Anomalous Emissions of SO2 During the Recent Eruption of Santa Ana Volcano, El Salvador, Central America

Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO₂ degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO₂ flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO₂ flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1^st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO₂ flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO₂ flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO₂ fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO₂ and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO₂ flux can provide important warning signals for incoming explosive activity in active volcanoes.     

The 2005 eruption of Ilamatepec (Santa Ana) volcano,El Salvador

We report the stratigraphic sequence of the 2005 eruption of Ilamatepec volcano together with sedimentological and chemical analyses of its products.Structural and textural characteristics of the deposits indicate that the eruption was driven by a small-volume rhyolitic intrusion at shallow levels, which resulted first in the collapse of the existing hydrothermally altered fan of previous deposits inside the crater lake, driving phreatic explosions with launching of blocks on ballistic trajectories; later the magma interacted with lake waters producing several hydromagmatic pyroclastic density currents (PDCs). These flows were energetic enough to knock down pine trees up to distances of 1.8 km from the crater in the E-NE sector of the volcano. Finally, ejection of ballistic blocks that landed on previously emplaced, wet pyroclastic density current deposits, caused the generation of a lahar that flowed down the steep eastern flank toward the El Jabillal gully. Subsequent lahars occurred as a result of intense rain caused by hurricane Stan.Radiocarbon ages on paleosols and charcoal fragments, separating previous volcanogenic sequences, indicate that similar eruptions have occurred more frequently in the past centuries, than previously thought.The new data confirms that Ilamatepec volcano is one of the most active volcanoes in El Salvador. Nevertheless, more detailed studies of the eruptive sequence of Ilamatepec volcano are mandatory to establish future eruptive patterns.     

Anomalous Diffuse CO2 Emission prior to the January 2002 Short-term Unrest at San Miguel Volcano, El Salvador, Central America

On January 16, 2002, short-term unrest occurred at San Miguel volcano. A gas-and-steamash plume rose a few hundred meters above the summit crater. An anomalous microseismicity pattern, about 75 events between 7:30 and 10:30 hours, was also observed. Continuous monitoring of CO₂ efflux on the volcano started on November 24, 2001, in the attempt to provide a multidisciplinary approach for its volcanic surveillance. The background mean of the diffuse CO₂ emission is about 16 g m^-2 d^-1, but a 17- fold increase, up to 270 g m^-2 d^-1, was detected on January 7, nine days before the January 2002 short-term unrest at San Miguel volcano. These observed anomalous changes on diffuse CO₂ degassing could be related to either a sharp increase of CO₂ pressure within the volcanic-hydrothermal system or degassing from an uprising fresh gas-rich magma within the shallow plumbing system of the volcano since meteorological fluctuations cannot explain this observed increase of diffuse CO₂ emission.     

Underground Temperature Measurements as a Tool for Volcanic Activity Monitoring in the Island of Tenerife, Canary Islands

The spatial distribution of groundwater temperatures in the volcanic island of Tenerife, Canary Islands, has been inferred through measurements of water temperatures collected in the vast network of wells and subhorizontal tunnels, locally called “galleries,” which constitutes the main water supply of the island. The spatial coverage of the network of galleries allows us to reach from depth almost any geological feature of the island. The complex spatial distribution of temperatures in the interior of Tenerife is the result of the complex geological evolution of the island. Groundwater temperatures are greatly affected by groundwater flow and are considerably warmer in those galleries located in areas where water circulation is reduced due to the low permeability of materials and/or to the low infiltration rate of cooling meteoric water. In this sense, groundwater temperature should be characterized in quiescent conditions (background level), in order to facilitate monitoring changes in heat flow, such as those induced by ascending gases expected with an increase in volcanic activity.     

Geochemical Changes in Spring Water Associated with the 2000 Eruption of the Miyakejima Volcano, Japan

Water was sampled from eight springs and a lake in volcanic Miyakejima Island of Japan after the 2000 eruption. Major chemical and isotopic compositions of the water were analyzed. Significant increases of sulfate ion are observed in several springs where the thickness of ejecta exceeds 32 mm. A good relationship of Cl/S mole ratios between spring water and leachate of the ejecta is observed. Sulfur isotopic compositions of the spring water become close to that of leachate of the ejecta as time elapses after the eruption. Consequently the sources of the added sulfate ion in the spring water after the eruption are interpreted to be anhydrite and adhered sulfur of the ejecta.     

喀拉喀托火山喷发过程与巽他海啸成因

介绍了2018年12月22日发生的巽他海峡喀拉喀托火山喷发的过程及其火山监测情况,并提取了欧空局哨兵1A遥感卫星在火山喷发前后的遥感影像,通过遥感影像的对比分析获得了火山锥体的坍塌范围;使用3DAnalyst软件模块对坍塌部分的DEM影像进行分析,计算出海平面以上火山锥体的坍塌体积约为54000000m3,海面以下崩塌锥体体积更加巨大,崩塌导致火山周围水体发生激荡形成海浪,海浪相干传播至周边海岸附近引发了巽他海峡海啸;海啸灾害主要发生在印尼万丹省西冷县和板底兰县西部沿海,与根据火山喷发引发海啸的传播路径推测的受灾地区基本一致。     

Evolution of a vent-hosted hydrothermal system beneath Ruapehu Crater Lake,New Zealand

A two-year chemical monitoring program of Ruapehu Crater Lake shows that it has evolved considerably since the volcano's more active eruptive periods in the early 1970s. The present pH (20°C) of 0.6 is about one half unit more acid than the baseline values in the 1970s, whereas S/Cl ratios have increased markedly owing in part to declining HCl inputs into the lake, but also to absolute increases in SO₄ levels which now stand at the highest values ever recorded. Increases in K/Mg and Na/Mg ratios over the 20-year period are attributed to hydrothermal reaction processes in the vent which are presently causing dissolution of previously formed alteration phases such as natroalunite. These observations, combined with results of a recent heat budget analysis of the lake, have led to the development of hydrothermal convection model for the upper portion of the vent. Possible vent/lake chemical reaction processes between end member reactants have been modelled with the computer code CHILLER. The results are consistent with the view that variations in lake chemistry, which are initiated by the introduction of fresh magmatic material into the vent, reflect the extent of dissolution reaction progress on the magmatic material and/or its alteration products. The results also provide insights into the role of such vent processes in the formation of high sulfidation-type ore deposits.     

Temporal changes in the chemistry of lake water within Yugama Crater,Kusatsu-Shirane Volcano,Japan: Implications for the evolution of the magmatic hydrothermal system

The chemical composition and temperature of lake water within Yugama Crater, Kusatsu-Shirane Volcano, Japan, have fluctuated markedly over the period 1966 to 2005. From 1966 to 1981, water temperature was relatively low, and Cl⁻ and SO₄²⁻ concentrations gradually decreased. These trends are explained by the growth of a sealing zone that formed between the region of hot rock surrounding the degassing magma and cool crust saturated with groundwater. The sealing zone acted to restrict the emission of magmatic volatiles.     

Volcanic Tremor at Mt. Etna,Italy, Preceding and Accompanying the Eruption of July – August, 2001

The July 17 – August 9, 2001 flank eruption of Mt. Etna was preceded and accompanied by remarkable changes in volcanic tremor. Based on the records of stations belonging to the permanent seismic network deployed on the volcano, we analyze amplitude and frequency content of the seismic signal. We find considerable changes in the volcanic tremor which mark the transition to different styles of eruptive activity, e.g., lava fountains, phreatomagmatic activity, Strombolian explosions. In particular, the frequency content of the signal decreases from 5 Hz to 3 Hz at our reference station ETF during episodes of lava fountains, and further decreases at about 2 Hz throughout phases of intense lava emission. The frequency content and the ratios of the signal amplitude allow us to distinguish three seismic sources, i.e., the peripheral dike which fed the eruption, the reservoir which fed the lava fountains, and the central conduit. Based on the analysis of the amplitude decay of the signal, we highlight the migration of the dike from a depth of ca. 5 km to about 1 km between July 10 and 12. After the onset of the effusive phase, the distribution of the amplitude decay at our stations can be interpreted as the overall result of sources located within the first half kilometer from the surface. Although on a qualitative basis, our findings shed some light on the complex feeding system of Mt. Etna, and integrate other volcanological and geophysical studies which tackle the problem of magma replenishment for the July–August, 2001 flank eruption. We conclude that volcanic tremor is fundamental in monitoring Mt. Etna, not only as a marker of the different sources which act within the volcano edifice, but also of the diverse styles of eruptive activity. An erratum to this article is available at .     

Bathymetric and geochemical investigation of Kawah Ijen Crater Lake, East Java, Indonesia

A bathymetric survey of Kawah Ijen crater lake was conducted by acoustic sounding in 1996 to compare the lake morphology with those measured in 1922, 1925 and 1938, and to calculate the present lake volume. Even though the lake experienced several hydrothermal eruptions, the maximum depth became shallower (182 m) than before (200 m), resulting in a reduced lake volume (3.0×10⁷ m³).Fifty-two major and minor constituents including rare earth elements and polythionates (PT) of the lake waters at various depths were determined by ICP-AES, ICP-MS and HPLC, respectively. These ions except for several volatile elements are taken up by lake fringe through congruent dissolution of pyroclastics of Kawah Ijen volcano. Most ions are homogeneously distributed throughout the lake, although PT showed a considerable vertical variation. Rare earth elements (REE) in the Kawah Ijen water as well as those from other hyper-acidic crater lakes show distribution patterns likely due to the three rock dissolution (preferential, congruent and residual) types, and their logarithmic concentrations linearly depend upon the pH values of the lake waters.Using the PT degradation kinetics data, production rates of PT, injection rates of SO₂ and H₂S into the lake were estimated to be 114, 86 and 30 tons/day, respectively. Also travel time of the spring water at the Banyupahit Riverhead from Kawah Ijen was estimated to be 600–1000 days through the consideration of decreasing rates of PT. Molten sulfur stocks containing Sn, Cu, Bi sulfides and Pb-barite exposed on the inner crater slope were presumed to be extinct molten sulfur pools at the former lake bottom. This was strongly supported by the barite precipitation temperature estimated through the consideration of the temperature dependence of Pb-chlorocomplex formation.     

Hydroacoustic noise precursors of the 1990 eruption of Kelut Volcano, Indonesia

The results of a hydroacoustic monitoring experiment in the Kelut Crater lake, Indonesia, prior to its 1990 eruption, are presented, with the benefit of hindsight. Indeed, the underwater noise levels in three widely separated frequency bands, together with the lake water temperature, was radio-transmitted and almost continuously recorded from a period of quiescence of the volcano till the onset of its 10 February 1990, eruption, which destroyed the monitoring buoy. The comparative analysis of the noise variations in the three bands, together with seismic and temperature data, have shed light on the mechanisms underlying the pre-eruptive activity. The three acoustic levels had shown conspicuous, yet distinctive, changes prior to the eruption. Acoustic level in the low-frequency (1–50 Hz) band, which increased one year before the resumption of seismic activity and the lake warming up, is interpreted as the result of boiling at depth. The source of high-acoustic level in the audiometric (500–5000 Hz) range is clearly the bubbling of volcanic gases, occurring as a strong convective column in the middle of the lake. From the variations of this audiometric level, we have estimated that the degassing rate in the lake increased by a hundred-fold during the pre-eruptive period. Variations of ultrasonic (20–100 kHz) frequency acoustic level seem to be related with pressure and thermal changes within the hydrothermal system and its rock matrix beneath the lake. In conclusion, this experiment demonstrates the potential of hydroacoustic monitoring as an early warning system at crater lake volcanoes.     

Transition from mildly-tholeiitic to calc-alkaline suite: the case of Chichontepec volcanic centre, El Salvador, Central America

The Chichontepec volcano is a Plio-Pleistocene composite volcano that erupted lavas ranging from high-alumina basalts to dacites. It experienced a caldera-forming paroxysmal eruption during the early Pleistocene. Pre-caldera lavas are mildly tholeiitic and they evolved mainly by low pressure crystal fractionation, notwithstanding the fact that most mafic lavas (low-MgO high-alumina basalts) retain traces of polybaric evolution. Conversely, post-caldera lavas, which are mainly pyroxene andesites, are clearly calc-alkaline, having evolved by open-system crystal fractionation. Sr–Nd isotopic data and trace elements characteristics indicate that the same mantle source was involved in the petrogenesis of these series. Modelling the AFC process showed that it did not play any role in the petrogenesis of these rocks; a crystal fractionation model is considered to be more relevant. A slight variation in the fractionating assemblage could have caused the transition from an early mildly tholeiitic trend to a late calc-alkaline one. Mineralogical evidence, mass-balance calculations and elemental chemistry support this hypothesis, assuming that the greater amount of pyroxene on the liquidus is at the expense of plagioclase; this would have prevented the trend in iron enrichment.     

Preliminary sensitivity study of eruption source parameters for operational volcanic ash cloud transport and dispersion models — A case study of the August 1992 eruption of the Crater Peak vent, Mount Spurr, Alaska

Ash clouds are one of the major hazards that result from volcanic eruptions. Once an eruption is reported, volcanic ash transport and dispersion (VATD) models are used to forecast the location of the ash cloud. These models require source parameters to describe the ash column for initialization. These parameters include: eruption cloud height and vertical distribution, particle size distribution, and start and end time of the eruption. Further, if downwind concentrations are needed, the eruption mass rate and/or volume of ash need to be known. Upon notification of an eruption, few constraints are typically available on many of these source parameters. Recently, scientists have defined classes of eruption types, each with a set of pre-defined eruption source parameters (ESP). We analyze the August 18, 1992 eruption of the Crater Peak vent at Mount Spurr, Alaska, which is the example case for the Medium Silicic eruption type. We have evaluated the sensitivity of two of the ESP – the grain size distribution (GSD) and the vertical distribution of ash – on the modeled ash cloud. HYSPLIT and Puff VATD models are used to simulate the ash clouds from the different sets of source parameters. We use satellite data, processed through the reverse absorption method, as reference for computing statistics that describe the modeled-to-observed comparison. With the grain size distribution, the three options chosen, (1) an estimated distribution based on past eruption studies, (2) a distribution with finer particles and (3) the National Oceanic and Atmospheric Administration HYSPLIT GSD, have little effect on the modeled ash cloud. For the initial vertical distribution, both linear (uniform concentration throughout the vertical column) and umbrella shapes were chosen. For HYSPLIT, the defined umbrella distribution (no ash below the umbrella), apparently underestimates the lower altitude portions of the ash cloud and as a result has a worse agreement with the satellite detected ash cloud compared to that with the linear vertical distribution for this particular eruption. The Puff model, with a Poisson function to represent the umbrella cloud, gave similar results as for a linear distribution, both having reasonable agreement with the satellite detected cloud. Further sensitivity studies of this eruption, as well as studies using the other source parameters, are needed.     

Implication of the temporal sulphur isotopic variation during the 2000 eruption of Miyakejima Volcano, Japan

Abstract   The variation of sulphur isotopic composition during the 2000 eruption of the Miyakejima Volcano was examined in order to monitor the temporal change of the volcanic activity. The δ³⁴S values of water-soluble sulphate leached from volcanic ash effused during intermittent eruptions from July to September 2005 range from +5 to +11‰ with a fluctuation of ca 3‰ within a single eruption. The δ³⁴S value of sulphuric acid mist collected with 'Cu-metal trap' placed on the flank of the volcano from December 2000 to January 2001 is +6.2‰. These sulphur isotopic compositions of sulphate, which were isotopically equilibrated in the subvolcanic hydrothermal system, indicate that the temperature of the hydrothermal system beneath the caldera increased after the period of intermittent phreatic and phreatomagmatic eruptions. Then, the δ³⁴S value of sulphuric acid trapped from January to March 2001 was +9.0‰ and the δ³⁴S value of water-soluble sulphate on volcanic ash emitted with minor eruption in May 2001 was +11.0‰, suggesting a decrease in temperature of the subvolcanic hydrothermal system.     

Implications for the thermal regime of acoustic noise measurements in Crater Lake,Mount Ruapehu,New Zealand

Hydrophone measurements of acoustic noise levels in the Crater Lake of Mount Ruapehu, New Zealand were made on 18 January 1991 from an inflatable rubber boat on the lake. The greatest sound pressures were recorded in the 1–10 Hz band, with sound levels generally decreasing about 20 dB per decade from 10 Hz to 80 kHz. The low frequency noise did not have an obvious relationship to the tremor observed at a seismic station within 1 km of the lake. The comparatively low levels of middle and high frequency sound meant that at the time of measurement, direct steam input did not make a significant contribution to the heating of Crater Lake. This is consistent with the earlier conclusion that during the last decade a major part of the heat input of Crater Lake has come from lake water that was heated below the lake and recycled back into the lake.     

Tidal triggering of seismic and volcanic phenomena during the 1879–1880 eruption of Islas Quemadas volcano in El Salvador, Central America

The Islas Quemadas dome in Lake Ilopango, El Salvador, was extruded during December 1879 to March 1880. The eruption took place in six distinct periods, five of which began near fortnightly minima in the amplitude of the semidiurnal solid earth tide. An earthquake swarm preceded dome extrusion. Felt earthquakes were carefully recorded during a two-day period preceding a destructive main shock that occurred on December 27, 1879. During this foreshock sequence the periods of highest earthquake activity occurred at times of maxima and minima in semidiurnal solid-earth tide. The four largest earthquakes, including the main shock, occurred at maxima in the semidiurnal tide.     

Subaqueous geothermal activity revealed by lacustrine sediments of the acidic Nakadake crater lake, Aso Volcano, Japan

Lacustrine sediments were sampled from the inaccessible acidic (pH = 0.43) Nakadake crater lake of Aso Volcano, Japan by a simple method. The sediments contain an extremely high content (74 wt.%) of sulfur, which exits as elemental sulfur, gypsum and anhydrite. The abundant elemental sulfur is likely formed by the reaction of SO₂ and H₂S gases and by the SO₂ disproportionation reaction in magmatic hydrothermal system below the crater lake. Based on the sulfur content of sediments and measurements of elevation change of the crater bottom, the sulfur accumulation rate at the Nakadake crater lake was calculated as 250 tonne/day, which is comparable with the SO₂ emission rate (200–600 tonne/day) from the Nakadake crater. The sediments include a small amount (9%) of clear glass shards that are apparently not altered in spite of the high reactivity of hyperacid lake water. This finding suggests that the clear glass shards are fragments of recently emitted magmas from fumaroles on the bottom of the crater lake and the magma emissions continuously occur even in quiescent periods.     

Morphology of ash aggregates from wet pyroclastic surges of the 1982 eruption of El Chichón Volcano, Mexico

The detailed stratigraphic study of the pyroclastic surge units S1, IU, and S3 produced during the most violent phases of the 1982 eruption of El Chichón volcano, contains a complex succession of hydromagmatic events triggered by the interaction of different proportions of magma and external water. Component analyses of the horizons within single units reveal that almost all wet and cohesive horizons contain ash aggregates. Based on their morphology and internal structure four different types of aggregates were distinguished: (a) accretionary lapilli, (b) armored lapilli, (c) irregular aggregates, and (d) cylindrical aggregates. The first three types have been described in the volcanological literature (field and experimental studies); cylindrical forms are reported here for the first time. These hollow cylindrical aggregates consist of concentric layers of crystals and glass fragments set in a finer-grained matrix. They formed around millimeter-size foliage fragments that are locally preserved in the interior of the aggregates as scorched or completely carbonized vestiges. SEM analyses suggest different mechanisms of formation for the four types of aggregates. Irregular aggregates and armored lapilli formed nearly instantaneously, whereas accretionary lapilli and cylindrical aggregates resulted from progressive aggregation of ash in different regions of the eruptive cloud.All types of ash aggregates contain fractured particles. This common feature suggests that particles ruptured during fragmentation prior to the growth of the aggregates. Broken clasts with cracks filled by a fine-grained matrix only occur inside the cylindrical ash aggregates and to a lesser degree in some types of accretionary lapilli. This suggests that small thermal contrasts at the contact of warm particles with the colder fine-grained matrix of the aggregate cause existing small fractures to propagate and open as the already weakened clasts deform slightly. The occurrence of all four types of aggregates in some horizons indicates that several mechanisms of aggregation occurred nearly simultaneously. The pyroclastic clouds therefore were not only stratified in terms of density but the content of fluid phases also were not uniform. A dark-red, Fe-rich amorphous film (locally rich in P and S) envelops the particles and fosters their preservation in the deposits by forming a hard shell. The composition of this cement reflects the abundance of these elements in acid fluids of hydrothermal systems that were intersected by the conduit during the eruption. In distal areas, fallout aggregates were incorporated by dissipating pyroclastic surges.     

Leakage of Active Crater lake brine through the north flank at Rincón de la Vieja volcano, northwest Costa Rica, and implications for crater collapse

The Active Crater at Rincón de la Vieja volcano, Costa Rica, reaches an elevation of 1750 m and contains a warm, hyper-acidic crater lake that probably formed soon after the eruption of the Rio Blanco tephra deposit approximately 3500 years before present. The Active Crater is buttressed by volcanic ridges and older craters on all sides except the north, which dips steeply toward the Caribbean coastal plains. Acidic, above-ambient-temperature streams are found along the Active Crater's north flank at elevations between 800 and 1000 m. A geochemical survey of thermal and non-thermal waters at Rincón de la Vieja was done in 1989 to determine whether hyper-acidic fluids are leaking from the Active Crater through the north flank, affecting the composition of north-flank streams.Results of the water-chemistry survey reveal that three distinct thermal waters are found on the flanks of Rincón de la Vieja volcano: acid chloride–sulfate (ACS), acid sulfate (AS), and neutral chloride (NC) waters. The most extreme ACS water was collected from the crater lake that fills the Active Crater. Chemical analyses of the lake water reveal a hyper-acidic (pH0) chloride–sulfate brine with elevated concentrations of calcium, magnesium, aluminum, iron, manganese, copper, zinc, fluorine, and boron. The composition of the brine reflects the combined effects of magmatic degassing from a shallow magma body beneath the Active Crater, dissolution of andesitic volcanic rock, and evaporative concentration of dissolved constituents at above-ambient temperatures. Similar cation and anion enrichments are found in the above-ambient-temperature streams draining the north flank of the Active Crater. The pH of north-flank thermal waters range from 3.6 to 4.1 and chloride:sulfate ratios (1.2–1.4) that are a factor of two greater than that of the lake brine (0.60). The waters have an ACS composition that is quite different from the AS and NC thermal waters that occur along the southern flank of Rincón de la Vieja.The distribution of thermal water types at Rincón de la Vieja strongly indicates that formation of the north-flank ACS waters is not due to mixing of shallow, steam-heated AS water with deep-seated NC water. More likely, hyper-acidic brines formed in the Active Crater area are migrating through permeable zones in the volcanic strata that make up the Active Crater's north flank. Dissolution and shallow subsurface alteration of north-flank volcanoclastic material by interaction with acidic lake brine, particularly in the more permeable tephra units, could weaken the already oversteepened north flank of the Active Crater. Sector collapse of the Active Crater, with or without a volcanic eruption, represents a potential threat to human lives, property, and ecosystems at Rincón de la Vieja volcano.