MgO-SiO_2-Cr-O体系的亚固相相关系及有关含Cr~(2+)端员矿物的热力学特征

在t=1100-1500℃和P=0-2.88GPa条件下,实验确定了与金属Cr平衡的SiO_2-Cr-O及MgO-SiO_2-Cr-O体系中的亚固相相关系。结果显示,在SiO_2-Cr-O体系中,只发现绿铬矿-金属铬-石英(或鳞石英)组合;而在含MgO体系中,出现Mg-Cr~(2+)橄榄石、辉石及尖晶石固溶体。Cr~(3+)在橄榄石和辉石中的含量在可测定限度之下。当X_(Cr~(2+))=[Cr~(2+)/(Mg+Cr~(2+))]>0.2时,辉石的结构由斜方晶系转为单斜晶系;尖晶石的结构由立方变为四方。对实验数据进行热力学模拟,求得Mg-Cr~(2+)在橄榄石,辉石及尖晶石固溶体中的混合参数(W),以及铬橄榄石(Cr_2SiO_4)、铬辉石(Cr_2Si_2O_6)和铬尖晶石(Cr_3O_4)的形成自由能(△G°)与温度的关系。     

钠长花岗岩—H2O—HF体系相关系及含黄玉花岗质岩石的成因

在Ｐ＝１００ＭＰａ,ｔ＝８４０－４５０℃条件下,通过钠长花岗岩Ｈ２Ｏ－ＨＦ体系相关系实验获得;（１）随体系Ｆ含量的增加,固相线温度显著下降。（２）石英和黄玉的温度稳定域上限升高,碱性长石的稳定域上限降低;在Ｆ≤４％时,体系能在固线性之上结晶出典型的黄玉花岗岩矿物组合;在Ｆ＝６％时,体系能在固相线之上结晶出典型的黄玉云英矿物组合;（２）含氟浅色花岗质熔体具有能分异出极端富Ｆ残余熔体的趋势。     

Subsolidus Phase Relations in the System MgO--SiO2--Gr--O in Equilibrium with Metallic Cr, and their Significance for the Petrochemistry of Chromium

Subsolidus phase relations have been determined in the systemsSiO₂-Cr-0 and MgO-SiO₂-Cr-O in equilibrium with metallic Cr,at 1100–1500C and 0–288 kbar. There are no ternaryphases in the SiO₂-Cr-O system at these conditions, ie. onlythe assemblage eskolaite + Cr-metal + SiO₂ is found. However,in the MgO-containing system, extensive substitution of Cr²⁺for Mg is observed in (Mg,Cr²⁺)₂SiO₄ olivine, (Mg,Cr²⁺)₂Si₂O₆pyroxene, and (Mg,Cr²⁺)Cr³⁺₂0₄ spinel. Cr ³⁺ levels in olivineand pyroxene are below detection limits. The pyroxene is orthorhombicat monoclinic at higher . The structure of the spinels becomestetragonally distorted at is limited by the breakdown of olivine to pyroxene + spinel+ metal. This maximum amount increases strongly with increasingtemperature, reaching >0.2 at 1500C and 48 kbar. Increasing pressure reduces the maximum. Increasing temperature also increases the maximum amounts of Cr²⁺ which substitute intopyroxene and spinel, indicating that end-member Cr₂Si₂0₆ andCr₃O₄ may become stable above 1650C if melting does not intervene.Powder X-ray diffraction analysis of selected runs has beenused to extract molar volumes of the Mg-Cr²⁺ solid solutionsas a function of composition, which may be extrapolated to predictmolar volumes for Cr₂SiO₄ (olivine), Cr₂Si₂O₆ (ortho- and clino-pyroxene)and Cr₂O₄ (cubic spinel) of 477, 680 and 449 cm³, respectively.The experimental data have been fitted to a thermodynamic model,including free energies of formation for end member Cr₂SiO₄,Cr₂Si₂O₆ and Cr₃O₄. This model is then used to predict the amountsof Cr²⁺ which can be expected in olivine in equilibrium withCr-bearing spinel as a function of T, P and fo₂. This amountincreases strongly with temperature along standard T-fo₂ buffercurves, and is sufficient to explain the observed high Cr contentsof olivine from komatiites and diamond inclusions at reasonableterrestrial fo, values. The lower fo₂ of the lunar environmentresults in significant Cr²⁺ in olivine being stable to muchlower temperatures. The tendency for the oxidation state ofCr, and hence its geochemical properties, to change with temperaturerelative to other redox reactions makes it a potentially usefulmonitor of the temperatures of uppermantle processes, and isa significant factor in the differing styles of igneous differentiationin the Earth and Moon. Corresponding author     

An enlarged and updated internally consistent thermodynamic dataset with uncertainties and correlations: the system K2O–Na2O–CaO–MgO–MnO–FeO–Fe2O3–Al2O3–TiO2–SiO2–C–H2–O2

We present, as a progress report, a revised and much enlarged version of the thermodynamic dataset given earlier (Holland & Powell, 1985). This new set includes data for 123 mineral and fluid end-members made consistent with over 200 P–T–X_CO2–f_O2 phase equilibrium experiments. Several improvements and advances have been made, in addition to the increased coverage of mineral phases: the data are now presented in three groups ranked according to reliability; a large number of iron-bearing phases has been included through experimental and, in some cases, natural Fe:Mg partitioning data; H₂O and CO₂ contents of cordierites are accounted for with the solution model of Kurepin (1985); simple Landau theory is used to model lambda anomalies in heat capacity and the Al/Si order–disorder behaviour in some silicates, and Tschermak-substituted end-members have been derived for iron and magnesium end-members of chlorite, talc, muscovite, biotite, pyroxene and amphibole. For the subset of data which overlap those of Berman (1988), it is encouraging to find both (1) very substantial agreement between the two sets of thermodynamic data and (2) that the two sets reproduce the phase equilibrium experimental brackets to a very similar degree of accuracy. The main differences in the two datasets involve size (123 as compared to 67 end-members), the methods used in data reduction (least squares as compared to linear programming), and the provision for estimation of uncertainties with this dataset. For calculations on mineral assemblages in rocks, we aim to maximize the information available from the dataset, by combining the equilibria from all the reactions which can be written between the end-members in the minerals. For phase diagram calculations, we calculate the compositions of complex solid solutions (together with P and T) involved in invariant, univariant and divariant assemblages. Moreover we strongly believe in attempting to assess the probable uncertainties in calculated equilibria and hence provide a framework for performing simple error propagation in all calculations in thermocalc, the computer program we offer for an effective use of the dataset and the calculation methods we advocate.     

Stable Phase Equilibrium of the Aqueous Ternary System Li~+//Cl~-,borate- H_2O at 348 K

正The Sichuan Basin,with an area of about 20×104 km2,is situated at 102.5°~110°E and 27.67°~32.67°N.The underground brine resources in Sichuan basin are a type of comprehensive liquid mineral resource.Pingluo     

Calculated Phase Relations in High-Pressure Metapelites in the System NKFMASH (Na2O-K2O-FeO-MgO-Al2O3-SiO2-H2O)

Using an internally consistent thermodynamic dataset and updatedmodels of activity–composition relation for solid solutions,petrogenetic grids in the system NKFMASH (Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O)and the subsystems NKMASH and NKFASH have been calculated withthe software THERMOCALC 3.1 in the P–T range 5–36kbar and 400–810°C, involving garnet, chloritoid,biotite, carpholite, talc, chlorite, kyanite/sillimanite, staurolite,phengite, paragonite, albite, glaucophane, jadeite, with quartz/coesiteand H₂O in excess. These grids, together with calculated AFMcompatibility diagrams and P–T pseudosections, are shownto be powerful tools for delineating the phase equilibria andP–T conditions of Na-bearing pelitic assemblages for avariety of bulk compositions from high-P terranes around theworld. These calculated equilibria are in good agreement withpetrological studies. Moreover, contours of the calculated phengiteSi isopleths in P–T pseudosections for different bulkcompositions confirm that phengite barometry is highly dependenton mineral assemblage. KEY WORDS: phase relations; HP metapelite; NKFMASH; THERMOCALC; phengite geobarometry     

Calculated Phase Relations in the System NCKFMASH (Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O) for High-Pressure Metapelites

Petrogenetic grids in the system NCKFMASH (Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the P–T range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H₂O in excess. These grids, together with calculated compatibilitydiagrams and P–T and T–X_Ca and P–X_Ca pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different P–T conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and P–Tconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in P–T and P–X_Capseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry     

Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions

正1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is     

Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists

Pressure–temperature grids in the system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O and its subsystems have been calculatedin the range 15–45 kbar and 550–900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressure–temperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H₂O-carriersin subducting slabs. Depending on bulk composition and pressure–temperaturepath, amphibole may or may not be a major H₂O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H₂O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists     

Phase Equilibria in the Ternary Systems KBr–K2B4O7–H2O and KCl–K2B4O7–H2O at 373 K

According to the compositions of the underground gasfield brines in the west of Sichuan Basin,the phase equilibria in the ternary systems KBr-K2B4O7-H2O and KCl-K2B4O7-H2O at 373 K were studied using the isothermal dissolution equilibrium method.The solubilities of salts and the densities of saturated solutions in these ternary systems were determined.Using the experimental data,phase diagrams and density-composition diagrams were constructed.The two phase diagrams were simple co-saturation type,each having an invariant point,two univariant curves and two crystallization regions.The equilibrium solid phases in the ternary system KBr-K2B4O7-H2O are potassium bromide （KBr） and potassium tetraborate tetrahydrate （K2B4O7·4H2O）,and those in the ternary system KCl-K2B4O7-H2O are potassium chloride （KCl） and potassium tetraborate tetrahydrate （K2B4O7·4H2O）.Comparisons of the phase diagrams of the two systems at different temperatures show that there is no change in the crystallization phases,but there are changes in the size of the crystallization regions.As temperature increases,the solubility of K2B4O7·4H2O increases rapidly,so the crystallization field of K2B4O7·4H2O becomes smaller.     

新疆阿尔泰造山带低压变质作用相平衡研究

通过对阿尔泰造山带低压型变质序列中典型泥质岩石进行详细的岩相学及相平衡研究,获得黑云母带变质作用的温度为445～550℃和压力为0.2～0.6 GPa;石榴石带为480～566℃、0.54±0.22 GPa;十字石带601±20℃、0.8±0.25GPa;十字石-红柱石带540±20℃、0.32±0.05 GPa,而632.4℃、0.785 GPa这个值不是红柱石的稳定范围,这可能是其早期中压变质作用条件;矽线石带为640℃、0.43 GPa左右,由于石榴石中有蓝晶石包体,因此其早期也可能经历中压条件的变质;堇青石-矽线石带740～800℃、0.4～0.7 GPa。阿尔泰造山带低压变质序列不是一个正常的变质序列,其野外变质梯度呈现“Z”字型特征。阿尔泰造山带低压变质作用可能形成于早期中压变质岩的挤压抬升和以此相关的大量花岗岩侵入的构造环境中。     

拉萨地块松多榴辉岩的变质演化过程:NCKMnFMASHTO体系中的相平衡关系

拉萨地块松多榴辉岩主要矿物组合为石榴子石、绿辉石、角闪石、多硅白云母、绿帘石、金红石。石榴子石环带不明显,核部成分均一,从核部到边部,镁铝榴石和钙铝榴石含量降低,可能分别记录了榴辉岩峰期及退变质过程信息。绿辉石显示微弱的成分环带,硬玉含量从核部到边部略有升高,部分绿辉石边部发育韭闪石退变质边,反映了在减压过程中外来流体进入体系的过程。多硅白云母具有高的Si含量(3.5~3.6),其中石榴石包体中的多硅白云母相对基质中的白云母有更高的Si值。本文利用Thermocalc变质相平衡模拟软件,结合详细岩相学观察,在NCKMn FMASHTO体系下,模拟松多含多硅白云母榴辉岩的变质演化过程。其中,榴辉岩峰期矿物组合为g+o+law+phn+ru,石榴石核部最大镁铝榴石值和石榴子石包体中多硅白云母最大Si值确定的榴辉岩峰期温压条件约为620℃,32×105Pa,榴辉岩经历了近等温降压的退变质过程。相平衡模拟结果表明拉萨地块松多榴辉岩经历了超高压变质作用过程,并经历了相对快速的折返过程到中部地壳层次。     

CaSO4-C-H2O体系研究：模拟实验与热力学探讨

传统认为TSR成因的固态沥青(焦沥青)属于热化学反应的终端产物,不会对TSR的反应进程起到重要作用.本文以活性炭作为固态沥青(焦沥青)的模型化合物,开展了CaSO4-C-H2O体系的热模拟实验研究,探讨了CaSO4-C-H2O体系发生TSR的热力学特征.实验结果表明,CaSO4-C-H2O体系在300℃时即可启动TSR,主要生成CaCO3、H2S和CO2等产物.这一TSR门限温度要远低于以往室内利用气态或液态烃类进行的TSR模拟实验温度范围,与热力学计算结果一致.利用HSC Chemistry 5.0软件进行TSR过程模拟,发现25～200℃时CaSO4-C-H2O体系发生的TSR完全受动力学控制,在温度保持不变情况下,压力增大不利于CaSO4-C-H2O体系发生TSR.较少的含水量对TSR有一定促进作用,而含水量过多则可能抑制TSR的进行,含水量对TSR的影响可能与CaSO4在水中的饱和浓度有关.在一定的温度下,当体系pH≤2时,随着pH逐渐降低,CaSO4的量呈线性递减,但在沉积盆地地层水pH范围内(pH＞4),pH对TSR的作用可以忽略不计.CaSO4-C-H2O体系发生的TSR反应是一个放热过程,并且随着温度升高,反应热逐渐增大.在25～200℃范围内,TSR反应热为12.9～133 J/molCaSO4.热力学计算以及模拟实验结果均暗示,固态沥青(焦沥青)可能比烃类更容易参与TSR.     

Metasomatic Phase Relations in the System CaO-MgO-SiO2-H2O-NaCl at High Temperatures and Pressures

An equation of state of solute silica in NaCl brines at 500 to 900°C and 4 to 15 kbar is formulated by making use of two experimentally determined properties of quartz solubility: the silica molality decreases in direct proportion to the logarithm of the NaCl mole fraction (X(NaCl)) at pressures approaching 10 kbar, and the relative silica molality (molality at a given NaCl mole fraction, m_x, divided by the molality in pure H₂O at the same P and T, m_o) is independent of temperature in the evaluated range. These two properties are expressed in the relation:

log(m_x/m_o)? = A + BX(NaCI),

where log(m_x/m_o)? denotes the logarithm of the ideal molality ratio, and A and B are functions of pressure, but not temperature or salinity, such that B = ?1.730 ? 1.431 × 10?³P + 5.923 × 10?⁴P² ?9.243 × lO?⁵P³, and A = 0 at P>10 kbar, whereas A = 0.6131 ? 0.1256P + 6.431 × 10?³P² at P≤10 kbar, as derived from fits to experimental data (Newton and Manning, 1999). The parameter A decreases from 0.214 to 0 from 4 to 9.5 kbar, and remains zero to 15 kbar; B decreases from ?1.373 to ?1.571 from 4 to 15 kbar. With the above relationship defining a variable X(NaCl)-T-P standard-state of solute silica, the activity of SiO₂ can be replaced by its molality for calculations of mineral-fluid equilibria over most of the conditions for metasomatism in the deep crust and upper mantle. Significant departures from ideality occur only at the lowest pressures, and low salinities.

Calculations on peridotite mineral stability in the simple system CaO-MgO-SiO₂-H₂O-NaCl at high T and P show that antigorite, brucite, and diopside are stable at 500°C and pressures of 5 to 15 kbar in the presence of concentrated NaCl solutions at low SiO₂ activities. At 700°C, anthophyllite is stable over a wide range of salinities at 5 kbar with tremolite but not with diopside. The presence of anthophyllite buffers silica solubility at a high, salinity-independent value close to quartz saturation. At 10 and 15 kbar and 700°C, talc replaces anthophyllite as the stable hydrate, and talc-trem-olite assemblages buffer SiO₂ fluid concentrations at high values nearly independent of salinity. At 900°C hydrates are unstable and diopside again becomes stable and coexists with enstatite in peridotites. These stability calculations correspond well to the observed progressive metamorphic sequence in peridotite bodies in the Central Alps.

This method of analysis may be useful in interpretation of metamorphosed ultramafic bodies in general, including the basal portions of obducted ophiolitic mantle lithosphere and the mantle wedge above subduction zones. More detailed calculations, including rocks containing feldspars, must take into account the more soluble major components of rocks, especially alkalis, as these will affect the activity coefficient of SiO₂ in NaCl solutions. The solubility of silica in the presence of minerals containing these components must be determined by additional measurements.     

On the Direction and Magnitude of Oxygen Isotope Fractionation Between Calcite and Aragonite at Thermodynamic Equilibrium

Oxygen isotope fractionation factors between calcium carbonates and water have been applied to ancient marine geochemistry principally for the purpose of geothermometry. The problem was encountered, however, with respect to the direction and magnitude of oxygen isotope fractionation between calcite and aragonite at thermodynamic equilibrium. This basically involves sound understanding of both thermodynamics and kinetics of oxygen isotope fractionation between inorganically precipitated carbonate and water at low temperatures. Thus the crucial issues are to acknowledge the processes of chemical reaction and isotopic exchange during precipitation of CaCO₃ minerals in solution, the kinetic mechanism of isotope equilibrium or disequilibrium, the effect of polymorphic transition from metastable aragonite to stable calcite under hydrous or anhydrous conditions, and the presence or absence of isotope salt effect on oxygen isotope exchange between carbonate and water in response to the hydrous or anhydrous conditions at thermodynamic equilibrium. Because good agreements exist in carbonate–water oxygen isotope fractionation factors between theoretical calculations and experimental determinations, it is encouraging to applying the thermodynamic and kinetic data to isotopic paleothermometry and geochemical tracing.     

An Evaluation of Phase Behaviors of the Oil-Gas-Water System in the Displacement of Crude Oil with CO2

CO₂ dissolution into an aqueous phase and water evaporation into a gaseous phase takes place during CO₂ injection into an oil reservoir. This study aims to evaluate the phase behaviors of the oil-gas-water system in the displacement of crude oil by CO₂. The composition of the JL oilfield in the northeast of China is taken as an example. The flash calculation of the oil-gas-water system was performed, based on the method presented by Li and Nghiem. The research re...     

交互四元体系Li~+,Mg~(2+)//SO_4~(2-),B_4O_7~(2-)-H_2O 288K时相平衡研究

采用等温溶解平衡法研究了288K时Li+,Mg2+//SO42-,B4O72--H2O四元体系的固液相平衡关系,测定了该四元体系在288K时平衡液相的溶解度和密度。依据实验测定的平衡溶解度数据及对应的平衡固相,绘制了该四元体系的平衡相图及密度组成图。研究结果表明:交互四元体系Li+,Mg2+//SO42-,B4O27--H2O288K时平衡相图中有2个共饱点,5条单变量曲线,4个结晶区对应的平衡固相分别为Li2B4O7.3H2O,Li2SO4.H2O,MgB4O7.9H2O和MgSO4.7H2O。     

胶北地块高压与低压泥质麻粒岩的相平衡关系与p-T演化轨迹

利用最新的内洽性热力学数据库和THERMOCALC3.21程序对胶北地块高压与低压泥质麻粒岩的相平衡关系进行了定量分析。计算了胶北地块高压泥质麻粒岩、低压泥质麻粒岩和夕线石榴黑云片岩等代表性富铝岩石KFMASH(K2O-FeO-MgO-Al2O3-SiO2-H2O)体系的p-T视剖面图,再现了这些岩石随温压条件变化可能出现的各种矿物组合与矿物成分变化,发现原岩成分不同的变质岩石,尽管变质演化过程有所差异,但在麻粒岩相变质条件下所形成的矿物组合一致。通过计算泥质岩石在高压(p=1.0GPa)和低压(p=0.5GPa)条件下的T-X视剖面图,发现极度富铁、贫镁的岩石,在高压麻粒岩相条件下并不会生成含蓝晶石的特征矿物组合,在低压麻粒岩相条件下也不会生成含堇青石的特征矿物组合。将样品实际观测结果与p-T视剖面图的计算结果对比,确定胶北地块高压泥质麻粒岩变质峰期的温压条件为830~860℃,1.25~1.4GPa,峰期后呈现顺时针样式的p-T演化轨迹,反映陆壳先碰撞增厚、后又快速减薄的地质动力学过程;确定胶北地块低压泥质麻粒岩变质峰期的温压条件为790~820℃,0.62~0.68GPa,峰期后呈现近等压冷却的p-T演化轨迹。     

大别山南部高压-超高压变质地体中云母片岩和片麻岩的相平衡研究

对于大别山高压一超高压变质带中大面积出露的云母片岩和片麻岩的变质条件和演化历史有不同的认识：如中低压绿帘角闪岩相,高压角闪岩相和超高压榴辉岩相。通过对大别山南部超高压榴辉岩区、高压榴辉岩区和宿松变质杂岩带中的云母片岩和片麻岩进行详细的岩相学及相平衡研究表明：它们的变质条件分别为610℃～690℃,1．2～1．4GPa;590～600℃、1．3～1．5GPa;520～590℃,0．9～1．4GPa,相当于高压绿帘角闪岩相、高压角闪岩相与榴辉岩相之间的过渡。依据超高压榴辉岩区绿帘石黑云片麻岩中的石榴石环带特征推测,它们很可能经过超高压变质阶段。现有矿物组合记录了抬升阶段的条件。但是高压榴辉岩区的石榴石绿帘石二云片麻岩和宿松变质杂岩带中石榴石云母片岩中的石榴石环带特征表明,其现有矿物组合记录了变质峰期条件,不应该经历更高压变质阶段。在KFMASH体系的PT视剖面图上计算多硅白云母Si含量等值线表明,在多数矿物组合中白云母的Si含量可作为地质压力计,但Si等值线的斜率受到矿物组合的控制。