Speleothems in a north Cuban cave register sea‐level changes and Pleistocene uplift rates

A flight of marine terraces along the Cuban coast records Quaternary sea‐level highstands and a general slowly uplifting trend during the Pleistocene. U/Th dating of these limestone terraces is difficult because fossil reef corals have been affected by open system conditions. Terrace ages are thus often based on geological and geomorphological observations. In contrast, the minimum age of the terraces can be constrained by dating speleothems from coastal mixing (flank margin) caves formed during past sea‐level highstands and carving the marine limestones. Speleothems in Santa Catalina Cave have ages >360 ka and show various cycles of subaerial–subaqueous corrosion and speleothem growth. This suggests that the cave was carved during the MIS 11 sea‐level highstand or earlier. Some stalagmites grew during MIS 11 through MIS 8 and were submerged twice, once at the end of MIS 11 and then during MIS 9. Phreatic overgrowths (POS) covering the speleothems suggest anchialine conditions in the cave during MIS 5e. Their altitude at 16 m above present sea level indicates a late Pleistocene uplift rate of <0.1 mm/ka, but modelling also shows uplift to have been insignificant over a long timespan during the middle Pleistocene since the cave was carved. Our study shows that some flank margin caves in the region of Matanzas are older than commonly believed (i.e. MIS 11 rather than MIS 5). These caves not only can be preserved but are good markers of interglacial sea‐level highstands, more reliable than marine abrasion surfaces. Copyright © 2018 John Wiley & Sons, Ltd.     

Tectonic uplift,sea level changes and Plio‐Pleistocene evolution of a coastal karst system: the Mount Saint Paul (Palawan,Philippines)

The St. Paul karst (Palawan, Philippines) is a tropical coastal karst, consisting of towers, cones, huge depressions and large caves. This area hosts the Puerto Princesa Subterranean River (PPSR, 24 km long), whose main entrance is a large spring along the coast and which is one of the largest cave complexes in eastern Asia. A geomorphological study performed by several field surveys and a morphometric analysis of the digital terrain model (DTM) and 3D cave models, allowed formulation of a first evolutionary framework of the karst system. The DTM was extracted from maps and aerial photographs in order to find different generations of ‘relict’ landforms, through the morphometric analysis of topographic surface and karst landforms. Several features suggest a long and multi‐stage evolution of the karst, whose age ranges from Pliocene to present. The southern and northern sectors of the area differ in their altimetric distribution of caves. In the southern sector, some large caves lie between 300 and 400 m asl and were part of an ancient system that developed at the base level of a past river network. In the northern sector, some mainly vadose caves occur, with a phreatic level at 120–130 m asl. An important phase of base‐level cave development is well documented in the inactive passages of PPSR at 50–80 m asl. Morphological features, such as horizontal solution passages and terraced deposits, suggest a phase of stillstand of the base level, which is recorded in the topography as low‐relief surfaces at 40–50 m asl. The age of this phase is probably Early Pleistocene, on the basis of assumed uplift rates. The more recent caves are still active, being located at the current sea level, but they show more than one cycle of flooding and dewatering (with calcite deposition). In the PPSR, several morphologic features, such as two main water level notches at +12·4 and +7·7 m asl and terraced alluvial deposits, suggest that the lower and active level passed through more than two high‐stands of sea level and so it could have formed throughout most of the Middle‐Late Pleistocene. Copyright © 2010 John Wiley & Sons, Ltd.     

Discussion on the article ‘Coastal and inland karst morphologies driven by sea level stands: a GIS based method for their evaluation' by Canora F,Fidelibus D and Spilotro G

Comments are presented on the article by Canora et al. (2012) dealing with karst morphologies driven by sea level stands in the Murge plateau of Apulia, southern Italy. Our comments start from cave levels, that are considered in the cited article as a proof of sea level stands. We argue that the presence of sub‐horizontal passages in cave systems is not a sufficient condition for correlating them with hypothetical past sea level stands. Such a correlation must be based upon identification of speleogenetic features within the karst systems, and/or geological field data. The problems encountered when using cave surveys for scientific research, and their low reliability (especially in the case of old surveys) are then treated, since they represent a crucial point in the paper object of this discussion. Eventually, we present some final consideration on cave levels and terraces, and on the specific case study, pointing out once again to the need in including geological field data to correctly find a correspondance between flat landforms and sea level fluctuations. Our main conclusion is that field data and information on speleogenesis of the underground karst landforms cannot be disregarded in a study that claims to deal with the influence of sea‐level changes on caves. Copyright © 2013 John Wiley & Sons, Ltd.     

Prograded foredunes of Western Australia's macro‐tidal coast – implications for Holocene sea‐level change and high‐energy wave impacts

The Holocene evolution of the Canning Coast of Western Australia has largely been overlooked so far mainly due to its remoteness and low population density. We report on new data from a sequence of foredunes inside the macro‐tidal Admiral Bay, 110 km southwest of Broome. Based on sediment cores, differential global positioning system (dGPS)‐based elevation transects, and stratigraphical analyses on outcrops of the relict foredunes, we aim at reconstructing Holocene coastal changes and relative sea levels (RSLs), as well as identifying and dating imprints of extreme‐wave events. Sedimentary analyses comprise the documentation of bedding structures, foraminiferal content and macrofaunal remains, grain size distribution, and organic matter. The chronological framework is based on 26 carbon‐14 accelerator mass spectrometry (¹⁴C‐AMS) datings. Marine flooding of the pre‐Holocene surface landward of the 2.5 km‐wide foredune barriers occurred 7400–7200 cal bp , when mangroves colonized the area. After only 200–400 years, a high‐energy inter‐tidal environment established and prevailed until c. 4000 cal bp , before turning into the present supralittoral mudflat. During that time, coastal regression led to beach progradation and the formation of aligned foredunes. Drivers of progradation were a stable RSL or gradual RSL fall after the mid‐Holocene and a positive sand budget. The foredunes overlie upper beach deposits located up to >2 m above the present upper beach level and provide evidence for a higher mid‐Holocene RSL. Discontinuous layers of coarse shells and sand are intercalated in the foredunes, indicating massive coastal flooding events. One such layer was traced over three dune ridges and dated to c. 1700–1550 cal bp . However, it seems that most tropical cyclones induce net erosion rather than deposition at aligned foredunes and thus, they are only suitable for reconstructing temporal variability if erosional features or sedimentation reliably tied to these events can be identified and dated accurately. Copyright © 2014 John Wiley & Sons, Ltd.     

Quantifying threats to groundwater resources in the Republic of Maldives Part I: Future rainfall patterns and sea‐level rise

Reserves of fresh groundwater on atoll islands are extremely fragile due to climatic and anthropogenic stresses. Of major concern is the quantity of water to be available in the coming decades under the influence of variable rainfall patterns, rising sea level, environmental conditions, and expected population growth that depends on groundwater resources. In this study, a 3‐dimensional numerical modelling approach using the SEAWAT modelling code is used to estimate freshwater lens volume fluctuation for 4 representative islands in the Republic of Maldives in response to long‐term changes in rainfall, sea‐level rise (SLR), and anthropogenic stresses such as groundwater pumping and short‐term impacts from tsunami‐induced marine overwash events. This work is divided into 2 papers. This first paper presents numerical model set‐up and calibration, and the effect of future rainfall patterns and SLR on fresh groundwater reserves. The second paper focuses on marine overwash events. The results of simulated future freshwater lens volume presented in the first study contribute to efficient groundwater resources planning and management for the Maldives in the upcoming decades. Freshwater lenses in small atoll islands (area < 0.6 km²) are shown to have a strong variability trends in the upcoming decades with expected reduction in lens volume between 11% and 36% due to SLR. In contrast, freshwater lenses in larger atoll islands (area > 1.0 km²) are shown to have less variability to changing patterns with expected reduction in lens volume between 8% and 26% due to SLR. Study results can provide water resource managers with valuable findings for consideration in water security measures.     

华南沿海地区验潮站资料反映的海平面变化与海岸升降

根据收集到的２５个验潮站资料,表明近几十年来华南沿海海平面大约平均以１．４５ｍｍ／ａ的速率上升,与全球海平面升高速率１．５ｍｍ／ａ接近。由各验潮站海平面的升降速率与全球海平面平均升高速率比较,得到验潮站所在海岸地壳速率在４．４～－４．１ｍｍ／ａ之间。其运动方向与由滨海相样品反映的晚更新世及全新世以来的海岸升降趋势大体相同,即现今海岸主要为中、晚全新世以来的继承性运动。     

Relative role and extent of marine and groundwater inundation on a dune‐dominated barrier island under sea‐level rise scenarios

Climate change and sea‐level rise will have severe impacts on coastal water resources around the world. However, whereas the influence of marine inundation is well documented in the literature, the impact of groundwater inundation on coastal communities is not well known. Here, core analysis, groundwater monitoring, and ground penetrating radar are utilized to assess the groundwater regime of the surficial aquifer on Bogue Banks Barrier Island (USA). Then, geospatial techniques are used to assess the relative roles and extents of groundwater and marine inundation on the dune‐dominated barrier island under sea‐level rise scenarios of 0.2, 0.5, and 1.0 m above current conditions by 2100. Additionally, the effects of rising water tables on onsite wastewater treatment systems (OWTS) are modelled using the projected sea‐level rise scenarios. The results indicate that the surficial aquifer comprising fine to medium sands responds quickly to precipitation. Water‐level measurements reveal varying thicknesses of the vadose zone (>3 to 0 m) and several groundwater mounds with radial flow patterns. Results from projected sea‐level rise scenarios suggest that owing to aquifer properties and morphology of the island, groundwater inundation may occur at the same rate as marine inundation. Furthermore, the area inundated by groundwater may be as significant as that affected by marine inundation. The results also show that the proportion of land in the study area where OWTS may be perpetually compromised by rising water tables under worst case scenarios may range from ~43 to ~54% over an 86‐year‐period. Copyright © 2014 John Wiley & Sons, Ltd.     

Water and air dynamics within a deep vadose zone of a karst massif: Observations from the Lukina jama–Trojama cave system (−1,431 m) in Dinaric karst (Croatia)

Extreme heterogeneity of karst systems makes them very challenging to study. Various processes within the system affect its global response, usually measured at karst springs. Research conducted in caves provides a unique opportunity for in situ analysis of separate processes in karst underground. The aim of the present study was to research the water and air dynamics within a deep karst system. Air and water basic physical parameters across the Lukina jama–Trojama cave system (?1,431 m) were continuously monitored during a 1‐year period. Recorded hydrograph of the siphon lake at the bottom of the cave was used to interpret the characteristics of an unexplored phreatic/epiphreatic conduit network. Water origin in the siphon was determined based on temperature and electrical conductivity. Air temperature and humidity monitoring revealed a strong inflow of air of sub‐zero temperature into the upper portion of the cave during winter. Cave passage morphology was interpreted as the main determinant of air dynamics, which caused ice to accumulate extensively in the upper portions of the cave and caused the temperature on the top of the homothermic zone to be significantly below the mean outside temperature. Air dynamics also lowered the temperature of water flowing through the cave vadose zone and feeding the phreatic zone of the massif. The pronounced temperature difference between the phreatic zone and the top of the homothermic zone probably contributed to the thermal gradient observed in the cave, which is steeper than in ice‐free caves in the area. Our results enabled the development of a conceptual model that describes coupling between air and water dynamics in the cave system and its surroundings.     

The influence of bedrock‐derived acidity in the development of surface and underground karst: evidence from the Precambrian carbonates of semi‐arid northeastern Brazil

Very extensive cave systems are developed in Precambrian Una Group carbonates in the Campo Formoso area, eastern Brazil. In contrast, the area is largely devoid of significant surface karst landforms, as would be expected given its semi‐arid climate. The caves in the area display many morphological features characteristic of deep‐seated hypogenic caves, such as lack of relationship with the surface, ramiform/network pattern, abrupt variations of passage cross‐sections and absence of fluvial sediments, but do not show evidence of vertical passages marking the ascending path of acidic water nor present extensive gypsum or acid clay mineral deposits. Hydrochemical analyses of present‐day ground water indicate that oxidation of bedrock sulphide is an active process, and sulphuric acid may be the main agent driving carbonate dissolution in the area. A shallow mode of speleogenesis is thus proposed, in which sulphuric acid produced through the oxidation of sulphide beds within the carbonates controls cave initiation and development. Moreover, the geological situation of the area in an ancient stable passive margin precludes the possibility of deep‐seated sources of acidity. Under dry climate, due to the absence of recharge, solutional landforms will be largely subdued in the surface. Hypogenic processes, if present, are likely to predominate, producing a landscape characterized by a marked disparity in the comparative degree of development between surface and underground landforms. Rates of karst landform development have traditionally been analysed through a climatic perspective, runoff being the main controlling factor in promoting karst development. This view needs to be reassessed in the light of the growing awareness of the importance of climate‐independent processes related to hypogenic sources of acidity. Copyright © 2003 John Wiley & Sons, Ltd.     

Impact of an inter‐basin water transfer and reservoir operation on a karst open streamflow hydrological regime: an example from the Dinaric karst (Croatia)

This paper describes the hydrological changes caused by inter‐basin water transfer and the reservoir development on the hydrological regimes of two rivers. The Sabljaki Reservoir in the Zagorska Mre?nica River and the Bukovik Reservoir in the upper Dobra River began operation in 1959. Both are part of the hydroelectric power plant (HEPP) Gojak, whose installed capacity is 50 m³/s. Their water volumes at the spillway altitudes of 320·10 and 320·15 m a. s. l. are 3·3 × 10⁶ and 0·24 × 10⁶ m³ respectively. Both the Dobra and Mre?nica Rivers are losing, sinking and underground karst rivers. A 9376‐m‐long tunnel provides water from the Sabljaki Reservoir to the HEPP Gojak, which was constructed in the Lower Dobra River. The Sabljaki Reservoir is located in the Pla?ki karst polje, while the Bukovik Reservoir is located in the neighbouring Ogulin karst polje. The consequences of the inter‐basin water transfer are strong and have caused abrupt changes in the hydrological regimes of the downstream sections of both rivers. At the same time, the construction and development of both the reservoirs have also caused hydrological changes to the upstream section of the Upper Dobra River. Copyright © 2010 John Wiley & Sons, Ltd.     

Pixel‐scale evaluation of SSM/I sea‐ice algorithms in the marginal ice zone during early fall freeze‐up

Observed reduction in recent sea ice areal extent and thickness has focused attention on the fact that the Arctic marine system appears to be responding to global‐scale climate variability and change. Passive microwave remote‐sensing data are the primary source underpinning these reports, yet problems remain in geophysical inversion of information on ice type and concentration. Uncertainty in sea‐ice concentration (SIC) retrievals is highest in the summer and fall, when water occurs in liquid phase within the snow–sea‐ice system. Of particular scientific interest is the timing and rate of new ice formation due to the control that this form of sea ice has on mass, energy and gas fluxes across the ocean–sea‐ice–atmosphere interface. In this paper we examine the critical fall freeze‐up period using in situ data from a ship‐based and aerial survey programme known as the Canadian Arctic Shelf Exchange study combined with microwave and optical Earth observations data. Results show that: (1) the overall physical conditions observed from aerial survey photography were well matched with coincident moderate‐resolution imaging spectroradiometer data and Radarsat ScanSAR imagery; (2) the shortwave albedo was linearly related to old ice concentration derived from survey photography; (3) the three SSM/I SIC algorithms (NASA Team (NT), NASA Team 2 (NT2), and Bootstrap (BT)) showed considerable discrepancies in pixel‐scale comparison with the Radarsat ScanSAR SICs well calibrated by the aerial survey data. The major causes of the discrepancies are attributed to (1) the inherent inability to detect the new thin ice in the NT and BT algorithms, (2) mismatches of the thin‐ice tie point of the NT2 algorithm, and (3) sub‐pixel ambiguity between the thin ice and the mixture of open water and sea ice. These results suggest the need for finer resolution of passive microwave sensors, such as AMSR‐E, to improve the precision of the SSM/I SIC algorithms in the marginal ice zone during early fall freeze‐up. Copyright © 2006 John Wiley & Sons, Ltd.     

Coastal conglomerates around the Hadjer el Khamis inselbergs (western Chad,central Africa): new evidence for Lake Mega‐Chad episodes

This paper reports on a study dealing with the rhyolitic inselbergs of Hadjer el Khamis that formed palaeoislands during Lake Mega‐Chad events. Field observations have shown that: (1) conglomeratic patches of immature to mature clasts are preserved at the feet of the Hadjer el Khamis inselbergs; (2) in cross‐section, their pro?le reveals a well de?ned cliff–platform junction at a constant elevation (325 m). The monolithological clasts show all degrees of roundness, from angular cobbles to well rounded pebbles. This wide range of maturity suggests a coastal origin for these cobbles. The system was permanently fed with angular clasts, which were progressively worn by waves. Cobbles that were wave‐worked for the longest time are the best rounded. The cliff–platform junction is the result of erosion by waves, which attacked and undercut the inselberg cliffs during Lake Mega‐Chad events. Asymmetrical erosion pro?les moreover suggest a wind regime dominated by SW to NE oriented winds. These interpretations have two implications. The elevation of the cliff–platform junction is an indication of the highest water level of Lake Mega‐Chad at 320–325 m, which is in agreement with other observations elsewhere in the basin. The SW to NE oriented winds show that monsoon‐related winds were prevalent during Lake Mega‐Chad events, suggesting the Inter‐Tropical Convergence Zone was located higher in latitude than today. Copyright © 2003 John Wiley & Sons, Ltd.     

Constraining Holocene sea levels using U‐Th ages of phreatic overgrowths on speleothems from coastal caves in Mallorca (Western Mediterranean)

Phreatic overgrowths on speleothems (POS) are carbonate formations deposited at the water table of caves in unique karstic coastal settings having morphologies that can be directly related to sea level at the time of formation. The U‐Th ages of calcite and aragonite overgrowths collected from the modern water table in coastal caves on Mallorca (Cova de Cala Varques A and Cova des Pas de Vallgornera) were determined using high‐precision MC‐ICPMS techniques. U‐Th ages indicate that phreatic carbonate deposition occurred between ca 2·8 and at least 0·6 ka BP and are in accord with an archeologically estimated age of 3·7–3·0 ka BP for a drowned prehistoric construction at a depth of 1 m below current sea level in a cave from the same area. Speleothem δ¹³C and δ¹⁸O and chemical composition of cave pools provide supportive evidence that POS reflect mixing between seawater and brackish water table. Copyright © 2010 John Wiley & Sons, Ltd.     

Dune phases in the Otaki‐Te Horo area (New Zealand): a geomorphic history

Optical dating, sedimentological analysis and soil profile development have been used to develop a chronology for, and an understanding of, the geomorphic evolution of the Holocene coastal plain between Otaki and Te Horo, North Island of New Zealand. The coastal plain has prograded 0·48 m a^?1 since sea‐levels reached their post‐glacial maximum 6500 years ago. Dune development on the plain, which is dependent on the supply of sediment suitable for dune building, has been episodic. Three periods of dune activity have been identified – the Foxton, Motuiti and Waitarere phases – the last two of which are believed to have resulted from anthropogenic activities. The dunes north of the Otaki River and south of Mangaone Stream are typical of a coastal dune system that extends from Patea in the north to Paekakariki in the south. However, this system is disrupted by the Otaki River and the gravels it delivers to the coastal zone. Immediately south of the river mouth the dunes are significantly smaller, coarser, and contain significantly more magnetic material. The character of the landforms is the result of: the reworking of the last glacial deposits; ongoing coastal progradation; variation in the input of sediment suitable for dune formation; the change in beach character because of gravel input; and the position of the Otaki River mouth. Copyright © 2006 John Wiley & Sons, Ltd.     

Variation of δ18O, δD and 3H in karst springs of south Kashmir,western Himalayas (India)

Water samples were collected from cold and warm karst springs for stable isotopes (δ¹⁸O and δD) and ³H from SE of Kashmir valley (western Himalayas) to distinguish the sources of recharge and infer their recharge areas. The spring water samples were most depleted in heavier isotopes in May (average δ¹⁸O: ?8.87‰ and δD: ?50.3‰) and enriched in September (average δ¹⁸O: ?7.58‰ and δD: ?48.1‰). The depleted ¹⁸O and ²H of spring waters bear the signatures of winter precipitation while as the enriched ¹⁸O and ²H of spring waters bear the signature of summer rainfall. D‐excess and ³H corroborate with the stable isotope results that the spring flow in spring season (May) and autumn (September) is dominantly controlled by the melting of winter snowmelt and summer rainfall, respectively. The results showed that unlike δD, the δ¹⁸O value in the karst spring waters decreases in January suggesting δ¹⁸O shift. The spring water samples also fall above the Local Meteoric Water Line and Global Meteoric Water Line indicating the δ¹⁸O shift due to interaction of groundwater with the host carbonate rocks during its traverse. The mean elevation of the recharge areas of the springs using δ¹⁸O and δD tracers was also estimated. Copyright © 2014 John Wiley & Sons, Ltd.     

A high‐altitude temporary spring in a compartmentalized carbonate aquifer: the role of low‐permeability faults and karst conduits

The aim of this research was to refine the actual conceptual model related to the activation of high‐altitude temporary springs within the carbonate Apennines in southern Italy. The research was carried out through geophysical, hydrogeological, hydrochemical and isotopic investigations at the Acqua dei Faggi experimental site during five hydrologic years. The research demonstrated that, in carbonate aquifers where low‐permeability faults cause the aquifer system to be compartmentalized, high‐altitude temporary springs may be recharged by groundwater. In such settings, neither surface water infiltration in karst systems nor perched temporary aquifers play a role of utmost importance. The rare (once or a few time a year) activation of such springs is due to the fact that groundwater unusually reach the threshold head that allows the spring to flow. The activation of the studied high‐altitude temporary spring also depended on relationships between a low‐permeability fault core and a karst system that locally interrupts the low‐permeability barrier. In fact, when the hydraulic head did not reach the karst system, the concentrated head loss within the fault core did not allow the spring to flow, because the groundwater entirely flowed through the fault towards the downgradient compartment. Copyright © 2009 John Wiley & Sons, Ltd.     

Morphology of the Itapeva to Tramandai transgressive dunefield barrier system and mid‐ to late Holocene sea level change

The surface morphology of the transgressive dunefield barrier extending from Itapeva to Tramandai along the northern littoral of Rio Grande do Sul, is examined and an attempt is presented to link morphological changes across the barrier to Holocene sea level changes. The 4·5 km wide Holocene barrier displays two typical morphologies: an inner part dominated by large‐scale, continuous alongshore, overlapping dunefield phases comprising sand sheets, dunes, deflation plains and precipitation ridges; and an outer part dominated by discontinuous, medium‐ to small‐scale, triangular to lobate transgressive dunefield phases, cut by both active and relict (palaeo‐) creeks or washouts. Holocene sea level in the region rose to c. +1 to +3 m above present reaching a maximum around 5100 years bp and then progressively fell to the present level. We argue that the effect on barrier development was to suppress the development of a drainage system during the rising and maximum stages, and encourage the development of an organized drainage system in the form of regularly spaced washouts during the falling period, and that this change in sea level from rising to falling therefore produced the large‐scale differences in barrier morphology. Copyright © 2006 John Wiley & Sons, Ltd.     

Imprints of wave climate and mean sea level variations in the dynamics of a coastal spit over the last 250 years: Cap Ferret,SW France

In coastal areas, sea level rise (SLR) and changing wave climates are expected to be the main oceanic drivers of shoreline adjustments. These drivers have been shown to vary on a wide spectrum of spatial and temporal scales. Nonetheless, a general rule about how this variability impacts global shorelines remains to be articulated. Here, we discuss the impacts of wave climate changes and SLR on the evolution of a barrier spit–inlet system over the last 250 years. The distal end of the Cap Ferret barrier spit, SW France, has undergone large-scale oscillations that were well correlated with variations of the decadal average of the winter North Atlantic Oscillation (NAO) index. The local wave climate hindcast supports that increased alongshore wave energy fluxes associated with the positive phase of the NAO were responsible for the updrift retreat of the spit. By opposition, the spit has elongated downdrift when waves were less energetic and more shore normal, as during the negative phase of the NAO. In addition, lower rates of SLR appeared to be necessary for the spit to develop, as higher rates of SLR very likely forced the adjacent inlet to enlarge, at the expense of the spit. These results should help to predict and detect coastal adjustments driven by climate change and by climate variability. © 2019 John Wiley & Sons, Ltd.     

Modelling the effect of Pliocene–Quaternary changes in sea level on stable and tectonically active land masses

A mathematical model was used to examine the effect of Pliocene and Quaternary changes in sea level on the development of tectonically active and inactive rock coasts. The model calculated rates of mechanical wave erosion according to such factors as the deep water wave regime, bottom topography and surface roughness, and the resistance of the rocks. Subaerial terraces were truncated or eliminated by subsequent terrace formation at lower elevations, especially on steeply sloping landmasses experiencing slow rates of uplift. Submarine terraces formed during glacial stillstands were best preserved when rapid subsidence quickly carried them below the level of wave action. On slowly subsiding landmasses, submarine terraces formed during interglacials and glacial periods experienced repeated erosional modification during subsequent periods of rising and falling sea level and were generally less distinctive. On rapidly rising or subsiding (>5 mm yr^‐1) landmasses, terraces that formed during interglacial stages alternated, above and below present sea level, with terraces formed during glacial stages. Despite some differences in terrace occurrence and elevational distribution, it may be difficult to distinguish profiles cut during accelerating or decelerating uplift. The amount of erosion during sea level oscillations increases with oscillation amplitude and the larger oscillations in the middle to late Quaternary were therefore more conducive to erosion than the smaller oscillations of the Pliocene and early Quaternary. The effect of oscillation amplitude may have been countered during the earlier stages of profile development, however, by steeper submarine gradients and reduced rates of wave attenuation. Copyright © 2014 John Wiley & Sons, Ltd.     

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.