塔里木地块库车坳陷早白垩世古地磁结果及磁倾角偏低的成因探讨

运用主成分分离及线性区段等方法 ,使早白垩世样品明显分离出二组磁组分 .叠加剩磁为喜山期重磁化 ,特征剩磁明显偏离现代地磁场方向 ,经倾斜校正后 ,有很好的一致性并通过了倒转检验 ,给出塔里木地块库车坳陷早白垩世巴西盖组古地磁新数据 .综合已有的古地磁结果 ,获得了塔里木地块早白垩世平均剩磁方向及平均古地磁极 ,阐明了塔里木地块早白垩世磁倾角明显偏低这一现象 .分析导致磁倾角偏低的诸多因素 ,认为压实作用可能是导致磁倾角偏低的重要因素之一 .     

Magnetic reorientation induced by pressure solution: A potential mechanism for orogenic-scale remagnetizations

New paleomagnetic analyses of Triassic, Cretaceous and Eocene strata in the south-central Pyrenees show evidence for a widespread remagnetization, located along the southern border of the Axial Zone, the Internal Sierras, and the northern part of the Jaca-Pamplona basin. This remagnetization, always reversed in polarity, was acquired after an extensive period of Late Eocene–Early Oligocene folding and tilting in the area, and affects limestones, sandstones, marls and red beds. In addition, a characteristic prefolding component was identified in 30% of Upper Cretaceous and Triassic red beds. These results, together with a revaluation of previously published paleomagnetic data from the central Pyrenees, indicate that the spatial distribution of the postfolding remagnetization coincides with that of a domain of pressure solution cleavage. A relationship between the intensity of the remagnetization and the characteristic (prefolding component) with respect to the density of cleavage surfaces, leads us to propose a mechanism for the remagnetization related to the development of pressure solution cleavage that is framed within the tectonic evolution of the central Pyrenees. Partial dissolution of rock under tectonic compression leads to the liberation and subsequent accumulation of insoluble minerals in cleavage planes. Magnetic grains are part of the relatively insoluble residue, and they reorient in the presence of the ambient field after they are freed during dissolution of the rock matrix. Chemical reequilibrium (dissolution and/or neoformation of magnetic carriers) during this process cannot be excluded. The remagnetization mechanism we propose can help to explain widespread remagnetizations in low to moderately deformed rocks without the need of large-scale migration of orogenic fluids.     

The application of high resolution IRM acquisition to the discrimination of remanence carriers in Chinese loess

Summary High resolution isothermal remanent magnetisation (IRM) acquisition was performed on forty-one Chinese loess samples with the aim of investigating the effects of weathering on the remanence carrying mineralogy. Magnetic susceptibility was taken as a measure of the degree of weathering. This is a valid assumption based on previous studies which have demonstrated a close relationship between climate and magnetic susceptibility in the Chinese loess. Detailed analysis, based on fitting accumulative log-gaussian curves to IRM acquisition data, reveals up to four distinct coercivity components. The remanences of the two harder coercivity components are found to be almost independent of magnetic susceptibility. On the other hand, the remanences of the two softer coercivity components are found to be positively correlated with magnetic susceptibility. Most probably the two harder components are associated with detrital iron-oxides in the primary dustfall, whereas the softer components were created during pedogenesis.     

Paleomagnetic direction obtained by strain removal in the Pyrenean Permian redbeds at the “Col du Somport” (France)

In order to investigate the possibility and limitations of paleomagnetic works within strained regions, a paleomagnetic study, related with strain analysis has been conducted in the deformed Pyrenean Permian redbeds in the “Col du Somport” area. Paleomagnetic sampling together with strain estimates have been conducted in 6 sites through a fold. The results obtained by measuring the orientation and axial ratios of elliptical reduction spots show that (1) the shale beds have undergone a penetrative strain, (2) the sandy beds can be regarded as tectonically unstrained with reduction spots flattened in the bedding, showing that they recorded the compaction. It is shown that the total strain recorded in the slaty beds probably results from the superimposition of tectonic strain upon the compaction fabric. The paleomagnetic study shows that the primary pretectonic magnetization is widely overprinted by a secondary syn- or post-tectonic magnetic component. As both components appear to be carried by hematite pigment, their separation using classical demagnetization procedures has been difficult. A characteristic remanent magnetization (ChRM) has however been determined, when possible, as the hardest component in demagnetization curves. Then, the ChRM direction distributions are represented in stereographic density plots. Although these ChRM directions exhibit a clear tendency towards SE declinations and shallow inclinations, characteristic of Permian paleomagnetic field direction for the Iberian plate, the tilt correction does not induce a clustering of these directions. Strain is inferred to be responsible for this situation. Assuming that both pretectonic magnetization directions and bedding planes closely follow the material plane and line strain response model of March [1], an attempt has been made to remove the effect of strain upon the remanent magnetization. It is shown that when using a reconstructed tectonic strain tensor (i.e., the total strain tensor as measured in the field, corrected for an estimated compaction) we obtain a significant clustering of ChRM directions. The computation of the relevant VGP, gives a pole position (210.5°E, 42.0°N) compatible with the reference APWP for the Iberian plate. It is therefore inferred that the strain removal technique is a usable tool in order to obtain paleomagnetic results within such strained rocks.     

Thermal remagnetization and the paleointensity record of metamorphic rocks

We present a quantitative relationship between blocking temperature and time that, in principle, provides a calibration of thermal remagnetization in nature. For a given metamorphic temperature-time regime, one can decide whether a given laboratory blocking temperature (or for paleointensity work, a range of blocking temperatures) is consistent with primary natural remanence (NRM) or with a metamorphic overprint. Independent of the domain structure or the chemical composition of the magnetic minerals, two general types of behaviour are predicted. If the primary NRM possesses laboratory (or primary cooling) blocking temperatures within 100°C or so of the Curie temperature, thermal remagnetization at lower temperatures, even over times as long as 10⁶ years, is improbable. If the blocking temperatures are lower, viscous remagnetization is pronounced at temperatures well below those indicated by laboratory thermal demagnetization. An approximate scale of the “survival potential” of primary NRM in rocks of different metamorphic grades indicates that primary paleointensities are unlikely to be recovered from rocks metamorphosed above high-greenschist facies if the predominant magnetic mineral is nearly pure magnetite, or above middle-amphibolite facies if nearly pure hematite is predominant. Evidence from laboratory experiments and paleomagnetic field studies in metamorphic regions suggests, however, that these survival estimates are unduly optimistic. Chemical remagnetization through the destruction of primary magnetic minerals, and not thermal remagnetization, probably sets an effective upper temperature for the survival of primary NRM.     

扬子地块奥陶系碳酸盐岩重磁化机制探讨

碳酸盐岩是记录古地磁场信息的重要载体,然而,广泛存在的重磁化现象制约了碳酸盐岩在古地磁研究中的应用,其重磁化机制亟待解决.本文对采自贵州羊蹬地区的319块奥陶系碳酸盐岩定向样品作了详细的古地磁学和岩石磁学研究,其结果表明,94%样品(A类)记录了单一剩磁分量A,其解阻温度低于450℃;在地理坐标系下的平均方向为Dg/Ig=3.1°/48.1°(α₉₅=2.9°),对应的古地磁极(87.0°N,2.8°E,A₉₅=3.0°)与扬子地块古近纪-第四纪的古地磁极重合.6%样品(B类)记录了两个磁化分量,其高温分量(450℃~585℃)与A分量显著不同,但明显远离扬子块体早古生代古地磁极;低温分量(< 450℃)与A分量类似.说明羊蹬剖面奥陶系碳酸盐岩记录了两期重磁化.A分量和B低温分量的主要载磁矿物为磁黄铁矿(胶黄铁矿),B高温分量的主要载磁矿物为磁铁矿.这些磁性矿物都是成岩后的次生矿物.其中,解阻温度高于450℃的磁铁矿可能受晚燕山期造山运动影响生成;磁黄铁矿(胶黄铁矿)等矿物可能与印度板块与欧亚大陆碰撞引起的喜马拉雅造山运动所产生的流体作用有关,以后一期重磁化为主.新生代早期青藏高原隆升产生的流体在流经东南缘的碳酸盐岩等沉积岩层时,与原岩发生相互作用,使磁黄铁矿、胶黄铁矿、磁铁矿等磁性矿物生长并获得化学剩磁,造成了广泛重磁化.     

Remagnetization of the Early Paleozoic rocks from southern part of the Huabei basin (II)

The opinions vary on the secondary remagnetization mechanisms of carbonate rocks. The prevalent interpretations of magnetic remanences are either chemical in origin that invoked the large-scale migration of orogenic fluids. or thermoviscous magnetization involved burial diagenetic processes. The paleomagnetic study carried out in northwestern part of Henan Province (north of the Qinling orogenic belt) reveals that 90% of carbonate rocks have suffered from the secondary remagnetization. On the basis of rock magnetic experiments, the assemblage of the magnetic minerals, remanent carriers and its formation process, and the possible mechanisms of remagnetization in these carbonate rocks are discussed.     

Magnetic components contributing to the NRM of Middle Siwalik red beds

The components of the NRM in Middle Siwalik red beds are carried by two phases of hematite, a red pigment phase and a specular hematite phase. We present evidence in the form of a conglomerate test that the specularite phase carries a remanence acquired during or shortly after deposition. The red pigment, however, post-dates deposition, in many cases by at least one reversal boundary. This secondary component has a higher coercivity but a lower blocking temperature in these rocks and can therefore be selectively removed by thermal demagnetization to reveal a primary magnetization useful for magnetostratigraphic studies.     

泰国Khorat盆地二叠纪石灰岩的重磁化研究

泰国Ｋｈｏｒａｔ盆地西部的晚二叠世石灰岩的古地磁研究表明磁铁矿为稳定剩磁的主要载体多组分磁分量分离技术揭示了高温磁组分（或高矫顽力）具有呈对分布的正、反极性．但是，应用逐渐展平岩层法可以发现各采样点的平均特征磁化方向在岩层展平至３０％时．磁化方向最为集中．这一发现表明二叠纪石灰岩中所揭示出的磁化方向很可能形成于褶皱（期）过程中．野外观察表明，二叠纪石灰岩在印支期发生强烈褶皱并被晚三叠世湖相石灰岩角度不整合覆盖．所以二叠纪石灰岩的重磁化很可能发生在中、晚三叠世的印支期．这些石灰岩样品切片后经显微镜、扫描电镜和电子探针分析，次生磁铁矿多数与方解石微晶和铁质碳酸钙粒共生，且多分布在方解石脉附近．重磁化很可能是由于印支期造山运动时，铁质碳酸钙受碳水化合物流体的蚀变作用所引起的。     

Paleomagnetism of a paleocene pluton on jamaica

A Paleocene granodiorite pluton on Jamaica has been subject to extensive weathering caused by the tropical marine environment of the island. The natural remanence of 29 samples obtained from relatively fresh rock in two localities was found to consist of two components with overlapping coercivity ranges. Alternating field treatment proved ineffective for removing the secondary component without destroying the primary one. Thermal demagnetization of samples from the two localities was more effective and yielded paleomagnetic poles at 14.7°N, 11.6°W and 58.9°N, 15.9°E respectively. These pole positions are different from those available from contemporaneous North American rocks and from poles derived from Jamaican Cretaceous and Upper Miocene rocks. Mineralogical studies showed that the granodiorite has undergone an extensive maghemitization superposed on earlier class 2 deuteric oxidation and related to the weathering process. Some of the titanomaghemite has, however, been converted to titanohematite. Hence although the secondary remanence carried by the former was removable by thermal treatment at 500°C, its part carried by the latter could not be removed without simultaneously destroying the primary remanence carried by the residual titanomagnetite. The observed paleopole positions do not, therefore, represent the true Paleocene geomagnetic field, but suggest that the direction of magnetization of the pluton has been approximately equatorial and was probably acquired in a reversed geomagnetic field. This could be interpreted as having been caused by the behavior of the geomagnetic field during a polarity transition, but a more favorable interpretation appears to be a large anticlockwise tectonic rotation of the islands since the Paleocene.     

Separation of multicomponent NRM: combined use of difference and resultant magnetization vectors

For rock specimens carrying three superimposed remanence components with partially overlapping coercivity spectra, a modified form of the vector difference method proposed by Hoffman and Day (1978) can lead to greater precision in the estimate for the direction of the intermediate coercivity component. The modification is that the convergence point of great circles defined by differenceand resultant vectors is used to determine the direction of the intermediate component, rather than by using great circles defined only by difference vectors as in the Hoffman-Day technique.     

Grain size limit for SD hematite

Grain sizes in the range (10⁻⁴ to 10⁻¹ mm) are common in some rocks. Because thermal and/or chemical remanent magnetization of hematite in this range approaches intensities of single domain (SD) magnetite, careful exploration of this transition, may serve to develop new applications in rock magnetism that relate to magnetic anomaly source identification, and various paleomagnetic and grain size-dependent investigations.Grain size-dependent magnetic behavior of hematite reveals a SD–multidomain (MD) transition at 0.1 mm. This transition is recognized by variation in magnetic coercivity and susceptibility and is related to an anomaly in remanence recovery when cycling through the Morin transition. The coercivity decrease with increasing grain size occurs much more gradually above 0.1 mm than below this value. Magnetic susceptibility of the grains smaller than 0.1 mm has negligible dependence on the amplitude of the applied alternating magnetic field. For the larger grains a new amplitude-dependent susceptibility component is observed. The grain size of 0.1 mm is also associated with loss of most of the remanence when cycling through the Morin transition. This behavior is ascribed to a transition from the metastable SD to the MD magnetic state. The increase in magnetized volume causes the demagnetizing energy to destabilize the SD state, resulting in a transition where the demagnetizing energy is reduced by nucleation of the domain wall for grains larger than 0.1 mm. The 0.1 mm transition has no significant effect on shape of the temperature-dependent coercivity and saturation magnetization.     

Thermochemical remanent magnetization in Jurassic silicic volcanics from Nevada,U.S.A.

Characteristic magnetizations from Middle Jurassic dacitic to andesitic subaerial volcanics (the Fulstone and Artesia Formations) in the Buckskin Mountain Range, western central Basin and Range Province, are well-grouped, generally display univectorial decays to the origin in demagnetization and have hematite blocking temperatures restricted almost entirely to above 620°C. Petrographic, rock magnetic and electron microprobe investigations confirm that nearly pure hematite is the essential magnetic phase (up to about 10 vol. %) occurring as a replacement of coarse titaniferous magnetite phenocrysts and fine groundmass particles, as a secondary alteration product of ferromagnesian phenocrysts and as a mobilized phase filling cracks and other open spaces. The presence of antipodal directions in each flow unit and in interbedded volcanoclastic units (some having retained magnetite as a major magnetic phase) and magnetite-dominated remanences in time-equivalent intrusives cutting the flows indicates that the volcanics acquired their hematite remanence, a faithful record of the geomagnetic field, in high-temperature, deuteric oxidation during and following their emplacement, not during a later thermal event such as regional metamorphism. The remanence is probably a thermochemical remanent magnetization, although part may be of thermoremanent origin.     

The stable orientations of the net magnetic moment within single-domain particles: Experimental evidence for a range of stable states and implications for rock magnetism and palaeomagnetism

An idealised stable uniaxial single-domain (SD) particle permits only two possible stable positions in which the magnetic moment can lie, either closely parallel or anti-parallel to the particle long (easy) axis. In real acicular SD particles, which have generally been regarded as uniaxial, this implicit two state feature has never been challenged, whilst there has been considerable debate concerning the mechanism of moment reversal between the two states. We present experimental results suggesting that acicular SD particles may actually have a range of several quantifiable stable (or metastable) orientations of the net magnetic moment. In order to help explain our experimental observations we present a new simple model of acicular SD particles, which gives quantitative predictions verified by further experiments. The model also appears to be relevant to other SD particle morphologies and crystal structures (such as hematite). A possible physical basis for our model in acicular particles may lie in non-uniform SD structures (such as the flower or vortex states). Small variations in the non-uniform SD structures available to a particle might allow a range of stable positions of the net moment.The results have several implications for rock magnetism and palaeomagnetism. Firstly, the new model can quantitatively account for several previously unexplained diverse phenomena exhibited by real acicular SD particles. These include the acquisition of gyroremanences and field-impressed anisotropy in dilute dispersions of such particles, as well as observations of transverse components of remanence in individual acicular SD particles. All these phenomena are theoretically impossible in idealised uniaxial SD particles. Interestingly, it appears that these phenomena could now be used to quantify the deviation of real acicular SD particles from ideal uniaxial behaviour and also, therefore, the deviation from a uniform SD structure. In hematite, observations of large field-impressed anisotropy appear to be quantitatively explained by the available positions of the moment in the basal plane.Secondly, computations of the ancient field vector and palaeointensity from remanence anisotropy techniques would not only be controlled by the shape and distribution of the particles, but also by the range of possible stable orientations of the net moment within each SD particle. Laboratory analogue remanences (and, we suspect, natural remanences) would be influenced by the range of possible stable moment positions. Quantifying the range of these stable moment positions, upon acquisition of laboratory or natural remanences, should lead to improved methods of computing the ancient field direction and palaeointensity in anisotropic rocks.     

Separation of multi-component NRM: A general method

A method is presented which can successfully isolate components of remanent magnetization having intermediate relative stability in a single rock sample which contains any number of remanence components with overlapping coercivity or blocking temperature spectra. The approach consists of analysis of the path swept out by the vector destroyed during a detailed alternating field or thermal demagnetization run. The point of intersection determined for any two neighboring great circle segments identified in such a difference vector path defines the direction of such a component. Samples cored from a fragment of a Jurassic pillow basalt, shown to contain several components of magnetization, serve to illustrate the utility of the method for the case when the Zijderveld approach is unsuccessful.     

Paleomagnetism of the latest Precambrian/Cambrian Unicoi basalts from the Blue Ridge, northeast Tennessee and southwest Virginia: evidence for Taconic deformation

Three components of magnetization have been observed in ninety-six samples (twelve sites) of amygdaloidal basalts and “sedimentary greenstones” of the Unicoi Formation in the Blue Ridge Province of northeast Tennessee and southwest Virginia. These components could be isolated by alternating field as well as thermal demagnetization. One component, with a direction close to that of the present-day geomagnetic field is ascribed to recent viscous remanent magnetizations; another component, with intermediate blocking temperatures and coercivities, gives a mean direction of D = 132°, I = +43°,α₉₅ = 9° for N = 10 sites before correction for tilt of the strata. This direction and the corresponding pole position are close to Ordovician/Silurian data from the North American craton and we infer this magnetization to be due to a thermal(?) remagnetization during or after the Taconic orogeny. This magnetization is of post-folding origin, which indicates that the Blue Ridge in our area was structurally affected by the Taconic deformation. The third component, with the highest blocking temperatures and coercivities, appears to reside in hematite. Its mean direction, D = 276°, I = ?17°,α₉₅ = 13.8° for N = 6 sites (after tilt correction) corresponds to a pole close to Latest Precambrian and Cambrian poles for North America. The fold test is inconclusive for this magnetization at the 95% confidence level because of the near-coincidence of the strike and the declinations. We infer this direction to be due to early high-temperature oxidation of the basalts, and argue that its magnetization may have survived the later thermal events because of its intrinsic high blocking temperatures. A detailed examination of the paleomagnetic directions from this study reveals that the Blue Ridge in this area may have undergone a small counterclockwise rotation of about 15°.     

Magnetic,paleomagnetic and palynologic studies of Paleolithic depositions of the Akhshtyrskaya cave (Russia)

The paper presents the results of experimental rock-magnetic, paleomagnetic and palynologic study of Paleolithic sediments sampled along two profiles in the Akhshtyrskaya cave, situated in the vicinity of Black Sea shore. In the upper part of profiles, some magnetite was observed; in the middle and lower parts, strongly oxidized non-stoichiometric magnetite and hematite prevail. Thin maghemite covers on the surface of fine magnetite grains are present in the majority of specimens. Natural remanence has one characteristic component (CHRM), mostly of chemical origin, although in few specimens containing magnetite it may be sedimentary. Directions of CHRM obtained by standard paleomagnetic methods revealed anomalous pattern only in layer 3/2, which is slightly older than the overlying layer 3/1 whose age was established as (35±2)×10³ years BP by the U-Th method. This suggests that this paleomagnetic anomaly (PMA) can be correlated with Kargapolovo excursion dated on about (45−39)×10³ years BP. In the remaining overlying and underlying layers, directions of CHRM are grouped around the present geomagnetic field. Depth distributions of scalar magnetic parameters generally coincide with the lithological division of the profiles. Palynologic study revealed the presence of 22 pollen zones. Five thermomers separated with colder periods were found in the middle and lower parts of profile. The non-magnetite composition of magnetic fraction of the majority of studied sediments — oxidized nonstoichiometric magnetite and hematite — resulted in the lack of correlations between paleoclimatic and scalar magnetic characteristics.     

A paleomagnetic reinvestigation of the Upper Devonian Perry Formation: evidence for Late Paleozoic remagnetization

In view of the recent recognition of widespread Late Paleozoic remagnetization of Devonian formations across North America, we undertook a reinvestigation of the Upper Devonian Perry Formation of coastal Maine and adjacent New Brunswick. Thermal demagnetization of samples from the redbeds yielded a characteristic direction (D = 166°, I = 4°) that fails a fold test. Comparison of the corresponding paleopole (312°E, 41°S) with previously published Paleozoic poles for North America suggests that the sediments were remagnetized in the Late Carboniferous. After the removal of a steep, northerly component, the volcanics also reveal a shallow and southerly direction ( D = 171°, I = 25° without tilt correction). No stability test is available to date the magnetization of the volcanics; however, similarity of several of the directions to those seen in the sediments raises the suspicion that the volcanics are also remagnetized. Although the paleopole without tilt correction (303°E, 32°S) could be taken to indicate an early Carboniferous age for the remagnetization, scatter in the data suggests that the directions are contaminated by the incomplete removal of a steeper component due to present-day field. Thus, it is more likely that the volcanics were remagnetized at the same time as the sediments. Isothermal remanent magnetization (IRM) acquisition curves, blocking temperatures, coercivities and reflected light microscopy indicate that the magnetization is carried by hematite in the sediments and by both magnetite and hematite in the volcanics. It is therefore likely that the remagnetization of the Perry Formation involved both thermal and chemical processes related to the Variscan/Alleghenian orogeny. Our results indicate that previously published directions for the Perry Formation were based on the incomplete resolution of two magnetic components. These earlier results can no longer be considered as representative of the Devonian geomagnetic field.     

Chemical remanent magnetization due to deep-burial diagenesis in oolitic hematite-bearing ironstones of Alabama

Oolitic hematite-bearing ironstones of the Silurian Red Mountain Formation of Alabama are shown to carry a single-component remanence stable enough to have survived major folding (of probable Permian age). Nevertheless, the remanence direction (ten sites yielding a paleopole at 38.0°N, 132.4°E with dm = 3.6°, dp = 1.9°), its reverse polarity and a negative intraformational conglomerate test show that the remanence was very likely acquired during the Pennsylvanian—some 130 Ma after deposition. This remanence is likely a chemical remanent magnetization (CRM) acquired during diagenesis induced by heating due to deep burial under a Pennsylvanian clastic wedge. Two possible mechanisms for acquisition of CRM during deep-burial diagenesis are considered. In hypothesis I, the oolitic hematite transformed from original geothite when heated to about 80°C, acquiring CRM. In hypothesis II, the oolitic hematite originated from ferrihydrite and was too fine-grained to acquire stable CRM until heat raised the solubility of hematite allowing grain growth. Hypothesis I explains the timing of remanence acquisition better, but there is some evidence that oolitic goethites may be stable to considerably more than 80°C. Hypothesis II has some difficulty explaining preliminary paleomagnetic results from oolitic hematite-bearing ironstones of the Silurian Clinton Group, New York State. We prefer hypothesis I but both hypotheses remain plausible. Both hypotheses warn that continental red beds may also acquire CRM during diagenesis induced by deep-burial heating, long after deposition but before folding.     

Hysteresis effects of varying concentrations of magnetite,hematite, pyrrhotite,and greigite grains in a diamagnetic matrix

Summary The hysteresis properties of synthetic samples with very low contents of hematite, pyrrhotite, greigite and admixtures of magnetite and hematite in a diamagnetic matrix have been studied. The diamagnetic matrix used was sodium chloride (NaCl). The contents of the magnetic minerals varied for hematite from 0.5 to 6 wt%, for pyrrhotite from 0.02 to 0.2 wt% and for greigite from 0.02 to 0.6 wt%. Diamagnetic contributions to the magnetization curves can be distinguished in the measured samples. We observed a non-linear dependence of coercivity and saturation magnetization upon increasing contents of hematite as a result of effects of both the diamagnetic matrix and the hematite content. Only the saturation remanence which is measured in a zero magnetic field has a linear dependence on the hematite concentration. The shape of the hysteresis curves of admixtures of magnetite and hematite are probably caused by magnetostatic interactions.