Geophysical and Hydrochemical Identification of Flow Paths with Implications for Water Quality at an ARR Site

Two key challenges regarding the design and operation of aquifer recharge and recovery (ARR) systems are evaluating aquifer heterogeneity and understanding hydrochemical interactions. Uncertainty in this respect can impact the volume of recoverable water and the improvement in water quality. The objective of this research is to leverage the advantages of geophysical measurements and hydrochemical sampling to reveal the properties of an ARR site to inform current ARR system operations and future design decisions. Electrical resistivity tomography was used to image the subsurface below two key infiltration/extraction areas of an ARR site in Colorado, USA. Hydrochemical measurements on transects intersecting the geophysical measurements resolved bulk parameters (i.e., total organic carbon, nitrate, and major cations and anions) and trace organic chemicals (e.g., pharmaceuticals, personal care products). Conservative tracers were also used to estimate degrees of mixing and water travel times and to better assess the performance of the ARR site regarding water quality changes and water recovery. The electrical resistivity measurements suggest that certain areas of the infiltration basins have hydraulic connections to the extraction wells through preferential flow paths, compared with other infiltration basins that are separated by fine‐grained materials from their respective extraction wells. The hydrochemical results indicate that consistent improvements in water quality can be achieved in these preferential flow paths within relatively short travel times (<5 d) at this ARR site.     

Electromagnetic‐Induction Logging to Monitor Changing Chloride Concentrations

Water from the San Joaquin Delta, having chloride concentrations up to 3590 mg/L, has intruded fresh water aquifers underlying Stockton, California. Changes in chloride concentrations at depth within these aquifers were evaluated using sequential electromagnetic (EM) induction logs collected during 2004 through 2007 at seven multiple‐well sites as deep as 268 m. Sequential EM logging is useful for identifying changes in groundwater quality through polyvinyl chloride‐cased wells in intervals not screened by wells. These unscreened intervals represent more than 90% of the aquifer at the sites studied. Sequential EM logging suggested degrading groundwater quality in numerous thin intervals, typically between 1 and 7 m in thickness, especially in the northern part of the study area. Some of these intervals were unscreened by wells, and would not have been identified by traditional groundwater sample collection. Sequential logging also identified intervals with improving water quality—possibly due to groundwater management practices that have limited pumping and promoted artificial recharge. EM resistivity was correlated with chloride concentrations in sampled wells and in water from core material. Natural gamma log data were used to account for the effect of aquifer lithology on EM resistivity. Results of this study show that a sequential EM logging is useful for identifying and monitoring the movement of high‐chloride water, having lower salinities and chloride concentrations than sea water, in aquifer intervals not screened by wells, and that increases in chloride in water from wells in the area are consistent with high‐chloride water originating from the San Joaquin Delta rather than from the underlying saline aquifer.     

Aquifer Treatment of Sea Water to Remove Natural Organic Matter Before Desalination

An investigation of a sea water reverse osmosis desalination facility located in western Saudi Arabia has shown that aquifer treatment of the raw sea water provides a high degree of removal of natural organic matter (NOM) that causes membrane biofouling. The aquifer is a carbonate system that has a good hydraulic connection to the sea and 14 wells are used to induce sea water movement 400 to 450 m from the sea to the wells. During aquifer transport virtually all of the algae, over 90% of the bacteria, over 90% of the biopolymer fraction of NOM, and high percentages of the humic substance, building blocks, and some of the low molecular weight fractions of NOM are removed. Between 44 and over 90% of the transparent exopolymer particles (TEP) are removed with a corresponding significant reduction in concentration of the colloidal fraction of TEP. The removal rate for TEP appears to be greater in carbonate aquifers compared to siliciclastic systems. Although the production wells range in age from 4 months to 14 years, no significant difference in the degree of water treatment provided by the aquifer was found.     

Monitoring well interception with fractures in clayey till

When using monitoring wells for investigation of contaminant sources in clayey till, there is a high risk that fractures may cause mobile contaminants to bypass the monitoring wells. This paper indicates that the probability of interception between monitoring wells and hydraulic conductive fractures is often significantly less than 50%. Based on a field experiment and application of a calibrated discrete fracture matrix diffusion numerical model (FRAC3Dvs), the paper also evaluates pesticide-monitoring results for different positions of monitoring well screen relative to fractures. For well screens situated 0.25 and 2 m from a conductive fracture, the first concentrations of the pesticide metabolite (2,6 dichlorobenzamide, "BAM") would be measured two years and 18 years, respectively, after the contaminant had been transported into an underlying aquifer. In this way, underlying aquifers may be subjected to contamination by downward moving contamination without being observed in monitoring wells in the till.     

The unusual and large drawdown response of buried-valley aquifers to pumping

The buried-valley aquifers that are common in the glacial deposits of the northern hemisphere are a typical case of the strip aquifers that occur in many parts of the world. Pumping from a narrow strip aquifer leads to much greater drawdown and much more distant drawdown effects then would occur in a sheet aquifer with a similar transmissivity and storage coefficient. Widely used theories for radial flow to wells, such as the Theis equation, are not appropriate for narrow strip aquifers. Previously published theory for flow to wells in semiconfined strip aquifers is reviewed and a practical format of the type curves for pumping-test analysis is described. The drawdown response of strip aquifers to pumping tests is distinctive, especially for observation wells near the pumped well. A case study is presented, based on extensive pumping test experience for the Estevan Valley Aquifer in southern Saskatchewan, Canada. Evaluation of groundwater resources in such buried-valley aquifers needs to take into account the unusually large drawdowns in response to pumping.     

Long-Term Ground Water Quality Impacts from the Use of Hexazinone for the Commercial Production of Lowbush Blueberries

Lowbush blueberries, native to eastern Canada and Maine, are an important economic crop in these areas. Herbicides containing the active ingredient hexazinone are commonly applied to blueberry fields, and there is a high frequency of detection of relatively low concentrations of hexazinone in domestic wells located close to areas of lowbush blueberry production. The objective of this study was to determine the long-term impacts from hexazinone-based herbicide use on ground water quality in the immediate growing areas.
Physical and chemical hydrogeologic data were collected for an outwash sand and gravel aquifer in southwestern New Brunswick, Canada. The majority of the land overlying the aquifer is devoted to lowbush blueberry production. Twenty-one nested monitoring wells were sampled for hexazinone and hexazinone metabolites over a four-year period. Hexazinone was consistently detected at values of 1 to 8 parts per billion (ppb) in all but two of these wells, one that is upgradient of herbicide applications, and one that is downgradient with anoxic conditions. Hexazinone metabolites B and A1 were also detected in all but two of the 21 wells at values ranging from 0.5 to 2.5 ppb. The hexazinone and metabolite data suggest both aerobic and anaerobic degradation of hexazinone. Complete degradation of hexazinone appears to occur only in the one downgradient well exhibiting anoxic ground water conditions. Concentrations of hexazinone and its metabolites in the ground water were essentially constant over the four-year period.     

In Situ Vertical Circulation Column: Containment System for Small-Scale DNAPL Field Experiments

The in situ vertical circulation column (ISVCC) is a cylindrical containment system consisting of an instrumented steel cylinder used for experimental ground water studies in sandy aquifers. Vertical flow is imposed inside the ISVCC. Although vertical wells are an option, the ISVCC installed in the Borden Aquifer is instrumented with horizontal wells and monitoring ports to avoid creating vertical preferential flow paths. The cylinder was driven downward into the aquifer using a small backhoe equipped with a vibrating plate. The ISVCC penetrates the 2.3-m-thic sand aquifer and is keyed 20 cm into the underlying clay aquitard. The cylinder was installed inside a 2 m X 2 m steel sheet pile enclosure so that the enclosed segment of aquifer could be conveniently dewatered and then excavated to allow installation of the horizontal wells. The dispersivity of the column was comparable to literature values for long sand-packed laboratory columns.
Pure phase DNAPL (tetrachloroethene and 1,1,1-trichloroethane) was slowly pumped into two ports in the center of the column. Following this DNAPL injection, an aqueous solution of vitamin B₁₂ and reduced titanium was circulated through the column to promote degradation of the solvents. Processes observed in the ISVCC included DNAPL distribution, dissolution, and degradation, and geochemical evolution of the aquifer.
The ISVCC provides a convenient means for testing in situ technologies in the experimental stage or for selection of proven technologies to find the most effective at a specific site. It is inexpensive, easy to install, and maximizes control over flow distribution in a heterogeneous aquifer. Its application will be restricted where low hydraulic conductivity beds are present in the aquifer.     

Investigation of Possible Contamination of Shallow Ground Water by Deeply Injected Liquid Industrial Wastes

The objective of this study was to assess the possible impact of deep well disposal operations, conducted between 1958 and 1974, on the ground water quality in a shallow fresh water aquifer beneath Sarnia, Ontario, Canada. Because of the breakout of formation fluids in Sarnia and Port Huron, Michigan, in the early 1970s, it had been hypothesized that liquid waste from the disposal zone in bedrock had leaked through numerous abandoned oil, gas, and salt wells in the area up to the shallow fresh water aquifer and from there to the surface.
A monitoring well network of 29 5cm (2 inch) diameter piezometers was established in the thin sand and shale aquifer system, which exists between 30 and 70m (100 and 230 feet) below ground surface. In addition, a 300m (1000 foot) deep borehole was drilled and instrumented with a Westbay multilevel casing, which permitted sampling of the disposal zone.
Ground water samples from the shallow monitoring wells and the Westbay multilevel casing were analyzed for volatiles by GC/MS. Those volatile aromatics that were conspicuously present in the deep disposal zone, e.g., ethyl toluenes and trimethyl benzene, were not detected in the shallow monitoring wells. Thus, if contaminants from the disposal zone did indeed migrate to the shallow aquifer, contamination was not widespread and probably consisted mostly of displaced chloride-rich formation waters.     

Analysis of steady ground water flow toward wells in a confined-unconfined aquifer

A confined aquifer may become unconfined near the pumping wells when the water level falls below the confining unit in the case where the pumping rate is great and the excess hydraulic head over the top of the aquifer is small. Girinskii's potential function is applied to analyze the steady ground water flow induced by pumping wells with a constant-head boundary in a mixed confined-unconfined aquifer. The solution of the single-well problem is derived, and the critical radial distance at which the flow changes from confined to unconfined condition is obtained. Using image wells and the superposition method, an analytic solution is presented to study steady ground water flow induced by a group of pumping wells in an aquifer bounded by a river with constant head. A dimensionless function is introduced to determine whether a water table condition exists or not near the pumping wells. An example with three pumping wells is used to demonstrate the patterns of potentiometric surface and development of water table around the wells.     

Groundwater level responses in temperate mountainous terrain: regime classification,and linkages to climate and streamflow

Groundwater responses in temperate mountainous terrain are assessed using groundwater, hydrometric and climatic data from southern British Columbia, Canada. Well and stream hydrographs are analysed using a series of diagnostic tools including time series plots, hysteresis plots, and cross‐correlation plots. Characterizing the seasonal timing of the response requires consideration of the hydroclimatology of the region: rainfall‐dominated (pluvial), snowmelt‐dominated (nival) or hybrid (mixture of rain and snow). The magnitude and timing of the recharge and discharge response of the groundwater system was shown to depend on the storage and permeability characteristics of the aquifer and whether the system is stream‐driven or recharge‐driven. These two dominant stream‐aquifer system types were defined based on classifying different aquifer types found in the southwest portion of the province. The classification scheme and diagnostic tools have the potential to provide a framework for evaluating the responses of wells in other mountainous regions. Using this framework, the potential consequences of future climate change may then be better understood based on the interactions between the hydrogeological and hydroclimatic settings of these aquifers. Copyright © 2010 Her Majesty the Queen in right of Canada. Published by John Wiley & Sons. Ltd     

Management of the Wellfield Contaminated by Dense Chlorinated Hydrocarbons in Vilnius,Lithuania

Drinking water supply in Lithuania is entirely based on groundwater. Wellfields of Vilnius develop intermorainic ca. 50 m deep (in average) aquifer which is locally contaminated by chlorinated hydrocarbons— volatile organic compounds (VOCs). Groundwater abstraction activates VOCs migration from an abandoned factory into the pumping wells of one wellfield named “Vingis.” However monitoring data testify that only traces of VOCs were detected on the territory of this factory. Subsequent studies revealed the “secret”: dense VOCs have migrated from the territory of the polluter and have accumulated in lowermost places of pumped aquifer inside the wellfield. An attempt to ensure low concentration of VOCs in pumped water manipulating by pumping rates of more or less contaminated abstraction wells was not effective. Finally, an acceptable concentration of VOCs in supplied drinking water was ensured by permanent pumping out of the most polluted groundwater from some abstraction wells of the wellfield and diverting this water to the Neris River.     

Identifying Aquifer Type in Fractured Rock Aquifers using Harmonic Analysis

Determining aquifer type, unconfined, semi‐confined, or confined, by drilling or performing pumping tests has inherent problems (i.e., cost and complex field issues) while sometimes yielding inconclusive results. An improved method to cost‐effectively determine aquifer type would be beneficial for hydraulic mapping of complex aquifer systems like fractured rock aquifers. Earth tides are known to influence water levels in wells penetrating confined aquifers or unconfined thick, low‐porosity aquifers. Water‐level fluctuations in wells tapping confined and unconfined aquifers are also influenced by changes in barometric pressure. Harmonic analyses of water‐level fluctuations of a thick (～1000 m) carbonate aquifer located in south‐central Oklahoma (Arbuckle‐Simpson aquifer) were utilized in nine wells to identify aquifer type by evaluating the influence of earth tides and barometric‐pressure variations using signal identification. On the basis of the results, portions of the aquifer responded hydraulically as each type of aquifer even though there was no significant variation in lithostratigraphy. The aquifer type was depth dependent with confined conditions becoming more prevalent with depth. The results demonstrate that harmonic analysis is an accurate and low‐cost method to determine aquifer type.     

Field verification of stable perched groundwater in layered bedrock uplands

Data substantiating perched conditions in layered bedrock uplands are rare and have not been widely reported. Field observations in layered sedimentary bedrock in southwestern Wisconsin, USA, provide evidence of a stable, laterally extensive perched aquifer. Data from a densely instrumented field site show a perched aquifer in shallow dolomite, underlain by a shale-and-dolomite aquitard approximately 25 m thick, which is in turn underlain by sandstone containing a 30-m-thick unsaturated zone above a regional aquifer. Heads in water supply wells indicate that perched conditions extend at least several kilometers into hillsides, which is consistent with published modeling studies. Observations of unsaturated conditions in the sandstone over a 4-year period, historical development of the perched aquifer, and perennial flow from upland springs emanating from the shallow dolomite suggest that perched groundwater is a stable hydrogeologic feature under current climate conditions. Water-table hydrographs exhibit apparent differences in the amount and timing of recharge to the perched and regional flow systems; steep hydraulic gradients and tritium and chloride concentrations suggest there is limited hydraulic connection between the two. Recognition and characterization of perched flow systems have practical importance because their groundwater flow and transport pathways may differ significantly from those in underlying flow systems. Construction of multi-aquifer wells and groundwater withdrawal in perched systems can further alter such pathways.     

Characterization of a multilayer aquifer using open well dilution tests

An approach to characterization of multilayer aquifer systems using open well borehole dilution is described. The approach involves measuring observation well flow velocities while a nearby extraction well is pumped by introducing a saline tracer into observation wells and collecting dilution vs. depth profiles. Inspection of tracer profile evolution allows discrete permeable layers within the aquifer to be identified. Dilution profiles for well sections between permeable layers are then converted into vertical borehole flow velocities and their evolution, using an analytic solution to the advection-dispersion equation applied to borehole flow. The dilution approach is potentially able to measure much smaller flow velocities that would be detectable using flowmeters. Vertical flow velocity data from the observation wells are then matched to those generated using a hydraulic model of the aquifer system, "shorted" by the observation wells, to yield the hydraulic properties of the constituent layers. Observation well flow monitoring of pumping tests represents a cost-effective alternative or preliminary approach to pump testing each layer of a multilayer aquifer system separately using straddle packers or screened wells and requires no prior knowledge of permeable layer depths and thicknesses. The modification described here, of using tracer dilution rather than flowmeter logging to obtain well flow velocities, allows the approach to be extended to greater well separations, thus characterizing a larger volume of the aquifer. An example of the application of this approach to a multilayer Chalk Aquifer in Yorkshire, Northeast England, is presented.     

Comparison of Stainless Steel vs. PTFE Miniwells for Monitoring Halogenated Organic Solute Transport

Field tests of organic solute transport behavior have often been monitored using small-diameter wells (miniwells). To determine if experimental results could be significantly biased by sorption to, desorption from, or diffusion through sampling lines, dissolved concentrations of tetrachloroethene and carbon tetrachloride were measured in ground water samples collected simultaneously from the same spatial location during a forced-gradient test in the Borden aquifer using polytetrafluoroethene (PTFE) and stainless steel miniwells (1/8-inch O.D.).
A semiautomated organic analytical system was used on-site to obtain real-time results, which avoided sample holding problems and permitted optimizing sampling times. The breakthrough curves (plots of concentration vs. time) for both organic compounds indicate that under the conditions of this experiment (low organic solute concentrations, short exposure time of sampling lines to the plume, adequate flushing of sampling lines) there is no significant difference between concentration histories (breakthrough curves) collected using a polytetrafluoroethene sampling line and those collected using a stainless steel sampling line. This suggests that organic solute tailing seen in this and also in a similar transport experiment previously conducted at the site is the result of transport processes in the aquifer rather than an artifact introduced by the PTFE miniwells.     

Predicting average annual groundwater levels from climatic variables: an empirical model

On the basis of one-dimensional theoretical water flow model, we demonstrate that the groundwater level variation follows a pattern similar to recharge fluctuation, with a time delay that depends on the characteristics of aquifer, recharge pattern as well as the distance between the recharge and observation locations. On the basis of a water budget model and the groundwater flow model, we propose an empirical model that links climatic variables to groundwater level. The empirical model is tested using a partial data set from historical records of water levels from more than 80 wells in a monitoring network for the carbonate rock aquifer, southern Manitoba, Canada. The testing results show that the predicted groundwater levels are very close to the observed ones in most cases. The overall average correlation coefficient between the predicted and observed water levels is 0.92. This proposed empirical statistical model could be used to predict variations in groundwater level in response to different climate scenarios in a climate change impact assessment.     

The Optimal Spacing of Interfering Wells: An Analytic Solution

An exact expression is derived for the optimal spacing between interfering wells in a rectangular well field in an ideal confined aquifer. A simple, practical method for determining the optimal spacing is presented. The optimal spacing is shown to be substantially different from the spacing determined by use of the Theis formulation. The economic savings resulting from use of the revised approach are evaluated and found to be considerable, especially when the number of wells is large and the transmissivity of the aquifer low.     

Information effect on remediation design of contaminated aquifers using the pump and treat method

We examine the effect of uncertainty due to limited information on the remediation design of a contaminated aquifer using the pump and treat method. The hydraulic conductivity and contaminant concentration distributions for a fictitious contaminated aquifer are generated assuming a limited number of sampling locations. Stochastic optimization with multiple realizations is used to account for aquifer uncertainty. The optimization process involves a genetic algorithm (GA). As the number of realizations increases, a greater extraction rate and more wells are needed. There was a total cost increase, but the optimal remediation designs became more reliable. Stochastic optimization analysis also determines the locations for extraction wells, the variation in extraction rates as a function of the change of well locations, and the reliability of the optimal designs. The number of realizations (stack number) that caused the design factors to converge could be determined. Effective stochastic optimization may be achieved by reducing computational resources. An increase in the variability of the conductivity distribution requires more extraction wells. Information about potential extraction wells can be used to prevent failure of the remediation task.     

Effects of Improper Characterization of Aquifer Thickness on Estimates of Hydraulic Conductivity from Pumping Tests

Pumping test data for surficial aquifers are commonly analyzed under the assumption that the base of the aquifer corresponds to the bottom of the test wells (i.e., the aquifer is truncated). This practice can lead to inaccurate hydraulic conductivity estimates, resulting from the use of low saturated thickness values with transmissivity estimates, and not accounting for the effects of partially penetrating wells. Theoretical time-drawdown data were generated at an observation well in a hypothetical unconfined aquifer for various values of saturated thickness and were analyzed by standard curve-matching techniques. The base of the aquifer was assumed to be the bottom of the pumping and observation wells. The overestimation of horizontal hydraulic conductivity was found to be directly proportional to the error in assumed saturated thickness, and to the (actual) ratio of vertical to horizontal hydraulic conductivity (K_v/K_h). Inaccurately high estimates of hydraulic conductivity obtained by aquifer truncation can lead to overestimates of ground water velocity and contaminant plume spreading, narrow capture zone configuration estimates, and overestimates of available ground water resources.     

Monitoring of drawdown pattern during pumping in an unconfined physical aquifer model

In this study, we attempted to analyse a drawdown pattern around a pumping well in an unconfined sandy gravelly aquifer constructed in a laboratory tank by means of both experimental and numerical modelling of groundwater flow. The physical model consisted of recharge, aquifer and discharge zones. Permeability and specific yield of the aquifer material were determined by Dupuit approximation under steady‐state flow and stepwise gravitational drainage of groundwater, respectively. The drawdown of water table in pumping and neighbouring observation wells was monitored to investigate the effect of no‐flow boundary on the drawdown pattern during pumping for three different boundary conditions: (i) no recharge and no discharge with four no‐flow boundaries (Case 1); (ii) no recharge and reservoir with three no‐flow boundaries (Case 2); (iii) recharge and discharge with two no‐flow boundaries (Case 3). Based on the aquifer parameters, numerical modelling was also performed to compare the simulated drawdown with that observed. Results showed that a large difference existed between the simulated drawdown and that observed in wells for all cases. The reason for the difference could be explained by the formation of a curvilinear type water table between wells rather than a linear one due to a delayed response of water table in the capillary fringe. This phenomenon was also investigated from a mass balance study on the pumping volume. The curvilinear type of water table was further evidenced by measurement of water contents at several positions in the aquifer between wells using time domain reflectometry (TDR). This indicates that the existing groundwater flow model applicable to an unconfined aquifer lacks the capacity to describe a slow response of water table in the aquifer and care should be taken in the interpretation of water table formation in the aquifer during pumping. Copyright © 2001 John Wiley & Sons, Ltd.