major weapons testing periods, but continuously increasing plutonium and americium concentrations from 1954 to 1974. Thus, the nuclides may be coming from a large reservoir that has accumulated and mixed fallout since 1952. Such a concentration gradient for all of the nuclides requires their immobilization in the sediment after deposition.     

Beryllium-10 in continental sediments

The concentration of¹⁰Be has been measured in 10 samples taken from a transect of surface sediments beginning in the Atchafalaya River and extending across the Bay 136 km into the Gulf of Mexico. If corrected for a lower retentivity of sand for Be, they have a concentration that is constant within 13%. This concentration is about an order of magnitude smaller than that of deep ocean sediments. For comparison, measurements of¹⁰Be in rainwater, in a sample of soil and in a deep ocean core were made.     

Trace metals and radium in the Gulf of Mexico: An evaluation of river and continental shelf sources

Several studies have provided evidence for the enrichment of trace elements in coastal waters, particularly for copper. These enrichments have been attributed to diffusion from continental shelf sediments and to an influx of river water. We attempted to resolve between these sources by undertaking an extensive suite of measurements of trace metals (Cu, Ni, Cd), ²²⁶Ra and ²²⁸Ra in the surface waters of the Gulf of Mexico, along with trace metal profiles at 6 stations (April 1981 and December 1982). These data establish that enrichments of copper, nickel and cadmium occur in the shallow waters of the Gulf of Mexico. On the Mississippi continental shelf, high trace element concentrations (Cu, Ni: ～ 9 nmol/kg; Cd: ～ 200 pmol/kg) in lower-salinity waters (26‰) are similar to those observed in the Mississippi plume at the same salinity. This evidence suggests a river water source. On the other hand, trace element enrichments are also observed in the northern Gulf (Cu: +0.4 nmol/kg; Ni: +0.5 nmol/kg; Cd: +20 pmol/kg) which coincide with an increase in ²²⁸Ra but are not accompanied by decreased salinity. The excess of evaporation over precipitation in this region makes it possible that this water could be evaporated estuarine water; therefore, hydrographic observations cannot distinguish readily between river and shelf sources. A regional flux balance shows that most of the excess copper in the surface waters of the Florida Current can be supplied by the river-borne dissolved copper flux. Within the uncertainties of such calculations, the continental shelf copper flux must be less than or equal to the river flux.     

Sedimentary indicators of water movement in the western approaches to the English Channel

The continental shelf to the southwest of the British Isles is an area of intense tidal current activity. Although most of the sediment is coarse, it still contains a small proportion of fine (<63 μm) material, consisting mainly of biogenic debris. Coccoliths in particular are both common and widespread and they are found in the adjacent slope sediments. The results presented here show that coccolithophorid diversity is high in the deeper parts of Whittard Canyon, the abyssal plain, and on a small area of shelf. Diversity decreases away from the ocean towards the land. Coccoliths and coccospheres have also been recorded from surface water samples. Apart from the landward movement of oceanic water shown by the coccolithophorids, movement of material on the bottom from shelf to slope is shown by the distribution of benthic diatom frustules and mollusc shell chips cut by clionid sponges. Thus, a study of the fine sediment reveals details of sediment transport and water movement.     

Measurement of iodine-129 in seawater samples collected from the Japan Sea area using accelerator mass spectrometry: Contribution of nuclear fuel reprocessing plants

The concentrations of ¹²⁹I in seawater samples from two sites (off Sekine and the Toyama Bay) in the Japan Sea were determined by accelerator mass spectrometry. The observed concentrations exceed amounts expected from natural origin and globally distributed fallout due to nuclear weapons testing. Because the fraction of natural origin and global fallout is 2% and 8.9–13.8%, respectively, the residual more than 80% of the concentration must come primarily from nuclear fuel reprocessing plants. This result indicates a rapid distribution of ¹²⁹I through atmospheric transport on a global scale. The depth distribution of ¹²⁹I at the Toyama Bay in the Japan Sea shows that the ¹²⁹I maximum is in the mixed layer and that concentrations decrease with depth. The inventory of ¹²⁹I in water column is four times higher than that measured in the Gulf of Mexico which has almost the same depth at the Toyama Bay. This higher inventory probably reflects: (1) the rapid water sinking in the Japan Sea, (2) the difference of distance in sampling locations with respect to major ¹²⁹I releasing plants and (3) the strong increase in emissions from nuclear fuel reprocessing plants after the profile of the Gulf of Mexico was taken.     

Anthropogenic "Litter" and macrophyte detritus in the deep Northern Gulf of Mexico

A deep-sea trawl survey of the Northern Gulf of Mexico has documented the abundance and diversity of human-generated litter and natural detrital plant material, from the outer margin of the continental shelf out to the Sigsbee abyssal plain. Plastics were the most frequently encountered type of material. Litter and debris were encountered more frequently in the eastern than in the western GoM. Land-derived plant material was located primarily within the head of the Mississippi Canyon, whereas ocean-derived plant material was spread evenly throughout the NE GoM. Human discards were principally from ships offshore. Some of the material was contained in metal cans that sank to the sea floor, probably in order to conform to international agreements that prohibit disposal of toxic material and plastics. The Mississippi Canyon was a focal point for litter, perhaps due to topography, currents or proximity to shipping lanes.     

The 1982 eruptions of El Chichon volcano,Mexico (2): Observations and numerical modelling of tephra-fall distribution

Tephra fallout from the A-1 (March 29, 0532 UT), B (April 4, 0135 UT), and C (April 4, 1122 UT) 1982 explosive eruptions of El Chichon produced three tephra fall deposits over southeastern Mexico. Bidirectional spreading of eruption plumes, as documented by satellite images, was due to a combination of tropospheric and stratospheric transport, with heaviest deposition of tephra from the ENE tropospheric lobes. Maximum column heights for the eruptions of 27, 32, and 29 km, respectively, have been determined by comparing maximum lithic-clast dispersal in the deposits with predicted lithic isopleths based on a theoretical model of pyroclast fallout from eruption columns. These column heights suggest peak mass eruption rates of 1.1 × 10⁸, 1.9 × 10⁸, and 1.3 × 10⁸ kg/s. Maximum column heights and mass eruption rates occured early in each event based on the normal size grading of the fall deposits. Sequential satellite images of plume transport and the production of a large stratospheric aerosol plume indicate that the eruption columns were sustained at stratospheric altitudes for a significant portion of their duration. New estimates of tephra fall volume based on integration of isopach area and thickness yield a total volume of 2.19 km³ (1.09 km³ DRE, dense rock equivalent) or roughly twice the amount of the deposit mapped on the ground. Up to one-half of the erupted mass was therefore deposited elsewhere as highly dispersed tephra.     

241Pu/239+240Pu ratios in polar glaciers

The analyses of plutonium isotopes in dated strata of polar ice sheets indicate that the²⁴¹Pu/^239+240Pu activity ratio produced in the U.S.-dominated nuclear tests during the 1950s was about 26, while that in the U.S.S.R.-dominated weapons tests in the early 1960s was between 12 and 14. This difference provides time horizons for sedimentary deposits. Further, the²³⁹Pu/²⁴⁰Pu ratio may show a similar difference in fallout values from these two periods of weapons testing and may provide an additional, and perhaps more sensitive, chronology for sediments.     

Sediment deformation and plate tectonics in the Gulf of Oman

The continental margin off the Makran coast of Iran and Pakistan is an excellent example of active deformation of sediments at a compressive plate boundary. Seismic reflection profiles across the margin suggest that relatively flat-lying sediments from the Oman abyssal plain are being scraped off the Arabian plate and accreted onto the Eurasian plate in a series of tightly folded sediment ridges aligned parallel to the coast. The most active folding appears to be occurring in the southernmost of the ridges, where it has formed a frontal fold up to 750 m high, with a width of 3–4 km. Filling of the basins between the ridges with later sediment becomes progressively more complete towards the north, and produces a smooth continental shelf near the coast, where the ridges are completely buried by sediment. Evidence for the possible presence of northward-dipping thrust faults which uplift the ridges towards the coast is seen in the consistent back-tilting of the sediments in the inter-fold basins.Below the abyssal plain to the south of the folded zone the sediments are divided by a prominent reflector, horizon A, into an upper group of flat-lying beds that overlie strata which dip gently to the north. A sharp velocity increase occurs across this horizon. The deepest observable reflector, horizon B, is seen as a series of diffraction hyperbolae which dip conformably northwards at about 1°. Velocity determinations from refraction and variable-angle reflection stations over the abyssal plain indicate a thick pile of low-velocity material which is probably sediment lying above horizon B. The material directly below horizon B has a velocity of 4.5 ± 0.2km/s and is probably volcanic in origin.     

Variability of natural and bomb-produced radionuclide distributions in abyssal red clay sediments

The nature of sedimentation and mixing are examined in abyssal red clay sediments from the North Central Pacific using three types of indicators: ²³⁰Th/²³²Th, organic¹⁴C, and¹³⁷Cs and ^239.240Pu.²³⁰Th/²³²Th analysed revealed that the clay sedimentation rate in three box cores collected within a 50 km radius was less than 1.0 mm/10³ yr. However, analyses of the organic carbon in thin layers of sediment revealed that radiocarbon was present much deeper in the cores (down to 20 cm) than was expected from the ²³⁰Th/²³²Th distribution. In addition, both the stratigraphy and inventory of radiocarbon was significantly different between box cores. The distributions and inventories of¹³⁷Cs and^239.240Pu were similar to that found for radiocarbon, further illustrating the spatial variability of radionuclides in oligotrophic North Pacific red clays. These data suggest that bioturbational processes are important for transporting organic carbon down into the sediment column.     

Geochemical evidence for the origin of Late Triassic melange units in the Oman Mountains as a small ocean basin formed by continental rifting

A useful tool to elucidate past tectonic environments is the geochemistry of volcanic and sedimentary rocks when used together.The regional structural setting of the Oman Mountains indicates that deep-water sediments and volcanic rocks formed adjacent to the rifted Arabian margin in the Late Triassic near the axis of a narrow ocean basin of Red Sea-type. Tholeiitic to trachytic extrusives formed seamounts associated with Late Triassic reefal build-ups. “Immobile” trace element compositions point to a within-plate origin. The interbedded and overlying Late Triassic deep-sea sedimentary cover comprises ribbon radiolarites and both distal siliclastic and calcareous turbidites that accumulated on an abyssal plain at least ca. 180 km northeast of the Arabian continent. Associated ferromanganiferous oxide-sediments are interpreted as chemical precipitates derived from high-temperature vents in the spreading axis of the young ocean basin. Pervasive regional subsidence took place during end Triassic/Early Jurassic time.Later, in the Cretaceous, oceanic crust was consumed in a northeast-dipping subduction zone. MORB-type crust was subducted while Late Triassic volcanic edifices and sedimentary cover were accreted. During eventual trench-margin collision the Semail ophiolite split into blocks allowing sub-ophiolite melange rocks to be expelled upwards through corridors, creating the Batinah Melange. As the ophiolite nappe ploughed inboard over already thrust-assembled abyssal plain sediments (Hawasina Complex), some duplexes were uplifted, oversteepened, overturned and then slid backwards onto the ophiolite to form the Batinah Sheets.     

Impact of GODAE products on nested HYCOM simulations of the West Florida Shelf

Nested non-assimilative simulations of the West Florida Shelf for 2004–2005 are used to quantify the impact of initial and boundary conditions provided by Global Ocean Data Assimilation Experiment ocean products. Simulations are nested within an optimum interpolation hindcast of the Atlantic Ocean, the initial test of the US Navy Coupled Ocean Data Assimilation system for the Gulf of Mexico, and a global ocean hindcast that used the latter assimilation system. These simulations are compared to one that is nested in a non-assimilative Gulf of Mexico model to document the importance of assimilation in the outer model. Simulations are evaluated by comparing model results to moored Acoustic Doppler Current Profiler measurements and moored sea surface temperature time series. The choice of outer model has little influence on simulated velocity fluctuations over the inner and middle shelf where fluctuations are dominated by the deterministic wind-driven response. Improvement is documented in the representation of alongshore flow variability over the outer shelf, driven in part by the intrusion of the Loop Current and associated cyclones at the shelf edge near the Dry Tortugas. This improvement was realized in the simulation nested in the global ocean hindcast, the only outer model choice that contained a realistic representation of Loop Current transport associated with basin-scale wind-driven gyre circulation and the Atlantic Meridional Overturning Circulation. For temperature, the non-assimilative outer model had a cold bias in the upper ocean that was substantially corrected in the data-assimilative outer models, leading to improved temperature representation in the simulations nested in the assimilative outer models.