Polycyclic aromatic hydrocarbons in the atmospheres of Titan and Jupiter

Polycyclic aromatic hydrocarbons (PAHs) are important components of the interstellar medium and carbonaceous chondrites, but have never been identified in the reducing atmospheres of the outer solar system. Incompletely characterized complex organic solids (tholins) produced by irradiating simulated Titan atmospheres reproduce well the observed UV/visible/IR optical constants of the Titan stratospheric haze. Titan tholin and a tholin generated in a crude simulation of the atmosphere of Jupiter are examined by two-step laser desorption/multiphoton ionization mass spectrometry. A range of two- to four-ring PAHs, some with one to four alkylation sites are identified, with net abundance approximately 10(-4) g g-1 (grams per gram) of tholins produced. Synchronous fluorescence techniques confirm this detection. Titan tholins have proportionately more one- and two-ring PAHs than do Jupiter tholins, which in turn have more four-ring and larger PAHs. The four-ringed PAH chrysene, prominent in some discussions of interstellar grains, is found in Jupiter tholins. Solid state 13C NMR spectroscopy suggests approximately equal to 25% of the total C in both tholins is tied up in aromatic and/or aliphatic alkenes. IR spectra indicate an upper limit in both tholins of approximately equal to 6% by mass in benzenes, heterocyclics, and PAHs with more than four rings. Condensed PAHs may contribute at most approximately 10% to the observed detached limb haze layers on Titan. As with interstellar PAHs, the synthesis route of planetary PAHs is likely to be via acetylene addition reactions.     

Models of Jupiter and Saturn after Galileo mission

New models of Jupiter are based on observational data provided by the Galileo spaceprobe, which considerably improved previously existing estimates of the helium abundance in the atmosphere of Jupiter. These data yield for Jupiter’s atmosphere 20% of the solar oxygen abundance and do not agree with the results of the analysis of the collision of comet Shoemaker-Levy 9 with Jupiter (10 times the solar value). Therefore, both the models of Jupiter with water-depleted and water-enriched atmosphere are considered. By analogy with Jupiter, trial models of Saturn with a water-depleted external envelope are also developed. The molecular-metallic phase transition pressure of hydrogen P_m was taken to be 1.5, 2 and 3 Mbar. Since Saturn’s internal molecular envelope is noticeably enriched in the IR-component (its weight concentration, 0.25–0.30, being by a factor of 3–4 higher than in Jupiter), the phase transition pressure in Saturn can be lower than in Jupiter. In the constructed models, the IR-core masses are 3–3.5 M_⊕ for Jupiter and 3–5.5 M_⊕ for Saturn. Jupiter’s and Saturn’s IR-cores can be considered embryos onto which the accretion of the gas occurred during the formation of the planets. The mass of the hydrogen–helium component dispersed in the zone of planetary formation constitutes ≈2–5 planetary masses for Jupiter and ≈11–14 planetary masses for Saturn.     

Search for HD in Jupiter and Saturn

Upper limits are placed on the D/H ratio in the observed portions of the atmospheres of Jupiter and Saturn from observations at high S/N over the region of the 5-0 R(1) line of HD. The upper limits of 4 × 10^?5 and 6 × 10^?5 D/H on Jupiter and Saturn, respectively, are not inconsistent with present models for abundance ratios in the primitive solar nebula or with other estimates of this quantity from observations.     

Comparative evolution of Jupiter and Saturn

We present evolutionary sequences for Jupiter and Saturn, based on new non-gray model atmospheres, which take into account the evolution of the solar luminosity and partitioning of dense components to deeper layers. The results are used to set limits on the extent to which possible interior phase separation of hydrogen and helium may have progressed in the two planets. When combined with static models constrained by the gravity field, our evolutionary calculations constrain the helium mass fraction in Jupiter to be between 0.20 and 0.27, relative to total hydrogen and helium. This is consistent with the Galileo determination. The helium mass fraction in Saturn’s atmosphere lies between 0.11 and 0.21, higher than the Voyager determination. Based on the discrepancy between the Galileo and Voyager results for Jupiter, and our models, we predict that revised observational results for Saturn will yield a higher atmospheric helium mass fraction relative to the Voyager value.     

Spectra of simulated lightning on Venus,Jupiter, and Titan

Laser-induced plasmas in various gas mixtures were used to simulate lightning in other planetary atmospheres. This method of simulation has the advantage of producing short-duration, high-temperature plasmas free from electrode contamination. The laser-induced plasma discharges in air are shown to accurately simulate terrestrial lightning and can be expected to simulate lightning spectra in other planetary atmospheres. Spectra from 240 to 880 nm are presented for simulated lightning in the atmospheres of Venus, Earth, Jupiter, and Titan. The spectra of lightning on the other giant planets are expected to be similar to that of Jupiter because the atmospheres of these planets are composed mainly of hydrogen and helium. The spectra of Venus and Titan show substantial amounts of radiation due to the presence of carbon atoms and ions and show CN Violet radiation. Although small amounts of CH₄ and NH₃ are present in the Jovian atmosphere, only emission from hydrogen and helium is observed. Most differences in the spectra can be understood in terms of the elemental ratios of the gas mixtures. Consequently, observations of the spectra of lightning on other planets should provide in situ estimates of the atmospheric and aerosol composition in the cloud layers in which lightning is occuring. In particular, the detection of inert gases such as helium should be possible and the relative abundance of these gases compared to major constituents might be determined.     

The international outer planets watch atmospheres node database of giant-planet images

The Atmospheres Node of the International Outer Planets Watch (IOPW, formerly known as International Jupiter Watch; Russell et al., 1990) intends to encourage and coordinate the imaging observations and study of the atmospheres of the Giant Planets. The main activity of the atmospheres node is to provide an interaction between the professional and amateur astronomical communities maintaining a large database of images of the giant planets (primarily Jupiter and Saturn but with increasing contributions of Uranus and Neptune too). The observational datasets of Jupiter and Saturn correspond to images obtained in the visible range (300 nm-1 μm), during the last decade, most of them performed by amateur observers. We here describe the organization and structure of the database as posted on the Internet and in particular the PVOL software (Planetary Virtual Observatory Laboratory) designed to manage the site in the spirit of the Virtual Observatory projects. We also describe with examples the important role of the amateur-professional collaboration in the study of the atmospheres of Jupiter and Saturn in an epoch of large telescopes and spacecraft observations of both planets.     

Accretion disks around Jupiter and Saturn at the stage of regular satellite formation

Modern models of the formation of the regular satellites of giant planets, constructed with consideration for their structure and composition suggest that this process lasted for a considerable period of time (0.1–1 Myr) and developed in gas-dust circumplanetary disks at the final stage of giant planet formation. The parameters of protosatellite disks (e.g., the radial distribution of surface density and temperature) serve as important initial conditions for such models. Therefore, the development of protosatellite disk models that take into account currently known cosmochemical and physical restrictions remains a pressing problem. It is this problem that is solved in the paper. New models of the accretion disks of Jupiter and Saturn were constructed with consideration for the disk heating by viscous dissipation of turbulent motions, by accretion of material from the surrounding region of the solar nebula, and by radiation from the central planets. The influence of a set of input model parameters (the total rate of mass infall onto the disk, the turbulent viscosity and opacity of disk material, and the centrifugal radius of the disk) on thermal conditions in the accretion disks was studied. The dependence of opacity on temperature and the abundance and size of solid particles present in the disk was taken into account. Those constructed models that satisfy the existing constraints limit the probable values of input parameters (primarily rates of mass infall onto the disks of Jupiter and Saturn at the stage of regular satellite formation and, to a lesser extent, the disk opacities). Constraints on the location of the regions of formation of the major satellites of Jupiter and Saturn are suggested based on the constructed models and simple analytical estimates concerning the formation of satellites in the accretion disks. It is shown that Callisto and Titan could hardly be formed at significantly greater distances from their planets.     

New determination of monochromatic methane absorption coefficients with regard to the thermal conditions in the atmospheres of giant planets. IV. Jupiter and Saturn

Based on the data on the wavelength dependence of geometrical albedo for the disks of Jupiter and Saturn, we determined the trends in the height variation of the aerosol optical depth in the upper atmospheric layers of these planets, the fractional methane concentration in the Jovian atmosphere (0.00125), and the monochromatic methane absorption coefficients (or the superposition of these coefficients for methane and ammonia) typical of the thermal conditions in the atmospheres of Jupiter and Saturn in the wavelength range from 527 to 956 nm.     

The spatial distribution of long lived gas clouds emitted by satellites in the outer solar system

Simple models are presented for the spatial distribution of gases emitted by satellites in the outer solar system with emphasis on Io and Titan. The models, valid for long lived species in regions of space outside the gravitational zone of the parent satellite are applied to observed hydrogen and sodium clouds orbiting Jupiter and to an expected hydrogen cloud around Saturn.     

A comparison of the atmospheres of Jupiter and Saturn: deep atmospheric composition, cloud structure, vertical mixing, and origin.

We present our current understanding of the composition, vertical mixing, cloud structure and the origin of the atmospheres of Jupiter and Saturn. Available observations point to a much more vigorous vertical mixing in Saturn's middle-upper atmosphere than in Jupiter's. The nearly cloud-free nature of the Galileo probe entry site, a 5-micron hotspot, is consistent with the depletion of condensable volatiles to great depths, which is attributed to local meteorology. Somewhat similar depletion of water may be present in the 5-micron bright regions of Saturn also. The supersolar abundances of heavy elements, particularly C and S in Jupiter's atmosphere and C in Saturn's, as well as the progressive increase of C from Jupiter to Saturn and beyond, tend to support the icy planetesimal model of the formation of the giant planets and their atmospheres. However, much work remains to be done, especially in the area of laboratory studies, including identification of possible new microwave absorbers, and modelling, in order to resolve the controversy surrounding the large discrepancy between Jupiter's global ammonia abundance, hence the nitrogen elemental ratio, derived from the earth-based microwave observations and that inferred from the analysis of the Galileo probe-orbiter radio attenuation data for the hotspot. We look forward to the observations from Cassini-Huygens spacecraft which are expected to result not only in a rich harvest of information for Saturn, but a better understanding of the formation of the giant planets and their atmospheres when these data are combined with those that exist for Jupiter.     

A comparison of the interiors of Jupiter and Saturn

Interior models of Jupiter and Saturn are calculated and compared in the framework of the three-layer assumption, which rely on the perception that both planets consist of three globally homogeneous regions: a dense core, a metallic hydrogen envelope, and a molecular hydrogen envelope. Within this framework, constraints on the core mass and abundance of heavy elements (i.e. elements other than hydrogen and helium) are given by accounting for uncertainties on the measured gravitational moments, surface temperature, surface helium abundance, and on the inferred protosolar helium abundance, equations of state, temperature profile and solid/differential interior rotation. Results obtained solely from static models matching the measured gravitational fields indicate that the mass of Jupiter’s dense core is less than 14 M_⊕ (Earth masses), but that models with no core are possible given the current uncertainties on the hydrogen–helium equation of state. Similarly, Saturn’s core mass is less than 22 M_⊕ but no lower limit can be inferred. The total mass of heavy elements (including that in the core) is constrained to lie between 11 and 42 M_⊕ in Jupiter, and between 19 and 31 M_⊕ in Saturn. The enrichment in heavy elements of their molecular envelopes is 1–6.5, and 0.5–12 times the solar value, respectively. Additional constraints from evolution models accounting for the progressive differentiation of helium (Hubbard WB, Guillot T, Marley MS, Burrows A, Lunine JI, Saumon D, 1999. Comparative evolution of Jupiter and Saturn. Planet. Space Sci. 47, 1175–1182) are used to obtain tighter, albeit less robust, constraints. The resulting core masses are then expected to be in the range 0–10 M_⊕, and 6–17 M_⊕ for Jupiter and Saturn, respectively. Furthermore, it is shown that Saturn’s atmospheric helium mass mixing ratio, as derived from Voyager, Y=0.06±0.05, is probably too low. Static and evolution models favor a value of Y=0.11−0.25. Using, Y=0.16±0.05, Saturn’s molecular region is found to be enriched in heavy elements by 3.5 to 10 times the solar value, in relatively good agreement with the measured methane abundance. Finally, in all cases, the gravitational moment J₆ of models matching all the constraints are found to lie between 0.35 and 0.38×10⁻⁴ for Jupiter, and between 0.90 and 0.98×10⁻⁴ for Saturn, assuming solid rotation. For comparison, the uncertainties on the measured J₆ are about 10 times larger. More accurate measurements of J₆ (as expected from the Cassini orbiter for Saturn) will therefore permit to test the validity of interior models calculations and the magnitude of differential rotation in the planetary interior.     

Jupiter and Saturn: Near-infrared spectral albedos

The near-infrared (0.65–2.5μm) spectral albedo of Jupiter and Saturn with 1.5% spectral resolution is presented for the center of disk and for the limb. There is a distinct difference in the continuum slope between Jupiter and Saturn which may be attributed to a difference in the dust content or composition of the two atmospheres. There is an indication of limb brightening in the deepest CH₄ bands on Saturn. No limb brightening is found for Jupiter.     

Eddy mixing coefficient on Saturn

Data on the composition and thermal structure, and the Lyman-alpha dayglow of Saturn when analyzed in conjunction with photochemical models of the hydrocarbons and the atomic hydrogen production yield the homopause value of the eddy diffusion coefficient to be approximately 10⁸ cm² s^?1. The equatorial value of the eddy diffusion coefficient at the homopause of Saturn is thus found to be approximately 100 times greater than on Jupiter. The mesosphere (and presumably, troposphere) of Saturn appears to be considerably more turbulent than the upper atmosphere of Jupiter.     

Phosphine on Jupiter and Saturn from Cassini/CIRS

The global distribution of phosphine (PH₃) on Jupiter and Saturn is derived using 2.5 cm⁻¹ spectral resolution Cassini/CIRS observations. We extend the preliminary PH₃ analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH₃ at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH₃ shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH₃ abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH₃ distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH₃, permitting elevated PH₃ levels over Saturn's summer hemisphere.     

The structure of the planets Jupiter and Saturn

Planetary models for Jupiter and Saturn are computed using a fourth-order theory and a new molecular equation of state. The equation of state for the molecular hydrogen and helium planetary envelopes is taken from the Monte Carlo calculations of Slattery and Hubbard [Icarus 29, 187–192 (1976)]. Models for Jupiter are found that have a small amount of heavy elements either mixed with hydrogen and helium throughout the interior of the planet or concentrated in a small dense core. Saturn is modeled with a solar-composition hydrogen and helium envelope and a small derse core. We conclude that the molecular equation of state linked with suitable interior equations of state can produce Jovian models which satisfy the observational data. The planetary models show that the enrichment of heavy elements (relative to solar composition) is approximately 3 times for Jupiter and 10 times for Saturn.     

The abundances of ammonia in the atmospheres of Jupiter,Saturn, and Titan

An investigation of low-resolution ratio spectra of Jupiter, Saturn, and Titan in the region 5400–6500 Å has permitted new evaluations of ammonia absorption bands. The distribution of ammonia over the disk of Jupiter is very inhomogeneous. The carbon-to-nitrogen ratio is distinctly different from the solar value, but this is probably a result of uneven mixing of methane and ammonia, as suggested previously by Kuiper, rather than a compositional anomaly. The abundance of ammonia on Saturn also shows spatial variations, but appears constant in time over a 3-yr period. Two weak, unidentified absorptions were discovered in the red region of Titan's spectrum, in the absence of any detectable ammonia. The new upper limit is ηN < 120 cm-am.     

Mass-radius relationships in icy satellites after voyager

Using improved data for the masses and radii of the satellites of Jupiter and Saturn, models accounting for self-compression effects are presented for the interiors of Europa, Ganymede, Callisto, Rhea, and Titan. For the differentiated models, two different possible scenarios for heat transport are treated, as well as two different compositions for the silicate component. Undifferentiated models are also treated. In each case, the models of Ganymede, Callisto, and Titan show noticeable similarities. It is found that estimates of the ice-rock ratio are dependent upon the assumptions made about the heat transport mechanisms, the rock composition, and on the distribution of rock and ice in the satellite's interior.     

Mass spectrometric analysis in planetary science: Investigation of the surface and the atmosphere

Knowing the chemical, elemental, and isotopic composition of planetary objects allows the study of their origin and evolution within the context of our Solar System. Landed probes are critical to such an investigation. Instruments on a landed platform can answer a different set of scientific questions than can instruments in orbit or on Earth. Composition studies for elemental, isotopic, and chemical analysis are best performed with dedicated mass spectrometer systems. Mass spectrometers have been part of the early lunar missions, and have been successfully employed to investigate the atmospheres of Mars, Venus, Jupiter, Saturn, Titan, and in comet missions. Improved mass spectrometer systems are foreseen for many planetary missions currently in planning or implementation.     

Constraints on deep-seated zonal winds inside Jupiter and Saturn

The atmospheres of Jupiter and Saturn exhibit strong and stable zonal winds. How deep the winds penetrate unabated into each planet is unknown. Our investigation favors shallow winds. It consists of two parts. The first part makes use of an Ohmic constraint; Ohmic dissipation associated with the planet's magnetic field cannot exceed the planet's net luminosity. Application to Jupiter (J) and Saturn (S) shows that the observed zonal winds cannot penetrate below a depth at which the electrical conductivity is about six orders of magnitude smaller than its value at the molecular-metallic transition. Measured values of the electrical conductivity of molecular hydrogen yield radii of maximum penetration of 0.96RJ and 0.86RS, with uncertainties of a few percent of R. At these radii, the magnetic Reynolds number based on the zonal wind velocity and the scale height of the magnetic diffusivity is of order unity. These limits are insensitive to difficulties in modeling turbulent convection. They permit complete penetration along cylinders of the equatorial jets observed in the atmospheres of Jupiter and Saturn. The second part investigates how deep the observed zonal winds actually do penetrate. As it applies heuristic models of turbulent convection, its conclusions must be regarded as tentative. Truncation of the winds in the planet's convective envelope would involve breaking the Taylor-Proudman constraint on cylindrical flow. This would require a suitable nonpotential acceleration which none of the obvious candidates appears able to provide. Accelerations arising from entropy gradients, magnetic stresses, and Reynolds stresses appear to be much too weak. These considerations suggest that strong zonal winds are confined to shallow, stably stratified layers, with equatorial jets being the possible exception.     

For infrared spectrophotometry of Jupiter and Saturn

Infrared spectral observations of Mars, Jupiter, and Saturn were made from 100 to 470 cm^?1 using NASA's G. P. Kuiper Airborne Observatory. Taking Mars as a calibration source, we determined brightness temperatures of Jupiter and Saturn with approximately 5 cm^?1 resolution. The data are used to determine the internal luminosities of the giant planets, for which more than 75% of the thermally emitted power is estimated to be in the measured bandpass: for Jupiter L_J = (8.0 ± 2.0) × 10^?10L_⊙ and for Saturn L_S = (3.6 ± 0.9) × 10^?10. The ratio R of thermally emitted power to solar power absorbed was estimated to be R_J = 1.6 ± 0.2, and R_S = 2.7 ± 0.8 from the observations when both planets were near perihelion. The Jupiter spectrum clearly shows the presence of the rotational ammonia transitions which strongly influence the opacity at frequencies ?250 cm^?1. Comparison of the data with spectra predicted from current models of Jupiter and Saturn permits inferences regarding the structure of the planetary atmospheres below the temperature inversion. In particular, an opacity source in addition to gaseous hydrogen and ammonia, such as ammonia ice crystals as suggested by Orton, may be necessary to explain the observed Jupiter spectrum in the vicinity of 250 cm^?1.