喜马拉雅碰撞造山带新生代地壳深熔作用与淡色花岗岩

自从印度-欧亚大陆碰撞以来,伴随着构造演化和温度-压力-成分(P-T-X)的变化,喜马拉雅造山带中下地壳变质岩发生不同类型的部分熔融反应,形成性质各异的过铝质花岗岩。这些花岗岩在形成时代、矿物组成、全岩元素和放射性同位素地球化学特征上都表现出巨大的差异性。始新世构造岩浆作用形成高Sr/Y二云母花岗岩和演化程度较高的淡色花岗岩和淡色花岗玢岩,它们具有相似的Sr-Nd同位素组成,是碰撞早期增厚下地壳部分熔融的产物。渐新世淡色花岗岩主要为演化程度较高的淡色花岗岩,可能指示了喜马拉雅造山带的快速剥露作用起始于渐新世。早中新世以来的淡色花岗岩是喜马拉雅造山带淡色花岗岩的主体,是变泥质岩部分熔融的产物,包含两类部分熔融作用——水致白云母部分熔融作用(A类)和白云母脱水熔融作用(B类)。这两类部分熔融作用形成的花岗质熔体在元素和同位素地球化学特征上都表现出明显的差异性,主要受控于两类部分熔融作用过程中主要造岩矿物和副矿物的溶解行为。这些不同期次的地壳深熔作用都伴随着高分异淡色花岗岩,伴随着关键金属元素(Nb、Ta、Sn、Be等)的富集,是未来矿产勘探的重要靶区。新的观测结果表明:在碰撞造山带中,花岗岩岩石学和地球化学性质的变化是深部地壳物质对构造过程响应的结果,是深入理解碰撞造山带深部地壳物理和化学行为的重要岩石探针。     

两种主要过铝质花岗岩类的成因

二云母二长花岗岩到淡色花岗岩和富黑云母、含堇青石的英云闪长岩到二长花岗岩是两种不同的过铝质花岗岩类。它们可根据矿物、岩石组合及其在分异过程中过铝度的变化来加以区分。除极少数含白云母花岗岩类是由准铝质岩浆强烈分异或局部混染形成的外，大多数过铝质花岗岩类是由地壳岩石部分熔融所形成的。含白云母的花岗岩或富黑云母、含堇青石的花岗岩类的形成，不只取决于源区的性质，还受部分熔融的物理条件控制，其次采增厚地壳的     

东天山哈尔里克地区晚石炭世淡色花岗岩成因及其地质意义

淡色花岗岩对深入理解造山带构造演化具有重要意义.哈尔里克山南麓小铺地区出露多种类型的淡色花岗岩脉,包括黑云母花岗岩、二云母花岗岩、含电气石花岗岩以及含石榴石花岗岩.岩石地球化学研究显示这些淡色花岗岩整体具有高硅（SiO₂=73.22%~75.12%）、铝（Al₂O₃=13.59%~14.49%）、碱（ALK=7.11%~9.67%）,低钛（TiO₂=0.01%~0.14%）、铁（TFeO=0.26%~1.37%）、镁（MgO=0.09%~0.46%）、钙（CaO=0.46%~1.92%）的特点,属于弱过铝质钙碱性-钾玄岩系列岩石.其中黑云母花岗岩具有较高的CaO/Na₂O比值（0.46~0.47）和低的Rb/Sr比值（0.31~0.33）,指示其为砂质源岩经黑云母脱水熔融形成;二云母花岗岩和含电气石花岗岩具有较低的CaO/Na₂O比值（0.11~0.31）和高的Rb/Sr比值（1.41~3.75）,为泥质源岩经白云母脱水熔融形成;含石榴石花岗岩具有强烈的Eu负异常以及"海鸥状"稀土配分模式,为高分异型花岗岩.小铺淡色花岗岩初始岩浆温度较低（T=637~744℃）,结合其野外地质特征,认为其形成可能与深部物质的折返、造山带的伸展垮塌有关.利用LA-ICP-MS微区原位锆石U-Pb定年获得黑云母花岗岩的形成时代为308.5±2.2 Ma,含电气石花岗岩的形成时代为307.8±2.3 Ma,二者在误差范围内近乎一致,指示哈尔里克地区在晚石炭世末处于伸展构造背景.      

内蒙古乌拉特中旗乌兰地区含石榴石花岗岩锆石U-Pb年龄及地质意义

对乌拉特中旗乌兰地区含石榴石花岗岩进行了同位素地质年代学和岩石地球化学研究,探讨了其形成时代和构造背景。利用锆石SHRIMP U-Pb法测得含石榴石花岗岩岩体的年龄为（256.4±2.2） Ma,表明其形成于晚二叠世;岩石地球化学特征显示属弱过铝质I型花岗岩,物源主要为上陆壳硬砂岩,形成于后碰撞构造环境,源区岩浆部分熔融程度较低,可能是由I型花岗质流体与岩浆演化后期热液流体反应而分异结晶形成的。根据含石榴石花岗岩产出的大地构造位置、形成环境及侵位时代,推断研究区内华北板块北缘与西伯利亚板块南缘的碰撞缝合时间上限早于256.4 Ma。     

淡色花岗岩的岩石学和地球化学特征及其成因

淡色花岗岩(leucogranite)是一类高铝高硅碱的酸性侵入岩,主要地球化学特征是:SiO2≥72%,Al2O3≥14%,Na2O+K2O~8.5%,富Rb,亏损Th、Ba、Sr,稀土总量较一般花岗岩低(∑REE=(40~120)×10-6),且表现为中等分异的轻稀土弱富集型,一般具有Eu负异常;Sr-Nd-Pb-O同位素指示其岩浆明显的陆壳来源。淡色花岗岩主要发育于陆壳(俯冲)碰撞加厚带,由逆冲折返的俯冲板片变沉积岩部分经过脱水熔融产生。淡色花岗岩可划分为三种不同的岩石类型:(1)二云母型淡色花岗岩,由变泥质岩(或变硬砂岩)在中地壳水平经黑云母(和/或白云母)脱水熔融产生;(2)电气石型淡色花岗岩,由变泥质岩在较低温度下经白云母脱水熔融产生;(3)石榴子石型淡色花岗岩,由长英质下地壳经黑云母脱水熔融产生。源区残留独居石、磷灰石等富REE矿物是淡色花岗岩亏损REE、Th等元素的原因。源岩为变泥质岩及源区残留钾长石是淡色花岗岩亏损Sr、Ba的主要原因。     

藏南东部麻玛沟地区早古生代与中新世岩浆作用及其意义

喜马拉雅造山带东部错那县麻玛沟地区发育多种类型的花岗片麻岩和淡色花岗岩。锆石SHRIMP U-Pb地质年代学研究结果表明：花岗片麻岩（MM15）原岩结晶年龄为500.7±4.5Ma,含石榴子石淡色花岗岩中携带的继承性核部锆石年龄为498.6±3.4Ma,表明该地区经历了早古生代的岩浆作用事件。淡色花岗岩的结晶年龄区间为15.7~25.1Ma之间,为白云母脱水熔融的产物,可能是晚元古代-早古生代花岗质岩石发生低程度部分熔融的结果。锆石形态学表明该区的花岗片麻岩和淡色花岗岩均为过铝质花岗岩,并相对富集Cs、Rb、U、Pb,亏损Zr、Hf和低Nb/Ta比值,属于造山型花岗岩,支持该区域古生代岩浆作用事件与俯冲-碰撞造山作用相关,不是被动大陆边缘构造背景。结合前人数据推断：（1）从晚元古代末期开始,原特提斯洋向印度大陆的初始俯冲为自东向西的俯冲扩展模式;和（2）喜马拉雅造山带中新世淡色花岗岩为白云母脱水熔融和水致白云母熔融共同作用的结果,岩浆活动至少存在五个相。     

喜马拉雅造山带新生代花岗岩中两类石榴石的地球化学特征及其在地壳深熔作用中的意义

在喜马拉雅碰撞造山带中,石榴石是变泥质岩的主要造岩矿物,也是花岗岩或淡色体的重要副矿物,保存了有关地壳深熔作用的关键信息,是揭示大型碰撞造山带中-下地壳物质的物理和化学行为的重要载体。在喜马拉雅造山带内,新生代花岗质岩石(淡色花岗岩和混合岩中的淡色体)含两类石榴石,大多数为岩浆型石榴石,自形-半自形,不含包裹体,但淡色体中含有港湾状的混合型石榴石。岩浆型石榴石具有以下地球化学特征:(1)从核部到边部,显示了典型的"振荡型"生长环带;(2)富集HREE,亏损LREE,从核部到边部,Hf、Y和HREE含量降低;(3)显著的Eu负异常;(4)相对于源岩中变质石榴石,Mn和Zn的含量显著增高。岩相学和地球化学特征都表明:变泥质岩熔融形成的熔体(淡色体)捕获了源岩的变质石榴石,熔体与石榴石反应导致大部分元素的特征被改变,只在核部保留了源岩的部分信息。同时,在花岗质熔体结晶过程中,形成少量的岩浆型石榴石。这些石榴石摄取了熔体中大量的Zn,浓度显著升高,在斜长石和锆石同步分离结晶作用的共同影响下,石榴石中Eu为明显负异常,Hf、Y和HREE浓度从核部到边部逐渐降低。上述数据和结果表明,花岗岩中石榴石的矿物化学特征记录了精细的有关花岗岩岩浆演化的重要信息。     

初论高温花岗岩-伟晶岩锂铍成矿系统:以阿尔金中段地区为例

花岗岩-伟晶岩型锂铍矿床是锂铍矿床的重要类型。关于锂铍金属在源区花岗质岩浆形成过程的富集机制,岩石学家和矿床学家多强调锂铍花岗岩-伟晶岩的母花岗岩（淡色花岗岩）源于变沉积岩的白云母熔融,但实验岩石学显示白云母熔融其熔体量小（<10vol%）、熔体从岩石中提取锂铍的效率低。这意味着白云母熔融形成花岗质岩浆过程锂铍金属富集机制可能不是花岗质岩浆获取锂铍的主要机制。基于黑云母熔融可以获得大体积熔体（可达50vol%）的实验结果,指出变杂砂岩（黑云母片麻岩）与含黑云母的英云闪长质片麻岩部分熔融形成的黑云母花岗质高温岩浆（>800℃）其结晶形成黑云母花岗岩并可分异演化为淡色花岗岩与锂铍花岗岩-伟晶岩、并构成高温花岗岩-伟晶岩锂铍成矿系统,是花岗岩-伟晶岩型锂铍矿床形成的重要成矿系统,其特征与形成机制值得进一步研究。黑云母脱水熔融过程残留相没有富含锂铍矿物的形成,新形成的花岗质岩浆可以高效地从源岩中获取锂铍金属,是一种新的锂铍富集机制。研究团队于2018年率先进入阿尔金中段无人区开展稀有金属成矿作用的地质调查与考察。经过两年的野外地质调查,新发现2个中-大型花岗伟晶岩型锂铍矿（吐格曼铍锂矿与吐格曼北锂铍矿）和塔什萨依金绿宝石矿,发现大量的黑云母花岗岩、二云母花岗岩与伟晶岩,指出这些淡色花岗岩与伟晶岩成因于黑云母花岗岩的分异演化并构成高温花岗岩-伟晶岩锂铍成矿系统,初步构建花岗岩-伟晶岩锂铍成矿系统的3种组构类型,初步揭示吐格曼铍锂矿与吐格曼北锂铍矿形成于468~460Ma,为加里东期锂铍伟晶岩区。阿尔金中段高温花岗岩-伟晶岩系统成矿特征显示：1）高温黑云母花岗质岩浆可以通过连续的分异结晶形成从下往上依次分带、垂向叠置的系统（组构A）,即从黑云母花岗岩到二云母花岗岩、白云母花岗岩与钠长花岗岩、及从近岩体的电气石带到依次远离岩体的绿柱石带、锂辉石带和锂云母带。组构A锂铍伟晶岩的分带与传统的淡色花岗岩-伟晶岩系统中锂铍伟晶岩的分带相似。2）在剪切构造背景下,花岗岩的分异结晶形成从外到里依次为糜棱岩化黑云母花岗岩、二云母花岗岩与白云母花岗岩的环状岩体,而金绿宝石钠长花岗岩从环状岩体中穿出、并向外演化为金绿宝石伟晶岩、绿柱石伟晶岩和锂辉石伟晶岩,金绿宝石钠长花岗岩与金绿宝石伟晶岩的发育是此组构（组构B）的显著特征。3）在强挤压与剪切构造背景下,黑云母花岗岩呈片麻状,伴生的伟晶岩为二云母花岗质伟晶岩、顺围岩片麻理发育、无锂铍矿化。这些特征给我们一些重要启示：即构造动力作用影响与控制岩浆的结晶分异方式,金绿宝石可形成于高温花岗岩-伟晶岩锂铍成矿系统,形成于岩浆分异与演化低程度阶段的低分异花岗伟晶岩不成矿。     

四川平武稀有金属花岗岩与绿柱石的成矿属性

通过对四川平武稀有金属花岗岩体的岩石地球化学特征的研究，阐述该区花岗岩与绿柱石的成矿关系。研究表明：平武花岗岩体造岩矿物组合为石英、钠长石、钾长石和白云母；岩石化学成分铝过饱和、富钠、富碱性，稀土元素含量很低，富含Be,W,Sn,Li,Ta,Rb等稀有元素；属花岗岩浆高度分异演化晚期阶段的产物；由岩浆期后的云英岩化形成气成－热液型绿柱石宝石矿床。     

赣北大湖塘平苗矿段白云母花岗岩锆石U-Pb年代学、地球化学及地质意义

赣北大湖塘钨铜多金属矿集区位于扬子板块东南缘、江南造山带中段,是近年来查明的世界级钨矿产地之一。对大湖塘平苗矿段中粗粒白云母花岗岩进行了岩相学、锆石U-Pb年代学、地球化学及成矿作用的研究,结果表明,此花岗岩内白云母显示原生白云母的特性,LA-ICP-MS锆石U-Pb年龄为（145.7±0.6）Ma,与区内细粒黑云母花岗岩测试年龄相近,系同源岩浆演化结晶分异的结果,为燕山期多期次岩浆侵入的第二阶段。燕山期岩石单元先后有似斑状黑（二）云母花岗岩→细粒黑云母花岗岩、白云母花岗岩→花岗斑岩,白云母花岗岩是区内重要的成矿地质体之一。地球化学研究表明,该白云母花岗岩为高分异S型花岗岩,具有高硅（w（SiO₂）=73.14%~74.19%）、富碱、过铝质的特征及较高的分异指数,轻重稀土分馏明显,呈左高右低的深V型,Eu表现为强烈的亏损,存在REE四分组效应,Rb/Sr、Rb/Ba的平均值分别为151.81和245.21,表明岩浆是经历多阶段分离结晶、高度分异的结果。     

Petrogenesis of the Concordia Granite Gneiss and its relation to WMo mineralization in western Namaqualand, South Africa

The 1.1 Ga Concordia Granite Gneiss (CGG) is part of the late to postorogenic Spektakel Suite in the western Namaqualand Metamorphic Complex, South Africa. It intruded synkinematically, with respect to the main (D2) deformation event, into lower to middle crustal rocks and granite emplacement was more or less coeval with the peak of granulite-facies metamorphism ( > 800°C, 5 kbar). Several genetically related rock types, megacrystic garnet-bearing granite, minor aplitic leucogranites and pegmatites are distinguished. All varieties are SiO₂-rich (69–79 wt.%) peraluminous granites and show subalkaline-monzonitic magma characteristics. Geochemical differences in whole-rock chemistry between megacrystic granite and aplitic leucogranites (e.g., lower Al₂O₃, MgO, CaO, Ba, Zr; higher K₂O, Rb, Nb, W, Rb/Sr, Ga/Al) and the decrease of e.g., CaO, MgO, Fe₂O₃, Ba, Zr, Th/U with increasing SiO₂ in the megacrystic granites as well as the variation in Fe/Mn of magmatic garnets are best explained with crystal fractionation processes. Fractional crystallization of plagioclase produced potassium- and silica-rich residual melts characterised by very high Rb/Sr, Rb/Ba, U/Th, Mn/Fe ratios and higher concentration of W, Cu and Zn. Crystal fractionation processes also resulted in a relative LREE depletion and HREE enrichment (megacrystic granite: La/Lu)_cn = 8.87−31.67; aplitic leucogranite and pegmatites: La/Lu)_cn = 0.71−1.44) and evolution of pronounced negative Eu-anomalies. The crystallization sequence (near-solidus crystallization of biotite prior to alkali feldspar) suggests that the CGG magmas were H₂O-undersaturated over a long period of their evolution. Water saturation during late-stage crystallization is, however, indicated by coarse late-stage eutectic mineral textures, pegmatites and WMo-bearing siliceous rocks. Furthermore the economic potential of the CGG is supported by its geochemical signature (e.g., high U, Th contents) which is similar to evolved high heat production (HHP) granites. The granitic magmas are attributed to partial melting of peraluminous crustal source rocks and are tentatively interpreted as fractionated S-type granites. The WMo deposits represent vein-type and pegmatitic deposits genetically related to a deep-seated granitic system.     

喜马拉雅淡色花岗岩

在青藏高原南部的喜马拉雅地区,分布有两条世界瞩目的淡色花岗岩带。南带主要沿高喜马拉雅和特提斯喜马拉雅之间的藏南拆离系(STDS)分布,俗称高喜马拉雅淡色花岗岩带,构成喜马拉雅山的主体。北带淡色花岗岩位于特提斯喜马拉雅单元内,又被称之为特提斯喜马拉雅淡色花岗岩带。这些花岗岩多以规模不等的岩席形式侵入到周边沉积-变质岩系之中,或者呈岩株状产出于变质穹窿的核部。岩体本身大多岩性均匀,变形程度不等,但岩体边缘可见较多的围岩捕虏体,并在部分情况下见及围岩的接触变质作用,反映它们的异地侵位特征。上述两带中的淡色花岗岩在矿物组成和岩石类型上表现为惊人的相似性,主要由不同比例的石英、钾长石、斜长石、黑云母(5%)、白云母、电气石和石榴石等构成二云母花岗岩、电气石花岗岩和石榴石花岗岩三大主要岩石类型。从不同地区的野外观察来看,二云母花岗岩为喜马拉雅淡色花岗岩的主体岩石类型,而电气石花岗岩和石榴石花岗岩主要以规模不等的脉体形式赋存于二云母花岗岩之中,反映前两者晚期侵位的特征。地球化学特征上,这些花岗岩具有高Si、Al、K,低Ca、Mg、Fe、Ti的特点,接近花岗岩的低共熔点组分。绝大多数淡色花岗岩具有较高的含铝指数,属于过铝花岗岩。微量元素表现为较大的变化范围,但总体上表现为富集大离子亲石元素K、Rb和放射性元素U,而不同程度亏损Ba、Th、Nb、Sr、Ti等元素。稀土元素总量总体上明显低于世界上酸性岩的平均丰度,且绝大部分表现为轻-中等程度的稀土元素分馏和不同程度的Eu负异常。传统认为,喜马拉雅淡色花岗岩是原地-近原地侵位的纯地壳来源的低熔花岗岩。但本文通过分析提出,该花岗岩可能是从一种高温的花岗岩浆演化而来,其岩浆源区的性质或成因类型目前还难以确定。该岩浆在上升侵位的过程中曾经历过大规模地壳物质的混染,并发生了高度分离结晶作用。因此,喜马拉雅淡色花岗岩首先是一种高分异型的花岗岩,是真正意义上的异地深成侵入体,而并不是原地或半原地的部分熔融体。这种以大规模地壳混染和结晶分异作用为特征的花岗岩系,在花岗岩的研究内容中还未被充分地讨论。以前根据相关信息认为这些岩石来自于沉积岩部分熔融的结论,只是较多地注意到了后期地壳混染和结晶分异作用的特征。即使这些岩石的原始岩浆将来被证明真的来源于沉积岩系的部分熔融,那以前的结论也只能说是"歪打正着"。根据形成年龄和地质-地球化学特征,本文将这些花岗岩划分为原喜马拉雅(44~26Ma)、新喜马拉雅(26~13Ma)和后喜马拉雅(13~7Ma)三大阶段。其中第一阶段对应印度-亚洲汇聚而导致的大陆碰撞造山作用,而后两个阶段同加厚的喜马拉雅-青藏高原碰撞造山带拆沉作用有关,对应青藏高原的全面隆升。根据这些淡色花岗岩的岩石与地球化学特征,我们还不能支持青藏高原存在广泛的中地壳流动的模型。相反,俯冲的高喜马拉雅岩系在深部的部分熔融及随该岩系折返而发生的分离结晶作用可很好地解释淡色花岗岩所具有的系列特征。     

Elemental and boron isotopic variations in tourmaline in two-mica granite from the Cuona area,Tibet: Insights into the evolution of leucogranitic melt

Two-mica granite is the most common magmatic rock type in the Himalayan leucogranite belt, which has close relationship with rare metal mineralization. Its genesis is generally attributed to magmatic differentiation. In recent years, the mineral geochemical compositions are increasingly used to study magmatic differentiation, which are significant for deciphering the melt evolution and element migration processes. In this study, in-situ major and trace element and boron isotope compositions for tourmalines from two-mica granites in the Cuona and Cuonadong leucogranites in the Cuona area are conducted to determine microscopic changes in mineral assemblages and geochemical compositions. Analytical results show that the tourmalines in the Cuonadong leucogranite were crystallized earlier relative to the tourmalines in the Cuona leucogranite during magmatic differentiation. The volatile contents have a genetic relationship with incompatible elements in tourmaline, which is possibly responsible for the formation of tourmaline zonation and the enrichment of Sr, Zn, and Pb during magmatic differentiation. The B isotopic composition of tourmaline in the Cuona area suggests that the granitic magma was dominantly derived from the partial melting of the metasedimentary source rocks. Their B isotope variations likely resulted from fluid exsolution during B-rich melt evolution. High rare metal contents in tourmalines indicate that the two-mica granites in the Cuona area may have great mineralization potential.     

藏南吉隆淡色花岗岩地球化学特征、成因机制及其构造动力学意义

藏南吉隆淡色花岗岩体位于大喜马拉雅淡色花岗岩带的中部,是吉隆地区藏南拆离系剪切带上部的重要组成部分。地球化学特征显示,岩石具有高SiO_2(72.09%~74.02%)、Al_2O_3(14.54%~15.59%)和K_2O(4.55%~5.59%)含量,高K_2O/Na_2O比值(1.12~1.55)和A/CNK值(1.14~1.18),属于高钾钙碱性过铝质S型花岗岩。富集大离子亲石元素Rb和放射性生热元素U,亏损Ba、Nb、Sr和Zr等元素,具有明显的轻重稀土元素分异和Eu负异常(δEu=0.37~0.54)。具有高的Rb/Sr比值(3.6~9.7)和低的CaO/Na_2O比值(0.15~0.25),指示源区为泥质岩区;(~(87)Sr/~(86)Sr)_i和ε_(Nd)(t)变化范围分别为0.7548~0.7586和-14.0~-13.1,与大喜马拉雅变泥质岩的Sr-Nd同位素组成一致;锆石边部的ε_(Hf)(t)介于-16.0~-8.5之间,位于大喜马拉雅变泥质岩中碎屑锆石的演化线上,表明淡色花岗岩的源岩为大喜马拉雅变泥质岩。岩石(~(87)Sr/~(86)Sr)_i较高而Sr浓度较低,且随着Ba浓度的增加,Rb/Sr比值降低,表明淡色花岗岩是无水条件下白云母脱水熔融形成的,部分熔融可能与藏南拆离系(STDS)伸展拆离导致的深部构造减压密切相关。吉隆淡色花岗岩的形成反映了地壳伸展减薄背景下,构造减压导致的深部地壳物质中含水矿物(白云母)脱水熔融并沿向北伸展的STDS侵位的构造动力学过程。     

Lead isotope and trace element composition of K-feldspars from peraluminous granitoids of the Late Devonian South Mountain Batholith (Nova Scotia, Canada): implications for petrogenesis and tectonic reconstruction

The South Mountain Batholith (SMB) of southwestern Nova Scotia (Canada) is a Late Devonian (~375 Ma) composite intrusion, which crops over an area of about 7,300 km². This peraluminous granitoid body consists of rocks ranging from granodiorite through monzogranite and leucomonzogranite to leucogranite that locally host greisen tin-base metal mineralization. K-feldspar displays large compositional variations of trace elements and Pb isotopic ratios, particularly in the highly fractionated rocks. Many variations are consistent with processes of fractional crystallization, but a distinct enrichment of Rb, Li and Cs accompanied by low K/Rb, Ba/Rb, Eu/Eu* and K/Cs ratios point to the role of fluids during the late stages of magmatic evolution. The correlation of Pb isotopic ratios with the enriched elements and their ratios implies that the isotopic variations are an integral part of the evolution of the SMB. Together with well-defined isochronal relationships of Pb systems in the feldspars, the correlation suggests that fractional crystallization accompanied in the late stages by fluid fractionation led to the formation of Li–F-rich leucogranites. Internally derived U-rich fluids fractionated U/Pb ratios, which in turn produced distinct variations of ²⁰⁶Pb/²⁰⁴Pb and ²³⁸U/²⁰⁴Pb ratios in K-feldspars. This implies that the Pb isotopic values of K-feldspar, which have traditionally been used for tectonic reconstructions, might have been modified in many granitic rocks. Thus, only early magmatic K-feldspars, which show no discernible effects of fluid fractionation yield the initial Pb isotopic compositions of the parental granitic magmas and their sources. The data also show that the geochemical characteristics of the leucogranites are the results of magmatic evolution rather than a distinctive source.     

藏南错那洞淡色花岗岩成因：来自全岩地球化学和锆石U-Pb年龄的约束

藏南错那洞穹隆位于喜马拉雅造山带东部,淡色花岗岩是其核部组成部分之一。对其中的弱定向二云母花岗岩和含石榴子石二云母花岗岩进行LA-ICP-MS锆石U-Pb定年,显示其结晶年龄分别为(20.6±0.3) Ma和(16.7±0.2) Ma,属于喜马拉雅中新世淡色花岗岩。错那洞含石榴子石二云母花岗岩和弱定向二云母花岗岩均具有富硅(w(SiO2)为71.6%~74.6%)、富铝(w(Al2O3)为14.5%~16.1%)、富钾(w(K2O)为4%~4.7%)及高铝饱和指数(A/CNK=1.16~1.22)的特征,属高钾钙碱性系列的强过铝质花岗岩,并且两类花岗岩都富集Rb、U、K、Pb,相对亏损Nb、Ta、Zr、Ti。但含石榴子石淡色花岗岩具有明显的Eu负异常(Eu/Eu*=0.29~0.46),而弱定向二云母花岗岩Eu的负异常相对较弱(Eu/Eu*=0.58~0.80)。弱定向二云母花岗岩的Rb/Sr值为2.4~3.5,Ba含量为(200~253)×10-6,TiO2含量相对较低,表明错那洞弱定向二云母花岗岩是在无水条件下由变泥质岩中的白云母脱水熔融而形成,并且弱定向二云母花岗岩的产生可能与藏南拆离系(STDS)启动造成的构造减压有关。含石榴子石二云母花岗岩的K/Rb、Zr/Hf、Nb/Ta、Y/Ho值呈现出非球粒陨石异常,稀土四分组效应和异常高的Rb/Sr值(18.6~22.2)表明错那洞含石榴子石二云母花岗岩是经过岩浆高度演化而形成的。高度演化的岩浆有利于W、Sn、Be等稀有金属成矿。错那洞含石榴子石二云母花岗岩与错那洞穹隆的W-Sn-Be矿具有相邻的空间位置,两者之间可能存在一定的成因联系;而错那洞弱定向二云母花岗岩与扎西康Pb-Zn矿床在时间上和空间上都具有一致性,两者之间很可能也存在一定的成因联系。     

Chemical and isotopic (Pb,Sr) zonation in a peraluminous granite pluton: role of fluid fractionation

The Davis Lake pluton (DLP, ~800 km²) of southwestern Nova Scotia, Canada, part of the large peraluminous South Mountain batholith of ca. 380 Ma (U/Pb zircon, Ar/Ar mica), consists of granite and subordinate topaz–muscovite leucogranite that hosts greisen tin-base metal mineralization. A new Pb–Pb isochron age for leucogranite from the most evolved part of the DLP indicates a crystallization age of 378±3.6 Ma, coincident with other radiometric ages of the DLP (Rb–Sr, Re–Os, Pb–Pb). The intrusion displays a compositional zonation defined by lead and strontium isotopic ratios, as well as some major elements (e.g., Si, F), incompatible trace elements (e.g., Li, Rb, Ta, U, Sn), and elemental ratios (e.g., K/Rb and Nb/Ta). The greisens and the leucogranites that host them are characterized by extreme radiogenic compositions for Pb and Sr, and their chemical-isotopic trends are extensions of the trends displayed by the less evolved granites. The covariations of the isotopic ratios with several major and trace elements and elemental ratios as well as the Pb–Pb and Rb–Sr isochrones indicate that all phases of the intrusion originated from a homogeneous parental magma. The granitoid magma underwent extensive fractional crystallization of feldspars, minor biotite and accessory minerals (monazite, apatite and zircon) in a compositionally zoned magma chamber that was subsequently accompanied by fluid fractionation, during which time the internally derived fluorine-rich fluids modified the Rb/Sr, U/Pb and Th/Pb ratios, leading to distinct variations of ⁸⁷Sr/⁸⁶Sr, ²⁰⁶Pb/²⁰⁴Pb, ²³⁸U/²⁰⁴Pb and ²³²Th/²⁰⁴Pb isotopic ratios. These data therefore document the evolution of a granitic magma through magmatic (i.e., crystal fractionation), orthomagmatic (i.e., crystal-fluid fractionation) and hydrothermal (i.e., fluid fractionation) stages that culminated in the formation of a tin-base metal deposit. The Pb isotope data also constrain the source region for the DLP as being Avalonian basement that, by inference, must underlie much of the Meguma Terrane.Editorial responsibility: T.L. Grove