Scattering and anelastic attenuation of seismic energy in northern Greece

The relative contribution of scattering (Q _s ^–1 ) and intrinsic (Q _i ^–1 ) attenuation to the totalS-wave attenuation for the frequencies of 1.5, 3.0, 6.0 and 12.0 Hz has been studied by applying the radiative energy transfer theory, Data of local earthquakes which occurred in northern Greece and were recorded by the permanent telementered network of the Geophysical Laboratory of the University of Thessaloniki have been used. The results show that in this area the scattering attenuation is dominant over all frequencies while intrinsic attenuation is significantly lower. The estimatedQ _s ^–1 andQ _i ^–1 values have frequency dependences off ^–0.72 andf ^–0.45, respectively. The frequency dependence ofQ _s ^–1 is the same as that of the codaQ _c ^–1 , obtained by applying the single scattering model, which probably implies that the frequency dependence of the coda wave attenuation is attributed to the frequency dependence of the scattering attenuation.Q _c ^–1 values are very close to scattering attenuation for short lapse times, (10–20 sec), and intermediate between scattering and intrinsic attenuation for the longer lapse times, (50–100 sec). This difference is explained as the result of the depth-dependent attenuation properties and the multiple scattering effects.     

Characteristics of coda wave attenuation in Yunnan area

The characteristic of seismic coda wave attenuation in Yunnan area in 7 frequency-bands range from 1 Hz to 20 Hz was estimated by using the local earthquake's waveform data recorded from 22 Yunnan digital seismic stations.Coda attenuation Q-c1 of each station was firstly calculated by single scattering method. Then, mean free path Le and seismic albedo Bo of each station were calculated, and scattering attenuation Q-1s and intrinsic attenuation Q-1i were separated from total attenuation Q-1t by multiple lapse time window analysis based on the multiple scattering model in uniform random isotropic scattering medium. The attenuating characteristics in Yunnan show that most value of Le are in 10～30 km, with maximal within 2～6 Hz;Bo are about 0.5 at 1～2 Hz, but less than 0.5at other frequency-bands, which means Q-1i is comparable with Q-1s at 1～2 Hz, and after 1～2 Hz, Q-1i is greater than Q-1s and dominates the attenuation process. Q-1c is close to Q-1i at other frequency bands except 1～2 Hz.Results show that Q-1 especially Qs-1 varies spatially, Q-1 in eastern Yunnan zone is a bit higher than in northwestern Yunnan zone;northwestern Yunnan zone higher than southwestern Yunnan zone. Comparing with other results in global, Qs-1 in Yunnan is lower than the global average value among these results, Q-1i is higher than the global average value, and Q-1t lies the middle among these results.     

A case study of airborne and satellite remote sensing of a spring bloom event in the Gulf of Finland

The concentrations of chlorophyll-a (chl-a), total suspended solids (TSS) and the absorption coefficient of colored dissolved organic matter (a_CDOM(400)) are estimated in Case II waters using medium resolution imaging spectrometer (MERIS) satellite (full resolution [FR] level 1b, 300 m resolution) and AISA airborne spectrometer data acquired during a spring bloom in the Gulf of Finland, Baltic Sea on April 27, 2004. The accuracy of the estimation is analyzed using empirical band-ratio algorithms together with in situ observations that include water samples analyzed in a laboratory (variation ranges: 22–130 μg/l, 2.9–20 mg/l, and 1.29–2.61 m⁻¹ for chl-a, TSS and a_CDOM(400), respectively). Additional in situ estimates (transects) on these characteristics are available through absorption and scattering coefficients measured with an ac-9 absorption and attenuation meter installed in a flow-through system. The retrieval accuracy (R²) of all three water quality characteristics with MERIS data is close to or above 0.9, while the RMSE is 7.8 μg/l (22%), 0.74 mg/l (16%) and 0.08 m⁻¹ (5%), for chl-a, TSS and a_CDOM(400), respectively. The validity of the chl-a algorithm is tested using nine additional data points. The BIAS-error for these points is 5.2 μg/l and the RMSE is 10.6 μg/l. The effects of changes in the atmospheric characteristics on band-ratio algorithms in cases where no concurrent in situ reference data are available are analyzed using the MODerate spectral resolution atmospheric TRANSmittance algorithm and computer model (MODTRAN). The additional error due to these changes is estimated to be below 20% for the applied ratio algorithms. The water quality data available in the level 2 MERIS-product distributed by the European Space Agency did not include valid results for the date investigated here.     

Scattering and intrinsic attenuation in Cairo metropolitan area using genetic algorithm

A total number of 46 local earthquakes (2.0≤ML≤4.0) recorded in the period 2000–2011 by the Egyptian seismographic network (ENSN) were used to estimate the total (Q_t⁻¹), intrinsic (Q_i⁻¹) and scattering attenuation (Q_sc⁻¹) in Cairo metropolitan area, Egypt. The multiple lapse time window analysis (MLTWA) under the assumption of multiple isotropic scattering with uniform distribution of scatters was firstly applied to estimate the pair of L_e⁻¹, the extinction length inverse, and B₀, the seismic albedo, in the frequency range 3–24 Hz. To take into account the effect of a depth-dependent earth model, the obtained values of B₀ and L_e⁻¹ were corrected for an earth structure characterized by a transparent upper mantle and a heterogeneous crust. The estimated values of Q_t⁻¹, Q_sc⁻¹ and Q_i⁻¹ exhibited frequency dependences. The average frequency-dependent relationships of attenuation characteristics estimated for the region are found to be: Q_t⁻¹=(0.015±0.008)f ^{(−1.02±0.02)}, Q_sc⁻¹=(0.006±0.001)f ^{(−1.01±0.02)}, and Q_i⁻¹=(0.009±0.008)f ^{(−1.03±0.02)}; showing a predominance of intrinsic absorption over scattering attenuation. This finding implies that the pore-fluid contents may have great effect on the attenuation mechanism in the upper crust where the River Nile is passing through the study area. The obtained results are comparable with those obtained in other tectonic regions.     

Scattering attenuation and intrinsic absorption using uniform and depth dependent model – Application to full seismogram envelope recorded in Northern Chile

Two seismic wave attenuation factors, scatteringattenuation Q _s ^-1 and intrinsicabsorption Q _i ^-1 are measured using theMultiple Lapse Time Window (MLTW) analysis method forthree different frequency bands, 1–2, 2–4, and 4–8 Hz.Data from 54 temporally deployed seismic stationslocated in northern Chile are used. This methodcompares time integrated seismic wave energies withsynthetic coda wave envelopes for a multiple isotropicscattering model. In the present analysis, the waveenergy is assumed to decay with distance in proportionto1/GSF·exp(- (Q _s ^-1+Q _i ^-1)· r/v), where r, and v are the propagationdistance, angular frequency and S wave velocity,respectively, and GSF is the geometricalspreading factor. When spatial uniformity of Q _s ^-1, Q _i ^-1 and v isassumed, i.e. GSF = 4r ², theestimates of the reciprocal of the extinction length,L _e ^-1 (= (Q _s ^-1+Q _i ^-1)·/v), are 0.017,0.012 and 0.010 km^-1, and those of the seismicalbedo, B ₀ (= Q _s ^-1/ (Q _s ^-1+Q _i ^-1)), are 0.48, 0.40and 0.34 for 1–2, 2–4 and 4–8 Hz, respectively, whichindicates that scattering attenuation is comparable toor smaller than intrinsic absorption. When we assumea depth dependent velocity structure, we also findthat scattering attenuation is comparable to orsmaller than intrinsic absorption. However, since thequantitative estimates of scattering attenuationdepend on the assumed velocity structure (strength ofvelocity discontinuity and/or Moho depth), it isimportant to consider differences in velocitystructure models when comparing attenuation estimates.     

Intrinsic and Scattering Seismic Attenuation in W. Greece

—Intrinsic (Q _i ^-1) and scattering (Q _s ^-1) attenuation parameters have been determined in the seismically active region of W. Greece, which is continuously monitored by the University of Patras microearthquake network. One hundred and twenty-three local and shallow earthquakes close to the recording stations have been used and Wennerberg’s (1993) approach has been adopted. Results for 1 to 12 Hz range show that Q _i ^-1 is higher than Q _s ^-1 and coda Q values are close to Q _i ?, indicating that coda Q can be a reasonable estimate of intrinsic Q.     

Occurrence and distribution of phthalate esters in riverine sediments from the Pearl River Delta region,South China

Sixty-eight sediment samples collected from Dongjiang River, Xijiang River, Beijiang River and Zhujiang River in the Pearl River Delta (PRD) region, Southern China, were analyzed for 16 phthalate esters (PAEs). PAEs were detected in all riverine sediments analyzed, which indicate that PAEs are ubiquitous environmental contaminants. The Σ₁₆PAEs concentrations in riverine sediments in the PRD region ranged from 0.567 to 47.3 μg g⁻¹ dry weight (dw), with the mean and median concentrations of 5.34 μg g⁻¹ dw and 2.15 μg g⁻¹ dw, respectively. Elevated PAEs concentrations in riverine sediments in the PRD region were found in the highly urbanized and industrialized areas. Of the 16 PAEs, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP) and di(2-ethylhexyl) phthalate (DEHP) dominated the PAEs, with the mean and median concentrations of 1.12 μg g⁻¹ dw, 0.420 μg g⁻¹ dw and 3.72 μg g⁻¹ dw, and 0.429 μg g⁻¹ dw, 0.152 μg g⁻¹ dw and 1.55 μg g⁻¹ dw, respectively, and accounted for 94.2–99.7% of the Σ₁₆PAEs concentrations. Influenced by local sources and the properties of PAEs, a gradient trend of concentrations and a fractionation of composition from more to less industrialized and urbanized areas were discovered. As compared to the results from other studies, the riverine sediments in the PRD region were severely contaminated with PAEs. Information about PAEs contamination status and its effect on the aquatic organisms in the PRD region may deserve further attention.     

Attenuation of High Frequency P and S Waves in the Gujarat Region,India

The local earthquake waveforms recorded on broadband seismograph network of Institute of Seismological Research in Gujarat, India have been analyzed to understand the attenuation of high frequency (2–25 Hz) P and S waves in the region. The frequency dependent relationships for quality factors for P (Q _P) and S (Q _S) waves have been obtained using the spectral ratio method for three regions namely, Kachchh, Saurashtra and Mainland Gujarat. The earthquakes recorded at nine stations of Kachchh, five stations of Saurashtra and one station in mainland Gujarat have been used for this analysis. The estimated relations for average Q _P and Q _S are: Q _P = (105 ± 2) f ^{0.82 ± 0.01}, Q _S = (74 ± 2) f ^{1.06 ± 0.01} for Kachchh region; Q _P = (148 ± 2) f ^{0.92 ± 0.01}, Q _S = (149 ± 14) f ^{1.43 ± 0.05} for Saurashtra region and Q _P = (163 ± 7) f ^{0.77 ± 0.03}, Q _S = (118 ± 34) f ^{0.65 ± 0.14} for mainland Gujarat region. The low Q (<200) and high exponent of f (>0.5) as obtained from present analysis indicate the predominant seismic activities in the region. The lowest Q values obtained for the Kachchh region implies that the area is relatively more attenuative and heterogeneous than other two regions. A comparison between Q _S estimated in this study and coda Q (Qc) previously reported by others for Kachchh region shows that Q _C > Q _S for the frequency range of interest showing the enrichment of coda waves and the importance of scattering attenuation to the attenuation of S waves in the Kachchh region infested with faults and fractures. The Q _S/Q _P ratio is found to be less than 1 for Kachchh and Mainland Gujarat regions and close to unity for Saurashtra region. This reflects the difference in the geological composition of rocks in the regions. The frequency dependent relations developed in this study could be used for the estimation of earthquake source parameters as well as for simulating the strong earthquake ground motions in the region.     

Near-source attenuation of high-frequency body waves beneath the New Madrid Seismic Zone

Attenuation characteristics in the New Madrid Seismic Zone (NMSZ) are estimated from 157 local seismograph recordings out of 46 earthquakes of 2.6?≤?M?≤?4.1 with hypocentral distances up to 60 km and focal depths down to 25 km. Digital waveform seismograms were obtained from local earthquakes in the NMSZ recorded by the Center for Earthquake Research and Information (CERI) at the University of Memphis. Using the coda normalization method, we tried to determine Q values and geometrical spreading exponents at 13 center frequencies. The scatter of the data and trade-off between the geometrical spreading and the quality factor did not allow us to simultaneously derive both these parameters from inversion. Assuming 1/R ^1.0 as the geometrical spreading function in the NMSZ, the Q _P and Q _S estimates increase with increasing frequency from 354 and 426 at 4 Hz to 729 and 1091 at 24 Hz, respectively. Fitting a power law equation to the Q estimates, we found the attenuation models for the P waves and S waves in the frequency range of 4 to 24 Hz as Q _P?=?(115.80?±?1.36) f ^{(0.495?±?0.129)} and Q _S?=?(161.34?±?1.73) f ^{(0.613?±?0.067)}, respectively. We did not consider Q estimates from the coda normalization method for frequencies less than 4 Hz in the regression analysis since the decay of coda amplitude was not observed at most bandpass filtered seismograms for these frequencies. Q _S/Q _P?>?1, for 4?≤?f?≤?24 Hz as well as strong intrinsic attenuation, suggest that the crust beneath the NMSZ is partially fluid-saturated. Further, high scattering attenuation indicates the presence of a high level of small-scale heterogeneities inside the crust in this region.     

Variation of intrinsic and scattering attenuation of seismic waves with depth in the Bam region,East-Central Iran

The attenuation properties of the lithosphere in the Bam region, East-Central Iran, have been investigated. For this purpose, 42 local earthquakes having focal depths less than 25 km have been used. The quality factor of coda waves (Q_c) has been estimated using the single back-scattering model. The quality factors Q_p, Q_d (P and direct S-waves) have been estimated using the extended-coda normalization method. Q_i and Q_s (the intrinsic and scattering attenuation parameters) have been estimated for the region. The values of Q_p, Q_d, Q_c, Q_i and Q_s show a dependence on frequency in the range of 1.5–24 Hz for the Bam region. The average frequency-dependent relationships estimated for the region are Q_p=(36±6)f^(1.03±0.06), Q_d=(59±8)f^(1.00±0.03), Q_c=(79±5)f^(1.01±0.04), Q_s=(131±4)f^(1.01±0.04) and Q_i=(104±6)f^(1.01±0.05). A comparison between Q_i and Q_s shows that intrinsic absorption is predominant over scattering.The variation of Q has also been estimated at different lapse times to observe heterogeneities variation with depth. The variation of Q with frequency and lapse time shows that the lithosphere becomes more homogeneous with depth.The estimated Q_o values at different stations suggest a low value of Q indicating a heterogeneous and attenuative crust beneath the entire region.     

Selenium in sediments and biota from estuaries of southwest England

Selenium concentrations have been measured in sediment, fucoid macroalgae and macroinvertebrates from four estuaries of SW England (Yealm, Plym, Looe, Fal). Sediment concentrations ranged from about 0.4 μg g⁻¹ in the Yealm to 1.49 μg g⁻¹ at one site in the Plym. Concentrations in Fucus vesiculosus (0.05–0.31 μg g⁻¹) and F. ceranoides (0.05–0.51 μg g⁻¹) were significantly lower than corresponding concentrations in sediment but there was no correlation between algal and sediment concentrations. Selenium concentrations in Littorina littorea (∼4 μg g⁻¹), Hediste diversicolor (2.82–12.68 μg g⁻¹), Arenicola marina (∼17 μg g⁻¹) and Scrobicularia plana (1.18–6.85 μg g⁻¹) were considerably higher than concentrations in macroalga or sediment, suggesting that Se is effectively accumulated from the diet. Although Se concentrations in some invertebrates exceed toxicity thresholds for the diet of predacious birds and fish, no specific evidence for Se toxicity exists in these estuaries.     

Attenuation of P- and S-waves in the Chamoli Region, Himalaya, India

The attenuation properties of the crust in the Chamoli region of Himalaya have been examined by estimating the frequency-dependent relationships of quality factors for P waves (Q_α) and for S waves (Q_β) in the frequency range 1.5–24 Hz. The extended coda normalization method has been applied on the waveforms of 25 aftershocks of the 1999 Chamoli earthquake (M 6.4) recorded at five stations. The average value of Q_α is found to be varied from 68 at 1.5 Hz to 588 at 24 Hz while it varies from 126 at 1.5 Hz to 868 at 24 Hz for Q_β. The estimated frequency-dependent relations for quality factors are Q_α = (44 ± 1)f^(0.82±.04) and Q_β = (87 ± 3)f^(0.71±.03). The rate of increase of Q(f) for P and S waves in the Chamoli region is comparable with the other regions of the world. The ratio Q_β/Q_α is greater than one in the region which along with the frequency dependence of quality factors indicates that scattering is an important factor contributing to the attenuation of body waves in the region. A comparison of attenuation relation for S wave estimated here (Q_β = 87f^0.71) with that of coda waves (Q_c = 30f^1.21) obtained by Mandal et al. (2001) for the same region shows that Q_c > Q_β for higher frequencies (>8 Hz) in the region. This indicates a possible high frequency coda enrichment which suggests that the scattering attenuation significantly influences the attenuation of S waves at frequencies >8 Hz. This observation may be further investigated using multiple scattering models. The attenuation relations for quality factors obtained here may be used for the estimation of source parameters and near-source simulation of earthquake ground motion of the earthquakes, which in turn are required for the assessment of seismic hazard in the region.     

Estimation of the Intrinsic Absorption and Scattering Attenuation in Northeastern Venezuela (Southeastern Caribbean) Using Coda Waves

—Northeastern Venezuela has been studied in terms of coda wave attenuation using seismograms from local earthquakes recorded by a temporary short-period seismic network. The studied area has been separated into two subregions in order to investigate lateral variations in the attenuation parameters. Coda-Q ^?1 (Q _c ^?1) has been obtained using the single-scattering theory. The contribution of the intrinsic absorption (Q _i ^?1) and scattering (Q _s ^?1) to total attenuation (Q _t ^?1) has been estimated by means of a multiple lapse time window method, based on the hypothesis of multiple isotropic scattering with uniform distribution of scatterers. Results show significant spatial variations of attenuation the estimates for intermediate depth events and for shallow events present major differences. This fact may be related to different tectonic characteristics that may be due to the presence of the Lesser Antilles subduction zone, because the intermediate depth seismic zone may be coincident with the southern continuation of the subducting slab under the arc.     

Mixed memory, (non) Hurst effect, and maximum entropy of rainfall in the tropical Andes

Diverse linear and nonlinear statistical parameters of rainfall under aggregation in time and the kind of temporal memory are investigated. Data sets from the Andes of Colombia at different resolutions (15 min and 1-h), and record lengths (21 months and 8-40 years) are used. A mixture of two timescales is found in the autocorrelation and autoinformation functions, with short-term memory holding for time lags less than 15-30 min, and long-term memory onwards. Consistently, rainfall variance exhibits different temporal scaling regimes separated at 15-30 min and 24 h. Tests for the Hurst effect evidence the frailty of the R/S approach in discerning the kind of memory in high resolution rainfall, whereas rigorous statistical tests for short-memory processes do reject the existence of the Hurst effect.Rainfall information entropy grows as a power law of aggregation time, S(T) ∼ T^β with 〈β〉 = 0.51, up to a timescale, T_MaxEnt (70-202 h), at which entropy saturates, with β = 0 onwards. Maximum entropy is reached through a dynamic Generalized Pareto distribution, consistently with the maximum information-entropy principle for heavy-tailed random variables, and with its asymptotically infinitely divisible property. The dynamics towards the limit distribution is quantified. Tsallis q-entropies also exhibit power laws with T, such that S_q(T) ∼ T^β(q), with β(q) ? 0 for q ? 0, and β(q) ? 0.5 for q ? 1. No clear patterns are found in the geographic distribution within and among the statistical parameters studied, confirming the strong variability of tropical Andean rainfall.     

Lead in blood and eggs of the sea turtle, Lepidochelys olivacea, from the Eastern Pacific: Concentration, isotopic composition and maternal transfer

Concentrations of lead were assessed in the sea turtle, Lepidochelys olivacea, from a nesting colony of the Eastern Pacific. Twenty-five female turtles were sampled and a total of 250 eggs were collected during the “arribada” event of the 2005-2006 season. Considering the nesting season, the maternal transfer of lead (Pb) via egg-laying, in terms of metal burden in whole body, was 0.5%. Pb concentrations (in dry weight) in blood (0.95 ± 0.18 μg g⁻¹) and egg samples (yolk, 0.80 ± 0.10 μg g⁻¹; albumen, 1.08 ± 0.20 μg g⁻¹; eggshell, 1.05 ± 0.20 μg g⁻¹) were comparable or even lower than those found in other sea turtles. The isotope ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁸Pb) in blood (1.183 ± 0.0006 and 2.452 ± 0.0006, respectively) were comparable to that of natural Pb-bearing bedrock in Mexico (1.188 ± 0.005 and 2.455 ± 0.008, respectively). According to international norms of Pb, the health of this population and its habitats is acceptable for Pb and corresponds to basic levels of a nearly pristine environment.     

Unified approach to amplitude attenuation and coda excitation in the randomly inhomogeneous lithosphere

A unified model is proposed for explaining the frequency dependent amplitude attenuation and the coda wave excitation on the basis of the single scattering process in the randomly inhomogeneous lithosphere. Adopting Birch's law and a direct proportion between density and wave velocity, we statistically describe the inhomogeneous medium by one random function characterized by the von Karman autocorrelation function. We calculate the amplitude attenuation from the solid angle integral of scattered wave energy on the basis of the Born approxiimation after subtracting the travel-time fluctuation effect caused by slowly varying velocity inhomogeneities. This subtraction is equivalent to neglect energy loss by scattering within a cone around the forward direction. The random inhomogeneity of the von Karman autocorrelation function of order 0.35 with the mean square fractional fluctuation of 7.2×10^–3 1.3×10^–2 and the correlation distance of 2.15.1 km well explains observed backward scattering coefficientg and the ratioQ _P ^–1 /Q _S ^–1 , and observed and partially conjecturedQ _S ^–1 for frequencies between 0.5 Hz and 30 Hz.     

Monosulfidic black ooze accumulations in sediments of the Geographe Bay area, Western Australia

Mobilisation of sedimentary monosulfidic black ooze (MBO) may result in rapid deoxygenation and acidification of surface waters, and release of potentially toxic metals. This study examines the extent and nature of MBO accumulation in the Geographe Bay area, Western Australia. MBO accumulations were found to be widespread in benthic sediments of the Geographe Bay area with acid-volatile sulfide (AVS) contents as high as 320 μmol g⁻¹. The MBO materials often had unusually high dissolved sulfide (S^−II) concentrations in their pore-waters (up to 610 mg L⁻¹) and elevated elemental sulfur (S⁰) contents (up to 51 μmol g⁻¹). Dissolved S^−II is able to accumulate due to limited iron availability and S⁰ is largely its partial oxidation product. The availability of organic carbon and Fe limited MBO accumulation at many sites. A comparison of AVS and simultaneously extracted metal (SEM) concentrations has shown that metals are likely to be bound in sulfide complexes.     

Spatial variability in organic material sinking export in the Hudson Bay system,Canada, during fall

Spatial variations in the sinking export of organic material were assessed within the Hudson Bay system (i.e., Hudson Bay, Hudson Strait and Foxe Basin) during the second oceanographic expedition of ArcticNet, on board the CCGS Amundsen in early fall 2005. Sinking fluxes of particulate organic material were measured using short-term free-drifting particle interceptor traps deployed at 50, 100 and 150 m for 8–20 h at eight stations. Measurements of chlorophyll a (chl a), pheopigments (pheo), particulate organic carbon (POC), biogenic silica (BioSi), protists, fecal pellets and bacteria were performed on the collected material. In parallel, sea surface salinity and temperature were determined at 121 stations in the Hudson Bay system. Three hydrographic regions presenting different sedimentation patterns were identified based on average surface salinity and temperature. Hudson Strait was characterized by a marine signature, with high salinity (average=32.3) and low temperature (average=2.1 °C). Eastern Hudson Bay was strongly influenced by river runoff and showed the lowest average salinity (26.6) and highest average temperature (7.6 °C) of the three regions. Western Hudson Bay showed intermediate salinity (average=29.4) and temperature (average=4.4 °C). Sinking fluxes of total pigments (chl a+pheo: 3.37 mg m⁻² d⁻¹), diatom-associated carbon (19.8 mg m⁻² d⁻¹) and BioSi (50.2 mg m⁻² d⁻¹) at 50 m were highest in Hudson Strait. Eastern Hudson Bay showed higher sinking fluxes of total pigments (0.52 mg m⁻² d⁻¹), diatom-associated carbon (3.29 mg m⁻² d⁻¹) and BioSi (36.6 mg m⁻² d⁻¹) compared to western Hudson Bay (0.19, 0.05 and 7.76 mg m⁻² d⁻¹, respectively). POC sinking fluxes at 50 m were low and relatively uniform throughout the Hudson Bay system (50.0–76.8 mg C m⁻² d⁻¹), but spatial variations in the composition of the sinking organic material were observed. A large part (37–78%) of the total sinking POC was unidentifiable by microscopic observation and was qualified as amorphous detritus. Considering only the identifiable material, the major contributors to the POC sinking flux were intact protist cells in Hudson Strait (28%), fecal pellets in eastern Hudson Bay (52%) and bacteria in western Hudson Bay (17%). A significant depth-related attenuation of the POC sinking fluxes (average loss between 50 and 150 m=32%) and a significant increase in the BioSi:POC ratio (average increase between 50 and 150 m=76%) were observed in Hudson Strait and eastern Hudson Bay. For all other sinking fluxes and composition ratios, we found no statistically significant difference with depth. These results show that during fall, the sinking export of total POC from the euphotic zone remained fairly constant throughout the Hudson Bay system, whereas other components of the organic sinking material (e.g., chl a, BioSi, fecal pellets, protist cells) showed strong spatial variations.     

Levels of persistent organic pollutants and residual pattern of DDTs in small cetaceans from the coast of São Paulo, Brazil

The State of São Paulo is the most developed area in Brazil and was impacted by persistent organic pollutants for several decades. This study investigated organochlorines in five species of small cetaceans (Pontoporia blainvillei, Stenella frontalis, Sotalia guianensis, Tursiops truncatus and Steno bredanensis) found dead along the coast of São Paulo between 1997 and 2003. DDTs (15.9 μg g⁻¹ lipid; mean for all pooled individuals) and PCBs (8.08 μg g⁻¹) exhibited the highest concentrations in the animals, reflecting large amounts formerly used in Brazil. Lower levels of mirex (0.149 μg g⁻¹), HCB (0.051 μg g⁻¹), CHLs (0.008 μg g⁻¹) and HCHs (0.007 μg g⁻¹) were detected in all species. Residual pattern of DDTs in dolphins suggests that o,p′-DDT is more recalcitrant than p,p′-DDT in the body of the animals and/or the environment. In contrast to p,p′-DDT, residues of o,p′-DDT seem to be preferentially converted into o,p′-DDD rather than o,p′-DDE.