Alteration of fluid properties during the initial operation of a geothermal plant: results from in situ measurements in Groß Schönebeck

Recently, the thermal fluid loop has been established and continuosly operated for 7 days at the geothermal in situ laboratory in Groß Schönebeck (North German Basin). During this initial phase of fluid production, the fluid temperature, measured at the surface, continuously increased until a stable value of about 98 °C was established. Fluid physicochemical properties (pH, redox, density, temperature, and pressure) were measured online and in situ with a newly developed fluid monitoring system (FluMo). Additionally, fluid samples have been collected at various temperatures (in 5–10 °C steps) directly at the production well at about 10 bar pressure. From the pressurized sampling tool, the fluid was directly transferred into a heated autoclave, which allowed filtration (0.2 μm) in the absence of oxygen. Physicochemical parameters [pH, redox, electric conductivity, total dissolved solids (TDS)] as well as acid capacity (K _S 4.3) of these samples have been measured onsite at atmospheric conditions. Concentrations of anions, total organic carbon, and metals were analyzed later in the laboratory. Both, measurements in collected samples or in situ (FluMo) analysis of most the parameters density, electric conductivity, or TDS indicated relatively constant values over the whole production time (1.17–1.18 g · cm^?3, 215–221 mS · cm^?1, 241–260 g · L^?1, respectively). Good correlation was also found for pH values (pH = 6.6–6.9), whereas the redox values varied between ?1 and 46 mV when determined at 25 °C and decreased strongly when measured in situ with increasing temperature (?110 mV at 90 °C). The elemental composition of collected samples remained also relatively constant for most compounds and was clearly higher as compared with samples collected in 2011. Results of this study demonstrate that realistic, comprehensive, and time-resolved physicochemical data can be obtained by FluMo. These detailed data sets can be crucial to understand the complex geochemical processes in a thermal water loop and eventually to take required measures on time.     

Genesis of a Magnetite Layer in the Gabbro-10 Intrusion,Monchegorsk Complex,Kola Region: U–Pb SHRIMP-II Dating of Metadiorites

Geology of Ore Deposits - The Gabbro-10 intrusion is located in the southeastern part of the Early Proterozoic Monchegorsk layered complex of the Kola region. The intrusion, 1.4 × 0.7 km in...     

The Antarctic viewpoint of the Central Paratethys: cause, timing, and duration of a deep valley incision in the Middle Miocene Alpine–Carpathian Foredeep of Lower Austria

Global, glacio-eustatic sea-level changes massively influenced the depositional history of the Central Paratethyan region. Here, we correlate Middle Miocene global δ¹⁸O-shifts with ice volume changes on Antarctica and sea-level changes with corresponding phases of erosion (valley incision) and deposition in the Lower Austrian part of the Alpine–Carpathian Foredeep. This allows the exact dating of the valley formation. Two periods of positive δ¹⁸O-shifts resulted in sea-level drops of about 60 and 40 m, respectively. The first drop in the late Langhian (middle Badenian) at c. 13.9 Ma (Mi3b) was fast and caused severe erosion on the emerged foredeep. In a second, less pronounced step around 13.0 Ma (Mi4) in the middle Serravallian (late Badenian), the base level was further deepened after a period of alternating erosion and deposition. The combined sea-level change (80–120 m) fits well with the maximum thickness of Sarmatian sediments drilled within incised valley (110 m). The global sea-level falls affected not only the geological history of the foredeep. The intensive erosion (valley incision) is combined with delta progradation in the adjacent Vienna Basin. Due to this massive sea-level drop, the interruption of marine connections resulted in vast salt deposits and faunal crises within the Central Paratethys during this time.     

Geological interpretation of a deep seismic‐reflection transect across the boundary between the Delamerian and Lachlan Orogens,in the vicinity of the Grampians,western Victoria

A deep seismic‐reflection transect in western Victoria was designed to provide insights into the structural relationship between the Lachlan and the Delamerian Orogens. Three seismic lines were acquired to provide images of the subsurface from west of the Grampians Range to east of the Stawell‐Ararat Fault Zone. The boundary between the Delamerian and Lachlan Orogens is now generally considered to be the Moyston Fault. In the vicinity of the seismic survey, this fault is intruded by a near‐surface granite, but at depth the fault dips to the east, confirming recent field mapping. East of the Moyston Fault, the uppermost crust is very weakly reflective, consisting of short, non‐continuous, west‐dipping reflections. These weak reflections represent rocks of the Lachlan Orogen and are typical of the reflective character seen on other seismic images from elsewhere in the Lachlan Orogen. Within the Lachlan Orogen, the Pleasant Creek Fault is also east dipping and approximately parallel to the Moyston Fault in the plane of the seismic section. Rocks of the Delamerian Orogen in the vicinity of the seismic line occur below surficial cover to the west of the Moyston Fault. Generally, the upper crust is only weakly reflective, but subhorizontal reflections at shallow depths (up to 3 km) represent the Grampians Group. The Escondida Fault appears to stop below the Grampians Group, and has an apparent gentle dip to the east. Farther east, the Golton and Mehuse Faults are also east dipping. The middle to lower crust below the Delamerian Orogen is strongly reflective, with several major antiformal structures in the middle crust. The Moho is a slightly undulating horizon at the base of the highly reflective middle to lower crust at 11–12 s TWT (approximately 35 km depth). Tectonically, the western margin of the Lachlan Orogen has been thrust over the Delamerian Orogen for a distance of at least 25 km, and possibly over 40 km.     

Development of a three-dimensional basin model to evaluate the site effects in the tectonically active near-fault region of Gölyaka basin,Düzce,Turkey

Natural Hazards - The high seismicity and tectonic activity of the study area located in a near-fault region in Gölyaka, Düzce, results in a bedrock geometry highly complex in the sense...     

Life in the sublittoral zone of long-lived Lake Pannon: paleontological analysis of the Upper Miocene Szák Formation,Hungary

Life and depositional environments in the sublittoral zone of Lake Pannon, a large, brackish Paratethyan lake from the Late Miocene, were reconstructed from fossils and facies of the Szák Formation. This formation is exposed in several, roughly coeval (9.4–8.9 Ma) outcrops, located along strike of the paleo-shelf-break in northwestern Hungary. The silty argillaceous marl of the formation was deposited below storm wave base, at 20–30 to 80–90 m water depth. The abundance of benthic organisms indicates that the bottom water was usually well oxygenated. Interstitial dysoxia, however, may have occurred immediately below the sediment–water interface, as evidenced by occasional preservation of trace fossils such as Diplocraterion. The fauna comprised endemic mollusks, including brackish cockles of the subfamily Lymnocardiinae, dreissenid mussels (Congeria), and highly adapted, uniquely large-sized deep-water pulmonate snails (planorbids and lymnaeids). Ostracods were dominated by endemic species and, in some cases, endemic genera of candonids, leptocytherids, cypridids, and loxoconchids. Fish remnants include a sciaenid otolith and the oldest skeletal occurrence of Perca in Europe. The phytoplankton comprised exclusively endemic coccolithophorids, mostly endemic dinoflagellates (prevailingly Spiniferites), and cosmopolitan green algae. The Late Miocene fauna and flora of Lake Pannon were in many ways similar to the modern Caspian biota, and in particular cases can be regarded as its precursor.     

Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.     

Spinels,Fe–Ti oxide minerals,apatites, and carbonates hosted in the ophiolites of Eastern Desert of Egypt: mineralogy and chemical aspects

Spinels, Fe–Ti oxide minerals, apatites, and carbonates hosted in ophiolitic serpentinites and metagabbros of Gabal Garf (southern ED) and Wadi Hammariya (central ED) of Egypt are discussed. Microscopic and electron probe studies on these minerals are made to evaluate their textural and compositional variations. Alteration of chromites led to form ferritchromite and magnetite; rutile–magnetite intergrowths and martite are common in serpentinites. Fine trillis exsolution of ilmenite–magnetite and ilmenite–hematite and intergrowth of rutile–magnetite and ilmenite–sphene are recorded. Composite intergrowth grains of titanomagnetite–ilmenite trellis lamellae are common in metagabbros. The formation of ilmenite trellis and lamellae in magnetite and titanomagnetite indicate an oxidation process due to excess of oxygen contained in titanomagnetite; trapped and external oxidizing agents. This indicates the high P _H2O and oxygen fugacity of the parental magma. The sulfides minerals include pyrrhotite, pyrite and chalcopyrite. Based on the chemical characteristics, the Fe–Ti oxide from the ophiolitic metagabbros in both areas corresponds to ilmenite. The patites from the metagabbros are identified as fluor-apatite. Carbonates are represented by dolomites in serpentinites and calcite in metagabbros. Spinel crystals in serpentinites are homogenous or zoned with unaltered cores of Al-spinel to ferritchromit and Cr-magnetite toward the altered rims. Compared to cores, the metamorphic rims are enriched in Cr# (0.87–1.00 vs. 0.83–0.86 for rims and cores, respectively) and impoverished in Mg# (0.26–0.48 vs. 0.56–0.67) due to Mg–Fe and Al (Cr)–Fe³⁺ exchange with the surrounding silicates during regional metamorphism rather than serpentinization process. The Fe–Ti oxides have been formed under temperature of ~800 °C for ilmenite. Al-spinels equilibrated below 500–550 °C, while the altered spinel rims correspond to metamorphism around 500–600 °C. Geochemical evidence of the podiform Al-spinels suggest a greenschist up to lower amphibolite facies metamorphism (at 500–600 °C), which is isofacial with the host rocks. Al-spinel cores do not appear to have re-equilibrated completely with the metamorphic spinel rims and surrounding silicates, suggesting relic magmatic composition unaffected by metamorphism. The composition of Al-spinel grains suggest an ophiolitic origin and derivation by crystallization of boninitic magma that belonging to a supra-subduction setting could form either in forearcs during an incipient stage of subduction initiation or in back-arc basins.     

Numerical simulations of landslide-stabilizing piles: a remediation project in Söke,Turkey

A catastrophic landslide following a rainy season occurred in the backyard of a school building in Söke, Turkey. The landslide caused property damage and adversely affected the present forest cover. Immediately after the landslide, double-row stabilizing piles were designed and constructed based on the findings of two-dimensional (2D) finite element (FE) analyses to take an urgent precaution. To remedy the problem, pile displacements were monitored using inclinometers, and it was observed that the measured displacements were greater than the values calculated in the design stage. Accordingly, two different three-dimensional (3D) numerical FE models were used in tandem with the inclinometer data to determine the load transfer mechanism. In the first model, numerical analyses were made to predict the pile displacements, and while the model predicted successfully the displacement of the piles constructed in the middle with reasonable accuracy, it failed for the corner piles. In the second model, the soil load transfer between piles was determined considering the sliding mass geometry, the soil arching mechanism and the group interaction between adjacent piles. The results of the second model revealed that the middle piles with large displacements transferred their loads to the corner piles with smaller displacements. The generated soil loads, perpendicular to the sliding direction, restricted pile deformations and piles with less displacement were subjected to greater loads due to the bowl-shaped landslide. A good agreement between the computed pile displacements and inclinometer data indicates that the existing soil pressure theories should be improved considering the position of the pile in the sliding mass, the depth and deformation modulus of stationary soil, the relative movement between the soil and piles and the relative movement of adjacent piles.     

First Evidence of Lamprophyric Magmatism from the Konya Region,Turkey: a Genetic Link to High-K Volcanism

In the vicinity of Konya （Turkey）,mafic,micro-porphyritic sub-volcanic rocks intrude into the Mesozoic units,which represents the only example of such a rock type in the region.40Ar/39Ar dating of two whole rock samples from the sub-volcanics gave ages of 13.72±0.13 and 12.40±0.11 Ma,suggesting temporal association to the Late Miocene-Pliocene high-K calc-alkaline volcanism in the region.The mineral chemistry and geochemical data permit us to classify the rocks as ＂minette＂ lamprophyres.They include diopside and phlogopite phenocrysts in a microcrystalline groundmass composed of sanidine,phlogopite,diopside and titano-magnetite.Segregation and ocelli-like globular structures occur commonly in the samples.In terms of major elements,the lamprophyres are calcalkaline,and potassic to ultrapotassic rocks.All the lamprophyres display strong enrichments in LILE （Rb,Ba,K,Sr）,radiogenic elements （Th,U） and LREE （La,Ce） and prominent negative Nb,Ta,and Ti anomalies on primordial mantle-normalized trace element diagrams.Geochemical data suggest that the lamprophyres and high-K calc-alkaline rocks in the region derived from a subduction-modified lithospheric mantle source affected by different metasomatic events.Lamprophyric magmatism sourced phlogopite-bearing veins generated by sediment-related metasomatism via subduction,but high-K calc-alkaline magmas are possibly derived from a mantle source affected by fluid-rich metasomatism.     

The interaction of tectonics,climate and eustasy in controlling dolomitization: A case study of Cenomanian–Turonian,shallow marine carbonates of the Iberian Basin

During the Cretaceous, high global sea-level and low latitudinal temperature variations led to the growth of epeiric carbonate platforms. Platform-scale dolomitization of these platforms is not common, reflecting the low Mg/Ca ratio of seawater and a humid climate. This study describes the processes governing pervasive dolomitization of a land-attached carbonate platform within the Iberian Basin. Dolomite is planar to sub-planar with a geochemical signature consistent with dolomitization from penesaline seawater. Dolomitization was most pervasive during a 1 Myr period in the middle Cenomanian, by repeated reflux of seawater from brine pools formed on the top of a southward-prograding carbonate platform. Tilting and structural reorganization in the Upper Cenomanian led to a reversal in polarity of the platform, and dolomitization was restarted by the northward reflux of seawater. Rising relative sea-level and oceanic acidification led to back-stepping of the platform such that the supply of dolomitizing fluids was cut off. In the Lower Turonian, pervasively dolomitized rudist rudstone facies in the south of the study area indicate that dolomitization restarted, either penecontemporaneously or later, from highly evaporated Campanian–Maastrichtian seawater. A systematic increase in dolomite crystal size up-section ties broadly, but not entirely, to stratigraphy. It is possible that these textural differences reflect changes in fluid chemistry, limestone permeability or precursor rock texture. However, the lack of stratigraphic conformance, and the preservation of the earliest-formed dolomite only in the oldest sediments, could indicate a progressive recrystallization of early-formed dolomite through repeated reflux of brines. As such, the succession appears to preserve a fossilized record of dolomite recrystallization through time during the Cenomanian–Turonian. The results of this study therefore provide a record of the progressive dolomitization of a carbonate platform and demonstrate the important interplay of climate and basin-scale tectonics on dolomite distribution and crystallinity.     

Joint evaluation of gravity, electrical and magnetotelluric methods for geothermal potential of fractured Aptian reefal carbonates in the Hmaima–El Gara area (Oued Serrat basin, Central–Western Tunisia)

Hmaima–El Gara area is located in Central–Western Tunisia and is known as an important geothermal province. In this study, we attempt to delineate the subsurface structures of the area using integrated interpretation of gravity, electrical and magnetotelluric data. The Hmaima thermal aquifer, associated with fractured Aptian reefal limestones, is characterized by high gravity and high resistivity. Horizontal gradient and Euler deconvolution method has been applied to the gravity data and provided fast information about both the depth and trends of the shallower subsurface structures in the area. As several of the mapped lineaments correlate with published geological fault trends, the other lineaments may be indicators of new insights for hydrothermal exploitation in the Hmaima–El Gara area (economical potential favorite zones).     

Complex basin evolution in the Gökova Gulf region: implications on the Late Cenozoic tectonics of southwest Turkey

Southwestern Turkey experienced a transition from crustal shortening to extension during Late Cenozoic, and evidence of this was recorded in four distinct basin types in the Mu?la–Gökova Gulf region. During the Oligocene–Early Miocene, the upper slices of the southerly moving Lycian Nappes turned into north-dipping normal faults due to the acceleration of gravity. The Kale–Tavas Basin developed as a piggyback basin along the fault plane on hanging wall blocks of these normal faults. During Middle Miocene, a shift had occurred from local extension to N–S compression/transpression, during which sediments in the Eskihisar–T?naz Basins were deposited in pull-apart regions of the Menderes Massif cover units, where nappe slices were already eroded. During the Late Miocene–Pliocene, a hiatus occurred from previous compressional/transpressional tectonism along intermountain basins and Yata?an Basin fills were deposited on Menderes Massif, Lycian Nappes, and on top of Oligo–Miocene sediments. Plio-Quaternary marked the activation of N–S extension and the development of the E–W-trending Mu?la–Gökova Grabens, co-genetic equivalents of which are common throughout western Anatolia. Thus, the tectonic evolution of the western Anotolia during late Cenozoic was shifting from compressional to extensional with a relaxation period, suggesting a non-uniform evolution.     

Contents of Fixed-Ammonium (NH_4~+) in Lamprophyres in the Zhenyuan Gold Orefield, Yunnan Province, China: Implications for Its Characteristics of the Source Region

This paper determined the fixed-ammonium (NH 4) contents of lamprophyres in the Zhenyuan gold orefield, Yunnan Province, China. The results show that the NH 4 contents of minettes in the orefield range from 120×10 -6 to 469×10 -6 and those of kersantites from 74.3 ×10 -6 to 136×10 -6 . These values are higher than those of other mantle-derived rocks (less than 50×10 -6 ), but lower than those of carbonaceous wall rocks in the orefield (from 1200×10 -6 to 1343×10 -6 ). Combining with the Sr isotopic composition, this paper suggested that lamprophyres in the orefield with high NH 4 contents relative to other mantle-derived rocks would not have resulted from the primary magma contaminated by crustal materials in the process of rising or in the magma chamber, but from mantle metasomatism.     

Comparing the performance of base map scales in GIS-based avalanche simulation: a case study from Palandöken,Turkey

Snow avalanches are very complex and dynamic events that cause serious risk to human lives, infrastructure, and facilities in mountain environments. In this study, GIS-based avalanche simulations were investigated in terms of base map scale over the simulation sensitivity. Study area consisted of the avalanche region from Sultanseki Hill to Hodaklar Hill near the Palandöken skiing site in Erzurum, eastern part of Turkey. In analysis, 1:1,000 (field surveying), 1:5,000 (orthophoto) and 1:25,000 (standard topographic maps) scaled maps were used as base maps. The avalanche simulation was constructed by Triangulated Irregular Network (TIN) extracted from the base maps by using GIS-based ELBA+ simulation model. When 1:1,000-scaled map results were taken as reference simulations at 1:25,000-scaled maps, the best results for the potential area affected by avalanche and the maximum run-out distance were provided. Besides, using 1:5,000-scaled maps showed close correlation with the maximum track width, velocity, flow height, and pressure.     

Granitic rocks as a source of granite: The Gösta and Sundsta Granites,south-west Sweden

Granites, among them three generations of microline-rich granites, intruded repeatedly between 1600 and 900 Ma in the South-western Swedish Gneiss Complex. The deformed and metamorphosed Gösta and Sundsta granites are medium-grained, pale greyish red rocks belonging to the oldest generation of microclinerich granites.Biotite dominates over hornblende. Allanite, titanite, apatite and zircon are important accessory minerals. The granites are metaluminous and syeno- to monzogranitic in composition. SiO₂ varies between 70.4 and 78.7% and K₂O/Na2_O between 0.86 and 2.32. Na and K are poorly correlated with the other major elements. The rocks are low in MgO (< 0.9%) and FeO (< 3.6%). They are characterized by high Rb/Sr, Ba/Sr and Ba/Rb ratios. The ratio Nb/Ta is almost constant ( 12) and the ratio Al/Ga decreases slightly with increasing SiO₂ content. The Gösta granite has small, negative Eu anomalies, differentiated light and almost flat heavy rare earth element patterns. It intruded into continental crust approximately 1560 Ma ago. It is argued that the granites formed from continental rocks by pseudoeutectic partial melting at a fairly shallow depth. The source is older than the dominant country rock.     

Tectonic evolution of the deep crust: Variscan reactivation by extension and thrusting of Precambrian basement in the Bragança and Morais massifs (Tras-os-Montes,NE Portugal)

Abstract

The Braganca amd Morais Massifs (NE Portugal) comprise a pile of four nappes on lop of the Autochthon of the Central-Iberian Zone : a Parautochthon (PTC), a Lower Allochthon (LATC), an Ophiolitic Complex (OTC) and an Upper Allochton (UATC). This article focuses on the tectonic evolution of the prc-Variscan basement preserved in the Upper Allochthonous Thrust Complex. (1) In the Morais Massif, the UATC is mainly composed of orthogneisscs, micaschists and high-grade melamorphic rocks restricted to a small duplex between the orthogneisses and the ophiolitic complex. The orthogneisses are pervasively deformed by D6 (Variscan D1). characterized by NNW-SSE stretching lineation, C-S structures, and sense of shear to the SSE. The high-grade melamorphic rocks show at least three ductile deformation phases older than the gneisses deformation. The micaschists and the orthogneisses are cut by mafic sills and dykes transformed into amphibolites by the Variscan tec-tonometamorphic evolution. In a restricted domain where dykes arc less deformed, two deformation events can be recognized and arc considered to be pre-Variscan. The walls of the dykes show a N-S stretching and mineral lineation interpreted as resulting from D6 (Variscan D1). (2) In the Braganca Massif, the UATC comprises mafic to ultrainafic igneous and high-grade melamorphic rocks, and paragncisses with ky-eclogite lenses. Six ductile deformation phases are recognized. The D1 to D4 events may correspond to a complete pre-Variscan orogenic cycle, from subduction (D1) to collision (D2-DS) and thrusting of the high-grade metamorphic rocks to upper levels in the crust (D3-D4); D5 may result from the Lower Palaeozoic extensional event that marks the begining of the Variscan Wilson cycle; D6 is interpreted as the first Variscan orogenic event with southward movement. The UATC of the Cabo Ortegal anil Braganca Massifs comprise mainly upper mantle/lower erustal rocks. By contrast, the UATC of the Ordenes and Morais Massifs is mainly composed of middle to upper erustal rocks. Vic propose that this is the result of a regional ductile normal fault (extensional event) that was active prior to the Variscan orogeny, in Lower Palaeozoic times, and affected a Precambrian basement.     

Polaris as a guide to northern exploration: Ore textures,paragenesis and the origin of the carbonate-hosted Polaris Zn–Pb Mine,Nunavut, Canada

The Polaris Zn–Pb Mine in Nunavut, Canada was one of the largest single Mississippi Valley-type ore deposits in the world. Over 20 Mt of sphalerite (ZnS) and galena (PbS) was hosted in brecciated carbonate rocks of the Upper Ordovician Thumb Mountain Formation. Three paragenetic stages are recognized: 1) early dolomite and marcasite; 2) main stage sulphide and dolomite; and 3) late calcite, marcasite and barite. Ore mineral textures range from discrete crystals to massive crystal aggregates and formed as replacements of the dolomite host rock or as fracture- and open space-filling mineralization. Zinc concentration is highest in the core of the deposit where botryoidal aggregates predominate, whereas iron is concentrated in the upper part. Observations of temperature and in situ sulphur isotope fractionation support a genetic model for the Polaris deposit in which thermochemical sulphate reduction occurred within the deposit, with locally generated hydrocarbons acting as a reducing agent. Information from the Polaris Mine indicates that hydrothermal alteration including dolomite, marcasite and barite; complex paragenesis with numerous ore textures; T_h values > 100 °C associated with organic-rich strata; and a geochemical signature that includes in situ sulphur fractionation are effective predictors for determining which showings are prospective in the vast central Arctic Pb–Zn district.